scholarly journals Geochemistry pollution status and ecotoxicological risk assessment of heavy metals in the Pahang River sediment after the high magnitude of flood event

2020 ◽  
Author(s):  
K. Y. Lim ◽  
N. A. Zakaria ◽  
K. Y. Foo

Abstract The present work is aimed at assessing the aftermath effects of the 2014 flood tragedy on the distribution, pollution status and ecological risks of the heavy metals deposited in the surface river sediment. A series of environmental pollution indexes, specifically the enrichment factor (EF), geo-accumulation index (Igeo), contamination factor (CF), modified degree of contamination (mCd), pollution load index (PLI), potential ecological risk index (PERI) and sediment quality guidelines (SQGs) have been adopted. Results revealed that the freshly deposited sediments collected soon after the flood event were dominated by Cu, Fe, Pb, Ni, Zn, Cr and Cd, with the average concentrations of 38.74, 16,892, 17.71, 4.65, 29.22, 42.36 and 0.29 mg/kg, respectively. According to the heavy metal pollution indexes, Pahang River sediments were moderately to severely contaminated with Pb, Ni, Cu, Zn and Cr, while Cd with the highest risk of 91.09 was the predominant element that illustrated an aesthetic ecological risk to the water body after the tragic flood event. The findings highlighted a critical deterioration of the heavy metals content, driven by the catastrophic flood event, which has drastically altered their geochemical cycles, sedimentary pollution status and biochemical balance of the river's environment.

2011 ◽  
Vol 137 ◽  
pp. 262-268 ◽  
Author(s):  
Guo Tao Liu ◽  
Xiao Yan Zheng ◽  
Xu Ya Peng ◽  
Jian Hua Li

The concentrations of heavy metals (Cu, Zn, Pb, Cd, Ni, Cr, As) in the surface sediment of Liangtan River were determined by using atomic absorption spectrometry (AAS) and atomic fluorescence spectrometry (AFS), and the toxic effects and sediment pollution assessment were conducted systematically by using Sediment Quality Guidelines (SQG), Hakanson Potential Ecological Risk Index. Moreover, the underlying source of heavy metal was analyzed. The results indicated that the concentrations of Cu, Zn, Pb, Cd, Ni, Cr, As were 29.4-158.1, 40.2-291.3, 23.4-148.2, 0.01-0.79, 6.4-106.2, 17.9-170.6, 1.3-45.1mg/kg respectively. Base on the SQG, besides Cd concentrations of few sampling sites were above the threshold effects level (TEL), the rest heavy metal concentrations of most sampling sites were all between TEL and the probable effects level (PEL), and biological toxicity effects may take place, especially Baishiyi, Hangu and Huilongba, harmful biological toxicity effects may frequently take place. Compared to background values of soil heavy metals in the Three Gorges Reservoir Region, the heavy metals in Liangtan River sediments showed higher ecological risk, and the ecological risk of the heavy metals, arranged from the highest to lowest pollution degree, was as follows Cd, As, Cu, Pb, Ni, Zn, Cr.


2020 ◽  
Vol 20 (2) ◽  
pp. 77-85
Author(s):  
S. A. Ndur ◽  
S. Y. Nyarko ◽  
I. Quaicoe ◽  
L. B. Osei

Sediment contamination by heavy metals resulting from anthropogenic activities is increasingly becoming a global concern due to the risk it poses to human well-being and ecological integrity at large. The purpose of this study was to assess the heavy metals loading in sediment along the Kawere stream. Ten sediment samples were collected, acid digested and analysed for copper (Cu), lead (Pb), cadmium (Cd), manganese (Mn), zinc (Zn), nickel (Ni), chromium (Cr), cobalt (Co) and iron (Fe) using a Varian AA240FS Atomic Absorption Spectrometer (AAS). The Australian and New Zealand Environment and Conservation Council (ANZECC) guidelines for freshwater sediment quality was used as the benchmark against which the measured metal concentrations were compared. Nemerow’s pollution and potential ecological risk indices were used to evaluate the pollution status and ecological risk levels of the heavy metals in the stream. The results obtained indicated that, except Cu which exceeded the ANZECC trigger value of 65 mg/kg at three sampling sites (K01=171.29 mg/kg, K05=170.83 mg/kg and K07=113.31 mg/kg), all other measured heavy metals concentrations were below their corresponding ANZECC values. Heavy metal pollution assessment showed that three samples (K01, K05 and K07) were slightly polluted, suggesting the likelihood of posing a health threat to the aquatic organisms and humans. Calculated Ecological Risk Index (RI) ranged from 3.229 to 19.750 (RI < 150), representing a low ecological risk. As such, the metals, Cu, Ni, Cd, Pb, Cr, and Zn pose a low ecological risk to the aquatic ecosystem. Although the ecological risk is low based on the current results, constant monitoring of the stream quality is recommended due to the increasing human activities along the stream as well as the sediments ability to accumulate and remobilise heavy metals back into the water column and possibly transferring them through the food chain.   Keywords: Heavy Metals, Sediment, Ecological Risk Assessment, Pollution, Stream


