scholarly journals Generation potential of organic matter of the Upper Jurassic deposits within the Karabash search zone

Georesursy ◽  
2021 ◽  
Vol 23 (1) ◽  
pp. 52-59
Author(s):  
Ivan K. Komkov ◽  
Marina V. Dakhnova ◽  
Maria A. Bolshakova ◽  
Svetlana V. Mozhegova
Keyword(s):  
Organic Matter ◽  
Oil And Gas ◽  
Upper Jurassic ◽  
Source Rocks ◽  
Core Material ◽  
Data Mapping ◽  
Degree Of Maturity ◽  
Bazhenov Horizon ◽  
Rock Eval ◽  
Carbon Concentrations

The article considers the geochemical characteristics of the rocks of the Bazhenov and Nizhnetutleim formations in the southwestern part of the West Siberian oil and gas province, or rather in the territory of the Karabash search zone. The work was carried out on the basis of the core material study of the section of 29 wells within the Karabash zone by pyrolysis on the Rock-Eval 6. The regularities of the distribution of organic carbon concentrations (Сorg, %) on the studied territory were obtained. With the help of data mapping, it was established that the maximum concentrations of organic matter are timed to the southern regions of the zone (the most submerged parts of the paleobasin). The assessment of the catagenesis degree (degree of maturity) of organic matter of the Bazhenov horizon in the study area was carried out. Level maturity of organic matter of rocks is specified in the parameter Tmax Rock-Eval. Within the study area it’s increasing from South to North, from graduation PK3 (according to the scale of N.B. Vassoevich) (Tmax < 430 0С) in the area of wells Verkhnetyumskaya 34 to MK2 (Tmax 440–445 0С) in the area of Molodezhnaya and the Zapadno-Frolovskaya square. The resulting catagenetic zoning determined the boundaries of the generation kitchen for this territory. Generation scale for the Upper Jurassic source rocks was estimated, taking into account its lithofacial structure.

scholarly journals Changing depositional environments in the semi-restricted Late Jurassic Lemeš Basin (Outer Dinarides; Croatia)

Facies ◽  
2021 ◽  
Vol 68 (1) ◽  
Author(s):  
Michael A. J. Vitzthum ◽  
Hans-Jürgen Gawlick ◽  
Reinhard F. Sachsenhofer ◽  
Stefan Neumeister
Keyword(s):  
Organic Matter ◽  
Deep Water ◽  
Carbonate Platform ◽  
Upper Jurassic ◽  
Depositional Environments ◽  
Source Rocks ◽  
Terrestrial Organic Matter ◽  
Kerogen Type ◽  
Marine Algal ◽  
Rock Eval

AbstractThe up to 450 m-thick Upper Jurassic Lemeš Formation includes organic-rich deep-water (max. ~ 300 m) sedimentary rocks deposited in the Lemeš Basin within the Adriatic Carbonate Platform (AdCP). The Lemeš Formation was investigated regarding (1) bio- and chemostratigraphy, (2) depositional environment, and (3) source rock potential. A multi-proxy approach—microfacies, Rock–Eval pyrolysis, maceral analysis, biomarkers, and stable isotope ratios—was used. Based on the results, the Lemeš Formation is subdivided from base to top into Lemeš Units 1–3. Deposition of deep-water sediments was related to a late Oxfordian deepening event causing open-marine conditions and accumulation of radiolarian-rich wackestones (Unit 1). Unit 2, which is about 50 m thick and Lower early Kimmeridgian (E. bimammatum to S. platynota, ammonite zones) in age, was deposited in a restricted, strongly oxygen-depleted basin. It consists of radiolarian pack- and grainstones with high amounts of kerogen type II-S organic matter (avg. TOC 3.57 wt.%). Although the biomass is predominantly marine algal and bacterial in origin, minor terrestrial organic matter that was transported from nearby land areas is also present. The overlying Unit 3 records a shallowing of the basin and a return to oxygenated conditions. The evolution of the Lemeš Basin is explained by buckling of the AdCP due to ophiolite obduction and compressional tectonics in the Inner Dinarides. Lemeš Unit 2 contains prolific oil-prone source rocks. Though thermally immature at the study location, these rocks could generate about 1.3 t of hydrocarbon per m2 surface area when mature.

