Requirements for the Treatment of Effluents from Chemical Pulp Mills in the F.R.G.

1988 ◽  
Vol 20 (1) ◽  
pp. 19-24 ◽  
Author(s):  
L. Huber ◽  
H. Baumung

In 1986, the 11 chemical pulp mills in the F.R.G. produced 350,00 t of bleached sulfite pulp. With the enactment of the so-called minimum requirements in 1982, general standards for the treatment of effluents were promulgated for this branch of industry. They comprise various measures, such as high-grade recovery of spent liquor including its evaporation and incineration, partial or total reuse of condensates from evaporation or reduction of their load by stripping, and mechanical treatment of total waste water. In view of the persisting high pollution levels of German rivers caused by pulp mills, more stringent standards reflecting the present state of the art will be implemented in 1991. This paper deals with these standards, covering the applicable in-plant and external abatement measures, such as extended cooking, substitution of elemental chlorine and biological treatment for decisive improvement of the chemical pulp mill effluent situation.

2015 ◽  
Vol 2015 ◽  
pp. 1-10 ◽  
Author(s):  
Tamara Llano ◽  
Noelia García-Quevedo ◽  
Natalia Quijorna ◽  
Javier R. Viguri ◽  
Alberto Coz

The evolution of lignin, five- and six-carbon sugars, and other decomposition products derived from hemicelluloses and cellulose was monitored in a sulfite pulp mill. The wastewater streams were characterized and the mass balances throughout digestion and total chlorine free bleaching stages were determined. Summative analysis in conjunction with pulp parameters highlights some process guidelines and valorization alternatives towards the transformation of the traditional factory into a lignocellulosic biorefinery. The results showed a good separation of cellulose (99.64%) during wood digestion, with 87.23% of hemicellulose and 98.47% lignin dissolved into the waste streams. The following steps should be carried out to increase the sugar content into the waste streams: (i) optimization of the digestion conditions increasing hemicellulose depolymerization; (ii) improvement of the ozonation and peroxide bleaching stages, avoiding deconstruction of the cellulose chains but maintaining impurity removal; (iii) fractionation of the waste water streams, separating sugars from the rest of toxic inhibitors for 2nd generation biofuel production. A total of 0.173 L of second-generation ethanol can be obtained in the spent liquor per gram of dry wood. The proposed methodology can be usefully incorporated into other related industrial sectors.


Author(s):  
Alexandra Leshchinskaya

MICROWAVE WOOD CHIP TREATMENT USE IN CHEMICAL PULP MANUFACTURING   (TECHNICAL-ECONOMIC ASSESMENT)   A. Leshchinskaya   Plekhanov Russian University of Economics. 36 Stremyannyy Pereulok, 115093 Moscow, Russia, e-mail: [email protected]]   Keywords: chemical pulping, microwave wood modification, pulp, softwood, wood chips.   Large volumes of cellulose are produced from wood chips by chemical methods. Low permeability of many wood species causes problems in the chemical pulp industry. These include: very long cooking times, high chemical consumption, large material losses, high energy consumption, and environmental pollution. New microwave (MW) wood modification technology can provide an increase in wood permeability for liquids and gases, which solves many of these problems. The technology works  by applying intensive MW power to green wood, which generates steam pressure within wood cells. High internal pressure destroys weak elements of wood structure, opens pores and forms micro and macro cracks. A several thousand-fold increase in wood permeability can be achieved in species previously found to be impermeable to liquids and gases. It allows a significant increase in the speed of pulp cooking and improves a production processes. The study of the technology showed radical potential improvements in the pulp industry through: increase in mill throughput significant reduction of chemical consumptionreduction of energy consumption •     increase in pulp quality and yield improvement of environmental performance.   Pulp manufacturing process includs timber chipping, microwave chip treatment, steaming, cooking, washing, and pulp making. The use of MW wood chip treatment in pulp mills with outputs of 50,000 to 500,000 air dry tons (ADT) per year requires MW equipment with power from 1000 to 10,000 kW. Economic modelling of this technology used in different pulp mill conditions allowed assessment of the effect of capital costs, electricity costs, labour costs and other cost components to specific total costs of MW chip processing. Economic assessment of MW technology application showed that specific costs of softwood chip processing at electricity costs of 0.08 - 0.12 US$/kWh are 25.4 -33.7 US$/ADT of pulp. Electricity costs form the most significant part of the total specific costs of MW processing and form 51-69% shear in the total specific costs. Under the same conditions capital costs form 15-20% shear, and labour costs form 5-18% shear of the total specific costs. The electricity cost increase from $0.04 to $0.24/kWh provides specific MW processing cost rise by 2.7 to 3.1 times at pulp mill output range 50,000 to 500,000 ADT/year. New technology use allows benefits up to 7 – 22 Mil US$ per year for pulp mills with output of more than 200,000 ADT/year. The technology can be used by pulp mills with batch and continuous digesting and is not limited by mill throughput. Ecological impacts and high economic advantages of this MW technology application in pulp and paper industry provide good opportunity for commercialisation.  


