Biofiltration of dichlorobenzenes

2001 ◽  
Vol 44 (9) ◽  
pp. 287-293 ◽  
Author(s):  
F. Roberge ◽  
M.J. Gravel ◽  
L. Deschênes ◽  
C. Guy ◽  
R. Samson
Keyword(s):  
Gas Phase ◽  
Contaminated Soil ◽  
Cooling System ◽  
Ambient Air ◽  
Animal Manure ◽  
Full Scale ◽  
Peat Moss ◽  
Aerobic Treatment ◽  
Load Variations ◽  
System A

The use of air biofiltration for the degradation of dichlorobenzenes (1,2-DCB and 1,4-DCB) was studied at a refinery site. At this plant, 93 m3/h of contaminated groundwater, used in a cooling system and containing a maximum of 2 ppm of dichlorobenzenes, had to be treated. Stripping of the DCBs followed by biofiltration was selected as the most suitable technology to avoid volatilization in ambient air as expected with a wastewater aerobic treatment system. A stripper of 15 m height and 1.27 m diameter was designed as a first step treatment to volatilize DCBs with 3400 m3/h of air. Two full-scale biofilters of 70 m3 each were built and filled with 45 m3 of filtering media for the adsorption and biodegradation of the DCBs in the gas-phase. Filtering media was composed mainly of peat moss, with animal manure, wood chips and DCBs contaminated soil. Air to be treated was also contaminated with naphthalene. Laboratory tests showed an effective microbial activity in the contaminated soil and in the filtering media for DCBs degradation. Degradation of naphthalene induced slower degradation of DCBs. Full-scale operation was studied during four months. Water flow and DCBs content in the water entering the stripper were lower than expected with only 57 m3/h and a maximum concentration of only 240 ppb. Effective desorption was obtained in the stripper in the full-scale operation (more than 99% removal). Full-scale biofilters maintained a DCB concentration of less than 1 ppmv in the air outlet, but removal efficiency varied between 0 and 79% because of the low DCB inlet concentrations, load variations and sporadic naphthalene presence.

scholarly journals Enhancement of Poly-Crystal PV Panels Performance by Air-to-Air Heat Exchanger Cooling System

2021 ◽  
Vol 16 ◽  
pp. 157-163
Author(s):  
Khaleel Abushgair
Keyword(s):  
Heat Exchanger ◽  
Cooling System ◽  
Ambient Air ◽  
Bottom Surface ◽  
Solar Panels ◽  
Pv System ◽  
System A ◽  
Pv Module ◽  
Back Panel ◽  
The Impact

The temperature of silicon Poly-Crystal photovoltaic (PV) solar panels has a significant impact on their efficiency emphasizing the necessity of cooling approach to be used. The current study looked at the impact of adopting a unique forced convictive air-to-air heat exchanger as a cooling approach to boost the efficiency of PV solar panels, as efficiency of silicon Poly-Crystal PV solar panels would decrease as its temperature increased. The research was carried out experimentally with both an uncooled and cooled PV system. A unique cooling system for PV panels was designed and experimentally investigated in Amman, Jordan included a heat exchanger connected to a blower that drove ambient air over the back-panel surface and a chimney to draw the cooled air outside. This cooling system would improve the PV panel's efficiency. It was found that by directing cooled air over the bottom surface of the PV module at an ideal rate of 0.01020 m3/s, the temperature of the PV module could be reduced from an average of 40 °C (without cooling) to 34 °C. As a result, the efficiency and output power of PV modules increased by roughly 2 % and 12.8 %, respectively.

scholarly journals Detection and quantification of gas-phase oxidized mercury compounds by GC/MS

2016 ◽  
Vol 9 (5) ◽  
pp. 2195-2205 ◽  
Author(s):  
Colleen P. Jones ◽  
Seth N. Lyman ◽  
Daniel A. Jaffe ◽  
Tanner Allen ◽  
Trevor L. O'Neil
Keyword(s):  
Gas Phase ◽  
Elemental Mercury ◽  
Ambient Air ◽  
Gas Chromatography Mass Spectrometry ◽  
Gas Chromatograph ◽  
Mercury Compounds ◽  
System A ◽  
Collection Device ◽  
Cast Doubt ◽  
Mercury Halides

Abstract. Most mercury pollution is emitted to the atmosphere, and the location and bioavailability of deposited mercury largely depends on poorly understood atmospheric chemical reactions that convert elemental mercury into oxidized mercury compounds. Current measurement methods do not speciate oxidized mercury, leading to uncertainty about which mercury compounds exist in the atmosphere and how oxidized mercury is formed. We have developed a gas chromatography/mass spectrometry (GC-MS)-based system for identification and quantification of atmospheric oxidized mercury compounds. The system consists of an ambient air collection device, a thermal desorption module, a cryofocusing system, a gas chromatograph, and an ultra-sensitive mass spectrometer. It was able to separate and identify mercury halides with detection limits low enough for ambient air collection (90 pg), but an improved ambient air collection device is needed. The GC/MS system was unable to quantify HgO or Hg(NO3)2, and data collected cast doubt upon the existence of HgO in the gas phase.