scholarly journals Differentiation of the Generation Potential of the Menilite and Istebna Beds of the Silesian Unit in the Carpathians Based on Compiled Pyrolytic Studies

Energies ◽  
2021 ◽  
Vol 14 (21) ◽  
pp. 6866
Author(s):  
Irena Matyasik ◽  
Małgorzata Labus ◽  
Maria Kierat ◽  
Karol Spunda
Keyword(s):  
Weight Loss ◽  
Organic Matter ◽  
Source Rocks ◽  
Decomposition Products ◽  
Pyrolysis Products ◽  
Higher Temperature ◽  
Degree Of Maturity ◽  
Menilite Shales ◽  
Gaseous Hydrocarbons ◽  
Rock Eval

The study of the source rocks was carried out with the use of various analytical methods in order to assess their generation potential and to predict the decomposition products of organic matter. The selected samples from the Menilite Beds from the Silesian and Dukla units, as well as the Istebna layers from the Silesian unit, which are classified as weak and medium source rocks in the Carpathian oil system, were examined. The generation potential and type of the products obtained from the pyrolysis of the analyzed source rocks, despite the often comparable overall content of organic matter, are significantly different. Menilite shale generated a higher abundance of hydrocarbons (alkanes, alkenes, and isoalkanes) by stage pyrolysis, which suggested that the organic matter of Menilite shale is different from the Istebna source rocks. Moreover, the thermogravimetric analysis showed a two-stage weight loss in the case of Menilite shales, while the Istebna shales were characterized by a one-stage weight loss at higher temperature. For the Istebna layers, n-alkanes from the C1–C5 range were detected as the main pyrolysis products, which proves the gas-forming type of the organic matter dispersed in these sediments. Rock-Eval analyses showed that the organic matter reached a degree of maturity corresponding to the early thermocatalytic processes (the initial oil window stage) and therefore was able to generate liquid and gaseous hydrocarbons. The comparison of the decomposition temperatures of the organic matter from the Rock-Eval and TG analyses allowed us to conclude that both measurements correlate well and can be equally used to assess the level of thermal transformations of organic matter.

Finnmark Platform Composite Tectono-Sedimentary Element, Barents Sea

2021 ◽  
pp. M57-2020-20
Author(s):  
E. Henriksen ◽  
D. Ktenas ◽  
J. K. Nielsen
Keyword(s):  
High Frequency ◽  
Oil And Gas ◽  
Barents Sea ◽  
Upper Jurassic ◽  
Source Rocks ◽  
Basement Rocks ◽  
Sea Bottom ◽  
Middle Carboniferous ◽  
Uralian Orogen ◽  
Glacial Periods

