A Promising Combination of Two Phosphate Removal Techniques: Biological P-Removal and the Crystalactor

1991 ◽  
Vol 24 (10) ◽  
pp. 329-332
Author(s):  
P. M. J. Janssen ◽  
J. H. Rensink ◽  
E. Eggers
Keyword(s):  
1991 ◽  
Vol 24 (10) ◽  
pp. 231-237
Author(s):  
W. G. Werumeus Buning ◽  
F. W. A. M. Rijnart ◽  
P. P. Weesendorp

To meet two levels of nitrogen and phosphorus removal (effluent standards Ntot 20 and 10 mg/l and Ptot 2 and 1 mg/l respectively) various systems were compared in a desk study. After a cost estimate and an assessment f the advantages and drawbacks, the oxidation ditch with biological by pass phosphate removal turned out to be the best system.


2006 ◽  
Vol 53 (3) ◽  
pp. 191-198 ◽  
Author(s):  
X.-D. Hao ◽  
M.C.M. van Loosdrecht

Phosphate removal and recovery can be combined in BNR processes. This may be realised by struvite precipitation from the supernatant of the sludge in anaerobic compartments. This can be beneficial for either improving bio-P removal effluent quality or lowering the influent COD/P ratio required for bio-P removal. For this reason, a patented BNR process, BCFS®, was developed and applied in The Netherlands. Several questions relating to P-recovery and behaviour of the system remain unclear and need to be ascertained. For this purpose, a modelling technique was employed in this study. With the help of a previous developed model describing carbon oxidation and nutrient removal, three cases were fully simulated. The simulations demonstrated that there was an optimal stripping flow rate and P-recovery would increase in costs and bio-P activity might be negatively affected due to decreased bio-P efficiency if this value was exceeded. The simulations indicated that the minimal CODbiod/P ratio required for the effluent standard (1 g P/m3) could be lowered from 20 to 10 with 36% of P-recovery. A simulation with dynamic inflow revealed that the dynamic influent loads affected slightly the anaerobic supernatant phosphate concentration but the effluent phosphate concentration would not be affected with regular P-recovery.


2013 ◽  
Vol 45 (3) ◽  
pp. 368-378 ◽  
Author(s):  
Egle Saaremäe ◽  
Martin Liira ◽  
Morten Poolakese ◽  
Toomas Tamm

Phosphorus (P) is one of the nutrients causing eutrophication in many of our waterways. In the present study, we investigated Sachtofer PR Ca-Fe oxide granules as a potential P sorption material (PSM) for constructed wetlands. We found the P sorption with various experiments as follows: the 24 h batch experiment with the highest initial concentration of 50 mgP L−1 yielded 0.48 mgP g−1 P removal per mass unit, the kinetic P removal batch experiment of 600 h duration yielded 1.25 mgP g−1, the maximum phosphorus adsorption capacity estimated from the Langmuir equation yielded 23.78 mgP g−1, and the long term flow-through experiment with drainage ditch water yielded indicative saturated sorption of 1.4 mgP g−1. Flow-through experiments revealed that phosphate removal was rapid and the efficiency was 10–70%, depending on the retention time and age of granules. Possible weaknesses of this material for sorption filter systems were found to include the loss of mass caused by the rapid dissolution of gypsum, increased sulfate and calcium concentrations in the water, and rapidly changing hydraulic conductivity. Considering hydraulic and chemical properties, further pilot experiments are necessary to develop technical solutions for optimal use of Ca-Fe oxide granules in sorption filter systems at constructed wetlands.


RSC Advances ◽  
2016 ◽  
Vol 6 (7) ◽  
pp. 5871-5880 ◽  
Author(s):  
Shao-bo Liu ◽  
Xiao-fei Tan ◽  
Yun-guo Liu ◽  
Yan-ling Gu ◽  
Guang-ming Zeng ◽  
...  

This work explored the efficiency and mechanisms of phosphate (P) removal by Ca-impregnated biochar prepared from CaCl2-pretreated ramie stem (Ca-RSB) and ramie bark (Ca-RBB).


2009 ◽  
Vol 60 (11) ◽  
pp. 2929-2938 ◽  
Author(s):  
Xiang-yong Zheng ◽  
Hai-Nan Kong ◽  
De-yi Wu ◽  
Chong Wang ◽  
Yan Li ◽  
...  

The aim of this study was to investigate the effects of current density, gap between electrodes, urine dosage, dilution and hydrolysis on phosphate removal from human urine by electrocoagulation technique using iron as electrodes. It was shown that, although a high current density and a long electrolysis time favored the removal of phosphate, an appropriate value for these two parameters can be obtained by taking into account the consumption of energy and iron in addition to P removal. In this study, current density 40 mA/cm2 and electrolysis time 20 min were shown to be optimal for 1.0 L pure urine to achieve nearly a complete removal (98%) efficiency of phosphate under the conditions of electrode area 160 cm2, the stirring speed 150 rpm, and the gap between electrodes 5 mm. Increase of gap between electrodes had little effect on phosphate removal, although it increased the energy consumption dramatically. The use of a high urine dosage reduced the efficiency of phosphate removal but increased the amount of removed phosphate. When pure urine was diluted with tap water, use of a higher tap water proportion for dilution expedited the electrolysis to achieve a nearly complete removal of phosphate in solution, but dilution caused the increase in energy consumption. It was also revealed that the hydrolysis of urine prior to electrocoagulation treatment impeded phosphate removal.


