scholarly journals CHANGES IN THE CONTENT AND QUALITY OF ORGANIC MATTER IN AGRARIAN SOILS OF NON-CHERNOZEM ZONE DEPENDING ON ANTHROPOGENIC IMPACT

2010 ◽  
pp. 13-22
Author(s):  
N. Ismagilova
Keyword(s):  
Organic Matter ◽  
Optical Density ◽  
Humic Acids ◽  
Humus Content ◽  
Fulvic Acids ◽  
Black Soil ◽  
Organic Fertilizers ◽  
Optimal Interval ◽  
Humus State

On the basis of experimental and literary data the assessment of humus state of arable layer of differently cultivated typical agrarian-grey heavy loamy non-eroidated soils of the center of the Non-Black Earth zone of Russia was carried out. The gradations of humus content corresponding to the different level of soil fertility were determined. The optimal interval of humus content is calculated on the basis of its minimal value in non-erodized agrarian soils of the region and optimal limits of transforming organic matter. It is shown that at development of grey soils under forest in arable horizonThe content of humus, fulvic acids, mobile humic acids, extracted 0.1 n. NaOH, decreases, and the amount of humic acids associated with Ca sharply increases with the increase of their optical density and ratio to mobile humic acids to the level in agronomic black soil. Further domestication of agrarian soils on the background of systematic application of increased doses of organic fertilizers, along with increasing the content of humus, there are reverse changes in the ratio of these fractions of humic acids. At the same time, the optical density of humic acids associated with clay minerals decreases significantly, which indicates the processes of their renewal and enrichment by aliphatic structures. Criteria of difference between agrarian soils and podzolic soils and agronomic chernozems by quality of humus in arable horizon are discussed.

scholarly journals Haplic chernozems humus condition of Western Bug and Styr terraced landscapes

2016 ◽  
pp. 296-308
Author(s):  
Pavlo Papish ◽  
Halyna Ivanyuk ◽  
Ihor Papish
Keyword(s):  
Organic Matter ◽  
Clay Minerals ◽  
Optical Density ◽  
Humic Acids ◽  
Fulvic Acids ◽  
Soil Thickness ◽  
Humus Profile ◽  
Haplic Chernozems ◽  
High Degree ◽  
Very High

Volyn Upland Haplic Chernozems are distributed mainly on the terrace landscapes of the Western Bug and the Styr and their tributaries (Chornohuzka, Luha, Lypa). Most of these soils are old ploughlands that have experienced various types of degradation. Haplic Chernozems are low-humus soils and they have low storages of humus substance in the 20 cm arable layer and middle storages of humus in 100 cm soil thickness. There is correlation of C humic acids to C fulvic acids within 1.2–3.3 in the humus profile. Among the various fractions of humic substances the 2nd fraction associated to Calcium dominates. A content of “free” humic acids (1rst fraction) is very low and the amount of humin is low. The optical density of humic acids ( 0,001% НА Е1 cm, 465 nm ) are high and very high. The organic matter of Volyn Upland Haplic Chernozems has some regional peculiarities. First, it caused by topographical conditions of its formation and evolution in the Holocene. Chernozems of the 1st terrace of the River Western Bug are extremely deep. They have progressive-accumulative type of humus distribution in profile, humate type of humus in upper 100 cm layer, a very high degree of organic matter humification and the same content of humic fraction associated to Calcium and lowmiddle content of 3rd fraction associated to clay minerals. The molecules of humic acids in the humus horizon of Chernozems of the 1rst terrace are better structured that indicates the older age of humus in these soils. Chernozems of the 2nd terrace above the floodplain of the River Styr are middle-deep soils. They are characterised by the regressive-accumulative type of humus distribution in profile, humate-fulvate type of humus and very high degree of organic matter humification only in 25–50 cm layer. The content of fractions associated to Calcium and clay minerals is predominantly high. Key words: Haplic Chernozems, humus, humic acids, fulvic acids, optical density, humus condition.

