scholarly journals Stainless Steel Cyclic Voltammograms in Dioscorea Opposita Flour Media

2021 ◽  
Vol 6 (3) ◽  
pp. 535-542
Author(s):  
Isana Supiah Yosephine Louise ◽  
Siti Marwati ◽  
S. Sulistyani ◽  
Heru Pratomo Al ◽  
Felix Arie Setiawan
Keyword(s):  
Stainless Steel ◽  
Energy Consumption ◽  
Water Electrolysis ◽  
Gas Production ◽  
Hydrogen Gas ◽  
Cyclic Voltammograms ◽  
Electrolysis Process ◽  
Dioscorea Opposita ◽  
The Media ◽  
The Cost

Improving the efficiency of hydrogen gas production in the water electrolysis process draws great attention from many scholars. To improve the efficiency of the process and reduction in the cost, stainless steel has been widely implemented in the industrial water electrolysis process. Electrolyte modification is also one of the methods to improve the water electrolysis process. The study used Dioscorea opposita tuber flour as a media addition in an alkaline solution. The efficiency of water electrolysis was evaluated by cyclic voltammetry. The result showed that the activity of the electrode and energy consumption were increased with values of 29 and 23%, respectively, by adding 3 g of the media. However, no media addition showed the lowest energy consumption regarding overpotential value. In general, the Dioscorea opposita tuber flour tends to cover the electrode and reduce the activity. Moreover, the utilization of wastewater from Dioscorea opposita flour industry is still beneficial to produce hydrogen gas instead of using freshwater.

scholarly journals Electrochemical Production of Hydrogen in Fermented Flour by Stainless Steel Electrode

2020 ◽  
Vol 32 (4) ◽  
pp. 835-838
Author(s):  
Isana Supiah Yosephine Louise ◽  
Suyanta ◽  
Endang W. Laksono
Keyword(s):  
Stainless Steel ◽  
Gas Production ◽  
Hydrogen Gas ◽  
Stainless Steel Electrode ◽  
Cathodic Current ◽  
Steel Electrode ◽  
Cathodic Peak Potential ◽  
Production Of Hydrogen ◽  
The Media ◽  
Electrochemical Production

Hydrogen gas production with an electrochemical method requires more energy. This research aimed to determine the efficiency of the electrolysis process in product and energy consumptions using stainless steel as a working electrode and various concentration of the fermented flour as the media. The fermented flour was prepared by fermentation of Manihot utilissima with Monascus sp. and characterized by infrared spectroscopy. The stainless steel was characterized by voltammetry, SEM-EDX, XRD and gas sorption analyzer. The results showed that stainless steel activity was decreased in the fermented flour because the surface of stainless steel was being covered. Moreover, addition of 0-2 g/L water fermented flour had relatively similar stainless steel activity. The cathodic current peaks were at -4.86 × 10-4 and -4.87 × 10-4 mA, respectively, for 0 and 2 g/L media. The processes had consumed the same energy with -0.0996 V of cathodic peak potential.

scholarly journals Aplikasi teknologi elektrolisis plasma pada proses produksi Klor-Alkali

2018 ◽  
Vol 11 (3) ◽  
pp. 141
Author(s):  
Nelson Saksono ◽  
Fakhrian Abqari ◽  
Setijo Bismo
Keyword(s):  
Energy Consumption ◽  
Cooling System ◽  
Electricity Consumption ◽  
Electrical Energy ◽  
Gas Production ◽  
Glow Discharge Plasma ◽  
Electrolysis Process ◽  
Plasma Electrolysis ◽  
Chlorine Gas ◽  
Technology Applications

