scholarly journals Experimental Study on Pore Structure and Gas Desorption Characteristics of a Low Rank Coal: Impact of Moisture

Author(s):  
Ming-yi Chen ◽  
Ya-pu Yang ◽  
Xiao-yun Chen ◽  
Fu-chao Tian ◽  
Wei-li Sun ◽  
...  

Abstract Coal and gas outburst is one of the most serious disasters for underground coal mining. The water adsorbed on coal can leads to that the pore structure of moist coal is different from that of dry coal, thereby affecting methane desorption characteristics of coal for the outburst risk prediction. In this paper, the impact of moisture on pore structure and methane desorption performance were investigated. The analysis on low-temperature nitrogen gas adsorption tests show that the micropores (pore diameter < 10 nm) are most affected by the adsorbed water. In particular, for water-equilibrated coal sample at 98% relatively humidity, the micropores less than 4 nm analyzed by DFT pore size distributions almost disappear probably due to the blocking effect of the formed water clusters and capillary water. In this case, the micropores can still contributes most sites for gas adsorption. Furthermore, the fractal dimension at relative pressure of 0–0.5 (D1) and 0.5–1 (D2) calculated by the Frenkel-Halsey-Hill model indicates that, when moisture content is less than 4.74%, D1 decreases rapidly while D2 shows a slight change; whereas, further increases in moisture content results in that D2 decreases significantly and D1 remains at about 2.32. Further investigation shows that, below the equilibrium moisture content, the ultimate desorption volume (A) and initial desorption rate (V0) are closely related to D1, while the desorption constant (Kt) mainly depends on D2. Therefore, the adsorbed moisture has significant negative impact on methane desorption performances by affecting characteristics of coal’s pores.

Energies ◽  
2019 ◽  
Vol 12 (11) ◽  
pp. 2094 ◽  
Author(s):  
Yujie Yuan ◽  
Reza Rezaee

Porosity and pore size distribution (PSD) are essential petrophysical parameters controlling permeability and storage capacity in shale gas reservoirs. Various techniques to assess pore structure have been introduced; nevertheless, discrepancies and inconsistencies exist between each of them. This study compares the porosity and PSD in two different shale formations, i.e., the clay-rich Permian Carynginia Formation in the Perth Basin, Western Australia, and the clay-poor Monterey Formation in San Joaquin Basin, USA. Porosity and PSD have been interpreted based on nuclear magnetic resonance (NMR), low-pressure N2 gas adsorption (LP-N2-GA), mercury intrusion capillary pressure (MICP) and helium expansion porosimetry. The results highlight NMR with the advantage of detecting the full-scaled size of pores that are not accessible by MICP, and the ineffective/closed pores occupied by clay bound water (CBW) that are not approachable by other penetration techniques (e.g., helium expansion, low-pressure gas adsorption and MICP). The NMR porosity is largely discrepant with the helium porosity and the MICP porosity in clay-rich Carynginia shales, but a high consistency is displayed in clay-poor Monterey shales, implying the impact of clay contents on the distinction of shale pore structure interpretations between different measurements. Further, the CBW, which is calculated by subtracting the measured effective porosity from total porosity, presents a good linear correlation with the clay content (R2 = 0.76), implying that our correlated equation is adaptable to estimate the CBW in shale formations with the dominant clay type of illite.