2020 ◽  
Vol 8 (1) ◽  
pp. 89 ◽  
Author(s):  
Kalimur Rahman ◽  
Saurav Barua ◽  
Fahim Ahammad ◽  
Md. Akramul Alam

The Shitalakya River, located near Dhaka City of Bangladesh, supplies water to the city dwellers and hence it is essential to determine pollu-tion condition, ecological risk and sources of heavy metals in the river sediments. Sediment works as the sink and source of heavy metals in the riverine ecosystem. The samples collected from the ten sites of the Shitalakhya River were investigated in the study. Average concentra-tion of different heavy metals in the sediments are Cu>Zn>Ni>Pb>Cr>Cd. Geo-accumulation index reveals moderately pollute Cu concen-tration, unpolluted to moderately pollute Ni concentration and unpolluted for the rest of the heavy metals. The order of geo-accumulation index are Cu>Ni>Pb>Cd>Zn>Cr. Overall, the heavy metals render low potential ecological risk and the order of potential ecological risk index are Cd>Cu>Ni>Pb>Cr>Zn. Though the concentration of Cd is low in sediment, it poses higher ecological risk. Positive matrix factor-ization (PMF) identifies two sources of pollution, S1 and S2. Where, S1 consists with Cu, Ni, Pb, Zn; which come from industrial wastewater. S2 consists with Cr, Cd, Pb, Zn; which originate from natural sources. The outcomes of the study provide as a reference to plan, control and manage heavy metal pollution and protect the water source of the Shitalakhya River.    


2013 ◽  
Vol 726-731 ◽  
pp. 1809-1812
Author(s):  
Ji Cai Qiu

To find out the heavy metal pollution condition from the Beng River sediment, we see the region from Beng River Rubber Dam to the Yimeng Road Bridge as research object.We monitored and surveyed on the three kinds of metal components (Cu, Zn, Cd) in the sediments from eight sectionsthe. With reference to the relevant domestic standards, we established sediment pollution evaluation criteria suitable for the region., We conducted the evaluation of ecological risk and pollution levels with the detection results by standard index of the potential ecological risk index and Nemerow France France. The results showed that: the heavy metals ecological risk index in Sediment from Beng River Rubber Dam to the Yimeng Road bridge section, Nemerow pollution index was 6.95, It was heavily polluted. This showed that the heavy metals in river sediment pollution was very serious.


2020 ◽  
Author(s):  
Nhung Thi Ha Pham ◽  
Izabella Babcsányi ◽  
Andrea Farsang

