Some Recent Developments in the Characterization of Estuarine Particulates

1986 ◽  
Vol 18 (4-5) ◽  
pp. 83-92 ◽  
Author(s):  
J. M. Martin ◽  
J. M. Mouchel ◽  
P. Nirel
Keyword(s):  
Exchange Capacity ◽  
Small Range ◽  
Coastal Zones ◽  
Amorphous Oxides ◽  
Al Content ◽  
Physical Environments ◽  
Recent Developments ◽  
Varied Chemical ◽  
Cationic Exchange ◽  
Highly Correlated

Estuaries and coastal zones are characterised by very varied chemical and physical environments. As a result, heterogenous reactions predominate between dissolved and mineral phases, and with the biota. These reactions primarily affect elements and compounds located at the particulate surface. Thus the determination of surface properties of particles is an important key to understanding interactions of trace elements and organic compounds between particulate and dissolved phases in estuarine and coastal systems. Specific surface area (SSA), cationic exchange capacity (CEC) and heat of immersion (∆H) have been measured on native untreated suspended sediment and after oxidation with 15% H2O2. SSA and ∆H have also been measured on samples Leached with NaOH and Na-dithionite in order to remove amorphous aluminosilicates. Results indicated that SSA is controlled by amorphous oxides and is related to the Al content of samples and their granulometry, suggesting an almost uniform coating of the detrital core by amorphous oxides. On the other hand, CEC and ∆H, which appear to be highly correlated, are controlled by both organic matter and amorphous oxides. Studies on electrophoretic mobility have provided additional data on the excess of charge at the interface between suspended matter and electrolytic medium. Particles in suspension in fresh, sea, and estuarine waters appear ubiquitously to exhibit a small range of negative surface charge. This uniformity is attributed to the presence of organic surface coatings on the particles (Loder and Liss, 1985). Finally, the significance of organic and oxide coatings as carriers of trace metal pollutants is discussed. It is shown that their importance in terms of flux is usually Low despite their major role in controlling solid-liquid interactions.

Synthesis and Characterization of Silver-Histidine Complex Doped Montmorillonite Antibacterial Agent

2012 ◽  
Vol 510 ◽  
pp. 757-761 ◽  
Author(s):  
Shu’e Duan ◽  
Yun Hui Zhai ◽  
Ying Juan Qu
Keyword(s):  
Antibacterial Agent ◽  
Sea Water ◽  
Antibacterial Activities ◽  
Exchange Capacity ◽  
Salt Tolerant ◽  
X Ray Diffraction ◽  
Ion Exchange Reaction ◽  
Cationic Exchange ◽  
Loading Amount

In this paper a novel colorless and salt-tolerant silver-histidine complex doped montmorillonite (Na-MMT) antibacterial agent (SHMMT) power was synthesized by ion exchange reaction using silver-histidine complex ion [Ag (his)] + as precursor, and characterized by atomic absorption spectrophotometer (AAS) and power X-ray diffraction (XRD). The antibacterial activities against Pseudoalteromonas carrageenovora were examined by a modified broth dilution test and the plate counting method. The salt-tolerant property was determined by the antibacterial activities of the sea water soaked SHMMT. The results showed that the Ag loading amount of SHMMT powder reached 1.7mmol/g, far more than the cationic exchange capacity (CEC) of Na-MMT. SHMMT powder had high bacterial activity eventhough it was soaked in the sea water for 30 days. 1

scholarly journals Changes in suspension properties of structural modified montmorillonites

Cerâmica ◽  
2001 ◽  
Vol 47 (301) ◽  
pp. 4-8 ◽  
Author(s):  
C. Volzone ◽  
L. B. Garrido
Keyword(s):  
Particle Size ◽  
Structural Disorder ◽  
Physicochemical Characteristics ◽  
Exchange Capacity ◽  
X Ray Diffraction ◽  
Flow Properties ◽  
Flow Curves ◽  
Structural Modifications ◽  
Fine Particle Size ◽  
Cationic Exchange