2017 ◽  
Vol 36 (3-4) ◽  
pp. 904-918 ◽  
Author(s):  
Deyong Guo ◽  
Xiaojie Guo

In this paper, scanning electron microscopy, low-temperature N2 adsorption and CH4 isothermal adsorption experiments were performed on 11 coal samples with Ro,max between 0.98 and 3.07%. The pore structure characteristics of coals (specific surface area, total volume distribution) were studied to assess the gas adsorption capacity. The results indicate that there is significant heterogeneity on coal surface, containing numerous channel-like pores, bottle-shaped pores and wedge-shaped pores. Both Langmuir volume (VL) and Langmuir pressure (PL) show a stage change trend with the increase of coalification degree. For different coalification stages, there exist different factors influencing the VL and PL values. For low-rank coals (Ro,max < 1.1%), the increase of VL values and decrease of PL values are mainly due to the abundant primary pore and fracture within coal. For middle-rank coals (1.1% < Ro,max < 2.1%), the moisture content, vitrinite content and total pore volume are all the factors influencing VL, and the reduction of PL is mainly attributed to the decrease of moisture content and inertinite content. Meanwhile, this result is also closely related to the pore shape. For high-rank coals (Ro,max > 2.1%), VL values gradually increase and reach the maximum. When the coal has evolved into anthracite, liquid hydrocarbon within pore begins pyrolysis and gradually disappears, and a large number of macropores are converted into micropores, leading to the increase of specific surface area and total pore volume, corresponding to the increase of VL. In addition, the increase of vitrinite content within coal also contributes to the increase of VL. PL, reaches the minimum, indicating that the adsorption rate reaches the largest at the low pressure stage. The result is mainly controlled by the specific surface area and total pore volume of coal samples. This research results will provide a clearer insight into the relationship between adsorption parameters and coal rank, moisture content, maceral composition and pore structure, and it is of great significance for better assessing the gas adsorption capacity.


2021 ◽  
Vol 21 (1) ◽  
pp. 22-42
Author(s):  
Xiangchun Li ◽  
Zhongbei Li ◽  
Fan Zhang ◽  
Qi Zhang ◽  
Baisheng Nie ◽  
...  

Based on gas adsorption theory, high-pressure mercury intrusion (HPMI), low-temperature liquid nitrogen gas adsorption (LT-N2GA), CO2 adsorption, scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR) and small-angle X-ray scattering (SAXS) techniques were used to analyze the pore structures of six coal samples with different metamorphisms in terms of pore volume, specific surface area (SSA), pore size distribution (PSD) and pore shape. Combined with the gas adsorption constant a, the influence and mechanism of the pore structure of different coal ranks on gas adsorption capacity were analyzed. The results show that there are obvious differences in the pore structure of coals with different ranks, which leads to different adsorption capacities. To a large extent, the pore shapes observed by SEM are consistent with the LT-N2GA isotherm analysis. The pore morphology of coal samples with different ranks is very different, indicating the heterogeneity among the coal surfaces. Adsorption analysis revealed that mesopore size distributions are multimodal and that the pore volume is mainly composed of mesopores of 2–15 nm. The adsorption capacity of the coal body micropores depends on the 0.6–0.9 nm and 1.5–2.0 nm aperture sections. The influence of coal rank on gas desorption and diffusion is mainly related to the difference in pore structure. The medium metamorphic coal sample spectra show that the number of peaks in the high-wavenumber segment is small and that it is greater in the high metamorphic coal. The absorption intensity of the C–H stretching vibration peak of naphthenic or aliphatic hydrocarbons varies significantly among the coal samples. Over a small range of angles, as the scattering angle increases, the scattering intensity of each coal sample gradually decreases, and as the degree of metamorphism increases, the scattering intensity gradually increases. That is, the degree of metamorphism of coal samples is directly proportional to the scattering intensity. The influence of coal rank on gas adsorption capacity is mainly related to the difference in pore structure. The gas adsorption capacity shows an asymmetric U-shaped relationship with coal rank. For higher rank coals (Vdaf < 15%), the gas adsorption consistently decreases significantly with increasing Vdaf. In the middle and low rank coal stages (Vdaf > 15%), it increases slowly with the increase of Vdaf. We believe that the results of this study will provide a theoretical basis and practical reference value for effectively evaluating coal-rock gas storage capacity, revealing the law of CBM enrichment and the development and utilization of CBM resources.