scholarly journals Characterization of wastewater from landfills - amount and type of humic substances extracted from leachate

2019 ◽  
Vol 80 ◽  
pp. 03002
Author(s):  
Maria Elisabete Silva ◽  
Marlene Santos ◽  
Isabel Brás
Keyword(s):  
Organic Matter ◽  
Humic Substances ◽  
Functional Groups ◽  
Humic Acids ◽  
Fulvic Acids ◽  
Organic Fertilizers ◽  
Structural Composition ◽  
Carboxylic Groups ◽  
Humification Degree

This study aimed to characterize the humic substances (HS) extracted from landfills wastewater – leachates, with different ages of exploration. To reach the objective it was applied spectroscopy techniques, UV-Vis and FTIR spectra, as well as the ratio between the absorbance analysed. First, the HS were extracted, then fractionated in fulvic acids (FA) and humic acids (HA) and it was evaluated the phytotoxicity. HS content in the leachates were higher than the typical values found in the natural aquatic humic sources. It has been identified that the leachate HS, HA and FA aromatic fractions increased with the increase of the landfilling age, suggesting that the degree of humification increased with the landfilling age. All the HS showed a high aromaticity and humification degree. The HS extracts irrespective of their source presents similar structural composition. The functional groups found are in agreement with the literature: phenols, alcohols, carboxylic groups, aliphatic structures, among others. It was found that HA are mainly organic matter with a higher aromatic degree than FA. The HS and HA showed absence of phytotoxicity, testing by germination index, suggesting that may be used to produce liquid organic fertilizers.

scholarly journals Organic Matter Properties of Spent Button Mushroom Substrate in the Context of Soil Organic Matter Reproduction

Agronomy ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 204 ◽  
Author(s):  
Marcin Becher ◽  
Magdalena Banach-Szott ◽  
Agnieszka Godlewska
Keyword(s):  
Organic Matter ◽  
Humic Acids ◽  
Fulvic Acids ◽  
Total Carbon ◽  
Carbonate Content ◽  
Qualitative Properties ◽  
Button Mushrooms ◽  
Potential Impact ◽  
High Share

The objective of the work was to evaluate selected properties of spent substrates used for growing button mushrooms (SMSs) and the content and quality of the organic matter in this material in the context of rational use for fertilisation purposes and potential impact on the soil environment. The materials were sampled at production facilities located in the east of Mazovia. The density and amount of spent substrate on shelves where mushrooms were cultivated were determined. The following were analysed in the laboratory: reaction, carbonate content, TC (total carbon) and TOC (total organic carbon) contents, total nitrogen, organic matter fraction composition, and humic acids properties. It was confirmed that this material had a marked potential to enrich soils in organic matter, nitrogen, and carbonates. The analysis revealed that the most important qualitative properties of the organic matter were related to the relatively high share of labile organic compounds (the fraction separated with 0.05 M H2SO4 and the fraction of fulvic acids). The humic acids had similar properties regardless of their origins. The humic acids (HAs) molecules displayed a substantial share of aliphatic structures which are typical of these materials at their initial decomposition stage. It can be assumed that, due to such properties, spent mushroom substrates are materials which can be directly introduced into the soil to improve their quality and prevent degradation.

scholarly journals Humus conditions of the Pre-Dnisterian Podolia Haplic Chernozems

2017 ◽  
pp. 204-213
Author(s):  
Andriy Lisovskiy ◽  
Vladyslav Harbar
Keyword(s):  
Organic Matter ◽  
Humic Acids ◽  
Fulvic Acids ◽  
Perennial Grasses ◽  
Organic Fertilizers ◽  
Plant Residues ◽  
General Tendency ◽  
Organic C ◽  
Calcium Carbonates ◽  
Haplic Chernozems