Rheological changes were found in smectite (Wyoming- and Cheto-type montmorillonites) suspensions after structural modifications. The effect of the particle size and Na+ exchange on the flow curves of 6% wt/wt suspensions of smectites with and without Na2CO3 were examined. Mineralogical, structural and physicochemical characteristics were studied by X-ray diffraction (XRD), infrared spectroscopy (IR), cationic exchange capacity (CEC), Mg2+, Al3+ determinations, particle size distribution and swelling index (SI). Grinding in an oscillating mill modified the particle sizes. The montmorillonite grain size and the structural disorder increased after larger grinding times. The grinding treatment modified the apparent viscosity and the yield stress of the montmorillonite suspensions. The homoionic Na Cheto-type montmorillonite with fine particle size (obtained by grinding) increased the flow properties. Nevertheless, rheological properties were lower than those of suspensions of the Wyoming-type montmorillonite. Montmorillonite-types reacted differently with Na2CO3 additions and this behavior may be related to their structural composition. The Na2CO3 activation improved the flow properties of the original Wyoming-type montmorillonite and after 30 s grinding.

scholarly journals Mineralogical characterization of natural clays from Brazilian Southeast region for industrial applications

Cerâmica ◽  
2017 ◽  
Vol 63 (366) ◽  
pp. 253-262 ◽  
Author(s):  
N. I. Alvarez Acevedo ◽  
M. C. G. Rocha ◽  
L. C. Bertolino
Keyword(s):  
Specific Surface ◽  
Clay Fraction ◽  
Exchange Capacity ◽  
Size Analysis ◽  
Mineralogical Characterization ◽  
Southeast Region ◽  
Pore Size Analysis ◽  
Two Samples ◽  
Natural Clays ◽  
Cationic Exchange

Abstract Characterization studies of clays are often performed to identify possible markets for these materials. Bearing this in mind, two samples of natural clays from the Southeast region of Brazil were studied. Conventional techniques of characterization were used. Granulometric analysis and determination of cationic exchange capacity of these clays were also performed. Nitrogen adsorption-desorption measurements were used to determine the Brunauer-Emmett-Teller specific surface area, and Barrett-Joyner-Halenda and t-plot pore size analysis were carried out. The results obtained were similar for the two clays. Both present high clay fraction (above 80 wt%) composed of illite, kaolinite and quartz minerals. Stratified illite-smectite structures were also observed. Traces of calcite were detected in one of the clay samples, while traces of montmorillonite were observed in the other sample. These results were corroborated by the low cationic exchange capacity values obtained for both clays. These clays showed good adsorptive properties, evidenced by their specific surface areas, with predominantly mesoporous structures and slit-like pores. According to their features, these clays have potential use as adsorbents to replace more expensive materials due to their easy availability and low cost.

scholarly journals The Identification of Electrolyte Property of Humus-Contained Andosol Soil Using Cu-Zn Electrodes

2020 ◽  
Vol 3 (2) ◽  
pp. 71
Author(s):  
Irvan Maulana Firdaus ◽  
Diva N.M.D. Masyitoh ◽  
Tharra A.N. Azizah ◽  
Febiyanto Febiyanto
Keyword(s):  
Single Cell ◽  
Cell System ◽  
Exchange Capacity ◽  
Waste Materials ◽  
Humus Substance ◽  
Electrode Area ◽  
Electrode Distance ◽  
Cationic Exchange ◽  
Cu And Zn