Plasma electrolysis technology applications in Chlor-Alkali process productionChlor-alkali industry sector is one of the important industrial sectorsin chemical industry. However, the chlor-alkali industry is one of the industry sectors that consume the most electrical energy due to the production using the methodof electrolysis. Plasma electrolysis is an electrolysis process with high voltage so that produce the glow discharge plasma in electrolyte solution. This method can be applied in the production of chlor-alkali and can reduce energy consumption several times. This research is aimed to observe the plasma electrolysis method in producing chlorine gas and also to measure the electricity consumption needed in chlor-alkali production process. This study was conducted by using plasma electrolysis reactor equipped by electrodes and cooling system. Process variables observed are voltage, NaCl concntration, and anode depth. Result of this research shows that the increase of all variables will cause the increase of chlorine gas production. The highest chlorine gas production is 1.44 mmol for 15 minutes at 400 V and 0.15 M NaCl solution where the anode position is at the surface of solution. Energy consumption of the process reaches 284 kJ/mmol Cl2, which is 38 times lower than electrolysis process in the same reactor configuration.Keywords: electrolysis, plasma electrolysis, production of chlor-alkali AbstrakIndustri klor-alkali merupakan salah satu industri penting dalam industri kimia dengan konsumsi energi listrik yang tinggi karena proses produksinya menggunakan metode elektrolisis. Elektrolisis plasma merupakan proses elektrolisis dengan tegangan yang jauh lebih tinggi sehingga terbentuk lecutan api listrik pada larutan elektrolit. Metode ini dapat diterapkan dalam aplikasi produksi klor-alkali dan mampu mengurangi konsumsi energi listrik hingga beberapa kali lipat. Penelitian ini bertujuan untuk menguji metode elektrolisis plasma dalam menghasilkan gas klor serta mengukur konsumsi energi listrik yang dibutuhkan dalam proses produksi klor-alkali. Penelitian dilakukan menggunakan reaktor elektrolisis plasma yang telah dilengkapi elektroda dan sistem pendingin. Variabel proses yang diamati meliputi tegangan, konsentrasi NaCl, dan kedalaman anoda. Hasil percobaan menunjukkan kenaikan produksi gas klor dengan meningkatnya tegangan, konsentrasi NaCl dan kedalaman anoda. Produksi gas klor tertinggi adalah sebesar 1,44 mmol yang diperoleh selama 15 menit proses pada tegangan 400 V dan konsentrasi NaCl 0,15 M dimana posisi anoda pada permukaan larutan. Konsumsi energi listrik mencapai 284 kJ/mmol Cl2 yang berarti 38 kali lebih rendah dibanding proses elektrolisis dalam konfigurasi reaktor yang sama.Kata kunci: elektrolisis, elektrolisis plasma, produksi klor-alkali

scholarly journals Straight-Parallel Electrodes and Variable Gap for Hydrogen and Oxygen Evolution Reactions

2019 ◽  
Vol 2019 ◽  
pp. 1-11 ◽  
Author(s):  
María J. Lavorante ◽  
Carla Y. Reynoso ◽  
Juan I. Franco
Keyword(s):  
Energy Consumption ◽  
Electrical Resistance ◽  
Negative Electrode ◽  
Water Electrolysis ◽  
Alkaline Water Electrolysis ◽  
Stainless Steel 316L ◽  
Reduction Of Energy Consumption ◽  
The One ◽  
Definition Of ◽  
The Cost

The challenges to be overtaken with alkaline water electrolysis are the reduction of energy consumption, the maintenance, and the cost as well as the increase of durability, reliability, and safety. Having these challenges in mind, this work focused on the reduction of the electrical resistance of the electrolyte which directly affects energy consumption. According to the definition of electrical resistance of an object, the reduction of the space between electrodes could lower the electrical resistance but, in this process, the formation of bubbles could modify this affirmation. In this work, the performance analyses of nine different spaces between stainless steel 316L electrodes were carried out, although the spaces proposed are not the same as those from the positive electrode (anode) to the separator and from the separator to the negative electrode (cathode). The reason why this is studied is that stoichiometry of the reaction states that two moles of hydrogen and one mole of oxygen can be obtained per every two moles of water. The proposed spaces were 10.65, 9.20, 8.25, 7.25, 6.30, 6.05, 4.35, 4.15, and 3.40 millimetres. From the nine different analysed distances between electrodes, it can be said that the best performance was reached by one of the smallest distances proposed, 4.15 mm. When the same distance between electrodes was compared (the same and different distance between electrodes and separator), the one that had almost twice the distance (negative compartment) presented an increase in current density of approximately 33% with respect to that where both distances (from electrodes to separator) are the same. That indicates that the stichometry of the electrolysis reaction influenced the performance.

scholarly journals COMPARISON STUDY OF STAINLESS STEEL CYCLIC VOLTAMMOGRAMS IN VARIOUS NATURAL MEDIA ADDITION: PRODUCT AND VOLTAGE EFFICIENCY