The humus state of chernozems typical of Pre-Dnisterian Podolia is investigated. It has been established that for the content of humus the chernozems typical of the Pre-Dnisterian Podolia are low humus (2.78–3.98 %). With depth, the content of humus decreases gradually, indicating a uniformly accumulative type of distribution of organic matter in the soil profile. It is determined that in typical chernozems the phenomenon of moderate migration of humic acids is observed, thus forming a deep humus profile. Humic content to the depth of 90–100 cm is dominated by humic acids (Cga:Cfais 1.12–1.78). The general tendency of relative “pluralisation” of the arable lay eras a result of its agronomic exhaustion has been observed. In relation to the Cga to the general organic C, the chernozems soil of the study area is characterized by a high and very high degree of humification of organic matter. It is proved that the intensity of the migration processes of humic acids decreases in the direction of strengthening the hardness of the GTK territory, due to the tightening of calcium carbonates closer to the surface of the soil. Its middle and lower parts were formed, to a large extent, by infiltration of humic acids, moreover, mainly due to the calcium humates. In the case of the use of chernozems without the use of organic fertilizers, the processes of mineralization of plant residues and humus are more active, and the balance of humus is scarce. However, when applying a setoff measures, you cannot only prevent loss of humus but also increased their content. Such a complex should include the following measures: soil replenishment with organic substances, in particular, the planting of perennial grasses and sown crops, the abandonment of a higher grain of grain; minimizing cultivation; creation of optimal ratios of crops in crop rotation to reduce humus losses; the application of meliorants, which would ensure the strengthening of soil fixation of newly formed humus substances. Key words: Pre-Dnisterian Podolia, Haplic Chernozems, humus, humic acids, fulvic acids.

scholarly journals Characterization of Soil Organic Matter Individual Fractions (Fulvic Acids, Humic Acids, and Humins) by Spectroscopic and Electrochemical Techniques in Agricultural Soils

Agronomy ◽  
2021 ◽  
Vol 11 (6) ◽  
pp. 1067
Author(s):  
Aleksandra Ukalska-Jaruga ◽  
Romualda Bejger ◽  
Guillaume Debaene ◽  
Bożena Smreczak
Keyword(s):  
Molecular Weight ◽  
Organic Matter ◽  
Soil Organic Matter ◽  
Humic Substances ◽  
Humic Acids ◽  
Agricultural Soils ◽  
Fulvic Acids ◽  
Sorption Properties ◽  
Aliphatic Chains

The objective of this paper was to investigate the molecular characterization of soil organic matter fractions (humic substances (HS): fulvic acids-FAs, humic acids-HAs, and humins-HNs), which are the most reactive soil components. A wide spectrum of spectroscopic (UV–VIS and VIS–nearIR), as well as electrochemical (zeta potential, particle size diameter, and polydispersity index), methods were applied to find the relevant differences in the behavior, formation, composition, and sorption properties of HS fractions derived from various soils. Soil material (n = 30) used for the study were sampled from the surface layer (0–30 cm) of agricultural soils. FAs and HAs were isolated by sequential extraction in alkaline and acidic solutions, according to the International Humic Substances Society method, while HNs was determined in the soil residue (after FAs and HAs extraction) by mineral fraction digestion using a 0.1M HCL/0.3M HF mixture and DMSO. Our study showed that significant differences in the molecular structures of FAs, Has, and HNs occurred. Optical analysis confirmed the lower molecular weight of FAs with high amount of lignin-like compounds and the higher weighted aliphatic–aromatic structure of HAs. The HNs were characterized by a very pronounced and strong condensed structure associated with the highest molecular weight. HAs and HNs molecules exhibited an abundance of acidic, phenolic, and amine functional groups at the aromatic ring and aliphatic chains, while FAs mainly showed the presence of methyl, methylene, ethenyl, and carboxyl reactive groups. HS was characterized by high polydispersity related with their structure. FAs were characterized by ellipsoidal shape as being associated to the long aliphatic chains, while HAs and HNs revealed a smaller particle diameter and a more spherical shape caused by the higher intermolecular forcing between the particles. The observed trends directly indicate that individual HS fractions differ in behavior, formation, composition, and sorption properties, which reflects their binding potential to other molecules depending on soil properties resulting from their type. The determined properties of individual HS fractions are presented as averaged characteristics over the examined soils with different physico-chemical properties.