scholarly journals Detection and quantification of gas-phase oxidized mercury compounds by GC/MS

2016 ◽  
Author(s):  
C. P. Jones ◽  
S. N. Lyman ◽  
D. A. Jaffe ◽  
T. Allen ◽  
T. L. O'Neil
Keyword(s):  
Gas Phase ◽  
Elemental Mercury ◽  
Ambient Air ◽  
Gas Chromatography Mass Spectrometry ◽  
Gas Chromatograph ◽  
Mercury Compounds ◽  
System A ◽  
Collection Device ◽  
Cast Doubt ◽  
Mercury Halides

Abstract. Most mercury pollution is emitted to the atmosphere, and the location and bioavailability of deposited mercury largely depends on poorly understood atmospheric chemical reactions that convert elemental mercury into oxidized mercury compounds. Current measurement methods do not speciate oxidized mercury, leading to uncertainty about which mercury compounds exist in the atmosphere and how oxidized mercury is formed. We have developed a gas chromatography/mass spectrometry-based system for identification and quantification of atmospheric oxidized mercury compounds. The system consists of an ambient air collection device, a thermal desorption module, a cryofocusing system, a gas chromatograph, and an ultra-sensitive mass spectrometer. It was able to separate and identify mercury halides with detection limits low enough for ambient air collection (90 pg), but an improved ambient air collection device is needed. The GC/MS system was unable to quantify HgO or Hg(NO3)2, and data collected cast doubt upon the existence of HgO in the gas phase.

Analysis of a Solar Space Cooling System Using Liquid Desiccants

1990 ◽  
Vol 112 (4) ◽  
pp. 246-250 ◽  
Author(s):  
P. Gandhidasan
Keyword(s):  
Heat Exchanger ◽  
Cooling System ◽  
Cooling Water ◽  
Ambient Air ◽  
Solution Concentration ◽  
Simple Expression ◽  
Ventilation Mode ◽  
Cooling Water Temperature ◽  
System A ◽  
Space Cooling

For tropical countries, solar space cooling is an attractive proposition. Dehumidification of air in hot, humid climates is almost as important as cooling. Removal of moisture from the air is much easier to achieve than cooling the air. The proposed cooling system operates on the ventilation mode. The ambient air is dehumidified using liquid desiccants followed by adiabatic evaporative cooling. The desiccant soon becomes saturated with the water extracted from the air and can be regenerated by using solar energy. For this system, a simple expression is derived in this paper to predict the amount of heat removed from the space to be conditioned in terms of known initial parameters through a simplified vapor pressure correlation and effectiveness of the dehumidifier and the heat exchanger. The effect of ambient air conditions, solution concentration, the cooling water temperature and the effectiveness of the dehumidifier and the heat exchanger on the performance of the cooling system are also discussed in this paper.

scholarly journals Anaerobic Digestion and Removal of Sulfamethoxazole, Enrofloxacin, Ciprofloxacin and Their Antibiotic Resistance Genes in a Full-Scale Biogas Plant

Antibiotics ◽  
2021 ◽  
Vol 10 (5) ◽  
pp. 502
Author(s):  
Andrea Visca ◽  
Anna Barra Caracciolo ◽  
Paola Grenni ◽  
Luisa Patrolecco ◽  
Jasmin Rauseo ◽  
...  
Keyword(s):  
Antibiotic Resistance ◽  
Anaerobic Digestion ◽  
Resistance Genes ◽  
Emerging Contaminants ◽  
Antibiotic Resistance Genes ◽  
Animal Manure ◽  
Full Scale ◽  
Antibiotic Residues ◽  
Anaerobic Digesters ◽  
One Year

Anaerobic digestion is one of the best ways to re-use animal manure and agricultural residues, through the production of combustible biogas and digestate. However, the use of antibiotics for preventing and treating animal diseases and, consequently, their residual concentrations in manure, could introduce them into anaerobic digesters. If the digestate is applied as a soil fertilizer, antibiotic residues and/or their corresponding antibiotic resistance genes (ARGs) could reach soil ecosystems. This work investigated three common soil emerging contaminants, i.e., sulfamethoxazole (SMX), ciprofloxacin (CIP), enrofloxacin (ENR), their ARGs sul1, sul2, qnrS, qepA, aac-(6′)-Ib-cr and the mobile genetic element intI1, for one year in a full scale anaerobic plant. Six samplings were performed in line with the 45-day hydraulic retention time (HRT) of the anaerobic plant, by collecting input and output samples. The overall results show both antibiotics and ARGs decreased during the anaerobic digestion process. In particular, SMX was degraded by up to 100%, ENR up to 84% and CIP up to 92%, depending on the sampling time. In a similar way, all ARGs declined significantly (up to 80%) in the digestate samples. This work shows how anaerobic digestion can be a promising practice for lowering antibiotic residues and ARGs in soil.

