Effect of PEG-2000 on saturation magnetization Fe3O4 particles synthesized with coprecipitation method

2017 ◽  
Vol 1 (1) ◽  
pp. 49
Author(s):  
Dwi Puryanti ◽  
Dori Andani ◽  
Merry Thressia
Keyword(s):  
Magnetic Properties ◽  
Saturation Magnetization ◽  
Base Material ◽  
Diffraction Method ◽  
Coprecipitation Method ◽  
X Ray Diffraction ◽  
Magnetization Saturation ◽  
Sand Base ◽  
The Village

<p class="Abstract">Synthesis of Fe<sub>3</sub>O<sub>4</sub> particles was performed using coprecipitation method. Iron sand base material obtained by processing the iron rocks by means of destruction and extraction. Iron rocks were taken from the village Surian, South Solok of West Sumatera. Iron sand that has been extracted reacted with HCL and NH<sub>4</sub>OH. Furthermore, the PEG-2000 were added to see its effect on the resulting magnetization saturation. Variations in the composition ratio of iron sand and PEG-2000 are 1:0, 1:1, 1:2 and 1:4. The crystal structure of the sample was confirm using x-ray diffraction method. Characterization of magnetic properties carried out using vibrating Sample Magnetometer (VSM). The results of magnetic properties show that the saturation magnetization decreases with increasing of PEG-2000 content in the range of 99.50emu/g - 0,84 emu/g.</p>

scholarly journals Effect of PEG-2000 on saturation magnetization Fe3O4 particles synthesized with coprecipitation method

2017 ◽  
Vol 1 (1) ◽  
pp. 49
Author(s):  
Dwi Puryanti ◽  
Dori Andani ◽  
Merry Thressia
Keyword(s):  
Magnetic Properties ◽  
Saturation Magnetization ◽  
Base Material ◽  
Diffraction Method ◽  
Coprecipitation Method ◽  
X Ray Diffraction ◽  
Magnetization Saturation ◽  
Sand Base ◽  
The Village

<p class="Abstract">Synthesis of Fe<sub>3</sub>O<sub>4</sub> particles was performed using coprecipitation method. Iron sand base material obtained by processing the iron rocks by means of destruction and extraction. Iron rocks were taken from the village Surian, South Solok of West Sumatera. Iron sand that has been extracted reacted with HCL and NH<sub>4</sub>OH. Furthermore, the PEG-2000 were added to see its effect on the resulting magnetization saturation. Variations in the composition ratio of iron sand and PEG-2000 are 1:0, 1:1, 1:2 and 1:4. The crystal structure of the sample was confirm using x-ray diffraction method. Characterization of magnetic properties carried out using vibrating Sample Magnetometer (VSM). The results of magnetic properties show that the saturation magnetization decreases with increasing of PEG-2000 content in the range of 99.50emu/g - 0,84 emu/g.</p>

scholarly journals Effect of Heating Temperature on Magnetic Properties of Fe3O4 Synthesized by Coprecipitation Method

2020 ◽  
Vol 12 (1) ◽  
pp. 11-15
Author(s):  
Dwi Puryanti
Keyword(s):  
Magnetic Properties ◽  
Raw Materials ◽  
Heating Temperature ◽  
Low Cost ◽  
Base Material ◽  
Diffraction Method ◽  
Coprecipitation Method ◽  
Effect Of Temperature ◽  
X Ray Diffraction ◽  
Recording Material

The synthesis of Fe3O4 nanoparticles with iron rock raw materials was carried out using a coprecipitation method. Iron rocks were taken from the Surian village, South Solok of West Sumatera. This research was conducted to utilize local materials and produce low cost, varied magnetic materials to be applied to the electric and electronics industries. Iron sand as a base material was obtained by processing the iron rocks through destruction and extraction. Iron sand that has been extracted is reacted with HCL and NH4OH. Furthermore, the PEG-2000 were added as a template to homogenize and inhibit the growth of particles. Heating temperature variation performed to see the effect of temperature on the magnetic properties of the particles. Heating temperature variations were used at 500 ̊C, 600 ̊C, and 700 ̊C. Phase composition of the samples were confirm using X-ray diffraction method. Characterization of magnetic properties carried out using Vibrating Sample Magnetometer (VSM). The results of magnetic properties show that the saturation magnetization decreases with increasing heating temperature in the range of 32.6883 emu/g, 20,1632 emu/g, and 10.4734 emu/g respectively. The value of coercive force, HC obtained in the range of 13,840 A/m – 19,120 A/m. The results show that Fe3O4 can be used as a magnetic recording material.

scholarly journals Green synthesis and characterization of hexaferrite strontium-perovskite strontium photocatalyst nanocomposites

