scholarly journals Phase equilibrium occurring during low-carbon iron-based melt deoxidation with silicostrontium

2021 ◽  
Vol 64 (6) ◽  
pp. 413-419
Author(s):  
L. A. Makrovets ◽  
O. V. Samoilova ◽  
G. G. Mikhailov ◽  
I. V. Bakin
Keyword(s):  
Liquid Metal ◽  
Liquid Iron ◽  
Equilibrium Constants ◽  
Low Carbon ◽  
Processing Technologies ◽  
Oxide Melt ◽  
Steel Modification ◽  
Oxide Phases ◽  
Steel Processing ◽  
The Moment

At the moment, to improve quality of metal (especially low-alloyed), out-of-furnace steel processing technologies are used with complex alloys utilization, which include alkaline earth metals (ALM) in addition to silicon. Study of strontium additives effect on deoxidation and liquid steel modification processes is one of the promising areas of research in field of metallurgical technologies. Thermodynamic modeling of phase equilibria in Fe – Sr – Si –C– O system melt was carried out using method of constructing surface of components solubility in metal. Solubility surface determines stability limits of non-metallic phases formed during deoxidation, depending on composition of liquid metal of the studied system. The  calculation was carried out using equilibrium constants of reactions occurring in the melt during deoxidation, as well as the first order interaction parameters (according to Wagner) of elements in liquid iron. Activity of the oxide melt components was determined using theory of subregular ionic solutions. Activity of the gas phase was calculated taking into account partial pressures. Simulations were performed for two temperatures (1550 and 1600  °C) for fixed carbon concentrations (0 (no carbon in liquid iron) and 0.1 % (low-carbon metal melt)). It has been shown that, in comparison with silicon, strontium is stronger deoxidizing agent in liquid metal. According to the simulation results, liquid oxide non-metallic inclusions of variable composition or strontium ortho- and metasilicates Sr2SiO4 and SrSiO3 (with an increase in strontium concentration) should be the main oxide phases in deoxidation products. Decrease in the temperature of liquid metal leads to changes in phase formation (formation of SrSiO3 silicate becomes possible).

scholarly journals Thermodynamic modeling of isotherms of oxygen solubility in liquid metal of Fe – Mg – Al – O system

2019 ◽  
Vol 62 (8) ◽  
pp. 639-645 ◽  
Author(s):  
G. G. Mikhailov ◽  
O. V. Samoilova ◽  
L. A. Makrovets ◽  
L. A. Smirnov
Keyword(s):  
Solid Solution ◽  
Liquid Metal ◽  
Liquid Iron ◽  
Thermodynamic Modeling ◽  
Equilibrium Constants ◽  
Oxygen Solubility ◽  
Ionic Solutions ◽  
Temperature Range ◽  
Oxide Melt ◽  
Oxide Phases

Studying the interaction between oxygen and magnesium and aluminum dissolved in liquid iron is an important task in order to choose optimal parameters for refining and casting of steels. Relevance of this research is caused by determining the possibility and conditions for formation of unfavorable refractory particles of magnesium oxideand magnesian spinel in a metal melt. In the course of this research, thermodynamic modeling of phase equilibria implemented in liquid metal of such systems as Fe – Mg – O, Fe – Al – O and Fe – Mg – Al – O within the temperature range of 1550 – 1650 °С was carried out. Calculation was made using the technique of constructing the solubility surfaces for the metal components which connects quantitative changes in composition of a liquid metal with qualitative changes in composition of products obtained as a result of interaction of a metallic melt’s components. The modeling method was based not only on usin­g equilibrium constants of reactions occurring between components of the systems under research in the selected temperature range, but also on taking into account the values of interaction parameters of the first order (according to Wagner) of elements in liquid iron. In order to simulate activities of the oxide melt conjugated with the metallic one, approximation of the theory of subregular ionic solutions was used. To model activities of oxides solid solution, approximation of the theory of regular ionic solutions was used. And the theory of ideal ionic solutions was used for the solid solution of spinels. In the course of the work, isotherms of oxygen’s solubility in liquid metal of systems Fe – Mg – O, Fe – Al – O and Fe – Mg – Al – O have been constructed, and regions of thermodynamic stability of oxide phases conjugated with the metallic melt have been determined. In particular, compositions area of a liquid metal which is going to be in equilibrium with the solid solution of spinels | FeAl 2 O 4 , MgAl 2 O 4 | solid solution has been determined for Fe – Mg – Al – O system. Results obtained in the course of thermodynamic modeling have been compared to experimental data.

