scholarly journals Поляризационные процессы в тонких слоях аморфного MoS-=SUB=-2-=/SUB=-, полученных методом высокочастотного магнетронного распыления

2020 ◽  
Vol 54 (5) ◽  
pp. 461
Author(s):  
А.А. Кононов ◽  
Р.А. Кастро Арата ◽  
Д.Д. Главная ◽  
В.М. Стожаров ◽  
Д.М. Долгинцев ◽  
...  
Keyword(s):  
Relaxation Time ◽  
Charge Transport ◽  
Relaxation Process ◽  
Molybdenum Disulfide ◽  
Dielectric Spectroscopy ◽  
Activation Energies ◽  
Thin Layers ◽  
Polarization Process ◽  
Relaxation Polarization ◽  
Dipole Polarization

Abstract The polarization processes in thin layers of amorphous molybdenum disulfide MoS_2 are studied by dielectric spectroscopy techniques. The process of dipole-relaxation polarization is observed. The microscopic parameters of the system are calculated, and the relaxation time of the dipole-polarization process, as well as the activation energies E _ a and E _σ of the relaxation process and conductivity, respectively, are determined. The fact that the two activation energies are close to each other suggests that the processes of relaxation and charge transport are driven by the same mechanism.

scholarly journals Exact statistical solution for the hopping transport of trapped charge via finite Markov jump processes

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Andrey A. Pil’nik ◽  
Andrey A. Chernov ◽  
Damir R. Islamov
Keyword(s):  
Charge Transport ◽  
Thin Layers ◽  
Jump Processes ◽  
Dielectric Films ◽  
Algebraic Equations ◽  
Markov Jump ◽  
Statistical Solution ◽  
Linear Algebraic Equations ◽  
Special Cases ◽  
Thin Dielectric Films

AbstractIn this study, we developed a discrete theory of the charge transport in thin dielectric films by trapped electrons or holes, that is applicable both for the case of countable and a large number of traps. It was shown that Shockley–Read–Hall-like transport equations, which describe the 1D transport through dielectric layers, might incorrectly describe the charge flow through ultra-thin layers with a countable number of traps, taking into account the injection from and extraction to electrodes (contacts). A comparison with other theoretical models shows a good agreement. The developed model can be applied to one-, two- and three-dimensional systems. The model, formulated in a system of linear algebraic equations, can be implemented in the computational code using different optimized libraries. We demonstrated that analytical solutions can be found for stationary cases for any trap distribution and for the dynamics of system evolution for special cases. These solutions can be used to test the code and for studying the charge transport properties of thin dielectric films.

scholarly journals Thermodynamic Analysis of Relaxation Model for Non-Equilibrium Phase Behavior of Hydrocarbon Mixtures

2021 ◽  
Vol 2090 (1) ◽  
pp. 012138
Author(s):  
I M Indrupskiy ◽  
P A Chageeva
Keyword(s):  
Relaxation Time ◽  
Phase Behavior ◽  
Relaxation Process ◽  
Thermodynamic Analysis ◽  
Balance Equation ◽  
Equilibrium Phase ◽  
Characteristic Relaxation Time ◽  
Relaxation Model ◽  
Entropy Balance ◽  
Non Equilibrium

Abstract Mathematical models of phase behavior are widely used to describe multiphase oil and gas-condensate systems during hydrocarbon recovery from natural petroleum reservoirs. Previously a non-equilibrium phase behavior model was proposed as an extension over generally adopted equilibrium models. It is based on relaxation of component chemical potentials difference between phases and provides accurate calculations in some typical situations when non-instantaneous changing of phase fractions and compositions in response to variations of pressure or total composition is to be considered. In this paper we present a thermodynamic analysis of the relaxation model. General equations of non-equilibrium thermodynamics for multiphase flows in porous media are considered, and reduced entropy balance equation for the relaxation process is obtained. Isotropic relaxation process is simulated for a real multicomponent hydrocarbon system with different values of characteristic relaxation time using the non-equilibrium model implemented in the PVT Designer module of the RFD tNavigator simulation software. The results are processed with a special algorithm implemented in Matlab to calculate graphs of the total entropy time derivative and its constituents in the entropy balance equation. It is shown that the constituents have different signs, and the greatest influence on the entropy is associated with the interphase flow of the major component of the mixture and the change of the total system volume in the isotropic process. The characteristic relaxation time affects the rate at which the entropy is approaching its maximum value.

