Ancient acid rains in Ediacaran – an alternative story for sulfate sedimentation
Abstract Vast deposits of anhydrite and magnesite widely distributed in Ediacaran strata of East Siberia near the Riphean unconformity. Anhydrite-rich rocks are not look like of evaporitic origin find mostly nodules and the layers of chicken-wire structure otherwise disseminated as tiny sulfate forms amongst the terrigenous rocks. Here we propose an alternative point of view for anhydrite appearance – the enrichment of Sulphur because of the slashing increase the content of sulfur in the Ediacaran atmosphere due to high volcanic activity. It is suggested that the ancient Earth's atmosphere could have also been influenced by powerful sulfuric acid rains that eroded the Precambrian dolomites causing their aggressive degradation. Chemical reactions with dolomite and sulfuric acid showed that in the early stages an unstable phase of bassanite occur which later stabilized as anhydrite after its heating as an analogue of aging. Aggressive acids have caused global process of dolomite karstification of the Siberian craton with appearance in Ediacaran strata in addition to the sulfate phases, including magnesite and sulphurous phases of pyrite and barite.