Thermodynamic Modeling of Phase Equilibrium in Fe-Y-Cr-C-O Liquid Metal System

2017 ◽  
Vol 265 ◽  
pp. 862-867 ◽  
Author(s):  
G.G. Mikhailov ◽  
L.A. Makrovets
Keyword(s):  
Liquid Metal ◽  
Chemical Reactions ◽  
Equilibrium Constants ◽  
Oxide System ◽  
Critical Parameters ◽  
Low Carbon ◽  
Metal System ◽  
Oxide Melt ◽  
Liquid Metal System ◽  
Existence Domain

The thermodynamic characteristics of processes in the liquid metal system Fe–Y–Cr–C–O are considered as applied to low-carbon and low-alloy metal. The critical parameters for the state diagram of the oxide system Y2O3–Cr2O3 were established based on the values quoted in literature. The temperature dependence of the melting reaction constant Y2O3·Cr2O3 was determined. The coordinates of eutectic transformation points for the system Y2O3–Cr2O3 were calculated. In accordance with subregular solution theory, the energetic parameters which are necessary to calculate the activities Cr2O3 and Y2O3 of oxide melts in the system Y2O3–Cr2O3 were determined. The energetic parameters of subregular solution theories for the oxide system FeO–Cr2O3–Y2O3 were determined based on the values for the binary systems FeO–Y2O3, FeO–Cr2O3 and Y2O3–Cr2O3. The view of this diagram, as coupled with the existence domain of liquid metal within the framework of the quaternary system Fe–Y–Cr–O–С, suggests that low-carbon chromic liquid metal when injected with yttrium can form the following non-metallic inclusions: |Cr2O3|, |Y2O3|, |FeO·Cr2O3|, |Y2O3·Cr2O3| or oxide melt (FeO, Y2O3, Cr2O3). Oxide melt may contain up to 2 % of divalent chrome (Cr2+). The equilibrium constants for the main reactions of steel deoxidation with the formation of liquid, solid and gas products of chemical reactions were also established. The activity of components dissolved in metal was calculated using interaction parameters. The set of derived expressions for the activity of components and the dependences of equilibrium constants of chemical reactions and phase transformations allowed us to diagram the surface of component solubility in liquid metal (SCSM). SCSM diagrams show the compositions of liquid metal and indicate oxide phases which are in equilibrium with liquid metal.

Thermodynamic Modelling of Rare-Earth Elements - Oxygen Interaction

2016 ◽  
Vol 843 ◽  
pp. 39-45 ◽  
Author(s):  
G.G. Mikhailov ◽  
L.A. Makrovets ◽  
L.A. Smirnov
Keyword(s):  
Rare Earth ◽  
Liquid Metal ◽  
Active Components ◽  
Oxide Systems ◽  
Al Content ◽  
Oxide Melt ◽  
Metal Melts ◽  
Oxide Phases ◽  
Component Solubility ◽  
Oxygen Interaction

Fusibility curves of FeO–La2O3–Al2O3, FeO–Ce2O3–Al2O3, La2O3– Ce2O3–Al2O3 oxide systems are created based on the literature data and modern thermodynamic theories of oxide and metal melts. Admitting the oxide systems conjugation with the area of metal melts existence, we define oxide phases, which can maintain the equilibrium with metal melts of Fe–Ce–Al–O, Fe–La–Ce–Al–O systems. The surfaces of component solubility are created for above mentioned metal melts. For Fe–Ce–Al–O system it is established that the following phases can be at equilibrium with metal: Al2O3, Сe2O3, FeO∙Al2O3, Сe2O3∙11Al2O3, Сe2O3∙Al2O3, and the oxide melt (FeO, Al2O3, Сe2O3, СeO2). For Fe–La–Ce–Al–O system the following oxide phases can be at equilibrium with the liquid metal: La2O3, Al2O3, Сe2O3, La2O3∙Al2O3, Сe2O3∙11Al2O3, Сe2O3∙Al2O3, and the oxide melt (FeO, La2O3, Al2O3, Сe2O3, СeO2). Diagrams of active components consumption, which are used to establish the possibility of chosen equilibrium, are created for iron deoxidation with cerium and aluminium as well as with Ce and La at fixed Al content (0.01 wt. %).

