Effect of 2D Alpha-Zirconium Phosphate Nanosheets in Interfacial Tension Reduction and Wettability Alteration: Implications for Enhanced Oil Recovery

SPE Journal ◽  
2022 ◽  
pp. 1-13
Author(s):  
Song Qing ◽  
Hong Chen ◽  
Li-juan Han ◽  
Zhongbin Ye ◽  
Yihao Liao ◽  
...  
Keyword(s):  
Electron Microscopy ◽  
Interfacial Tension ◽  
Oil Recovery ◽  
Zirconium Phosphate ◽  
Contact Angle Measurement ◽  
Angle Measurement ◽  
Wettability Alteration ◽  
Tetrabutylammonium Hydroxide ◽  
Transmission Electron ◽  
2D Nanosheets

Summary α-Zirconium phosphate (α-ZrP) nanocrystals were synthesized by refluxing method and subsequently exfoliated into extremely thin 2D nanosheets by tetrabutylammonium hydroxide (TBAOH) solution. Dynamic light scattering, scanning electron microscopy (SEM), and transmission electron microscopy (TEM) were used to characterize the size distribution and morphology of α-ZrP nanosheets. Interfacial tension (IFT) and contact angle measurement were conducted by different concentrations of α-ZrP nanosheets solutions. The results displayed that the wettability of porous media surface was altered from oleophilic to hydrophilic and the IFT decreased with the increasing of α-ZrP nanosheets concentrations. A new method was proposed to calculate the Hamaker constant for 2D α-ZrP nanosheets. The calculated results displayed that α-ZrP nanosheets were not easy to agglomerate under experimental environment and when the interaction energy barrier increased, the transport amount of α-ZrP nanosheets also increased. Coreflooding tests were also performed with various concentrations and the oil recovery efficiency increased from 33.59 to 51.26% when α-ZrP nanosheets concentrations increased from 50 to 1,000 ppm.

scholarly journals Experimental and modeling study of wettability alteration through seawater injection in limestone: a case study

2020 ◽  
Vol 17 (3) ◽  
pp. 749-758
Author(s):  
Omolbanin Seiedi ◽  
Mohammad Zahedzadeh ◽  
Emad Roayaei ◽  
Morteza Aminnaji ◽  
Hossein Fazeli
Keyword(s):  
Oil Recovery ◽  
Contact Angle Measurement ◽  
Angle Measurement ◽  
Carbonate Reservoirs ◽  
Water Flooding ◽  
Wettability Alteration ◽  
Rock Surface ◽  
Indirect Contact ◽  
Molecular Kinetic Theory ◽  
Wet Condition

AbstractWater flooding is widely applied for pressure maintenance or increasing the oil recovery of reservoirs. The heterogeneity and wettability of formation rocks strongly affect the oil recovery efficiency in carbonate reservoirs. During seawater injection in carbonate formations, the interactions between potential seawater ions and the carbonate rock at a high temperature can alter the wettability to a more water-wet condition. This paper studies the wettability of one of the Iranian carbonate reservoirs which has been under Persian Gulf seawater injection for more than 10 years. The wettability of the rock is determined by indirect contact angle measurement using Rise in Core technique. Further, the characterization of the rock surface is evaluated by molecular kinetic theory (MKT) modeling. The data obtained from experiments show that rocks are undergoing neutral wetting after the aging process. While the wettability of low permeable samples changes to be slightly water-wet, the wettability of the samples with higher permeability remains unchanged after soaking in seawater. Experimental data and MKT analysis indicate that wettability alteration of these carbonate rocks through prolonged seawater injection might be insignificant.

UV-Durable Superhydrophobic Textiles with UV-Shielding Property by Coating Fibers with ZnO/SiO2 Core/Shell Particles

2012 ◽  
Vol 441 ◽  
pp. 351-355 ◽  
Author(s):  
Chao Hua Xue ◽  
Wei Yin ◽  
Shun Tian Jia ◽  
Jian Zhong Ma
Keyword(s):  
Electron Microscopy ◽  
Contact Angle Measurement ◽  
Angle Measurement ◽  
Core Shell ◽  
Uv Shielding ◽  
Transmission Electron ◽  
Blocking Property ◽  
Poly Ethylene ◽  
Shell Particles ◽  
Surface Morphologies

ZnO/SiO2 core/shell particles were fabricated and coated on poly (ethylene terephthalate) (PET) textiles, followed by hydrophobization with hexadecyltrimethoxysilane, to achieve superdrophobic surfaces with UV-shielding property. Transmission electron microscopy (TEM) was employed to reveal the fabrication of ZnO/SiO2 core/shell particles. Scanning electron microscopy (SEM) was conducted to investigate the surface morphologies of the textile and the coating of the fibers. UV-Vis spectrophotometry and contact angle measurement indicated that the incorporation of ZnO onto fibers imparted UV-blocking property to the textile surface, while the coating of SiO2 shell on ZnO made the superhydrophobicity of the as-treated PET textile surface UV-durable.