&lt;p&gt;The soil utilized for grape growing not only has faced the pollution problems but also could be suffered ecological risk by heavy metals from chemical fertilizers and Cu-fungicides. H&amp;#233;tsz&amp;#337;l&amp;#337; vineyard (1.4 ha) with an alkaline reaction in soil (the average soil pH of the 0-10 cm soil layer was 8.02), which is located along and on the southern slope of Tokaj-hill, Tokaj-Hegyalja, Hungary was chosen as study area of this study. The total concentration of heavy metals, enrichment factors (EFs), pollution load index (PLI) and contamination factor (CF) were used to assess the current status and pollution degree of heavy metals in vineyard soil. Besides, the potential ecological risk would be evaluated via the ecological risk factor (Ei) of an individual metal (Zn, Pb, Co, Ni, Cr, Cu) and the potential ecological risk index (PER) of all studied metals.&lt;/p&gt;&lt;p&gt;Analysis results showed that all of the heavy metals had lower total contents on average compared with the Hungarian background and pollution limits (Joint Decree (6/2009. (IV. 14) KvVM-E&amp;#252;M-FVM and 10/2000. (VI. 2) K&amp;#246;M-E&amp;#252;M-FVM-KHVM), except for Cu (36.19 mg/kg), Ni (36.50 mg/kg) and Cr (60.26 mg/kg). Thus, the topsoil of H&amp;#233;tsz&amp;#337;l&amp;#337; vineyard in Tokaj was contaminated by Ni, Cr, and Cu at a moderate level. EF analysis (Sc as reference element) reflected that Cu (EF = 2.70) was enriched moderately, in contrast Zn (EF = 1.22), Pb (EF = 1.05), Co (EF = 1.00) were not enriched in the vineyard topsoils. Although EF of Ni and Cr obtained at Tokaj were 1.66 and 2.30 respectively, EF&lt;sub&gt;min&lt;/sub&gt; of these studied metals were around 1 and they EF&lt;sub&gt;max &lt;/sub&gt;were higher than 2 demonstrated that these elements were enriched at some positions. The general assessment of EFs of all soil samples illustrated the anthropogenic origin of Cu, Cr, and Ni while Zn, Pb, and Co were enriched mainly from the geogenic process; and the enrichment process of heavy metals occurred more strongly at the bottom of the slope. CF, which was determined, could be divided into two groups in value, in which CF &amp;#8804; 1 presented a low contamination for Pb (CF = 0.71); Co (CF = 1.00), and 1 &lt; CF &lt; 3 was a moderate contamination for remaining metals Zn, Ni, Cr and Cu with CF figures were 1.06, 1.68, 2.28 and 2.08, respectively. Besides, the topsoil of H&amp;#233;tsz&amp;#337;l&amp;#337; vineyard was considered in the moderate pollution status with FLI was 1.35. The results of Ei indicated that all heavy metal in the topsoil of vineyard showed a low ecological risk, with the descending order of contaminants was Cu (10.38) &gt; Ni (10.07) &gt; Co (4.98) &gt; Cr (4.55) &gt; Pb (3.54) &gt; Zn (1.06). In addition, the mean PER was 34.59 and it revealed a low ecological risk for all metals in the vineyard soil. Even though there was a low potential ecological risk, the moderate level pollution of heavy metals, enrichment process, and the continuous using chemical compounds in viticulture could cause serious risk pollution by heavy metals in the future.&lt;/p&gt;


Proceedings ◽  
2019 ◽  
Vol 44 (1) ◽  
pp. 1 ◽  
Author(s):  
Agnieszka Gruszecka-Kosowska

The aim of these investigations was to determine the impact of heavy metals bound with deposited particulate matter (PM) on contamination degree and related toxicological effects by calculating enrichment indices, namely, the geo-accumulation index (Igeo), contamination factor (CF), and enrichment factor (EF), as well as the ecological risk index (ERI) and modified hazard quotient (mHQ). Calculations were made based on the selected element concentrations determined in deposited PM samples in Krakow. The results of the investigations revealed that deposited PM was enriched in heavy metals. As Igeo provides information on the level of metal accumulation, it was found that deposited PM was practically uncontaminated with Be, Cd, and Tl (class 0) but heavily to extremely contaminated (class 5) with Co and Sn and extremely contaminated (class 6) with As, Ba, Cr, Cu, Li, Mn, Ni, Pb, Sr, Ti, V, and Zn. On the other hand, the calculated values of CF revealed very high contamination of deposited PM with Cd and Zn, considerable contamination with Sn, Pb, and As, and moderate contamination with Cu and Li. Values of calculated EF revealed that among the investigated elements, only Zn originated from anthropogenic sources. For Cd, a small influence of anthropogenic sources was observed. For Pb and Sn, non-crustal sources of emission were expected. The calculated ERI values indicated potential ecological risk levels that were very high for Cd and considerable for Zn, as well as low potential ecological risk for As, Co, Cr, Cu, Ni, Pb, and Tl. Moreover, the calculated mHQ values of severity of contamination were extreme for Zn, considerable for Cr, and moderate for As, Cu, and Pb. The analysis revealed that the impact of atmospheric and re-suspended PM on inhabitants constitutes a complex effect of a mixture of heavy metals simultaneously affecting human health.


2017 ◽  
Vol 76 (8) ◽  
pp. 2177-2187 ◽  
Author(s):  
Xu Wang ◽  
Lijun Ren ◽  
Fengchao Jiao ◽  
Wenjie Liu

The concentrations of eight heavy metals (Cr, Hg, As, Pb, Cd, Cu, Zn, Ni) in six river sediment samples were collected for evaluation of the degree of the heavy metals pollution distribution and ecological risk of three main rivers' sediments in Jinan. Multivariate statistical techniques were used to determine the most common pollution sources. The results illustrated that all of the metals in Damatou and Xinfengzhuang sections of the Xiaoqing River were much higher than the background value, and the level of potential ecological risk index was very high. The remaining four sections had a low or moderate degree of ecological risk. Principal component analysis (PCA) showed that all metals, with the exception of As, formed the first component explaining 86.85% of the total variance and industry sources could be considered as the first component, while As alone could be the second component, representing agricultural source. The elements Cr and Zn were grouped together while the remaining six metals formed a separate category. Among all heavy metals, Hg and Cd were the most significant contributors to the pollution. Therefore, the prevention of pollution should pay more attention to controlling the sources, especially Hg and Cd.