scholarly journals Thermodynamic analysis of strontium deoxidizing ability in liquid iron at presence of aluminum

2021 ◽  
Vol 64 (10) ◽  
pp. 768-777
Author(s):  
L. A. Makrovets ◽  
O. V. Samoilova ◽  
G. G. Mikhailov ◽  
I. V. Bakin
Keyword(s):  
Thermodynamic Analysis ◽  
Liquid Iron ◽  
Equilibrium Constants ◽  
Oxide System ◽  
Ternary Oxide ◽  
Ionic Solutions ◽  
Energy Parameters ◽  
Oxide Melt ◽  
Temperature Dependences ◽  
First Time

Phase diagram of the ternary oxide system FeO - SrO -Al2O3 was constructed for the first time. In this system, the following compounds can be formed: hercynite FeAl2O4 and five strontium aluminates - Sr4Al2O7 , Sr3Al2O6 , SrAl2O4 , SrAl4O7 , SrAl12O19 . According to the calculations performed, solid solutions of oxides are not formed in the system, as it is confirmed by the literature data. In the course of modeling, the optimal energy parameters of the theory of subregular ionic solutions were selected for the components of the oxide melt (FeO, SrO, Al2O3 ). Thermodynamic analysis of strontium deoxidizing ability in liquid iron at presence of aluminum was carried out using the technique for constructing the surface of solubility of strontium and aluminum in metal for steelmaking temperatures (1550 and 1600 °C) and carbon concentrations of 0.1 and 0.4 %. The equilibrium constants of the reactions of formation of strontium aluminates Sr3Al2O6 and SrAl2O4 from the components of the metal melt were calculated for the temperature range of 1550 - 1650 °C. It was found that the rest of strontium aluminates can be formed in liquid metal only at temperatures above 1750 °C. The base of thermodynamic data for the studied systems is given: temperature dependences of equilibrium constants for reactions occurring between components; values of interaction parameters of the first order (according to Wagner) for elements in liquid iron; values of energy parameters of the theory of subregular ionic solutions (for oxide melt). It follows from the calculations that the formation of strontium monoaluminate SrAl2O4 and corundum Al2O3 is most probable as the interaction products in Fe -Al - Sr - O and Fe -Al - Sr - C - O systems.

scholarly journals Interfacial Phenomena and Inclusion Formation Behavior at Early Melting Stages of HCFeCr and LCFeCr Alloys in Liquid Iron

2021 ◽  
Author(s):  
Yong Wang ◽  
Andrey Karasev ◽  
Joo Hyun Park ◽  
Wangzhong Mu ◽  
Pär G. Jönsson
Keyword(s):  
Liquid Iron ◽  
Diffusion Zone ◽  
Early Stage ◽  
Interfacial Phenomena ◽  
Solid Alloy ◽  
Low Carbon ◽  
High Carbon ◽  
Free Zone ◽  
Formation Behavior ◽  
Predetermined Time

AbstractChromium is normally added to liquid alloy in the form of different grades of ferrochromium (FeCr) alloys for the requirement of different alloy grades, such as stainless steels, high Cr cast iron, etc.. In this work, inclusions in two commercially produced alloys, i.e., high-carbon ferrochromium (HCFeCr) and low-carbon ferrochromium (LCFeCr) alloys, were investigated. The FeCr alloy/liquid iron interactions at an early stage were investigated by inserting solid alloy piece into contact with the liquid iron for a predetermined time using the liquid-metal-suction method. After quenching these samples, a diffusion zone between the alloys and the liquid Fe was studied based on the microstructural characterizations. It was observed that Cr-O-(Fe) inclusions were formed in the diffusion zone, FeOx inclusions were formed in the bulk Fe, and an “inclusion-free” zone was detected between them. Moreover, it was found that the HCFeCr was slowly dissolved, but LCFeCr alloy was rapidly melted during the experiment. The dissolution and melting behaviors of these two FeCr alloys were compared and the mechanism of the early-stage dissolution process of FeCr alloys in the liquid Fe was proposed.

