Inhomogeneous feed gas processing in industrial ozone generation

2008 ◽  
Vol 58 (11) ◽  
pp. 2077-2082 ◽  
Author(s):  
Fabio Krogh ◽  
Reto Merz ◽  
Rudolf Gisler ◽  
Marco Müller ◽  
Bernhard Paolini ◽  
...  

The synthesis of ozone by means of dielectric barrier discharge (DBD) is extensively used in industry. Ozone generators available on the market differ in ozone production capacities, electrode arrangements and working parameters, but operate with a uniformly distributed filamentary discharge plasma pattern. In the presented work the benefits of inhomogeneous feed gas processing are explored. Causality between power induction, production efficiency and working parameters are investigated. Different electrode arrangements, evenly distributed within a given space parameter, were designed, simulated, manufactured and tested on a representative scale. A finite element model was utilized to simulate an inhomogeneous power induction pattern along the ozone generator tube. The simulation yielded the local power density, the local gas temperature gradient and the relative DBD packing density. Results show that the degree of filamentation turns out to be decisive, indicating a new potential by means of plasma tailoring. An arrangement with a pronounced power induction at the inlet of the ozone generator revealed several advantages over homogeneous plasma processing arrangements, for which an increase in robustness and a reduction in electrical power consumption are achieved.

2020 ◽  
Vol 0 (0) ◽  
Author(s):  
Amit Kumar ◽  
Chhotu Ram ◽  
Adebabay Tazeb

AbstractEnergy conservation has become an essential step in pulp and paper industry due to diminishing fossil reserves and high cost of energy. Refining is a mechanical treatment of pulp that modifies the structure of the fibres in order to achieve desired paper-making properties. However, it consumes considerable amount of energy. The electrical power consumption has a direct impact on paper manufacturing cost. Therefore, there is a requirement to minimize the energy cost. Enzyme-assisted refining is the environment friendly option that reduces the energy consumption for papermaking. Enzyme-assisted refining is defined as mechanical refining after pretreatment of pulp with enzymes such as cellulases and hemicellulases. It not only reduces the energy consumption but also improves the quality of finished paper. Enzymes improve the beatability of pulp at same refining degree (°SR) and desired paper properties can be achieved at decreased refining time. The selection of suitable enzyme, optimization of enzyme dose and appropriate reaction time are the key factors for energy reduction and pulp quality improvement during enzyme-assisted refining.


2021 ◽  
Vol 13 (6) ◽  
pp. 1150
Author(s):  
Yang Zhong ◽  
Aiwen Lin ◽  
Chiwei Xiao ◽  
Zhigao Zhou

In this paper, based on electrical power consumption (EPC) data extracted from DMSP/OLS night light data, we select three national-level urban agglomerations in China’s Yangtze River Economic Belt(YREB), includes Yangtze River Delta urban agglomerations(YRDUA), urban agglomeration in the middle reaches of the Yangtze River(UAMRYR), and Chengdu-Chongqing urban agglomeration(CCUA) as the research objects. In addition, the coefficient of variation (CV), kernel density analysis, cold hot spot analysis, trend analysis, standard deviation ellipse and Moran’s I Index were used to analyze the Spatio-temporal Dynamic Evolution Characteristics of EPC in the three urban agglomerations of the YREB. In addition, we also use geographically weighted regression (GWR) model and random forest algorithm to analyze the influencing factors of EPC in the three major urban agglomerations in YREB. The results of this study show that from 1992 to 2013, the CV of the EPC in the three urban agglomerations of YREB has been declining at the overall level. At the same time, the highest EPC value is in YRDUA, followed by UAMRYR and CCUA. In addition, with the increase of time, the high-value areas of EPC hot spots are basically distributed in YRDUA. The standard deviation ellipses of the EPC of the three urban agglomerations of YREB clearly show the characteristics of “east-west” spatial distribution. With the increase of time, the correlations and the agglomeration of the EPC in the three urban agglomerations of the YREB were both become more and more obvious. In terms of influencing factor analysis, by using GWR model, we found that the five influencing factors we selected basically have a positive impact on the EPC of the YREB. By using the Random forest algorithm, we found that the three main influencing factors of EPC in the three major urban agglomerations in the YREB are the proportion of secondary industry in GDP, Per capita disposable income of urban residents, and Urbanization rate.


Atmosphere ◽  
2017 ◽  
Vol 8 (12) ◽  
pp. 126 ◽  
Author(s):  
Matthew Ninneman ◽  
Sarah Lu ◽  
Pius Lee ◽  
Jeffery McQueen ◽  
Jianping Huang ◽  
...  

2010 ◽  
Vol 3 (4) ◽  
pp. 2291-2314
Author(s):  
G. Sarwar ◽  
K. W. Appel ◽  
A. G. Carlton ◽  
R. Mathur ◽  
K. Schere ◽  
...  