Fuel ◽  
2021 ◽  
Vol 293 ◽  
pp. 120465
Author(s):  
Chao Zheng ◽  
Dongmin Ma ◽  
Yue Chen ◽  
Zheng Gao ◽  
Jinxiang Teng

Resources ◽  
2020 ◽  
Vol 9 (9) ◽  
pp. 111
Author(s):  
Barbara Bielowicz ◽  
Jacek Misiak

In this paper, we discuss the impact of the rank of coal, petrographic composition, and physico-chemical coal properties on the release and composition of syngas during coal gasification in a CO2 atmosphere. This study used humic coals (parabituminous to anthracite) and lithotypes (bright coal and dull coal). Gasification was performed at temperatures between 600 and 1100 °C. It was found that the gas release depends on the temperature and rank of coal, and the reactivity increases with the increasing rank of coal. It was shown that the coal lithotype does not affect the gas composition or the process. Until 900 °C, the most intense processes were observed for higher rank coals. Above 1000 °C, the most reactive coals had a vitrinite reflectance of 0.5–0.6%. It was confirmed that the gasification of low-rank coal should be performed at temperatures above 1000 °C, and the reactivity of coal depends on the petrographic composition and physico-chemical features. It was shown that inertinite has a negative impact on the H2 content; at 950 °C, the increase in H2 depends on the rank of coal and vitrinite content. The physicochemical properties of coal rely on the content of maceral groups and the rank of coal. An improved understanding these relationships will allow the optimal selection of coal for gasification.


2015 ◽  
Vol 26 (3-4) ◽  
pp. 116-123
Author(s):  
A. P. Korzh ◽  
T. V. Zahovalko

Recently, the number of published works devoted to the processes of synanthropization of fauna, is growing like an avalanche, which indicates the extreme urgency of this theme. In our view, the process of forming devices to coexist with human and the results of his life reflects the general tandency of the modern nature evolution. Urbanization is characteristic for such a specific group of animals like amphibians, the evidence of which are numerous literature data. Many researchers use this group to assess the bioindicative quality of the environment. For this aim a variety of indicators are used: from the cellular level of life of organization up to the species composition of the group in different territories. At the same time, the interpretation of the results is not always comparable for different areas and often have significantly different interpretations by experts. Urban environment, primarily due to the contamination is extremely aggressive to amphibians. As a consequence, the urban populations of amphibians may be a change in the demographic structure, affecting the reproductive ability of the population, the disappearance of the most sensitive species or individuals, resizing animals, the appearance of abnormalities in the development, etc. At the same time play an important amphibians in the ecosystems of cities, and some species in these conditions even feel relatively comfortable. Therefore, it is interesting to understand the mechanisms of self-sustaining populations of amphibians in urban environments. To assess the impact of natural and anthropogenic factors on the development of amphibian populations were used cognitive modeling using the program Vensim PLE. Cognitive map of the model for urban and suburban habitat conditions were the same. The differences concerned the strength of connections between individual factors (migration, fertility, pollution) and their orientation. In general, factors like pollution, parasites, predators had negative impact on the population, reducing its number. The birth rate, food and migration contributed to raising number of individuals. Some of the factors affected on the strength to of each other as well: the majority of the factors affected the structure of the population, had an influence on the fertility. Thanks to it the model reflects the additive effect of complex of factors on the subsequent status of the population. Proposed and analyzed four scenarios differing strength and duration of exposure. In the first scenario, a one-time contamination occurs and not subsequently repeated. The second and third scenario assumes half board contamination, 1 year (2 scenario) and two years (scenario 3). In the fourth scenario, the pollution affected the population of amphibians constantly. In accordance with the results of simulation, much weaker than the natural populations respond to pollution - have them as an intensive population growth and its disappearance at constant pollution is slow. Changes to other parameters of the model showed that this pollution is the decisive factor -only the constant action leads to a lethal outcome for the populations. All other components of the model have a corrective effect on the population dynamics, without changing its underlying trand. In urban areas due to the heavy impact of pollution maintaining the population is only possible thanks to the migration process – the constant replenishment of diminishing micropopulations of natural reserves. This confirms the assumption that the form of existence metapopulations lake frog in the city. In order to maintain the number of amphibians in urban areas at a high level it is necessary to maintain existing migration routes and the creation of new ones. Insular nature of the placement of suitable habitats in urban areas causes the metapopulation structure of the types of urbanists. Therefore, the process of urbanization is much easier for those species whicht are capable of migration in conditions of city. In the initial stages of settling the city micropopulationis formed by selective mortality of the most susceptible individuals to adverse effects. In future, maintaining the categories of individuals is provided mainly due to migration processes metapopulisation form of the species of existence is supported). It should be noted that the changes in the previous levels are always saved in future. In the case of reorganizations of individuals we of morphology can assume the existence of extremely adverse environmental conditions that threaten the extinction of the micropopulations. 


