scholarly journals Sol-gel synthesis, crystal structure and magnetic properties of nanocrystalline praseodymium orthoferrite

2021 ◽  
Vol 23 (2) ◽  
pp. 196-203
Author(s):  
Xuan Vuong Bui ◽  
Anh Tien Nguyen
Keyword(s):  
Crystal Structure ◽  
Magnetic Properties ◽  
Single Phase ◽  
Crystal Size ◽  
Annealing Temperature ◽  
Sol Gel ◽  
Gel Method ◽  
Lattice Volume ◽  
Sol Gel Synthesis ◽  
Paramagnetic Properties

In this work, nano-sized crystalline praseodymium orthoferrite was successfully synthesized via sol-gel method using water – methanol co-solvent. Single-phase PrFeO3 nanoparticles were formed after annealing the precursors at 650, 750, 850, and 950 °C during 60 min. The crystal size, lattice volume and coercivity (Hc) of nanocrystalline PrFeO3 increase with the annealing temperature. The obtained praseodymium orthoferrite exhibited paramagnetic properties with Hc = 28 – 34 Oe

scholarly journals Synthesis of SrFe12O19 by sol-gel method and its morphology and magnetic properties

2016 ◽  
Vol 19 (3) ◽  
pp. 5-10
Author(s):  
Quynh Anh Bao Le ◽  
Vu Hoang Nguyen ◽  
Hoang Thi Thuy Tran ◽  
Ha Ky Phuong Huynh
Keyword(s):  
Crystal Structure ◽  
Magnetic Properties ◽  
Single Phase ◽  
Sol Gel ◽  
X Ray Diffraction ◽  
Powder Morphology ◽  
Gel Method ◽  
Sol Gel Method ◽  
Structure Morphology ◽  
Xrd Patterns

In this research, strontium hexa-ferrite nanoparticles (SrFe12O19) were synthesized by sol-gel method. The crystal structure, morphology and magnetic properties of nanoparticles were investigated using X-ray Diffraction (XRD), Scanning Electron Microscope (SEM) and Vibrating Sample Magnetometer (VSM). The XRD patterns confirmed the formation of single phase M-type hexagonal crystal structure for powders which was calcined above 700oC. The product shows the magnetization of 66 emu/g, which is consistent with pure hexa-ferrite obtained by other methods, and the magnetic coercivity of 6,145 kOe higher than expected for this hexa-ferrite. The powder morphology is composed of aggregates of hexagonal particles with an average particles size of above 100nm.

Annealing Effects on the Physical and Magnetic Properties of Tb1.5Y1.5Fe5O12 Films Nanoparticles Prepared by Sol-Gel Method

2013 ◽  
Vol 756 ◽  
pp. 91-98 ◽  
Author(s):  
Ftema W. Aldbea ◽  
Noor Bahyah Ibrahim ◽  
Mustafa Hj. Abdullah
Keyword(s):  
Particle Size ◽  
Magnetic Properties ◽  
Annealing Temperature ◽  
Quartz Substrate ◽  
Sol Gel ◽  
Lattice Parameter ◽  
Gel Method ◽  
X Ray ◽  
Sol Gel Method ◽  
Iron Garnet

Terbium –substituted yttrium iron garnet (Tb1.5Y1.5Fe5O12) films nanoparticles were successfully prepared by a sol-gel method. The films were deposited on the quartz substrate using spin coating technique. To study effect of annealing temperature, the annealing process was executed at 700, 800 and 900 °C in air for 2 hours. The X-ray diffraction (XRD) proved that the pure phase of garnet structure was detected for the film annealed at 900 °C. The lattice parameter increased with the increment of annealing temperature and the highest value of 12.35 Å was obtained at 900 °C. Field Emission Scanning Electron Microscope (FE-SEM) results showed that the particle size increased from 43nm to 56nm as annealing temperature increased from 700 to 900°C. The film’s thickness also affected by increasing of annealing temperature and become thin at 900 °C due to densification process occurred at high annealing temperature. The elemental compositions of the Tb1.5Y1.5Fe5O12 film were detected using an Energy Dispersive X-raySpectroscopy (EDX). Magnetic properties at room temperature were measured using a Vibrating Sample Magnetometer (VSM).The saturation magnetization Ms increased with the annealingtemperature and showed a high value of 104emu/cm3, but the coercivity Hc of the film was decreased due to the increment of the particle size. Normal 0 21 false false false MS X-NONE X-NONE MicrosoftInternetExplorer4 Terbium –substituted yttrium iron garnet (Tb1.5Y1.5Fe5O12) films nanoparticles were successfully prepared by a sol-gel method. The films were deposited on the quartz substrate using spin coating technique. To study effect of annealing temperature, the annealing process was executed at 700, 800 and 900°C in air for 2 hours. The X-ray diffraction (XRD) proved that the pure phase of garnet structure was detected for the film annealed at 900 °C. The lattice parameter increased with the increment of annealing temperature and the highest value of 12.35 Å was obtained at 900 °C. Field Emission Scanning Electron Microscope (FE-SEM) results showed that the particle size increased from 43nm to 56nm as annealing temperature increased from 700 to 900 °C. The film’s thickness also affected by increasing of annealing temperature and become thin at 900 °C due to densification process occurred at high annealing temperature. The elemental compositions of the Tb1.5Y1.5Fe5O12 film were detected using an Energy Dispersive X-ray Spectroscopy (EDX). Magnetic properties at room temperature were measured using a Vibrating Sample Magnetometer (VSM).The saturation magnetization Ms increased with the annealing temperature and showed a high value of 104emu/cm3, but the coercivity Hc of the film was decreased due to the increment of the particle size. st1\:*{behavior:url(#ieooui) } /* Style Definitions */ table.MsoNormalTable {mso-style-name:"Table Normal"; mso-tstyle-rowband-size:0; mso-tstyle-colband-size:0; mso-style-noshow:yes; mso-style-priority:99; mso-style-qformat:yes; mso-style-parent:""; mso-padding-alt:0cm 5.4pt 0cm 5.4pt; mso-para-margin:0cm; mso-para-margin-bottom:.0001pt; mso-pagination:widow-orphan; font-size:11.0pt; font-family:"Calibri","sans-serif"; mso-ascii-font-family:Calibri; mso-ascii-theme-font:minor-latin; mso-fareast-font-family:"Times New Roman"; mso-fareast-theme-font:minor-fareast; mso-hansi-font-family:Calibri; mso-hansi-theme-font:minor-latin; mso-bidi-font-family:"Times New Roman"; mso-bidi-theme-font:minor-bidi;}