<p><em>This study investigated the electrolyte property of humus-contained andosol soil using Volta cell. The electrodes that are used were Cu and Zn for cathode and anode, respectively. This research was done by varying electrode area and distance between Cu and Zn electrodes. The varied electrode area was 20, 30, and 40 cm<sup>2</sup>, whereas the electrode distance was 3, 4, and 5 cm. Then, the current and voltage profiles of Volta cell system were measured using a digital multimeter. The result showed that humus-contained andosol soil has an electrolyte property. Electrolyte property of andosol soil might be due to the humus substance that has a high cationic-exchange capacity. Besides, it showed that the increase of the electrode area, the current and voltage were increased gradually. In contrast, the increase in current and voltage could be found by the decrease of electrode distance. In addition, the use of 24-Volta cells system enhancing current and voltage compared to a single cell. It suggests that the increase of current and voltage was relatively proportional to the number of Volta cell. Therefore, this research can be a reference for the identification of electrolyte property of natural or waste materials.</em></p>

scholarly journals COMPOSITE OF CHITOSAN VANILIN / SULFONATED POLYSTYRENE AS POLYMER ELECTROLYTE MEMBRANES : CATIONIC EXCHANGE CAPACITY, SWELLING DEGREE AND THERMAL PROPERTIES

2016 ◽  
Vol 10 (2) ◽  
pp. 116
Author(s):  
Edi Pramono ◽  
Candra Purnawan ◽  
Yuniawan Hidayat ◽  
Jati Wulansari ◽  
Sayekti Wahyuningsih
Keyword(s):  
Thermal Properties ◽  
Composite Membranes ◽  
Exchange Capacity ◽  
Membrane Composition ◽  
Sulfonated Polystyrene ◽  
Swelling Degree ◽  
Electrolyte Membranes ◽  
Three Stages ◽  
Cationic Exchange

Research on the preparation and characterization of sulfonated polystyrene (PST) /chitosan vanillin (KV) composite as electrolyte membranes has been conducted in order to investigate the effect of PST and KV composition  to its chemical and physical properties. Polystyrene was modified by sulfonation reaction to produces PST<strong>, </strong>meanwhile chitosan was modified by schift base reaction to produces KV. The composite membranes were prepared by casting method and were characterized in order to identify the functional groups contained in the composite, the cation exchange capacity (CEC), the Swelling Degree (SD), the thermal properties and the morphology. The peak of imine vibration in the FTIR spectrum indicates that the chitosan vanilin was succesfully synthesized. Meanwhile, the peak of sulfonate vibration indicates the product of sulfonation on polystyrene. The result of CEC analysis shows that the addition of sulfonate groups on polystyrene and the addition of phenolic groups on chitosan increase the CEC value. The increasing of PST and KV concentration in membrane enhance the CEC value. However, the increasing of PST concentration in membrane composition even decrease the Swelling Degree of membranes. Meanwhile, the increasing of KV concentration increase the swelling degree of membranes. Thermal analysis shows that the thermal decomposition of membranes occurs in three stages i.e. the dehydration of water molecules, the degradation of the subtituen groups and the plasticizer and the degradation of the back bone of chitosan and polystyrene.

Superphosphate and stocking rate effects on a native pasture oversown with Stylosanthes humilis in central coastal Queensland. 3. The balance of native species in the pasture

1978 ◽  
Vol 18 (95) ◽  
pp. 808 ◽  
Author(s):  
NH Shaw ◽  
MB Dale
Keyword(s):  
Native Species ◽  
Floristic Composition ◽  
Exchange Capacity ◽  
Response To Treatment ◽  
Data Sets ◽  
Heteropogon Contortus ◽  
Native Pasture ◽  
Total Exchange Capacity ◽  
Highly Correlated ◽  
Stocking Rates