Strengthening Low Carbon Steels for Oil and Gas Spiral Welded Pipes

2006 ◽  
Author(s):  
I. Yu. Pyshmintsev ◽  
D. A. Pumpyanskyi ◽  
Yu. O. Kamenskih ◽  
I. N. Poznyakovsky ◽  
I. L. Permyakov
Keyword(s):  
Oil And Gas ◽  
Controlled Rolling ◽  
Carbon Steels ◽  
Low Carbon ◽  
Line Pipe ◽  
Low Carbon Steels ◽  
Factors Affecting ◽  
Steel Processing ◽  
Line Pipe Steel ◽  
Strain Hardening Behavior

Strengthening mechanisms applied for modern line pipe steel design were studied. Low carbon steels alloyed with Mn, Mo, V, Nb processed by the way of controlled rolling were developed for spiral welded X65-X80 line pipes up to 1420 mm diameter. Formation of the microstructure during steel processing was studied. The effects of typical microstructure for the steels on mechanical properties, strain hardening behavior and Bauschinger effect were studied. Main metallurgical factors affecting on strength measured in plates and pipes were revealed using physical and computer simulations.

Phase Equilibria in a Liquid Metal of Fe-La-Ce-O System at 1600 °С

2020 ◽  
Vol 299 ◽  
pp. 468-474 ◽  
Author(s):  
Gennady G. Mikhailov ◽  
L.A. Makrovets ◽  
O.V. Samoilova
Keyword(s):  
Rare Earth ◽  
Liquid Metal ◽  
Phase Equilibria ◽  
Phase Diagrams ◽  
Liquid Iron ◽  
Rare Earth Metals ◽  
Liquid Oxygen ◽  
Oxide Systems ◽  
Calculation Technique ◽  
Steelmaking Technology

Thermodynamic modeling of phase equilibria in a liquid metal of Fe–La–Ce–O system at 1600 °С, using the technique of constructing the solubility surfaces for the components of a metal, was carried out. The calculation technique allowed assessing the depth of liquid iron de-oxidation at a complex use of lanthanum and cerium as deoxidizing agents. Also, diagrams of de-oxidants’ consumption for one ton of liquid oxygen-containing iron were calculated in the course of the work. Carrying out a calculation of the solubility surfaces for the components of a metal required simulation of phase diagrams of the following oxide systems: FeO–La2O3–Ce2O3, FeO–CeO2–La2O3, CeO2–La2O3–Ce2O3. The obtained results might be of interest for optimization of the use of rare-earth metals in steelmaking technology.

THERMODYNAMICS OF THE PROCESSES OF INTERACTION OF LIQUID METAL COMPONENTS IN Fe – Mg – Al – La – O SYSTEM

2018 ◽  
Vol 61 (6) ◽  
pp. 460-465
Author(s):  
G. G. Mikhailov ◽  
L. A. Makrovets ◽  
L. A. Smirnov
Keyword(s):  
Rare Earth ◽  
Liquid Metal ◽  
Rare Earth Elements ◽  
Phase Equilibria ◽  
Thermodynamic Modeling ◽  
Equilibrium Constants ◽  
Rare Earth Metals ◽  
Oxide Systems ◽  
Metal Melts ◽  
Steel Deoxidation