2020 ◽  
Vol 43 (1) ◽  
pp. 26-42 ◽  
Author(s):  
Zahra Hajian Karahroudi ◽  
Kambiz Hedayati ◽  
Mojtaba Goodarzi
Keyword(s):  
Magnetic Properties ◽  
Green Synthesis ◽  
Sol Gel ◽  
Synthesis Method ◽  
Combustion Method ◽  
Lemon Juice ◽  
X Ray Diffraction ◽  
X Ray ◽  
Auto Combustion

AbstractThis study presents a preparation of SrFe12O19– SrTiO3 nanocomposite synthesis via the green auto-combustion method. At first, SrFe12O19 nanoparticles were synthesized as a core and then, SrTiO3 nanoparticles were prepared as a shell for it to manufacture SrFe12O19–SrTiO3 nanocomposite. A novel sol-gel auto-combustion green synthesis method has been used with lemon juice as a capping agent. The prepared SrFe12O19–SrTiO3 nanocomposites were characterized by using several techniques to characterize their structural, morphological and magnetic properties. The crystal structures of the nanocomposite were investigated via X-ray diffraction (XRD). The morphology of SrFe12O19– SrTiO3 nanocomposite was studied by using a scanning electron microscope (SEM). The elemental composition of the materials was analyzed by an energy-dispersive X-ray (EDX). Magnetic properties and hysteresis loop of nanopowder were characterized via vibrating sample magnetometer (VSM) in the room temperature. Fourier transform infrared spectroscopy (FTIR) spectra of the samples showed the molecular bands of nanoparticles. Also, the photocatalytic behavior of nanocomposites has been checked by the degradation of azo dyes under irradiation of ultraviolet light.

Magnetodielectric Ni ferrite ceramics with Bi2O3 additive for potential antenna miniaturizations

2009 ◽  
Vol 24 (2) ◽  
pp. 324-332 ◽  
Author(s):  
X.T. Liew ◽  
K.C. Chan ◽  
L.B. Kong
Keyword(s):  
Magnetic Properties ◽  
Dielectric Loss ◽  
Grain Growth ◽  
Sintering Temperature ◽  
Magnetic Loss ◽  
Liquid Phase Sintering ◽  
X Ray Diffraction ◽  
Low Dielectric ◽  
High Concentrations

This paper reports on the preparation and characterization of nickel ferrite (NiFe1.98O4) ceramics doped with Bi2O3 as sintering aid. Focus has been on the effects of concentration of Bi2O3 and sintering temperature on the densification, grain growth, dielectric, and magnetic properties of the NiFe1.98O4 ceramics, with an aim at developing magnetodielectric properties, with almost equal real permeability and permittivity, as well as sufficiently low magnetic and dielectric loss tangents, over 3 to 30 MHz (high frequency or HF band). X-ray diffraction results indicated that there is no obvious reaction between NiFe1.98O4 and Bi2O3, at Bi2O3 levels of up to 7 wt% and temperatures up to 1150 °C. The addition of Bi2O3 facilitated a liquid phase sintering mechanism for the densification of NiFe1.98O4 ceramics. The addition of Bi2O3 not only improved the densification but also promoted the grain growth of NiFe1.98O4 ceramics. To achieve sufficiently low dielectric loss tangent, the concentration of Bi2O3 should not be less than 5 wt%. The low dielectric loss tangents of the samples doped with high concentrations of Bi2O3 can be attributed to the full densification of the ceramics. Magnetic properties of the NiFe1.98O4 ceramics, as a function of sintering temperature and Bi2O3 concentration, can be qualitatively explained by the Globus model. Promising magnetodielectric properties have been obtained in the sample doped with 5% Bi2O3 and sintered at 1050 °C for 2 h. The sample has almost equal values of permeability and permittivity of ∼12, together with low dielectric and magnetic loss tangents, over 3 to 30 MHz. This material might be useful for the miniaturization of HF (3 to 30 MHz) antennas.

scholarly journals Characterization of Pr-Doped LaF3 Nanoparticles Synthesized by Different Variations of Coprecipitation Method

2019 ◽  
Vol 2019 ◽  
pp. 1-17 ◽  
Author(s):  
M. S. Pudovkin ◽  
D. A. Koryakovtseva ◽  
E. V. Lukinova ◽  
S. L. Korableva ◽  
R. Sh. Khusnutdinova ◽  
...  
Keyword(s):  
Electron Microscopy ◽  
Optical Spectroscopy ◽  
Coprecipitation Method ◽  
Luminescence Lifetime ◽  
X Ray Diffraction ◽  
X Ray ◽  
Transmission Electron ◽  
Hall Method ◽  
Stoichiometric Proportion