2019 ◽  
Vol 20 (2) ◽  
pp. 1-11
Author(s):  
Isana Supiah Yosephine Louise ◽  
Endang Widjajanti Laksono ◽  
Dewi Yuanita Lestari
Keyword(s):  
Stainless Steel ◽  
Mangifera Indica ◽  
Aloe Vera ◽  
Cyclic Voltammograms ◽  
Artocarpus Altilis ◽  
Seed Flour ◽  
Nephelium Lappaceum ◽  
Leaf Powder ◽  
The Media ◽  
Mango Seed

The cyclic voltammogram is widely used to analyse the electrolysis process. The use of various media, namely rambutan seed flour (Nephelium lappaceum), mango seed flour (Mangifera indica), breadfruit leaf powder (Artocarpus altilis), peria extract (Momordi charantia) and aloe vera extract (Aloe vera), in this study is to deliberately mimic the occurrence of those media in wastewater produced by several industries. The electrolysis analysis on the presence of several media would minimize the preparation steps on wastewater utilization for generating hydrogen as renewable energy. The research looks at the potential of wastewater as the raw material for the electrolysis process. In this research, stainless steel cyclic voltammograms were studied on water electrolysis. The electrolysis was done in base solution and adding various media, such as rambutan seed flour (Nephelium lappaceum), mango seed flour (Mangifera indica), breadfruit leaf powder (Artocarpus altilis), peria extract (Momordi charantia) and aloe vera extract (Aloe vera) in various concentrations, 0 - 10 g per litter of water. By reviewing the activity of a stainless steel electrode to decompose water molecules, the media generally caused the occurrence of covering by relatively large molecules around the electrode surface, resulting in decreased activity of the stainless steel electrodes. The optimum condition occurred with the addition of breadfruit leaf powder in all treatments with similar electrode activity as much as 1.68. The result could be implemented in a wastewater electrolysis processes containing the media to generate hydrogen gas. ABSTRAK: Voltammogram berkitar banyak digunakan bagi menganalisis proses elektrolisis. Dalam kajian ini pelbagai jenis media telah sengaja digunakan seperti tepung biji rambutan (Nephelium lappaceum), tepung biji mangga (Mangifera indica), serbuk daun sukun (Artocarpus altilis), ekstrak peria (Momordi charantia) dan ekstrak lidah buaya (Aloe vera), bagi memimik terjadinya media-media tersebut dalam sisa air buangan yang terhasil daripada beberapa industri. Analisis elektrolisis pada pelbagai media dapat mengurangkan langkah-langkah persiapan pada penggunaan sisa air bagi menghasilkan hidrogen sebagai tenaga boleh baharu. Penilitian kajian ini bertumpu pada potensi sisa air sebagai bahan kasar bagi proses elektrolisis. Kajian ini adalah tentang elektrolisis air voltammogram berkitar pada keluli tahan karat. Proses elektrolisis telah dilakukan pada larutan dasar dan dengan menambah pelbagai media, seperti tepung biji rambutan (Nephelium lappaceum), tepung biji mangga (Mangifera indica), serbuk daun sukun (Artocarpus altilis), ekstrak petola (Momordi charantia) dan ekstrak lidah buaya (Aloe vera) dalam pelbagai kepekatan, 0 - 10 gram pada setiap liter air. Penurunan aktiviti elektrod keluli tahan karat telah disebabkan oleh aktiviti elektrod keluli tahan karat yang mengurai molekul air dan diliputi molekul-molekul besar pada permukaan elektrod. Keadaan optimum telah berlaku dengan penambahan serbuk daun sukun pada semua rawatan dengan aktiviti elektrod serupa sebanyak 1.68. Dapatan kajian dapat digunakan dalam proses elektrolisis sisa air yang mengandungi media bagi menghasilkan gas hidrogen.

scholarly journals Studi Ketebalan Elektroda Pada Produksi Gas HHO (Hidrogen Hidrogen Oksigen) Oleh Generator Hho Tipe Basah Dengan Katalis NaHCO3 (Natrium Bikarbonat)

2015 ◽  
Vol 8 (2) ◽  
pp. 38-49
Author(s):  
Ihsan Sopandi ◽  
Yuli Hananto ◽  
Bayu Rudiyanto
Keyword(s):  
Stainless Steel ◽  
Direct Current ◽  
Alternative Energy ◽  
Steel Plate ◽  
Gas Production ◽  
Hydrogen Gas ◽  
304 Stainless Steel ◽  
Thickness Variation ◽  
Stainless Steel Plate ◽  
Stainless Steel 304