scholarly journals Role of Inorganic and Organic Fractions in Animal Manure Compost in Lead Immobilization and Microbial Activity in Soil

2016 ◽  
Vol 2016 ◽  
pp. 1-9 ◽  
Author(s):  
Masahiko Katoh ◽  
Wataru Kitahara ◽  
Takeshi Sato
Keyword(s):  
Microbial Activity ◽  
Contaminated Soil ◽  
Animal Manure ◽  
Water Soluble ◽  
Residual Fraction ◽  
Inorganic Component ◽  
Manure Compost ◽  
Microbial Enzyme ◽  
Lead Immobilization ◽  
Inorganic Fraction

This study aimed to identify how the ratio of inorganic-to-organic components in animal manure compost (AMC) affected both lead immobilization and microbial activity in lead-contaminated soil. When AMC containing 50% or more inorganic fraction with high phosphorous content was applied to contaminated soil, the amounts of water-soluble lead in it were suppressed by over 88% from the values in the soil without compost. The residual fraction under sequential extraction increased with the inorganic fraction in the AMC; however, in those AMCs, the levels of microbial enzyme activity were the same or less than those in the control soil. The application of AMC containing 25% inorganic fraction could alter the lead phases to be more insoluble while improving microbial enzyme activities; however, no suppression of the level of water-soluble lead existed during the first 30 days. These results indicate that compost containing an inorganic component of 50% or more with high phosphorus content is suitable for immobilizing lead; however, in the case where low precipitation is expected for a month, AMC containing 25% inorganic component could be used to both immobilize lead and restore microbial activity.

Numerical Simulation on the Temperature Characteristics of Indirect Air Cooling System

2015 ◽  
Vol 741 ◽  
pp. 536-540
Author(s):  
Xiao Zhi Qiu ◽  
Yan Ming Zhao ◽  
Bao Hua Huang ◽  
Wei Xu
Keyword(s):  
Numerical Simulation ◽  
Wind Speed ◽  
Cooling System ◽  
System Change ◽  
Temperature Characteristic ◽  
Air Cooling ◽  
Ansys Software ◽  
System A ◽  
Air Cooling System ◽  
Simulation Results

Based on the analysis of indirect air cooling system, a numerical simulation model of indirect air cooling system was constructed by ANSYS software. According to the different wind speed condition, the temperature characteristic of indirect air cooling system was analyzed. The simulation results show that with the increase of wind speed, the ventilation and heat release of the indirect air cooling system change greatly. It provides a theoretical basis for the design of the wind-proof device of indirect air cooling system.

Rechargeable Personal Air Conditioning Device

2016 ◽  
Author(s):  
Yilin Du ◽  
Jan Muehlbauer ◽  
Jiazhen Ling ◽  
Vikrant Aute ◽  
Yunho Hwang ◽  
...  
Keyword(s):  
Air Conditioning ◽  
Cooling System ◽  
Cooling Capacity ◽  
Comfort Level ◽  
Vapor Compression ◽  
Air Conditioning System ◽  
System A ◽  
Single Person ◽  
Vapor Compression Cycle ◽  
Compression Cycle

A rechargeable personal air-conditioning (RPAC) device was developed to provide an improved thermal comfort level for individuals in inadequately cooled environments. This device is a battery powered air-conditioning system with the phase change material (PCM) for heat storage. The condenser heat is stored in the PCM during the cooling operation and is discharged while the battery is charged by using the vapor compression cycle as a thermosiphon loop. The conditioned air is discharged towards a single person through adjustable nozzle. The main focus of the current research was on the development of the cooling system. A 100 W cooling capacity prototype was designed, built, and tested. The cooling capacity of the vapor compression cycle measured was 165.6 W. The PCM was recharged in nearly 8 hours under thermosiphon mode. When this device is used in the controlled built environment, the thermostat setting can be increased so that building air conditioning energy can be saved by about 5–10%.