scholarly journals The Influence of Annealing Temperature on the Structure and Magnetic Properties of Nanocrystalline BiFeO3 Prepared by Sol–Gel Method

2021 ◽  
Author(s):  
T. Pikula ◽  
T. Szumiata ◽  
K. Siedliska ◽  
V. I. Mitsiuk ◽  
R. Panek ◽  
...  
Keyword(s):  
Grain Size ◽  
Magnetic Properties ◽  
Annealing Temperature ◽  
Sol Gel ◽  
Weak Ferromagnetism ◽  
X Ray Diffraction ◽  
Gel Method ◽  
Sol Gel Method ◽  
Average Grain Size ◽  
Spin Cycloid

AbstractIn this work, BiFeO3 powders were synthesized by a sol–gel method. The influence of annealing temperature on the structure and magnetic properties of the samples has been discussed. X-ray diffraction studies showed that the purest phase was formed in the temperature range of 400 °C to 550 °C and the samples annealed at a temperature below 550 °C were of nanocrystalline character. Mössbauer spectroscopy and magnetization measurements were used as complementary methods to investigate the magnetic state of the samples. In particular, the appearance of weak ferromagnetic properties, significant growth of magnetization, and spin-glass-like behavior were observed along with the drop of average grain size. Mössbauer spectra were fitted by the model assuming cycloidal modulation of spins arrangement and properties of the spin cycloid were determined and analyzed. Most importantly, it was proved that the spin cycloid does not disappear even in the case of the samples with a particle size well below the cycloid modulation period λ = 62 nm. Furthermore, the cycloid becomes more anharmonic as the grain size decreases. The possible origination of weak ferromagnetism of the nanocrystalline samples has also been discussed.

The structure and magnetic properties of pure single phase BiFeO3 nanoparticles by microwave-assisted sol-gel method

2018 ◽  
Vol 735 ◽  
pp. 945-949 ◽  
Author(s):  
Shuai Zheng ◽  
Jiangying Wang ◽  
Jingji Zhang ◽  
Hongliang Ge ◽  
Zhi Chen ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Single Phase ◽  
Sol Gel ◽  
Gel Method ◽  
Sol Gel Method ◽  
Microwave Assisted ◽  
Bifeo3 Nanoparticles

scholarly journals Evaluation of La1−xSrxMnO3 (0 ≤ x < 0.4) synthesised via a modified sol–gel method as mediators for magnetic fluid hyperthermia

CrystEngComm ◽  
2016 ◽  
Vol 18 (3) ◽  
pp. 407-416 ◽  
Author(s):  
K. McBride ◽  
J. Cook ◽  
S. Gray ◽  
S. Felton ◽  
L. Stella ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Magnetic Fluid ◽  
Sol Gel ◽  
Magnetic Fluid Hyperthermia ◽  
Gel Method ◽  
Sol Gel Method ◽  
Lanthanum Strontium ◽  
Sol Gel Synthesis

A range of lanthanum strontium manganates (La1−xSrxMnO3) where 0 ≤ x ≤ 0.4 were prepared using a modified peroxide sol–gel synthesis. The crystal structure of these materials was investigated and their potential as mediators for magnetic fluid hyperthermia was evaluated.