Abstrak. Salah satu energi alternatif yang efektif dikembangkan sekarang ini untuk mengganti bahan bakar minyak yaitu hidrogen. Untuk mendapatkan gas hidrogen dapat  dilakukan melalui proses elektrolisis air dengan memecahkan senyawa H2O menjadi gas HHO (Hidrogen Hidrogen Oksigen) dengan bantuan listrik arus searah (Direct Current) melalui media elektroda berupa plat stainless steel 304. Pada penelitian ini, akan diteliti hasil produksi gas HHO oleh generator HHO tipe basah dengan metode elektrolisa H2O menggunakan variasi ketebalan elektroda jenis stainless steel 304 yaitu 0,8 mm, 1 mm dan 1,2 mm dengan katalis NaHCO3 (Natrium Bikarbonat) pada larutan elektrolitnya. Karakteristik yang diketahui meliputi konsumsi daya listrik yang digunakan oleh generator, volume gas yg dihasilkan,  laju produksi gas HHO yang dihasilkan dan efisiensi generator. Hasil penelitian dan pengujian generator HHO tipe basah ini didapatkan generator terbaik pada ketebalan elektroda 1 mm diperoleh data hasil pengujian dengan daya HHO yang digunakan sebesar 59,11 Watt, laju produksi gas HHO yang dihasilkan sebanyak 0,00054 kg/s dan efisiensi generator HHO sebesar 9,42 %. Study On The  Electrode Thickness In HHO (Hidrogen Hidrogen Oksigen) Gas Production By Wet Type HHO Generator With Catalyst NaHCO3 (Natrium Bikarbonat)Abstract. One of the alternative energy that effective and currently being developed to replace fossil fuels is hydrogen. To obtain the hydrogen gas can be done through the process of electrolysis of water by breaking the compound H2O into HHO (Hydrogen Hydrogen Oxygen) gas by using an electric direct current through the medium of 304 stainless steel plate  as an electrode. This research will be developing and observing HHO gas production process using HHO generator wet type (wet cell) through electrolysis H2O with thickness variation of electrode that used 0.8 mm, 1 mm and 1.2 mm of electrode 304 stainless steel plate with NaHCO3 (Nathrium Bicarbonat) catalyst in the electrolyte solution. Characteristics that will be observed including the consumption of electrical power used by the generators, produced gas volume, HHO gas production rate and generator efficiency. Results of research and HHO generator wet type (wet cell) testing have obtained the best generator at a thickness of 1 mm electrode, testing data obtained with the use of HHO power of 59.11 watts, the rate of production of HHO gas is 0.00054 kg/s and HHO generator efficiency by 9.42%.

Modelling and control of an alkaline water electrolysis process

2018 ◽  
Vol 1 (2) ◽  
pp. 9-14
Author(s):  
Marisol Cervantes-Bobadilla ◽  
Ricardo Fabricio Escobar Jiménez ◽  
José Francisco Gómez Aguilar ◽  
Tomas Emmanuel Higareda Pliego ◽  
Alberto Armando Alvares Gallegos
Keyword(s):  
Process Model ◽  
Water Electrolysis ◽  
Alkaline Water Electrolysis ◽  
Alkaline Water ◽  
Electrolysis Process ◽  
Linear Dynamic ◽  
Energy Current ◽  
Identification Technique ◽  
Nonlinear Static ◽  
And Control

In this research, an alkaline water electrolysis process is modelled. The electrochemical electrolysis is carried out in an electrolyzer composed of 12 series-connected steel cells with a solution 30% wt of potassium hydroxide. The electrolysis process model was developed using a nonlinear identification technique based on the Hammerstein structure. This structure consists of a nonlinear static block and a linear dynamic block. In this work, the nonlinear static function is modelled by a polynomial approximation equation, and the linear dynamic is modelled using the ARX structure. To control the current feed to the electrolyzer an unconstraint predictive controller was implemented, once the unconstrained MPC was simulated, some restrictions are proposed to design a constrained MPC (CMPC). The CMPC aim is to reduce the electrolyzer's energy consumption (power supply current). Simulation results showed the advantages of using the CMPC since the energy (current) overshoots are avoided.

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