Preliminary Evaluation of the 24 Ft. Diameter Fan Performance In the MinWaterCSP Large Cooling Systems Test Facility

2021 ◽  
Author(s):  
S. J. van der Spuy ◽  
D. N. J. Els ◽  
L. Tieghi ◽  
G. Delibra ◽  
A. Corsini ◽  
...  
Keyword(s):  
Scaling Laws ◽  
Static Pressure ◽  
Cooling System ◽  
Pressure Rise ◽  
Full Scale ◽  
Test Facility ◽  
Small Scale ◽  
Preliminary Evaluation ◽  
Cfd Analysis ◽  
Setting Angle

Abstract The MinWaterCSP project was defined with the aim of reducing the cooling system water consumption and auxiliary power consumption of concentrating solar power (CSP) plants. A full-scale, 24 ft (7.315 m) diameter model of the M-fan was subsequently installed in the Min WaterCSP cooling system test facility, located at Stellenbosch University. The test facility was equipped with an in-line torque arm and speed transducer to measure the power transferred to the fan rotor, as well as a set of rotating vane anemometers upstream of the fan rotor to measure the air volume flow rate passing through the fan. The measured results were compared to those obtained on the 1.542 m diameter ISO 5801 test facility using the fan scaling laws. The comparison showed that the fan power values correlated within +/− 7% to those of the small-scale fan, but at a 1° higher blade setting angle for the full-scale fan. To correlate the expected fan static pressure rise, a CFD analysis of the 24 ft (7.315 m) diameter fan installation was performed. The predicted fan static pressure rise values from the CFD analysis were compared to those measured on the 1.542 m ISO test facility, for the same fan. The simulation made use of an actuator disc model to represent the effect of the fan. The results showed that the predicted results for fan static pressure rise of the installed 24 ft (7.315 m) diameter fan correlated closely (smaller than 1% difference) to those of the 1.542 m diameter fan at its design flowrate but, once again, at approximately 1° higher blade setting angle.

scholarly journals Amines in boreal forest air at SMEAR II station in Finland

2018 ◽  
Vol 18 (9) ◽  
pp. 6367-6380 ◽  
Author(s):  
Marja Hemmilä ◽  
Heidi Hellén ◽  
Aki Virkkula ◽  
Ulla Makkonen ◽  
Arnaud P. Praplan ◽  
...  
Keyword(s):  
Boreal Forest ◽  
Gas Phase ◽  
Particle Number ◽  
Detection Limits ◽  
Ambient Air ◽  
Monthly Means ◽  
Ammonium Ions ◽  
Quadrupole Mass ◽  
Concentration Data ◽  
Diurnal Variability

Abstract. We measured amines in boreal forest air in Finland both in gas and particle phases with 1 h time resolution using an online ion chromatograph (instrument for Measuring AeRosols and Gases in Ambient Air – MARGA) connected to an electrospray ionization quadrupole mass spectrometer (MS). The developed MARGA-MS method was able to separate and detect seven different amines: monomethylamine (MMA), dimethylamine (DMA), trimethylamine (TMA), ethylamine (EA), diethylamine (DEA), propylamine (PA), and butylamine (BA). The detection limits of the method for amines were low (0.2–3.1 ng m−3), the accuracy of IC-MS analysis was 11–37 %, and the precision 10–15 %. The proper measurements in the boreal forest covered about 8 weeks between March and December 2015. The amines were found to be an inhomogeneous group of compounds, showing different seasonal and diurnal variability. Total MMA (MMA(tot)) peaked together with the sum of ammonia and ammonium ions already in March. In March, monthly means for MMA were < 2.4 and 6.8 ± 9.1 ng m−3 in gas and aerosol phases, respectively, and for NH3 and NH4+ these were 52 ± 16 and 425 ± 371 ng m−3, respectively. Monthly medians in March for MMA(tot), NH3, and NH4+ were < 2.4, 19 and 90 ng m−3, respectively. DMA(tot) and TMA(tot) had summer maxima indicating biogenic sources. We observed diurnal variation for DMA(tot) but not for TMA(tot). The highest concentrations of these compounds were measured in July. Then, monthly means for DMA were < 3.1 and 8.4 ± 3.1 ng m−3 in gas and aerosol phases, respectively, and for TMA these were 0.4 ± 0.1 and 1.8 ± 0.5 ng m−3. Monthly medians in July for DMA were below the detection limit (DL) and 4.9 ng m−3 in gas and aerosol phases, respectively, and for TMA these were 0.4 and 1.4 ng m−3. When relative humidity of air was > 90 %, gas-phase DMA correlated well with 1.1–2 nm particle number concentration (R2=0.63) suggesting that it participates in atmospheric clustering. EA concentrations were low all the time. Its July means were < 0.36 and 0.4 ± 0.4 ng m−3 in gas and aerosol phases, respectively, but individual concentration data correlated well with monoterpene concentrations in July. Monthly means of PA and BA were below detection limits at all times.

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