A set of Pr3+:LaF3 nanoparticles (NPs) were synthesized via coprecipitation method at three stoichiometric proportions of La(NO3)3, Pr(NO3)3, and NaF (1 : 0.8, 1 : 1, and 1 : 6, respectively). Two ways of mixing of the La(NO3)3, Pr(NO3)3, and NaF solutions (dropwise and swift addition) were used. One sample was subjected to microwave (MW) treatment for 30, 90, and 180 min. All the samples were characterized by transmission electron microscopy (TEM) and X-ray diffraction (XRD). For all the samples, optical spectroscopy experiments were carried out. The XRD data were analyzed via the Debye-Scherrer and Williamson-Hall methods. It was revealed that the way of mixing of the La(NO3)3, Pr(NO3)3, and NaF solutions strongly affects the shape of the NPs. The slow dropwise addition of the NaF solution leads to the plate-like NP (PLNP) formation; otherwise, the swift addition of the NaF solution leads to the formation of more sphere-like NPs (SLNPs). The size and regularity in shape of the NP increase with the increasing stoichiometric proportion of La(NO3)3, Pr(NO3)3, and NaF from 1 : 0.8 to 1 : 6. The size and regularity in shape of the SLNPs increase with the increasing time of MW treatment. The Debye-Scherrer and Williamson-Hall methods confirmed the anisotropic shape of the PLNPs. The Williamson-Hall method showed that the values of strain are almost similar for all the samples (around 14∗10-4). Optical spectroscopy experiments revealed that although all the samples have an equal chemical composition, the luminescence lifetimes for different samples differ between each other. The luminescence lifetime of the PLNPs is less than that of the SLNPs having an equal stoichiometric proportion of La(NO3)3, Pr(NO3)3, and NaF. The luminescence lifetime of the 1 : 1 SLNPs increases with the increasing time of MW treatment.

Mechanically Driven Alloying and Magnetic Properties in Immiscible Mn80Bi20 Nanocrystalline Powders

2013 ◽  
Vol 873 ◽  
pp. 217-220
Author(s):  
Min Xu ◽  
Qun Jiao Wang
Keyword(s):  
Magnetic Properties ◽  
Mechanical Alloying ◽  
Saturation Magnetization ◽  
Ball Milling ◽  
Solid Solubility ◽  
Milling Time ◽  
Early Stage ◽  
Nanocrystalline Powders ◽  
X Ray Diffraction ◽  
X Ray

The paper has described the formation of nanocrystalline Mn80Bi20powders by mechanical alloying and studied the changes of structure and magnetic properties of the powders during the process of ball milling by using X-ray diffraction and saturation magnetization σsmeasurements. The solid solubility of bismuth in manganese increases with milling time and tends to a stable value after 80h milling. The σsof Mn80Bi20increases abruptly with milling time at the early stage and begins to decrease after 15h. At the time of 15h, the σsreaches a maximum, which is about 7Am2/kg. The result shows an interesting information that the antiferromagnetic Mn and the diamagnetic Bi produce ferromagnetic Mn80Bi20in process of mechanical alloying.

Synthesis and Characterization of BiFeO3 Ceramic by Simple and Novel Methods

2016 ◽  
Vol 35 (6) ◽  
pp. 551-557 ◽  
Author(s):  
Omid Amiri ◽  
Mohammad Reza Mozdianfar ◽  
Mahmoud Vahid ◽  
Masoud Salavati-Niasari ◽  
Sousan Gholamrezaei
Keyword(s):  
Magnetic Properties ◽  
Domain Walls ◽  
Magnetic Domain ◽  
X Ray Diffraction ◽  
X Ray ◽  
Size Dependent ◽  
Magnetic Domain Walls ◽  
Magnetization Orientation ◽  
Thermal Stability Of

AbstractBiFeO3 nanopowders with new morphology have been synthesized by different methods. X-ray diffraction analysis, scanning electron microscopy, Fourier transform infrared and vibrating sample magnetometer were carried out at room temperature to study the structural and magnetic properties of as-synthesized products. VSM was utilized to measure the size-dependent magnetic behaviors of the as-prepared nanoparticles. Results show that the method has strong effect on the purity of the products. BFO synthesized by third method was pure. Crystallite size has a great effect on the magnetic properties. According to these results the nanoparticle diameter is smaller than the critical single-domain diameter, avoiding the configuration of magnetic domain walls decreases the magnetization. Even though the diameter of particle becomes even smaller, the thermal stability of the magnetization orientation decreases.