scholarly journals Zonal features of the dynamics of humus content in soils of Chernihiv region

2021 ◽  
pp. 115-125
Author(s):  
O. Grischenko ◽  
S. Romanova ◽  
V. Zapasnyi ◽  
I. Shabanova
Keyword(s):  
Organic Matter ◽  
Green Manure ◽  
Sharp Increase ◽  
Humus Content ◽  
Weighted Average ◽  
Sharp Decrease ◽  
Organic Fertilizers ◽  
Climatic Zones ◽  
Sown Area ◽  
Green Manure Crops

The humus condition of soils of Chernihiv region has been studied. The dynamics of humus content in the soils of the region during six rounds (1986–2015) of agrochemical certification of agricultural lands is generalized and analyzed. In comparison with the 5th round (1986–1990), there was a discrepancy between the processes of stabilization and increase of humus content in most districts and in the region as a whole in the ninth round (2006–2010), and in some districts in the tenth round (2011–2015) against the background of a sharp decrease in the application of organic fertilizers. It was found that the stabilization of humus content in the soils of the region during the V–VIII rounds of agrochemical certification and a sharp increase in its content in the ninth round, against a significant reduction of organic matter, correlates with the withdrawal of eroded, low-yielding lands with low humus content (r=0.76). Analyzing the dynamics of humus content over thirty years of research,it was found that its content has increased in all climatic zones, as well as in nineteen of the twenty-two districts of the region. The increase of the indicator is in the range of 0.01–0.72%, while in all districts there is a significant reduction of the surveyed areas and only in three districts of the region there is a decrease in the humus content. According to the results of the 10th round of agrochemical certification, the soils of Chernihiv region are characterized by an average humus content of 2.41%. The highest humus content is characterized by the soils of Bakhmatsky (3.56%), Talalaivsky (3.33%) and Pryluky (3.32%) districts, and the lowest — NovgorodSiversky (1.57%). Increasing the sown area of green manure crops, plowing straw and the use of other elements of biologization of agriculture are important factors in increasing the weighted average humus content in the soils of Chernihiv region.

scholarly journals Properties of Humic Acids in Meadow Soils Irrigated With the Slope-And Flooding System

2021 ◽  
Author(s):  
Magdalena Banach-Szott ◽  
Andrzej Dziamski
Keyword(s):  
Particle Size ◽  
Organic Matter ◽  
Organic Carbon ◽  
Humic Acids ◽  
Soil Samples ◽  
Hydrophobic Properties ◽  
Irrigation Ditch ◽  
Ft Ir ◽  
Degree Of Maturity

Abstract The aim of the research has been to determine the effect of many-year irrigation of unique grasslands on the properties of humic acids defining the quality of organic matter. The research was performed based on the soil (Albic Brunic Arenosol, the A, AE and Bsv horizons) sampled from Europe’s unique complex of permanent grasslands irrigated continuously for 150 years, applying the slope-and-flooding system; the Czerskie Meadows. The soil samples were assayed for the content of total organic carbon (TOC) and the particle size distribution. HAs were extracted with the Schnitzer method and analysed for the elemental composition, spectrometric parameters in the UV-VIS range, hydrophilic and hydrophobic properties and the infrared spectra were produced. The research results have shown that the HAs properties depended on the depth and the distance from the irrigation ditch. The HAs of the A horizon of the soils were identified with a lower “degree of maturity”, as reflected by the values of atomic ratios (H/C, O/C, O/H), absorbance coefficients, and the FT-IR spectra, as compared with the HAs of the Bsv horizon. The HAs molecules of the soils sampled furthest from the irrigation ditch were identified with a higher degree of humification, as compared with the HAs of the soils sampled within the closest distance. The results have demonstrated that many-year grassland irrigation affected the structure and the properties of humic acids.

