Determination and occurrence of organic micropollutants in reverse osmosis treatment for advanced water reuse

2012 ◽  
Vol 66 (1) ◽  
pp. 61-71 ◽  
Author(s):  
Veronica Gomez ◽  
Katariina Majamaa ◽  
Eva Pocurull ◽  
Francesc Borrull
Keyword(s):  
Wastewater Treatment ◽  
Reverse Osmosis ◽  
Water Reuse ◽  
Treatment Plant ◽  
Organic Micropollutants ◽  
Wastewater Reclamation ◽  
North East ◽  
Incomplete Removal ◽  
Wide Range ◽  
Ro Membrane

The growing demand on water resources has increased the interest in wastewater reclamation for multiple end-use applications such as indirect and direct potable reuse. In these applications, the removal of organic micropollutants is of a greater concern than in conventional wastewater treatment. This article presents a collection of data of trace organic micropollutants in an urban wastewater treatment plant (WWTP) in North East Spain using reverse osmosis (RO) membrane treatment. The RO rejection values of the organic molecules studied with a wide range of solute size and hydrophobicity were determined. Several chromatographic methods monitoring different endocrine disrupting chemicals (EDCs), pharmaceuticals and personal care products (PPCPs) were used. Results indicated that secondary effluents from this Spanish WWTP contained most of the studied organic compounds indicating incomplete removal of organics in the conventional treatment of the plant. However, the rejection of most micropollutants was high for all three RO membrane types (low energy, high rejection, fouling resistant) tested. It was observed that some selected micropollutants were less efficiently removed (e.g. the small and polar and the more hydrophobic) and the molecular weight and membrane material influenced removal efficiencies.

Survey on production quality of electrodialysis reversal and reverse osmosis on municipal wastewater desalination

2012 ◽  
Vol 66 (10) ◽  
pp. 2185-2193 ◽  
Author(s):  
Yi-Che Hsu ◽  
Hsin-Hsu Huang ◽  
Yu-De Huang ◽  
Ching-Ping Chu ◽  
Yu-Jen Chung ◽  
...  
Keyword(s):  
Wastewater Treatment ◽  
Reverse Osmosis ◽  
Wastewater Treatment Plant ◽  
Municipal Wastewater ◽  
Treatment Plant ◽  
Municipal Wastewater Treatment ◽  
Wastewater Reclamation ◽  
Sand Filter ◽  
Monovalent Ions

Water shortage has become an emerging environmental issue. Reclamation of the effluent from municipal wastewater treatment plant (WWTP) is feasible for meeting the growth of water requirement from industries. In this study, the results of a pilot-plant setting in Futian wastewater treatment plant (Taichung, Taiwan) were presented. Two processes, sand filter – ultrafiltration – reverse osmosis (SF-UF-RO) and sand filter – electrodialysis reversal (SF-EDR), were operated in parallel to evaluate their stability and filtrate quality. It has been noticed that EDR could accept inflow with worse quality and thus required less pretreatment compared with RO. During the operation, EDR required more frequent chemical cleaning (every 3 weeks) than RO did (every 3 months). For the filtrate quality, the desalination efficiency of SF-EDR ranged from 75 to 80% in continuous operation mode, while the conductivity ranged from 100 to 120 μS/cm, with turbidity at 0.8 NTU and total organic carbon at 1.3 mg/L. SF-EDR was less efficient in desalinating the multivalent ions than SF-UF-RO was. However for the monovalent ions, the performances of the two processes were similar to each other. Noticeably, total trihalomethanes in SF-EDR filtrate was lower than that of SF-UF-RO, probably because the polarization effects formed on the concentrated side of the EDR membrane were not significant. At the end of this study, cost analysis was also conducted to compare the capital requirement of building a full-scale wastewater reclamation plant using the two processes. The results showed that using SF-EDR may cost less than using SF-UF-RO, if the users were to accept the filtrate quality of SF-EDR.