Abstract. A new condensed toluene mechanism is incorporated into the Community Multiscale Air Quality Modeling system. Model simulations are performed using the CB05 chemical mechanism containing the existing (base) and the new toluene mechanism for the western and eastern US for a summer month. With current estimates of tropospheric emission burden, the new toluene mechanism increases monthly mean daily maximum 8-h ozone by 1.0–3.0 ppbv in Los Angeles, Portland, Seattle, Chicago, Cleveland, northeastern US, and Detroit compared to that with the base toluene chemistry. It reduces model mean bias for ozone at elevated observed ozone mixing ratios. While the new mechanism increases predicted ozone, it does not enhance ozone production efficiency. Sensitivity study suggests that it can further enhance ozone if elevated toluene emissions are present. While changes in total fine particulate mass are small, predictions of in-cloud SOA increase substantially.


2021 ◽  
Author(s):  
Xinrong Ren ◽  
Phillip Stratton ◽  
Hannah Daley ◽  
Russell Dickerson

<p>Aircraft observations of ozone, ozone precursors, and meteorological parameters were made over the New York City (NYC) and Baltimore areas during ozone exceedance events in summer 2018-2020.  Despite the continued reduction in anthropogenic emissions, ozone exceedance events still frequently occurred in the NYC area.  Ozone production efficiency, defined as the ratio of the ozone production rate to the NO<sub>x</sub> oxidation rate, calculated using these observations,  was about 14 ppb ozone produced per ppb NOx oxidized. This high ozone production efficiency likely contributes to the persistent ozone exceedance problem over the Long Island Sound and Connecticut coastal area, downwind of NYC under prevailing southwesterly winds.  There is some evidence for a decreasing trend although COVID-19 restrictions had an impact on 2020 emissions.  A box model, constrained by observations, was used to examine atmospheric photochemical oxidation processes.  Ozone production rates and their sensitivity to nitrogen oxides (NO<sub>x</sub>) and volatile organic compounds (VOCs) were calculated based on the model results. In general ozone production is VOC sensitive near emission sources and NOx sensitive away from source regions. While the Baltimore area is predominantly in the NOx sensitive region, the NYC area is transitioning from VOC sensitive to NOx sensitive.  Preliminary results show that controlling both NOx and VOCs reduces ozone production in the NYC area. Reducing VOCs can reduce ozone production in emission source regions and reducing NOx can reduce ozone production farther away from the source regions. The results from this work strengthen our understanding of ozone production and provide scientific information for emission control strategies to reduce air pollution in ozone non-attainment areas.</p>


2021 ◽  
Author(s):  
Cécile Ducrocq ◽  
Halldór Geirsson ◽  
Alex Hobé ◽  
Gylfi Páll Hersir ◽  
Thóra Árnadóttir ◽  
...  

<p>Crustal deformation in volcanic areas relates ground motions, measured by geodetic techniques, to physical (e.g. pressure or volumetric) changes of magmatic sources below the surface. These measurements contribute to studies of<!-- this is not optimal, changing it might require rewriting the entire sentence. Perhaps you want to break this sentence into two. --> ongoing processes at the source of possible unrest, and are thus key for hazard assessment in active volcanic areas around the globe. However, such assessments often rely on geodetic-based models with quite simplistic assumptions of the physical structure of the volcanic complex. Particularly, constant values of elastic parameters (e.g. Poisson’s ratio and shear moduli) are commonly used for entire active volcanic areas, thus overlooking the spatial effects of lithological properties, depth-dependant compression and temperature variations on those parameters. These simplifications may lead to inaccurate interpretation of the location, shape, and volume change of deformation sources.</p><p> </p><p>In this study we ask how the 3-D heterogeneities of the elastic crustal structure beneath the Hengill volcanic system, SW Iceland, affects models of deformation sources in the area. The Hengill area hosts two active volcanic systems (Hengill and Hrómundartindur), and two high-enthalpy geothermal power plants (Nesjavellir and Hellisheiði), which provide thermal and electrical power to Reykjavík, the capital of Iceland, only 30 km away. To retrieve information on the spatial heterogeneities in the shear moduli and Poisson’s ratio beneath the Hengill area, we first estimate the 3-D shallow density structure of the area using results from regional and local gravimetric surveys. We implement this structure, along with seismic tomographic studies of the SW Iceland, in a Finite Element Model to solve, using forward models, for the 3-D heterogeneities in the shear moduli and Poisson’s ratio beneath the Hengill area.<!-- This might be more effective if the order of these statements is changed, for example: To achieve [stated goal] we produce [FEM] using [results from geophysics]. --> Furthermore, we discuss the difference between static and kinematic elastic moduli, which is important when building deformation models from seismic tomography.<!-- My first reaction to this statement is: "How do you address this?" This could be answered directly, except if you think it detracts from the story. --> The new 3-D inferred elastic model is then used to re-estimate parameters for different sources of deformation causing uplift and subsidence in the area in the past decades. This study shows the importance of accounting for heterogeneities in the crustal elastic structure to estimate with higher accuracy the sources of deformation in volcanic areas around the world.</p>


2010 ◽  
Vol 10 (6) ◽  
pp. 3001-3025 ◽  
Author(s):  
S. Yu ◽  
R. Mathur ◽  
G. Sarwar ◽  
D. Kang ◽  
D. Tong ◽  
...  