AbstractThe Finnmark Platform Composite Tectono-Sedimentary Element (CTSE), located in the southern Barents Sea, is a northward-dipping monoclinal structural unit. It covers most of the southern Norwegian Barents Sea where it borders the Norwegian Mainland. Except for the different age of basement, the CTSE extends eastwards into the Kola Monocline on the Russian part of the Barents Sea.The general water depth varies between 200-350 m, and the sea bottom is influenced by Plio-Pleistocene glaciations. A high frequency of scour marks and deposition of moraine materials exists on the platform areas. Successively older strata sub-crop below the Upper Regional Unconformity (URU, which was) formed by several glacial periods.Basement rocks of Neoproterozoic age are heavily affected by the Caledonian Orogeny, and previously by the Timanide tectonic compression in the easternmost part of the Finnmark Platform CTSE.Depth to crystalline basement varies considerably and is estimated to be from 4-5 to 10 km. Following the Caledonian orogenesis, the Finnmark Platform was affected by Lower to Middle Carboniferous rifting, sediment input from the Uralian Orogen in the east, the Upper Jurassic / Lower Cretaceous rift phase and the Late Plio-Pleistocene isostatic uplift.A total of 8 exploration wells drilled different targets on the platform. Two minor discoveries have been made proving presence of both oil and gas and potential sandstone reservoirs of good quality identified in the Visean, Induan, Anisian and Carnian intervals. In addition, thick sequences of Perm-Carboniferous carbonates and spiculitic chert are proven in the eastern Platform area. The deep reservoirs are believed to be charged from Paleozoic sources. A western extension of the Domanik source rocks well documented in the Timan-Pechora Basin may exist towards the eastern part of the Finnmark Platform. In the westernmost part, charge from juxtaposed down-faulted basins may be possible.

scholarly journals Source rock characterization of mesozoic to cenozoic organic matter rich marls and shales of the Eratosthenes Seamount, Eastern Mediterranean Sea

2018 ◽  
Vol 73 ◽  
pp. 49 ◽  
Author(s):  
Sebastian Grohmann ◽  
Susanne W. Fietz ◽  
Ralf Littke ◽  
Samer Bou Daher ◽  
Maria Fernanda Romero-Sarmiento ◽  
...  
Keyword(s):  
Organic Matter ◽  
Mediterranean Sea ◽  
Source Rock ◽  
Eastern Mediterranean ◽  
Source Rocks ◽  
Eastern Mediterranean Sea ◽  
Potential Source Rock ◽  
Levant Basin ◽  
Rock Characterization ◽  
Rock Eval

Several significant hydrocarbon accumulations were discovered over the past decade in the Levant Basin, Eastern Mediterranean Sea. Onshore studies have investigated potential source rock intervals to the east and south of the Levant Basin, whereas its offshore western margin is still relatively underexplored. Only a few cores were recovered from four boreholes offshore southern Cyprus by the Ocean Drilling Program (ODP) during the drilling campaign Leg 160 in 1995. These wells transect the Eratosthenes Seamount, a drowned bathymetric high, and recovered a thick sequence of both pre- and post-Messinian sedimentary rocks, containing mainly marine marls and shales. In this study, 122 core samples of Late Cretaceous to Messinian age were analyzed in order to identify organic-matter-rich intervals and to determine their depositional environment as well as their source rock potential and thermal maturity. Both Total Organic and Inorganic Carbon (TOC, TIC) analyses as well as Rock-Eval pyrolysis were firstly performed for the complete set of samples whereas Total Sulfur (TS) analysis was only carried out on samples containing significant amount of organic matter (>0.3 wt.% TOC). Based on the Rock-Eval results, eight samples were selected for organic petrographic investigations and twelve samples for analysis of major aliphatic hydrocarbon compounds. The organic content is highly variable in the analyzed samples (0–9.3 wt.%). TS/TOC as well as several biomarker ratios (e.g. Pr/Ph < 2) indicate a deposition under dysoxic conditions for the organic matter-rich sections, which were probably reached during sporadically active upwelling periods. Results prove potential oil prone Type II kerogen source rock intervals of fair to very good quality being present in Turonian to Coniacian (average: TOC = 0.93 wt.%, HI = 319 mg HC/g TOC) and in Bartonian to Priabonian (average: TOC = 4.8 wt.%, HI = 469 mg HC/g TOC) intervals. A precise determination of the actual source rock thickness is prevented by low core recovery rates for the respective intervals. All analyzed samples are immature to early mature. However, the presence of deeper buried, thermally mature source rocks and hydrocarbon migration is indicated by the observation of solid bitumen impregnation in one Upper Cretaceous and in one Lower Eocene sample.