Water ◽  
2021 ◽  
Vol 13 (20) ◽  
pp. 2883
Author(s):  
Rasa Vismontienė ◽  
Arvydas Povilaitis

Biochar has received increased attention in environmental applications in recent years. Therefore, three pilot-scale denitrifying bioreactors, one filled with woodchips only and the other two enriched with 10% and 20% by volume of biochar from deciduous wood, were tested under field conditions for the removal of nitrate (NO3-N) and phosphate (PO4-P) from tile drainage water in Lithuania over a 3-year period. The experiment showed the possibility to improve NO3-N removal by incorporating 20% biochar into woodchips. Compared to the woodchips only and woodchips amended with 10% biochar, the NO3-N removal effect was particularly higher at temperatures below 10.0 °C. The results also revealed that woodchips alone can be a suitable medium for PO4-P removal, while the amendment of biochar to woodchips (regardless of 10% or 20%) can lead to large releases of PO4-P and other elements. Due to the potential adverse effects, the use of biochar in woodchip bioreactors has proven to be very limited and complicated. The experiment highlighted the need to determine the retention capacity of biochar for relevant substances depending on the feedstock and its physical and chemical properties before using it in denitrifying bioreactors.


1994 ◽  
Vol 30 (6) ◽  
pp. 193-202 ◽  
Author(s):  
Yoshitaka Matsuo

Three continuous flow enhanced biological phosphorus removal (EBPR) systems were operated to investigate the effect of the anaerobic SRT on the phosphate removal. The P removal in the system with a short anaerobic SRT declined due to growth of non phosphate accumulating microbes which competed in anaerobic substrate uptake against polyphosphate accumulating bacteria. The phosphorus removal, however, was improved by extending the anaerobic SRT. Restoration and stabilization of P removal by the long anaerobic SRT were confirmed in two other systems.


1996 ◽  
Vol 34 (1-2) ◽  
pp. 391-398 ◽  
Author(s):  
D. Wild ◽  
A. Kisliakova ◽  
H. Siegrist

In anaerobic digestion of excess sludge originating from enhanced biological phosphorus removal (EBPR) a complete hydrolysis of polyphosphate occurs. Varying information exists about the resulting return flow of phosphorus to the activated sludge plant. Magnesium, calcium and zeolites from detergents are the main species involved in the refixation of dissolved phosphate in the digester supernatant. Their interactions and mechanisms of phosphate removal have been characterized and quantified in experiments. The precipitation of struvite (MgNH4PO4·6H2O) evolves according to the equilibrium, whereas the fixation by calcium occurs kinetically controlled in the form of brushite (CaHPO4·2H2O) or hydroxyapatite (Ca5(PO4)3OH). Zeolites in digester sludge originate mainly from detergents. They represent around 7% of total solids entering the digester and their impact on digestion is given by 4 modes: The control of free cation concentrations as an exchanger, as a source for calcium ions, as generator of aluminum phosphate precipitation after being partly hydrolyzed and as a nucleus for crystallization processes. With the current sludge composition phosphate fixation processes in anaerobic digesters avert serious recycle load problems.


RSC Advances ◽  
2021 ◽  
Vol 11 (63) ◽  
pp. 39879-39887
Author(s):  
Weilong Zeng ◽  
Bing Li ◽  
Xueying Lin ◽  
Sihao Lv ◽  
Weizhao Yin ◽  
...  

This model is used to illustrate the enhanced P removal by oxidant stimulated ZVI.


2018 ◽  
Vol 56 (2C) ◽  
pp. 43-49
Author(s):  
Dang Thi Thanh Loc

Heat and humic acid modified sludge (MS) from drinking water treatment plant (DWTP) is used as an adsorbent for removal of phosphate (P) from aqueous solution. The MS was characterized by XRD and SEM observation. The effects of pH, adsorbent dosage, initial P concentration, and exposure time on the P removal were studied. Under identical treatment conditions (MS dosage = 10 g/L, initial P concentration = 10 mg/L, pH 7, 120 rpm, and room temperature), a removal efficiency of 91  % was obtained within 240 min. The Freundlich and Langmuir adsorption models were used for the mathematical description of adsorption equilibrium and it was found that P removal was best described by Langmuir model. The maximum adsorption capacity of the adsorbent based on sludge of Quang Te DWTP was 0.90 mg/g. The adsorption process followed pseudo-second-order kinetics (R2 ≥ 0.98). These findings suggest that MS has potential applications as a low-cost adsorbent for P treatment.


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