The Application of Nanoparticles in Enhancing Oil Recovery by Wettability Alteration

2015 ◽  
Vol 1120-1121 ◽  
pp. 369-377 ◽  
Author(s):  
Jia Feng Jin ◽  
Yan Ling Wang ◽  
Fei Liu
Keyword(s):  
Crude Oil ◽  
Solid Surface ◽  
Oil Recovery ◽  
Contact Angle Measurement ◽  
Contact Angles ◽  
Angle Measurement ◽  
Solid Surfaces ◽  
Wettability Alteration ◽  
Spreading Behavior ◽  
Conventional Surfactant

Wettability is one of most important characteristics for governing the flow and distribution of reservoir fluids in the porous media,the wetting and spreading behavior of liquids on the solid surfaces changes if the wettability of solid surface is altered. Recent studies show the spreading behavior of liquids on solid surface can be significantly improved after nanofluid treatment. In order to investigate the influence of wettability alternation on enhancing oil recovery after nanofluid treatment,flushing oil experiment and contact angle measurement were conducted in the laboratory. The first experiment involved flushing crude oil with the nanofluid and conventional surfactants, respectively. In the second case, the contact angles of oil phase in nanofluid (conventional surfactant solutions)-crude oil-slide systems were measured after treating 36 hours. The results indicated that nanofluid can produce a better flushing efficiency compared with that of conventional surfactant, and the contact angles of oil phase increased from 33° to 118° after nanofluid treatment in nanofluid/crude-oil/slide system. The mechanism of enhanced oil recovery of nanofluid is mainly wettability alternation.

scholarly journals Mechanism of active silica nanofluids based on interface-regulated effect during spontaneous imbibition

2021 ◽  
Author(s):  
Xu-Guang Song ◽  
Ming-Wei Zhao ◽  
Cai-Li Dai ◽  
Xin-Ke Wang ◽  
Wen-Jiao Lv
Keyword(s):  
Contact Angle ◽  
Interfacial Tension ◽  
Oil Recovery ◽  
Dynamic Contact Angle ◽  
Liquid Interface ◽  
Spontaneous Imbibition ◽  
Wettability Alteration ◽  
Low Permeability ◽  
Oil Water ◽  
Solid Liquid

AbstractThe ultra-low permeability reservoir is regarded as an important energy source for oil and gas resource development and is attracting more and more attention. In this work, the active silica nanofluids were prepared by modified active silica nanoparticles and surfactant BSSB-12. The dispersion stability tests showed that the hydraulic radius of nanofluids was 58.59 nm and the zeta potential was − 48.39 mV. The active nanofluids can simultaneously regulate liquid–liquid interface and solid–liquid interface. The nanofluids can reduce the oil/water interfacial tension (IFT) from 23.5 to 6.7 mN/m, and the oil/water/solid contact angle was altered from 42° to 145°. The spontaneous imbibition tests showed that the oil recovery of 0.1 wt% active nanofluids was 20.5% and 8.5% higher than that of 3 wt% NaCl solution and 0.1 wt% BSSB-12 solution. Finally, the effects of nanofluids on dynamic contact angle, dynamic interfacial tension and moduli were studied from the adsorption behavior of nanofluids at solid–liquid and liquid–liquid interface. The oil detaching and transporting are completed by synergistic effect of wettability alteration and interfacial tension reduction. The findings of this study can help in better understanding of active nanofluids for EOR in ultra-low permeability reservoirs.

Preparation of TiO2–SiO2 Hybrid Nanosols Coated Flame-Retardant Polyester Fabric Possessing Dual Contradictory Characteristics of Superhydrophobicity and Self Cleaning Ability

2020 ◽  
Vol 20 (3) ◽  
pp. 1780-1789 ◽  
Author(s):  
Priyanka Katiyar ◽  
Shraddha Mishra ◽  
Anurag Srivastava ◽  
N. Eswara Prasad
Keyword(s):  
Electron Microscopy ◽  
Contact Angle ◽  
Flame Retardant ◽  
Protective Clothing ◽  
Sol Gel ◽  
Contact Angle Measurement ◽  
Angle Measurement ◽  
Water Contact ◽  
Vis Spectroscopy ◽  
Self Cleaning

TiO2, SiO2 and their hybrid nanocoatings are prepared on inherent flame retardant textile substrates from titanium(IV)iso-proproxide (TTIP) and tetraethoxysilane (TEOS) precursors using a sol–gel process followed by hydrothermal treatment. The coated samples are further functionalized by hexadecyltrimethoxysilane (HDTMS) to impart superhydrophobicity. Sample characterization of the nanosols, nanoparticles and coated samples are investigated using, X-ray diffractometer, transmission electron microscopy, scanning electron microscopy, UV-Vis spectroscopy, contact angle measurement. Stain degradation test under mild UV irradiation shows almost 54% degradation of coffee stain within 4 hours measured by Spectrophotometer. UV-Vis Absorption Spectroscopy demonstrates complete degradation of methyl orange colorant within 3 hours. Hybrid nanosol coated and HDTMS modified inherent flame retardant polyester surfaces show apparent water contact angle as ~145°, which is much closer to proximity of superhydrophobic surfaces. Thus, the novelty of present work is, by using sol–gel technique, a bi-functional textile surface has been developed which qualifies the very specific requirements of protective clothing like self-cleaning property (imparted by TiO2 nanoparticles) and superhydrophobicity (imparted by SiO2 nanoparticles and further surface modification by HDTMS), which are entirely contradictory in nature, in a single fabric itself. Thus developed textile surfaces also possess the other attributes of protective clothing like flame retardancy and air permeability.

Experimental investigation of the effect of green TiO2/Quartz nanocomposite on interfacial tension reduction, wettability alteration, and oil recovery improvement

Fuel ◽  
2020 ◽  
Vol 263 ◽  
pp. 116599 ◽  
Author(s):  
Ghasem Zargar ◽  
Tooraj Arabpour ◽  
Abbas Khaksar Manshad ◽  
Jagar A. Ali ◽  
S. Mohammad Sajadi ◽  
...  
Keyword(s):  
Experimental Investigation ◽  
Interfacial Tension ◽  
Oil Recovery ◽  
Wettability Alteration ◽  
Tension Reduction
Sign in / Sign up

Export Citation Format

Share Document