scholarly journals Induction of microbial oxidative stress as a new strategy to enhance the enzymatic degradation of organic micropollutants in wastewater

2019 ◽  
Author(s):  
Amrita Bains ◽  
Octavio Perez-Garcia ◽  
Gavin Lear ◽  
David Greenwood ◽  
Simon Swift ◽  
...  
Keyword(s):  
Oxidative Stress ◽  
Wastewater Treatment ◽  
Oxygen Supply ◽  
Cytochromes P450 ◽  
Treatment Plant ◽  
Dairy Farm ◽  
Organic Micropollutants ◽  
Aquatic Life ◽  
Incomplete Removal ◽  
New Strategy

Organic micropollutants (OMPs) are pervasive anthropogenic contaminants of fresh and marine waters with known potential to adversely affect aquatic life (e.g. endocrine disruption). Their ubiquitous environmental occurrence is primarily attributed to wastewater treatment plant discharges following their incomplete removal by common biological treatment processes. This study assesses a new strategy for promoting the degradation of six model OMPs (i.e. sulfamethoxazole, carbamazepine, tylosin, atrazine, naproxen and ibuprofen) by stimulating microbial oxidoreductase production to counter the effects of oxidative stress caused by oxygen perturbation. Microbial cultures from dairy farm wastewater were exposed to a cyclical ON-OFF perturbations of oxygen supply, ranging from 0.16 to 2 cycles per hour (i.e. 2, 1, 0.5, 0.25 and 0.16 cycles/hour), in laboratory bioreactors. The activity and relative abundances of microbial oxidoreductases (such as peroxidases, cytochromes P450) were upregulated by oxygen perturbation. In comparison to controls subjected to constant oxygen levels, OMP concentrations in perturbed cultures decreased by 70±9% (mean ± SD). A distance-based linear model confirmed strong positive correlations between the relative abundance of the bacterial families, Rhodocyclaceae, Syntrophaceae and Syntrophobacteraceae, and oxygen perturbations. Our results confirm that intentional perturbation of oxygen supply to induce microbial oxidative stress can improve OMP removal efficiencies in wastewater treatment bioreactors.

Pilot scale reverse osmosis refinery wastewater treatment – a techno-economical and sustainability assessment

2021 ◽  
Author(s):  
Pedro D. A. Bastos ◽  
Maria António Santos ◽  
Pedro Jorge Carvalho ◽  
Svetlozar Velizarov ◽  
João G. Crespo
Keyword(s):  
Wastewater Treatment ◽  
Reverse Osmosis ◽  
Water Reuse ◽  
Sustainability Assessment ◽  
Pilot Scale ◽  
Refinery Wastewater ◽  
Wastewater Discharge ◽  
Wastewater Reclamation ◽  
Oil Refineries ◽  
The Past

Technologies for wastewater reclamation and water reuse within oil refineries have been gaining particular attention over the past decade due to legislative pressures associated with the efficient use of water resources and wastewater discharge.

scholarly journals Removal characteristics of dissolved organic matter and membrane fouling in ultrafiltration and reverse osmosis membrane combine processes treating the secondary effluent of wastewater treatment plant

2020 ◽  
Author(s):  
Jianwei Liu ◽  
Mengfei Zhao ◽  
Cui Duan ◽  
Peng Yue ◽  
Tinggang Li
Keyword(s):  
Organic Matter ◽  
Wastewater Treatment ◽  
Humic Acid ◽  
Fulvic Acid ◽  
Reverse Osmosis ◽  
Membrane Fouling ◽  
Municipal Wastewater ◽  
Treatment Plant ◽  
Municipal Wastewater Treatment ◽  
Ro Membrane