Synthesis and Characterization of Zinc Doped Hydroxyapatite for Bone Substitute Applications

2014 ◽  
Vol 660 ◽  
pp. 942-946
Author(s):  
Mohamad Firdaus Abdul Wahid ◽  
C.M. Mardziah ◽  
Koay Mei Hyie ◽  
N.R. Nik Roselina
Keyword(s):  
Crystal Size ◽  
Diffraction Method ◽  
Lattice Parameters ◽  
Phase Changes ◽  
Precipitation Method ◽  
Zinc Ions ◽  
Crystal Shape ◽  
X Ray Diffraction ◽  
X Ray

Hydroxyapatite was prepared by using precipitation method. The substitution of zinc ions in hydroxyapatite structure was studied by several characterization techniques. Several concentration of zinc ions were substituted into hydroxyapatite. Characterization technique such as X-ray diffraction method was used to study the phase changes and the lattice parameters with the addition of zinc. Field emission scanning electron microscopy was used to examine the influence of zinc on the crystal size and the morphology of the as-synthesized powders. Based on X-ray diffraction result, the addition of zinc affects the lattice parameters and phase. The result showed that zinc ions were substituted in the structure. As zinc substitution increased, the lattice parameters a and c decreased. The crystal shape of hydroxyapatite without zinc ions was regular shapes while hydroxyapatite with zinc ions was irregular and also tends to agglomerates with single particle was calculated about 28 - 34 nm .

scholarly journals Growth and Characterization of Pure and Doped L-Alanine Tartrate Single Crystals

2013 ◽  
Vol 2013 ◽  
pp. 1-5 ◽  
Author(s):  
K. Rajesh ◽  
B. Milton Boaz ◽  
P. Praveen Kumar
Keyword(s):  
Single Crystals ◽  
Vickers Microhardness ◽  
Diffraction Method ◽  
Dielectric Studies ◽  
X Ray Diffraction ◽  
X Ray ◽  
Cell Parameters ◽  
Ft Ir ◽  
Ft Ir Spectroscopy

Single crystals of pure and Lanthanum doped L-Alanine Tartrate were grown by slow evaporation method. The cell parameters were determined using single crystal X-ray diffraction method. To improve the physical properties of the LAT crystal, Lanthanum dopant was added by 2 mol%. ICP studies confirm the presence of Lanthanum in the grown LAT crystal. Transparency range of the crystal was determined using UV-VIS-NIR spectrophotometer. The functional groups of pure and doped LAT crystals were analyzed by FT-IR spectroscopy. Using Vickers microhardness tester, mechanical strength of the material was found. Dielectric studies of pure and doped LAT single crystals were carried out. The doped LAT crystal is found to have efficiency higher than that of pure LAT crystal.

scholarly journals Modification of the Magnetic Properties of Co2Y Hexaferrites by Divalent and Trivalent Metal Substitutions

2015 ◽  
Vol 241 ◽  
pp. 93-125 ◽  
Author(s):  
Sami H. Mahmood ◽  
Muna D. Zaqsaw ◽  
Osama E. Mohsen ◽  
Ahmad Awadallah ◽  
Ibrahim Bsoul ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Saturation Magnetization ◽  
Exchange Interactions ◽  
High Coercivity ◽  
Xrd Pattern ◽  
A Value ◽  
Type Phase ◽  
Ball Milling Technique ◽  
Xrd Patterns

The present study is concerned with the fabrication and characterization of Me2Y substituted hexaferrites, Ba2Me2Fe12-xTxO22(Me = Co2+, Mg2+, and Cr2+, and T = Fe3+, and Ga3+). The samples were prepared by the conventional ball milling technique and sintering at 1200° C. The effect of the choices of Me and T ions on the structural and magnetic properties of the hexaferrites were investigated. XRD patterns, magnetic parameters, and Mössbauer spectra of the Co2Y were consistent with a single phase Y-type hexaferrite. However, the CoCr-Y sample was found to be dominated by the Y-type hexaferrite, and M-type and BaCrO4minority phases were observed in the XRD pattern of the sample. The small increase in saturation magnetization from about 34 emu/g up to 37.5 emu/g was therefore attributed to the development of the M-type phase. On the other hand, XRD pattern of the Cr2Y sample indicated the dominance of the M-type phase in this sample. The high coercivity (1445 Oe) of this sample is evidence of the transformation of the material from a typically soft magnetic material (Y-type) to a hard magnet (M-type). The Ga-substitution for Fe in Co2Y did not affect the saturation magnetization significantly, but the coercivity was reduced. However, the sample Ba2CoMgFe11GaO22exhibited a significant reduction of the saturation magnetization down to a value 26.6 emu/g, which could be due to the attenuation of the super-exchange interactions induced by the Mg2+substitution.

Sign in / Sign up

Export Citation Format

Share Document