2018 ◽  
Vol 33 (2) ◽  
pp. 358-364
Author(s):  
Tatiana Aurora Condezo Castro ◽  
Claudio Mudadu Silva ◽  
Jorge Luiz Colodette ◽  
Ann H. Mounteer

Abstract Dissolving pulps could be considered as the future biorefineries, which normally generate liquor during the wood chip pre-hydrolysis (PHL). PHL has high chemical oxygen demand (COD) and biochemical oxygen demand (BOD). Mills do not have efficient means for disposal of PHL, being in general burned in the recovery boiler with a high cost due to its low consistency. The objectives of this work were to evaluate i) the biotreatability of PHL and the effects it would have on a kraft mill effluent biological treatment plant and ii) the use of ultrafiltration (UF) membrane to treat the PHL prior to biological treatment. PHL was generated into lab with a hydrothermal process and was mixed with kraft pulp mill effluent in different proportions and added to sequencing batch reactors (SBRs). The SBRs achieved high rates of COD removal (>75 %). However, treated effluent COD increased with the increase in PHL dose. This treatment using UF membranes reduced the COD load. Biotreatability of the UF permeate was higher than that of PHL. UF retentate, with 28 % of the volume and a much higher solids content than the initial PHL, would have a significantly lower evaporation energy demand if sent to the black liquor evaporators.


1985 ◽  
Vol 17 (1) ◽  
pp. 157-171 ◽  
Author(s):  
A Geller ◽  
L Göttsching

Despite internal measures modern sulphite pulp mills are still releasing considerable amounts of effluents loaded with organic pollutants. The main sources are the spent liquor evaporator and the bleach plant. In the laboratory scale two anaerobic systems (stirred fermentation vessel and fixed bed reactor) were tested for the fermentation of effluents from a magnesium sulphite mill. The efficiency of the fixed bed reactor was substantially better than the efficiency of the fermentor. Upon treatment of evaporator condensates, COD removal exceeded 90 % with corresponding BOD removal of 99 % after a residence time of 36 hours, whereas the necessary residence time for the same results was about 16 days in the fermentor. The methane production increased with increasing loading, reaching a maximum at a COD loading rate of 7 kg.m−3 .d−1. BOD elimination from bleaching effluents was better than 95 % with fixed bed reactor, whilst COD removal remained below 50 %. All experiments were run over a period of more than two years, exhibiting stability of the fixed bed filter, low needs for maintenance and negligible biomass generation.


1997 ◽  
Vol 35 (2-3) ◽  
pp. 235-243 ◽  
Author(s):  
R. Saunamäki

The performance of Finnish activated sludge plants (primary clarifier, equalization basin, buffer basin, aeration basin, secondary clarifier and sludge handling) was surveyed. Performance was generally found to be excellent. BOD7 removal averaged 94% at paper mills (21mg/l effluent concentration, 0.43 kg/t discharge) and 95% at chemical pulp mills (18 mg/l, 0.83 kg/t). CODCr removal averaged 82% at paper mills (158 mg/l effluent concentration, 3.52 kg/t discharge) and 60% at pulp mills (531 mg/l, 20.7 kg/t). Treated effluent from paper mills contained 0.57 mg/l (13.3 g/t) of total phosphorus and from pulp mills 1.31 mg/l (47.3 g/t). AOX removal was 45-65% and discharge 0.15-0.90 kg/t. Suspended solids removal averaged 91% at paper mills and 76% at pulp mills, the average overflow concentration in primary clarifier being about 150 mg/l at both types of mill. All activated sludge plants are designed according to either the low load or extended aeration principle; high load plants are no longer in use. The average sludge load was 0.15 kg BOD/(kg MLSS d), the sludge age at the extended aeration plants ranging from 20 to 50 d. Low load appearance to be the main reason for the good performance of the plants. Other factors included the introduction of equalization and buffer basins at many plants, and particularly the fact that aeration factors and nutrients were under control. All paper mill activated sludge plants use nitrogen and phosphorus additions, whereas pulp mill plants manage without phosphorus. Optimization of nutrient addition is vital because almost every mill in Finland has a limit for its phosphorus discharge. Total sludge production at the paper mill plants averaged 40.9 t/d, 15% of which (5.9 t/d, 6.0 kg/t) was biosludge. At the pulp mills the figures were 27.2 t/d (11.5 t/d biosludge, 9.5 kg/tp). Belt filter presses are used for dewatering at most plants and dry solids contents are usually 25-35%. New-generation screw presses have been introduced, mainly at new pulp mill activated sludge plants, yielding dry solids contents of 40%. Combined and dewatered sludge is normally burned in bark-fired boilers, although some mills still landfill their sludge.