At the present time, rare-earth elements in metallurgy are used in  the form of mischmetal – a rare-earth elements natural mixture (with  atomic numbers from 57 to 71). It contains about 50  wt.  % of cerium.  The remaining elements are mainly lanthanum and niobium. The specific composition is determined by the ore deposit. Inconstant composition of the modifier containing rare-earth metals (REM) can significantly reduce its efficiency. Experimentally, for every branded steels  composition the ratio of various REMs can’t be selected because of the  high costs of obtaining technically pure rare-earth metals. The task of  determining the each rare earth element optimum concentrations and  complex ligature composition can be solved by thermodynamic modeling. In the framework of thermodynamic modeling, the interaction  between magnesium, aluminum and lanthanum with oxygen in liquid  iron is presented. And the thermodynamic model of steel deoxidation  by these active metals composition is considered. On the basis of available literature data on the phase diagrams of the systems MgO – Al2O3 ,  MgO – La2O3 and La2O3 – Al2O3 , the coordinates of the invariant equilibria points in the system MgO – La2O3 – Al2O3 were determined. The  phase diagram of the system MgO – La2O3 – Al2O3 was constructed. It  made possible to establish all phase equilibria realized in the process  of deoxidation of steel with magnesium, lanthanum and aluminum and  to describe these phase equilibria by chemical reactions equations. The  activity of the components in liquid oxide melts was determined using  the theory of subregular ionic solutions, which takes into account the  dependence of the coordination number of cations on the composition  of the oxide melt. The activity of components in metal melts conjugated with oxide systems were determined by Wagner’s theory using the  parameters of the first order interaction. Equilibrium constants values  for the steel deoxidation reactions are installed indirectly by thermodynamic calculations. On the basis of the obtained data the components  solubility surface in the metal melts of Fe – Mg – Al – La – O system  was constructed, which allowed to determine the liquid metal composition regions associated with the corresponding oxide phase.

Three Generations Micro-Allying Steel Processing: Thirty Years of Successive Work at CMRDI

2020 ◽  
Vol 835 ◽  
pp. 324-334
Author(s):  
Maha El-Meligy ◽  
Taher El-Bitar
Keyword(s):  
Mechanical Properties ◽  
Temper Embrittlement ◽  
Steel Plates ◽  
Alloying Elements ◽  
Recrystallization Temperature ◽  
Low Carbon ◽  
Alloying Element ◽  
Hot Strip ◽  
Steel Processing ◽  
Steel Grades

The present article presents cumulative works, which were carried out in the field of micro-alloying steel processing at Central Metallurgical R&D Institute (CMRDI) and/or full scale trials in collaboration with the Egyptian steel industry.It was agreed upon defining three main generations of processing micro-alloying steel. The 1stgeneration starts officially on 1975 and continues up to 1995, where it deals with using Ti and V as micro-alloying elements for steel long products. On the year 1985, Central Metallurgical R&D Institute (CMRDI) succeeded to implement of HSLA V-micro-alloyed rebar steel grades at Delta steel mills instead of conventional rebar grades.The 2nd generation was starting on late 1995 and continued to 2005. It was dealing mainly with low carbon content steel (0.04-0.08 %) for flat products (plate and sheet). The most successfully used micro-alloying element was Nb. Beside its precipitate forming effect, Nb is working as substitution solid solution strengthener. Moreover, it raises the recrystallization temperature (Tr). Mainly, micro-alloyed flat steels were developed to fulfill the requirements of the American Petroleum Institute (API) specifications 5L- Product Specification Levels (PSL1) and (PSL2) for manufacturing oil and natural gas pipelines. Meanwhile, a newly born Compact Slab Processing (CSP)-hot strip direct rolling technology was created. On years 2002, the metal forming department in CMRDI succeeded to implement controlled rolling of hot strip Nb-steel sheet at the Compact Slab Process (CSP) Machine in Alexandria National Iron and Steel (ANSDK) Company. Controlled hot rolling schedules were used and followed by early and late cooling at the run out table (ROT). Both contracts were fruitfully succeeded to introduce the API X52 grade at ANSDK Company, followed by X60, and X70 steel grades at Ezz Flat Steel (EFS) Company. The essential mechanical properties of the processed API steel sheets were matched with the API 5L-PSL2 specifications.The 3rd generation was initially developed after 2005 and continued up to day. It deals with micro-alloying with special functional elements like Boron (B). Boron was favored as a micro-alloying element for bilateral effects. Boron carbide (B4C) precipitates are the hardest after diamond, which would be reflected on raising the mechanical properties of the steel. Moreover, Boron was favorably used because it delays the temper embrittlement phenomena. On year 2014, the National for Military Industrialization authority requested from CMRDI to collaborate with Military Factory 100 to develop a technology package for processing armor steel plates. Trials were started with a 3rd generation B-micro-alloyed steel alloy. Many other alloying elements were used beside Boron to develop extra high strength 6.0 mm thickness plates. Finish hot rolled plates were then subjected to a subsequent water quenching from 900 °C and followed by tempering at 250 °C for 20 min. Representation 50X50 cm2 steel plates were successfully passed after 3 bullets in front and 3 bullets rear shooting.

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