scholarly journals KEROGEN TYPES OF BAZHENOV FORMATION BASED ON PYROLYSIS DATA AND THEIR COMPARISON WITH OIL PARAMETERS

2017 ◽  
pp. 34-43
Author(s):  
E. E. Oksenoyd ◽  
V. A. Volkov ◽  
E. V. Oleynik ◽  
G. P. Myasnikova
Keyword(s):  
Organic Matter ◽  
Lower Cretaceous ◽  
Alternative Model ◽  
Oil And Gas ◽  
Upper Jurassic ◽  
Gas Content ◽  
Basin Modeling ◽  
Bazhenov Formation ◽  
Gas Bearing

Based on pyrolytic data (3 995 samples from 208 wells) organic matter types of Bazhenov Formation are identified in the central part of Western Siberian basin. Zones of kerogen types I, II, III and mixed I-II and II-III are mapped. Content of sulfur, paraffins, resins and asphaltenes, viscosity, density, temperature and gas content in oils from Upper Jurassic and Lower Cretaceous sediments (3 806 oil pools) are mapped. Oil gradations are identified and distributed. The alternative model of zones of kerogen II and IIS types is presented. The established distributions of organic matter types can be used in basin modeling and in assessment of oil-and-gas bearing prospects.

COAL AS A SOURCE OF OIL AND GAS: A CASE STUDY FROM THE BASS BASIN, AUSTRALIA

2003 ◽  
Vol 43 (1) ◽  
pp. 117 ◽  
Author(s):  
C.J. Boreham ◽  
J.E. Blevin ◽  
A.P. Radlinski ◽  
K.R. Trigg
Keyword(s):  
Organic Matter ◽  
Oil And Gas ◽  
Middle Eocene ◽  
Vitrinite Reflectance ◽  
Mineral Resources ◽  
Sedimentary Basins ◽  
Source Rocks ◽  
Gas Generation ◽  
Australian Context ◽  
Effective Source

Only a few published geochemical studies have demonstrated that coals have sourced significant volumes of oil, while none have clearly implicated coals in the Australian context. As part of a broader collaborative project with Mineral Resources Tasmania on the petroleum prospectivity of the Bass Basin, this geochemical study has yielded strong evidence that Paleocene–Eocene coals have sourced the oil and gas in the Yolla, Pelican and Cormorant accumulations in the Bass Basin.Potential oil-prone source rocks in the Bass Basin have Hydrogen Indices (HIs) greater than 300 mg HC/g TOC. The coals within the Early–Middle Eocene succession commonly have HIs up to 500 mg HC/g TOC, and are associated with disseminated organic matter in claystones that are more gas-prone with HIs generally less than 300 mg HC/g TOC. Maturity of the coals is sufficient for oil and gas generation, with vitrinite reflectance (VR) up to 1.8 % at the base of Pelican–5. Igneous intrusions, mainly within Paleocene, Oligocene and Miocene sediments, produced locally elevated maturity levels with VR up to 5%.The key events in the process of petroleum generation and migration from the effective coaly source rocks in the Bass Basin are:the onset of oil generation at a VR of 0.65% (e.g. 2,450 m in Pelican–5);the onset of oil expulsion (primary migration) at a VR of 0.75% (e.g. 2,700–3,200 m in the Bass Basin; 2,850 m in Pelican–5);the main oil window between VR of 0.75 and 0.95% (e.g. 2,850–3,300 m in Pelican–5); and;the main gas window at VR >1.2% (e.g. >3,650 m in Pelican–5).Oils in the Bass Basin form a single oil population, although biodegradation of the Cormorant oil has resulted in its statistical placement in a separate oil family from that of the Pelican and Yolla crudes. Oil-to-source correlations show that the Paleocene–Early Eocene coals are effective source rocks in the Bass Basin, in contrast to previous work, which favoured disseminated organic matter in claystone as the sole potential source kerogen. This result represents the first demonstrated case of significant oil from coal in the Australian context. Natural gases at White Ibis–1 and Yolla–2 are associated with the liquid hydrocarbons in their respective fields, although the former gas is generated from a more mature source rock.The application of the methodologies used in this study to other Australian sedimentary basins where commercial oil is thought to be sourced from coaly kerogens (e.g. Bowen, Cooper and Gippsland basins) may further implicate coal as an effective source rock for oil.