Abstract. A critical module of air quality models is the photochemical mechanism. In this study, the impact of the three photochemical mechanisms (CB4, CB05, SAPRC-99) on the Eta-Community Multiscale Air Quality (CMAQ) model's forecast performance for O3, and its related precursors has been assessed over the eastern United States with observations obtained by aircraft (NOAA P-3 and NASA DC-8) flights, ship and two surface networks (AIRNow and AIRMAP) during the 2004 International Consortium for Atmospheric Research on Transport and Transformation (ICARTT) study. The results show that overall none of the mechanisms performs systematically better than the others. On the other hand, at the AIRNow surface sites, CB05 has the best performance with the normalized mean bias (NMB) of 3.9%, followed by CB4 (NMB=−5.7%) and SAPRC-99 (NMB=10.6%) for observed O3≥75 ppb, whereas CB4 has the best performance with the least overestimation for observed O3<75 ppb. On the basis of comparisons with aircraft P-3 measurements, there were consistent overestimations of O3, NOz, PAN and NOy and consistent underestimations of CO, HNO3, NO2, NO, SO2 and terpenes for all three mechanisms although the NMB values for each species and mechanisms were different. The results of aircraft DC-8 show that CB05 predicts the H2O2 mixing ratios most closely to the observations (NMB=10.8%), whereas CB4 and SAPRC-99 overestimated (NMB=74.7%) and underestimated (NMB=−25.5%) H2O2 mixing ratios significantly, respectively. For different air mass flows over the Gulf of Maine on the basis of the ship data, the three mechanisms have relatively better performance for O3, isoprene and SO2 for the clean marine or continental flows but relatively better performance for CO, NO2 and NO for southwesterly/westerly offshore flows. The results of the O3-NOz slopes over the ocean indicate that SAPRC-99 has the highest upper limits of the ozone production efficiency (εN) (5.8), followed by CB05 (4.5) and CB4 (4.0) although they are much lower than that inferred from the observation (11.8), being consistent with the fact that on average, SAPRC-99 produces the highest O3, followed by CB05 and CB4, across all O3 mixing ratio ranges


2013 ◽  
Vol 842 ◽  
pp. 541-545
Author(s):  
Yun Guo ◽  
Zhi Qiang Huang ◽  
Shun Xin Yang

Natural gas heaters are widely used in gas-fired power plants to meet the combustion needs and to improve the combustion efficiency. For the control features and technical requirements of the natural gas heater, the computer automatic control system for natural gas heater has been designed,and realizes the temperature and liquid level real time measurement and control. The system increases significantly the control accuracy of natural gas temperature, eliminates potential unsafety and improves production efficiency.


2013 ◽  
Vol 13 (3) ◽  
pp. 6923-6969 ◽  
Author(s):  
G. Sarwar ◽  
J. Godowitch ◽  
B. Henderson ◽  
K. Fahey ◽  
G. Pouliot ◽  
...  

Abstract. We incorporate the recently developed Regional Atmospheric Chemistry Mechanism (version 2, RACM2) into the Community Multiscale Air Quality modeling system for comparison with the existing 2005 Carbon Bond mechanism with updated toluene chemistry (CB05TU). Compared to CB05TU, RACM2 enhances the domain-wide monthly mean hydroxyl radical concentrations by 46% and nitric acid by 26%. However, it reduces hydrogen peroxide by 2%, peroxyacetic acid by 94%, methyl hydrogen peroxide by 19%, peroxyacetyl nitrate by 40%, and organic nitrate by 41%. RACM2 predictions generally agree better with the observed data than the CB05TU predictions. RACM2 enhances ozone for all ambient levels leading to higher bias at low (< 60 ppbv) concentrations but improved performance at high (>70 ppbv) concentrations. The RACM2 ozone predictions are also supported by increased ozone production efficiency that agrees better with observations. Compared to CB05TU, RACM2 enhances the domain-wide monthly mean sulfate by 10%, nitrate by 6%, ammonium by 10%, anthropogenic secondary organic aerosols by 42%, biogenic secondary organic aerosols by 5%, and in-cloud secondary organic aerosols by 7%. Increased inorganic and organic aerosols with RACM2 agree better with observed data. While RACM2 enhances ozone and secondary aerosols by relatively large margins, control strategies developed for ozone or fine particles using the two mechanisms do not differ appreciably.


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