Abstract The widespread implementation of municipal wastewater treatment and reuse must first ensure the safety of reused wastewater. The effluent of the municipal wastewater treatment plant contains a large amount of dissolved organic matter (DOM), which adversely affects the reuse of wastewater. In this study, the ultrafiltration (UF) + reverse osmosis (RO) process was used to treat the effluent from wastewater treatment plants. The relationship between the removal performance, membrane fouling of the UF + RO process, and DOM characteristics of influent were studied. The results show that DOM can be removed effectively by UF + RO process. The UF mainly removes DOM with a molecular weight greater than 10 kDa, while RO has a significant removal effect on low-molecular DOM, which mainly cause UF and RO membrane fouling. The UF + RO process has a significant removal rate on fulvic acid, humic acid, tyrosine, and tryptophan, and the order is humic acid > fulvic acid > tyrosine > tryptophan. Fulvic acid contributed the most to the UF membrane fouling, while fulvic acid and protein-like proteins contributed mainly to the RO membrane fouling.

Upgrading of a small wastewater treatment plant in a cold climate region using a moving bed biofilm reactor (MBBR) system

2000 ◽  
Vol 41 (1) ◽  
pp. 177-185 ◽  
Author(s):  
G. Andreottola ◽  
P. Foladori ◽  
M. Ragazzi
Keyword(s):  
Wastewater Treatment ◽  
Wastewater Treatment Plant ◽  
Treatment Plant ◽  
Internal Surface ◽  
Full Scale ◽  
Biofilm Reactor ◽  
Cold Climate ◽  
Moving Bed Biofilm Reactor ◽  
Moving Bed ◽  
North East

The aim of this study was to evaluate the performance of a full-scale upgrading of an existing RBC wastewater treatment plant with a MBBR (Moving Bed Biofilm Reactor) system, installed in a tank previously used for sludge aerobic digestion. The full-scale plant is located in a mountain resort in the North-East of Italy. Due to the fact that the people varied during the year's seasons (2000 resident people and 2000 tourists) the RBC system was insufficient to meet the effluent standards. The MBBR applied system consists of the FLOCOR-RMP®plastic media with a specific surface area of about 160 m2/m3 (internal surface only). Nitrogen and carbon removal from wastewater was investigated over a 1-year period, with two different plant lay-outs: one-stage (only MBBR) and two stage system (MBBR and rotating biological contactors in series). The systems have been operated at low temperature (5–15°C). 50% of the MBBR volume (V=79 m3) was filled. The organic and ammonium loads were in the average 7.9 gCOD m−2 d−1 and 0.9 g NH4−N m−2 d−1. Typical carbon and nitrogen removals in MBBR at temperature lower than 8°C were respectively 73% and 72%.

OPTIMIZING OPERATION OF WASTEWATER TREATMENT PLANTS BY OFFLINE AND ONLINE COMPUTER SIMULATION

1994 ◽  
Vol 30 (2) ◽  
pp. 165-174 ◽  
Author(s):  
Ralf Otterpohl ◽  
Thomas Rolfs ◽  
Jörg Londong
Keyword(s):  
Computer Simulation ◽  
Wastewater Treatment ◽  
Activated Sludge ◽  
Nitrogen Removal ◽  
Wastewater Treatment Plants ◽  
Treatment Plant ◽  
Historical Analysis ◽  
Computer Work ◽  
Biological Phosphorus Removal ◽  
Wide Range

Computer simulation of activated sludge plant for nitrogen removal has become a reliable tool to predict the behaviour of the plant Models including biological phosphorus removal still require some practical experience but they should be available soon. This will offer an even wider range than today's work with nitrogen removal. One major benefit of computer simulation of wastewater treatment plants (WTP) is the optimization of operation. This can be done offline if hydrographs of a plant are collected and computer work is done with “historical” analysis. With online simulation the system is fed with hydrographs up to the actual time. Prognosis can be done from the moment of the computer work based on usual hydrographs. The work of the authors shows how accuratly a treatment plant can be described, when many parameters are measured and available as hydrographs. A very careful description of all details of the special plant is essential, requiring a flexible simulation tool. Based on the accurate simulation a wide range of operational decisions can be evaluated. It was possible to demonstrate that the overall efficiency in nitrogen removal and energy consumption of ml activated sludge plant can be improved.