scholarly journals Use of Geochemical Fossils as Indicators of Thermal Maturation: An Example from the Anambra Basin, Southeastern Nigeria

2015 ◽  
Vol 2015 ◽  
pp. 1-11 ◽  
Author(s):  
Olumuyiwa Adedotun Odundun
Keyword(s):  
Organic Matter ◽  
Oil And Gas ◽  
Land Plant ◽  
Source Rocks ◽  
Chemical Compositions ◽  
Organic Input ◽  
Southeastern Nigeria ◽  
Anambra Basin ◽  
Subsurface Sediments ◽  
Geochemical Studies

Organic geochemical studies and fossil molecules distribution results have been employed in characterizing subsurface sediments from some sections of Anambra Basin, southeastern Nigeria. The total organic carbon (TOC) and soluble organic matter (SOM) are in the range of 1.61 to 69.51 wt% and 250.1 to 4095.2 ppm, respectively, implying that the source rocks are moderately to fairly rich in organic matter. Based on data of the paper, the organic matter is interpreted as Type III (gas prone) with little oil. The geochemical fossils and chemical compositions suggest immature to marginally mature status for the sediments, with methyl phenanthrene index (MPI-1) and methyl dibenzothiopene ratio (MDR) showing ranges of 0.14–0.76 and 0.99–4.21, respectively. The abundance of 1,2,5-TMN (Trimethyl naphthalene) in the sediments suggests a significant land plant contribution to the organic matter. The pristane/phytane ratio values of 7.2–8.9 also point to terrestrial organic input under oxic conditions. However, the presence of C27 to C29 steranes and diasteranes indicates mixed sources—marine and terrigenous—with prospects to generate both oil and gas.

scholarly journals Timing of oil expulsion from source rocks and a revitalization of the pre-1970 model

2021 ◽  
Author(s):  
Per Arne Bjørkum
Keyword(s):  
Organic Matter ◽  
Source Rock ◽  
Heavy Oil ◽  
Low Temperatures ◽  
Upper Jurassic ◽  
Hydrogen Gas ◽  
Source Rocks ◽  
Co2 Gas ◽  
Chemical Attributes ◽  
Oil Expulsion

New data from North Sea Upper Jurassic source rock samples show no decline in the total amount of organic matter (TOC) within the oil expulsion window between 120 and 150°C which is a key prediction by today’s model for oil expulsion. However, today’s model for oil expulsion is not consistent with either subsurface source rock TOC data or chemical attributes of shallow oils. Instead, these data are more consistent with oil expulsion occurring at much lower temperatures and shallower depths, more similar to models advocated by most oil explorers prior to 1970 where the oil was assumed to have expelled at burial depths less than ~2km. In this paper, main oil expulsion has been determined to be take place at burial depths less than 1km and approximately 30°C. The oil is mobilized by CO2 gas which is generated from decomposing organic matter and is predicted to migrate out of the source rock and into nearby high-permeable rocks via horizontal fractures that originate from loadbearing swelling organic lamina and in a direction towards decreasing overburden. The thermally immature (heavy) oil is then converted to light crude within the reservoir oil starting at 60-70°C by hydrogenation. Hydrogen gas is common in subsurface fluids and is provided to pooled oil from coalification of organic matter in mudstones. Thus, if the supply of hydrogen is limited, in-reservoir thermal upgrading will be hampered. In this model, most of the heavy oil accumulations encountered are immature rather than due to biodegradation of mature oil at low temperatures.

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