Effect of Annealing Temperature on the Structural and Magnetic Properties of Co-Doped TiO2 Nanoparticles via Complex-Polymer Sol–Gel Method

2012 ◽  
Vol 12 (2) ◽  
pp. 950-954 ◽  
Author(s):  
Masoud Karimipour ◽  
J. Magnus Wikberg ◽  
Nasser Shahtahmasebi ◽  
Mahmood Rezaee Rokn Abad ◽  
M. M. Bagheri-Mohagheghi ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Tio2 Nanoparticles ◽  
Annealing Temperature ◽  
Sol Gel ◽  
Gel Method ◽  
Doped Tio2 ◽  
Sol Gel Method ◽  
Structural And Magnetic Properties ◽  
Complex Polymer ◽  
Co Doped

scholarly journals Effect of pH and annealing temperature on the structural and magnetic properties of cerium-substituted yttrium iron garnet powders produced by the sol-gel method

2016 ◽  
Vol 34 (2) ◽  
pp. 362-367 ◽  
Author(s):  
I. Yarici ◽  
M. Erol ◽  
E. Celik ◽  
Y. Ozturk
Keyword(s):  
Magnetic Properties ◽  
Yttrium Iron Garnet ◽  
Annealing Temperature ◽  
Ph Value ◽  
Sol Gel ◽  
Chelating Agent ◽  
Yttrium Iron ◽  
Gel Method ◽  
Sol Gel Method ◽  
Iron Garnet

AbstractCerium substituted yttrium iron garnet (Ce0.2Y2.8Fe5O12; Ce-YIG) nanoparticles were produced via the sol-gel method from solutions of Ce-, Y- and Fe-based precursors, a solvent and a chelating agent. The solutions were dried at 200°C and heat treated at temperatures between 800 °C and 1400°C for 3 h in air. The effects of pH and annealing temperature on the structure, phase formation, magnetic properties and crystallite size were investigated. A cubic YIG phase was obtained for the sample annealed at 1400 °C. The presented results showed that the pH value of the starting solution affects the crystal size and consequently, the saturation magnetization.

scholarly journals Structure and Magnetic Properties ofY3−xErxFe5O12(x=0.2,1.0, and 2.0) Thin Films Prepared by Sol-Gel Method

2011 ◽  
Vol 2011 ◽  
pp. 1-5 ◽  
Author(s):  
Ramadan Shaiboub ◽  
Noor Baa'yah Ibrahim ◽  
Mustaffa Abdullah ◽  
Ftema Abdulhade
Keyword(s):  
Thin Films ◽  
Saturation Magnetization ◽  
Single Phase ◽  
Annealing Temperature ◽  
Magnetic Measurements ◽  
Sol Gel ◽  
Spin Effect ◽  
Gel Method ◽  
Sol Gel Method ◽  
Surface Spin

NanoparticlesY3−xErxFe5O12(x=0.2, 1.0, and 2.0) thin films were prepared by sol-gel method and treated at 800, 900, and 1000∘C, respectively, for 2 h. The films have single phase garnet structure and the sizes of particles are in the range of 44 to 83 nm. The magnetic measurements show that the saturation magnetization decreased with increasing of Er concentration for all samples treated at different annealing temperatures. The saturation magnetization increased with the particle size due to the enhancement of the surface spin effect. The coercivity initially decreased forx=1.0and then increased forx=2.0with increasing annealing temperature.

scholarly journals Effects of Varying Alx Moles on the Structure and Luminescence Properties of ZnAlxO1.5x + 1:0.1% Tb3+ Nano Phosphor Prepared using Citrate sol-gel Method

2021 ◽  
Author(s):  
V Maphiri ◽  
L Melato ◽  
Mhlongo ◽  
TT Hlatshwayo ◽  
TE Motaung ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Electron Microscopy ◽  
Single Phase ◽  
Sol Gel ◽  
Gel Method ◽  
X Ray ◽  
Sol Gel Method ◽  
Transmission Electron ◽  
Nano Phosphor ◽  
Scanning Electron

Abstract Un-doped and ZnAlxO(1.5x + 1):0.1% Tb3+ (ZAOT) nano-powders were synthesized via citrate sol-gel method. The Alx moles were varied in the range of 0.25 ≤ x ≤ 5.0. The X-ray powder diffraction (XRD) data revealed that for the x < 1.5, the prepared samples crystal structure consists of mixed phases of the cubic ZnAl2O4 and hexagonal ZnO phases, while for the x ≥ 1.5 the structure consists of single phase of cubic ZnAl2O4. This was confirmed by the Raman and Fourier-Transform Infrared (FTIR) vibrational spectroscopy. Scanning electron microscopy (SEM) showed that varying Alx moles influences the morphology while Transmission electron microscopy (TEM) shows the dual morphology at x < 1.5. The photoluminescence (PL) revealed intense and distinct emissions attributed to both the host and Tb3+ transitions. The emission intensity highly depends on the Alx moles. The International Commission on Illumination (CIE) colour chromaticity showed that the emission colour could be tuned by varying the Alx moles.

Sign in / Sign up

Export Citation Format

Share Document