The percentage frequency of all herbaceous species in a native pasture oversown with S. humilis (T.S.) was measured at the beginning and end of an eight-year grazing experiment. Treatments imposed were three levels of molybdenized superphosphate (nil; 125 kg ha-1 annually; 250 kg ha-1 annually plus an extra 250 kg ha-1 initially) in factorial combination with four stocking rates and two sowing methods for T.S. (ground sowing into spaced cultivated strips or aerial sowing). Stocking rates were gradually increased during the experiment and for the last three years overlapping ranges were used for the three fertilizer levels; the overall range was then from 0.55 to 1.65 beast ha-1. Treatments did not induce any major changes in the proportions of native species in the pasture. Heteropogon contortus remained dominant and its frequency increased in all treatments. Of the total of 113 species recorded, only 18 reached 10 per cent frequency in at least one paddock on one occasion. Several of these showed statistically significant changes in response to treatment, but their relative importance was not greatly changed. Examination of the results by principal co-ordinate and canonical analysis, showed that the first vectors of the two data sets were highly correlated, indicating that the major control on floristic composition was not changed by oversowing with T.S. or by the treatments imposed. Treatment effects dominated in the second and third vectors in the final year. The controlling vector was found to be highly correlated with soil calcium, potassium, total exchange capacity and organic carbon, but the basis for the correlations remains undetermined.

Preparation of Organovermiculite for Adsorption of Organic Compounds

2012 ◽  
Vol 727-728 ◽  
pp. 1451-1456
Author(s):  
Andréa Lopes Silva ◽  
Francisco Kegenaldo Alves de Souza ◽  
Gelmires Araújo Neves ◽  
Romualdo Rodrigues Menezes ◽  
Hélio Lucena Lira ◽  
...  
Keyword(s):  
Organic Compounds ◽  
Organic Pollutants ◽  
Organic Contaminants ◽  
Exchange Capacity ◽  
Natural Clay ◽  
Modified Clay ◽  
Organically Modified ◽  
Dimethyl Ammonium ◽  
Cationic Exchange ◽  
Clay Materials

Organically modified clay minerals are widely used as sorbents for hydrophobic organic compounds e.g., organic pollutants treatment from water solutions. Natural clay materials are hydrophilic and therefore they are not efficient sorbents for organic compounds. Intercalations of natural clay materials, with organic cations, with quaternary ammonium groups may become these clays hydrophobic. Vermiculite is the mineralogical name given to hydrated laminar magnesium-aluminum-iron silicate; this natural clay was modified and used for the production of organically modified clay (organovermiculite), with the purpose of its use in removing organic contaminants. The organovermiculite was prepared using different concentrations of distearyl dimethyl ammonium chloride (praepagen) based on cationic exchange capacity of the clay. It was evident from the X-ray diffraction that the salt was incorporated to the clay structure confirming its organophilization and through the Foster swelling test it was observed the affinity between the organic pollutants and the organovermiculite.

Uncertainty quantification in geological modelling by Hessian-informed MCMC

2020 ◽  
Author(s):  
Zhouji Liang ◽  
Florian Wellmann
Keyword(s):  
Uncertainty Quantification ◽  
Stochastic Modelling ◽  
High Dimensional ◽  
Mcmc Methods ◽  
Inference Problem ◽  
Model Interpretation ◽  
Geological Modelling ◽  
High Dimensional Problem ◽  
Recent Developments ◽  
Highly Correlated

&lt;p&gt;Uncertainty quantification is an important aspect of geological modelling and model interpretation. Recent developments in geological modelling allow us to view the inversion as a problem in Bayesian inference, incorporating the uncertainties in the observations, the forward models and the prior knowledge from geologists. The sampling method Markov chain Monte Carlo (MCMC) is then often applied to solve this inference problem. However, this stochastic modelling approach is limited as the number of parameters increases to higher dimensions. To ensure an efficient sampling in a high dimensional problem, we take advantage of recent advances using Hessian-based MCMC methods in this work. The Hessian of the negative log posterior with respect to the input parameters is evaluated at the Maximum a Posteriori (MAP) point. A Laplace approximation of the posterior at the MAP is then given by the inverse of the local Hessian. This sampling approach provides a potentially less computationally expensive and more efficient way for high dimensional geological inverse modelling, especially in cases where parameters are highly correlated, a situation that commonly arises in geological modelling.&lt;/p&gt;

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