1999 ◽  
Vol 40 (11-12) ◽  
pp. 281-288 ◽  
Author(s):  
A. G. Werker ◽  
Eric R. Hall

This paper highlights results from a fundamental study into the fate of resin acids during biological treatment. Pulp mills in Canada rely on biological treatment systems for the removal of resin acids that are released from wood during pulping and bleaching. These are priority contaminants for the pulping industry since they have been associated with events of toxicity breakthrough. Although tighter mill control has helped to minimise the frequency of these events, it would be useful to have an understanding of the basic limitations of biological systems as the last line of defence for limiting resin acid discharges. The dependence of physico-chemical and biological phenomena on pH will influence the chances for successful biological removal of resin acids. Changes in pH within the typical range used for biological treatment significantly alter the bioavailability of resin acids and the ecology of the microorganisms responsible for their degradation. Changes in resin acid loading during continuous treatment also affect the microbial ecology. Further, the capacity of a treatment system to degrade resin acids is a function of the contaminant loading. Time delays for microbial community acclimation in response to a shift-up in loading are significantly long and are also a function of pH. The capacity to remove resin acids is readily gained and lost in a biological system. Hence the bioreactor operating conditions in conjunction with the period and amplitude of loading fluctuations can impact on the extent of biological removal for resin acids. Consequently, biological systems can be severely compromised by influent transient loading when it comes to the removal of specific contaminants like resin acids.


1999 ◽  
Vol 40 (11-12) ◽  
pp. 139-146 ◽  
Author(s):  
Mika A. Kähkönen ◽  
Mikko Liukkonen ◽  
Christoph Wittmann ◽  
Kimmo P. Suominen ◽  
Mirja S. Salkinoja-Salonen

Sediments were dated and the quality assessed by polyphasic approach in an area of Lake Saimaa, which has received waste water from bleached kraft pulp production since 1954. The chosen nonrecipient forest Lake Pyylampi was situated in the same area. The activities of the enzymes butyrate-esterase and aminopeptidase were depressed at the depth of 2 to 8 cm in the recipient but not in the forst lake sediment. In the same layers the contents of EOX-C1 and toxicity to Vibrio fischeri were very high compared to those above or below. Toxicity to microbial community in the 2 to 8 cm layer was also indicated by a gap in the ATP content and a drop in diatom species richness from the 70 species to < 50 reflecting decreased water quality of the pelagic area. All these changes dated to the period of heavy organic halogen discharges, from 1960 to late 1980s, which led to sediment accumulation of solvent soluble halogen at a depth of 2 to 8 cm, to 6.4 g m−2 (cm)−1. In the most polluted sediment layers heavy metal accumulation was too little to be related to the toxicity of these layers. Almost complete recovery of both the sediment microbial ecosystems and of the pelagic diatoms occurred after elemental chlorine was completely substituted by chlorine dioxide and biological treatment adopted for wastewaters. Butyrate-esterase and aminopeptidase, but not phosphatase, activities correlated positively with the ATP content of the sediment. Butyrate-esterase may be used as a tool to estimate microbial biomass.


Author(s):  
Andrea Vannini ◽  
Luca Paoli ◽  
Riccardo Fedeli ◽  
Sharon Kwambai Kangogo ◽  
Massimo Guarnieri ◽  
...  

AbstractIn this study, the release of Cu2+ and Zn2+ was investigated and modeled in the epiphytic lichen Evernia prunastri. Samples were incubated with solutions containing these metals at ecologically relevant concentrations (10 and 100 μM) and then transplanted to a remote area and retrieved after 1, 2, 3, 6, 12, and 18 months. The results showed that, after 12 months, all samples faced similar metal reductions of ca. 80–85%, but after this period, all the involved processes seem to be no longer capable of generating further reductions. These results suggest that the lichen E. prunastri can provide information about environmental improvements after exposure to high or very high pollution levels in a relatively short period of time.


TAPPI Journal ◽  
2020 ◽  
Vol 19 (3) ◽  
pp. 139-148
Author(s):  
MARYAM SADEGH MOUSAVI ◽  
NIKOLAI DEMARTINI

The accumulation of nonprocess elements in the recovery cycle is a common problem for kraft pulp mills trying to reduce their water closure or to utilize biofuels in their lime kiln. Nonprocess elements such as magne-sium (Mg), manganese (Mn), silicon (Si), aluminum (Al), and phosphorus (P) enter the recovery cycle via wood, make-up chemicals, lime rock, biofuels, and process water. The main purge point for these elements is green liquor dregs and lime mud. If not purged, these elements can cause operational problems for the mill. Phosphorus reacts with calcium oxide (CaO) in the lime during slaking; as a result, part of the lime is unavailable for slaking reactions. The first part of this project, through laboratory work, identified rhenanite (NaCa(PO4)) as the form of P in the lime cycle and showed the negative effect of P on the availability of the lime. The second part of this project involved field studies and performing a mass balance for P at a Canadian kraft pulp mill.


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