scholarly journals Sewer Mining as a Distributed Intervention for Water-Energy-Materials in the Circular Economy Suitable for Dense Urban Environments: A Real World Demonstration in the City of Athens

Water ◽  
2021 ◽  
Vol 13 (19) ◽  
pp. 2764
Author(s):  
Argyro Plevri ◽  
Klio Monokrousou ◽  
Christos Makropoulos ◽  
Christos Lioumis ◽  
Nikolaos Tazes ◽  
...  
Keyword(s):  
Wastewater Treatment ◽  
Circular Economy ◽  
Water Reuse ◽  
Wastewater Treatment Plants ◽  
Treatment Plant ◽  
Urban Environments ◽  
Treated Wastewater ◽  
Aquifer Recharge ◽  
Treatment Unit ◽  
Plant Nursery

Water reuse and recycling is gaining momentum as a way to improve the circularity of cities, while recognizing the central role of water within a circular economy (CE) context. However, such interventions often depend on the location of wastewater treatment plants and the treatment technologies installed in their premises, while relying on an expensive piped network to ensure that treated wastewater gets transported from the treatment plant to the point of demand. Thus, the penetration level of treated wastewater as a source of non-potable supply in dense urban environments is limited. This paper focuses on the demonstration of a sewer mining (SM) unit as a source of treated wastewater, as part of a larger and more holistic configuration that examines all three ‘streams’ associated with water in CE: water, energy and materials. The application area is the Athens Plant Nursery, in the (water stressed) city of Athens, Greece. SM technology is in fact a mobile wastewater treatment unit in containers able to extract wastewater from local sewers, treat it directly and reuse at the point of demand even in urban environments with limited space. The unit consists of a membrane bioreactor unit (MBR) and a UV disinfection unit and produces high quality reclaimed water for irrigation and also for aquifer recharge during the winter. Furthermore, a short overview of the integrated nutrient and energy recovery subsystem is presented in order to conceptualise the holistic approach and circularity of the whole configuration. The SM technology demonstrates flexibility, scalability and replicability, which are important characteristics for innovation uptake within the emerging CE context and market.

scholarly journals Direct Osmosis for Reverse Osmosis Fouling Control: Principles, Applications and Recent Developments

2009 ◽  
Vol 3 (1) ◽  
pp. 8-16 ◽  
Author(s):  
Jian-Jun Qin ◽  
Boris Liberman ◽  
Kiran A. Kekre ◽  
Ado Gossan
Keyword(s):  
Wastewater Treatment ◽  
Reverse Osmosis ◽  
Membrane Fouling ◽  
Chemical Potential ◽  
Water Desalination ◽  
Water And Wastewater Treatment ◽  
High Pressure Pump ◽  
Permeable Membrane ◽  
Fouling Control ◽  
Ro Membrane

Reverse osmosis (RO) has been widely applied in various water and wastewater treatment processes as a promising membrane technology. However, RO membrane fouling is a global issue, which limits it operating flux, decreases water production, increases power consumption and requires periodical membranes Cleaning-in-Place (CIP) procedure. This may result in low effectiveness, high cost and adds environmental issues related to the CIP solutions disposal. Forward osmosis (FO) or direct osmosis (DO) is the transport of water across a semi-permeable membrane from higher water chemical potential side to lower water chemical potential side, which phenomenon was observed in 1748. The engineered applications of FO/DO in membrane separation processes have been developed in food processing, wastewater treatment and seawater/brackish water desalination. In recent years, DO has been increasingly attractive for RO fouling control as it is highly efficient and environmentally friendly technique which is a new backwash technique via interval DO by intermittent injection of the high salinity solution without stoppage of high pressure pump or interruption of the operational process and allows keeping RO membrane continuously clean even in heavy bio-fouling conditions and operating RO membranes at high flux. This paper provides the state-of-the-art of the physical principles and applications of DO for RO fouling control as well as its strengths and limitations.

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