2020 ◽  
Vol 8 (3) ◽  
pp. 3-17
Author(s):  
Elena Blagoeva

The impact of the last global economic crisis (2008) on the European economy put a strain on higher education (HE), yet it also pushed the sector towards intensive reforms and improvements. This paper focuses on the “Strategy for the Development of Higher Education in the Republic of Bulgaria 2014-2020”. With a case study methodology, we explore the strategic endeavours of the Bulgarian government to comply with the European directions and to secure sustainable growth for the HE sector. Our research question is ‘How capable is the Bulgarian HE Strategy to overcome the economic and systemic restraints of Bulgarian higher education?’. Because the development of strategies for HE within the EU is highly contextual, a single qualitative case study was chosen as the research approach. HE institutions are not ivory towers, but subjects to a variety of external and internal forces. Within the EU, this is obviated by the fact that Universities obtain their funds from institutions such as governments, students and their families, donors, as well as EU-level programmes. Therefore, to explore how these pressures interact to affect strategic action on national level, the case method is well suited as it enabled us to study the phenomena thoroughly and deeply. The paper suggests the actions proposed within the Strategy have the potential to overcome the delay, the regional isolation and the negative impact of the economic crisis on the country. Nevertheless, the key elements on which the success or failure of this Strategy hinges are the control mechanisms and the approach to implementation. Shortcomings in these two aspects of strategic actions in HE seem to mark the difference between gaining long-term benefits and merely saving face in front of international institutions.


1997 ◽  
Vol 36 (4II) ◽  
pp. 947-957 ◽  
Author(s):  
Shahrukh Rafi Khan

This paper has a two-fold objective: first, to examine the terms on which Pakistan receives aid and whether its debt situation is sustainable, and second, to examine the impact of aid and debt on economic growth. It is found that there is little encouraging that can be said about how the terms on which Pakistan has received aid over time have changed, and its current debt situation is not sustainable. Also reported is the analysis done elsewhere which shows that aid has a negative (Granger) causal impact on GDP, and aid has a robust negative impact on economic growth after controlling for supplyside shocks. We provide various reasons for this negative association.


Author(s):  
Ajeng Embri Legawati ◽  
Nur Azizah ◽  
Achmad Ramadhan

Green beans cultivation technology using mice pets control has been implemented in the Gluranploso village, Benjeng Gresik. The implementation of the technology performed for 2.5 months from August to October 2017. The purpose of the implementation is aimed to reduce the dependence of farmers on the use of chemical pesticides so that the farmers are aware of the negative impact of chemical pesticides. Assessing the impact of the utilization of Bintaro fruit and fruit extracts to explore ways of making Bintaro as a natural biopesticide to overcome rat attack on green bean plants in the Gluranploso village. Pest control mice can reduce the rate of loss of the crops more effectively and efficiently. Finally, with the use of those natural resources as a biopesticide material can also maintain the environmental balance


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