Humus Substances and Soil Structure

2012 ◽  
Vol 63 (3) ◽  
pp. 31-36
Author(s):  
Erika Tobiašová ◽  
Juraj Miškolczi
Keyword(s):  
Humic Acids ◽  
Soil Structure ◽  
Size Fraction ◽  
Fulvic Acids ◽  
Optical Parameters ◽  
Humus Substances ◽  
Haplic Chernozems ◽  
Positive Correlations ◽  
The Stability

Abstract In this study, the soil structure of two soil types (Haplic Chernozems and Eutric Fluvisols) in four ecosystems (forest, meadow, urban and agro-ecosystem) with dependence on humus substances were compared. The stability of dry-sieved and waterresistant macro-aggregates and micro-aggregates with a dependence on the proportion of humus substance fractions was determined. Quantity of humus substances influenced mainly water-resistant aggregates. A positive correlation was recorded between size fraction of 2.3 mm and contents of humus substances (P < 0.01; r = +0.710) and fulvic acids (P < 0.05; r = +0.634), and negative correlation between size fraction of 0.5.1 mm and contents of humus substances (P < 0.05; r = -0.613) and fulvic acids (P < 0.01; r = -0.711). Humic acids influenced mainly the formation of dry-sieved aggregates and fulvic acids played an important role in micro-aggregate formation. The quality of humus substances influenced more intensively the formation of dry-sieved aggregates. There were positive correlations between optical parameters of humus substances and humic acids and larger dry-sieved aggregates (3.7 mm) and negative correlations with smaller (0.5.3 mm). The highest proportions of larger size of water-resistant aggregates (1. 20 mm) were in forest ecosystem, but smaller (0.25.1 mm) agreggates were dominated in agro-ecosystem.

scholarly journals EFFECT OF MICROBIAL PREPARATIONS ON THE HUMUS BALANCE IN SOD-PODZOLIC SOIL

2019 ◽  
Vol 29 ◽  
pp. 56-61
Author(s):  
L. V. Potapenko ◽  
L. М. Skachok ◽  
N. I. Horbachenko
Keyword(s):  
Organic Matter ◽  
Crop Rotation ◽  
Green Manure ◽  
Podzolic Soil ◽  
Humus Content ◽  
Organic Fertilizers ◽  
Organic Mineral ◽  
Rotation Methods ◽  
Comparative Results ◽  
Positive Effect

Objective. To study the efficiency of inoculation of seeds by biological preparations under in-fluence on humus balance in growing crops in short crop rotation. Methods. Field, laboratory, cal-culation-comparative. Results. It was found that the highest entrance of organic matter in the soil was due to the use of organo-mineral fertilizing system NPK-manure-green manure, which contrib-utes to the increase of organic carbon reserves by 17.4 t/ha without the use of microbial prepara-tions and by 18.0 t/ha against the background of microbial preparations in comparison with the mineral fertilizing system. The use of microbial preparations under the fertilizing systems NP-manure-green manure allows to increase the amount of organic matter entering the soil by 1.2 and 1.6 t/ha during crop rotation. Under the use of organic fertilizers (manure, green manure) in com-bination with mineral ones and seed inoculation, not only the recovery of fertility of sod-podzolic soil, but also increase in the content of humus within the limits of 0.43–0.53 t/ha is reported. The use of manure on the background of the NPK makes it possible to increase the humus reserves in the soil by 0.11 and 0.15 t/ha per year. During crop rotation, the amount of newly formed humus in this variant exceeded its mineralization loss by 0.42 t/ha without microbial preparations and by 0.58 t/ha on the background of microbial preparations. Conclusion. The positive effect of the use of biological preparations under inoculation of seeds in combination with the organo-mineral fertiliz-ing system on the content of humus in sod-podzolic soil on average by crop rotation was estab-lished. Organic-mineral fertilizing system (NPK + manure + green manure) provides the highest growth of humus reserve in soil — 0.53 t/ha per year. The use of microbial preparations in the cul-tivation of crops under this fertilizing system contributes to the increase of humus content in the soil by 0.16 t/ha during crop rotation.

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