2021 ◽  
Vol 10 (1) ◽  
pp. 1-19
Author(s):  
Abdullah Al Mamun ◽  
Protima Sarker ◽  
Md. Shiblur Rahaman ◽  
Mohammad Mahbub Kabir ◽  
Masahiro Maruo

The Dhaleswari river is considered as one of the most important rivers of Bangladesh due to its geographical location and ecological services. The present study attempts to evaluate the degree of heavy metal pollution, contamination, and accumulative behavior in  the sediment of the Dhaleswari river. The sediment samples were collected from fifteen different locations of the Dhaleswari river. Heavy metals were analyzed using the Flame Atomic Spectrophotometer (FAAS). The mean concentrations of Zn, Cu, Cr, Pb and Cd were 131.9, 48.89, 43.16, 33.23 and 0.37 mgkg-1, respectively. According to the United States Environmental Protection Agency (USEPA) Sediment Quality Guideline, the sediment of most of the locations were not polluted for Pb and Cd. But S-11 location for Cd (0.8 mg kg-1) was highly polluted. For Cr, Cu and Zn, maximum locations were moderately polluted. Although the geo-accumulation index (Igeo) values of Dhaleswari river sediments showed almost no severe contamination for most of the sampling locations, the pollution load index (PLI) values showed that most of the sampling sites were contaminated for all heavy metals tested. Moreover, for all measured heavy metals, the mean Contamination Factor (CF) values indicated moderate pollution, except for Cr, which suggested low pollution. The Pearson’s correlation coefficient matrix among the selected heavy metals of Dhaleswari river sediment showed no significant correlation among each other. Therefore, regular monitoring of the heavy metal concentration of the Dhaleshwari river sediment from different location is necessary to identify the sources of pollution so that proper initiative could be taken to prevent heavy metal pollution.


Author(s):  
Serkan Kürker

In this study, ecological risks arising from the accumulation of some heavy metals in surface sediments of Lake Tortum are discussed based on the use of ecological indices, such as enrichment factor (EF), contamination factor (CF), pollution load index (PLI), potential ecological risk index (PER) and the mean probable effect concentration quotient (mPEC-Q). Sediment samples were collected from six different sites using Van Veen grab and heavy metal and organic carbon content of sediments were determined. Results testify to the existence of minimal to moderate contamination in lake sediment. The highest value for the enrichment factor pertains to Cd caused by the use of fossil fuels in settlement areas in the lake catchment. PLI and PER estimations, on the other hand, reveals the presence of low heavy metals-induced ecological risk in lake sediments. Ranging between 15% and 29%, mPEC-Q values are indicative of the fact that Lake Tortum is a low-moderate priority site in terms of toxicity level caused by heavy metals.


Author(s):  
Fang Shen ◽  
Longjiang Mao ◽  
Runxia Sun ◽  
Jijing Du ◽  
Zhihai Tan ◽  
...  

Seven heavy metals (Cr, Mn, Co, Ni, Cu, Zn, Pb) were measured in surface sediments from the Lishui River watershed, an area with increased soil erosion in China. The mean concentrations of heavy metals were 61.20 mg/kg (Cr), 757.15 mg/kg (Mn), 9.39 mg/kg (Co), 25.31 mg/kg (Ni), 22.84 mg/kg (Cu), 91.66 mg/kg (Zn), and 40.19 mg/kg (Pb), respectively. The spatial distribution of heavy metals was site-specific, exhibiting a remarkably high level in the sampling stations with intense agricultural activities (Lixian) and industrial activities (Jinshi). Contamination indexes including contamination factor, pollution load index, nemerow multi-factor index, potential ecological risk index, and human health risk were used to assess the pollution degree of the river sediments. The results indicated the pollution degree of heavy metals decreased in the order of Mn>Pb>Zn>Cr>Cu>Ni>Co. Heavy metals resulted in non-pollution to moderate pollution, with low ecological risk and an acceptable carcinogenic risk caused by Cr and Ni for children and adults. Person’s correlation analysis and principal component analysis, coupled with cluster analysis, revealed that the sediments from the Lishui River were mainly influenced by two sources. Cr, Co, Ni, and Cu were mainly derived from natural sources, while Mn, Zn, and Pb originated from agricultural and industrial activities, mining, and vehicular traffic.


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