The Influence of Boundary Conditions and Surface Layer Thickness on Dielectric Relaxation of Liquid Crystals Confined in Cylindrical Pores

2000 ◽  
Vol 651 ◽  
Author(s):  
Z. Nazario ◽  
G. P. Sinha ◽  
F.M. Aliev
Keyword(s):  
Liquid Crystal ◽  
Boundary Conditions ◽  
Temperature Dependence ◽  
Layer Thickness ◽  
Dielectric Spectroscopy ◽  
Relaxation Times ◽  
Thin Layers ◽  
Short Axis ◽  
Librational Mode ◽  
Cylindrical Pores

AbstractDielectric spectroscopy was applied to investigate the dynamic properties of liquid crystal octylcyanobiphenyl (8CB) confined in 2000 Å cylindrical pores of Anopore membranes with homeotropic and axial (planar) boundary conditions on the pore walls. Homeotropic boundary conditions allow the investigation of the librational mode in 8CB by dielectric spectroscopy. We found that the dynamics of the librational mode is totally different from the behavior observed in investigations of relaxation due to reorientation of molecules around their short axis. The interpretation of the temperature dependence of relaxation times and of the dielectric strength of the librational mode needs the involvement of the temperature dependence of orientational order parameter. For samples with axial boundary conditions, layers of LCs with different thickness were obtained on the pore walls as a result of controlled impregnation of porous matrices with 8CB from solutions of different liquid crystal concentration. The process due to rotation of molecules around their short axis with single relaxation time observed for bulk 8CB is replaced by a process with a distribution of relaxation times in thin layers. This relaxation process broadens with decreasing layer thickness.

scholarly journals The Influence of the Relaxation Time on the Dynamic Hysteresis in Perovskite Solar Cells

2018 ◽  
Vol 173 ◽  
pp. 03017 ◽  
Author(s):  
Alexandra Palici ◽  
George Alexandru Nemnes ◽  
Cristina Besleaga ◽  
Lucian Pintilie ◽  
Dragos-Victor Anghel ◽  
...  
Keyword(s):  
Solar Cells ◽  
Relaxation Time ◽  
Dynamic Behavior ◽  
Perovskite Solar Cells ◽  
Time Interval ◽  
Electrical Model ◽  
Polarization Process ◽  
Dynamic Hysteresis ◽  
Scan Rate ◽  
Typical Range

We investigate the dynamic behavior of perovskite solar cells by focusing on the relaxation time τ, which corresponds to the slow de-polarization process from an initial bias pre-poled state. The dynamic electrical model (DEM) is employed for simulating the J-V characteristics for different bias scan rates and pre-poling conditions. Depending on the sign of the initial polarization normal or inverted hysteresis may be induced. For fixed pre-poling conditions, the relaxation time, in relation to the bias scan rate, governs the magnitude of the dynamic hysteresis. In the limit of large τ the hysteretic effects are vanishing for the typical range of bias scan rates considered, while for very small τ the hysteresis is significant only when it is comparable with the measurement time interval.

scholarly journals Molecular Association of Tetramethylurea and Chlorobenzene Molecules in Microwave Frequency Range

2010 ◽  
Vol 65 (10) ◽  
pp. 854-858
Author(s):  
Vimal Sharma ◽  
Nagesh Thakur
Keyword(s):  
Relaxation Time ◽  
Dielectric Relaxation ◽  
Viscous Flow ◽  
Relaxation Process ◽  
Binary Mixtures ◽  
Variation Method ◽  
Dielectric Relaxation Time ◽  
Flow Process ◽  
Dielectric Relaxation Process ◽  
Energy Parameters

The dielectric constant ε´ and dielectric loss ε´´ of the binary mixtures of tetramethylurea (TMU) and chlorobenzene (CB) have been calculated at 9.883 GHz by using standard standing microwave techniques. Gopalakrishna’s single frequency concentration variation method has been used to calculate dipole moment μ and dielectric relaxation time τ for different mole fractions of TMU in the binary mixture at different temperatures of 25 °C, 30 °C, 35 °C, and 40 °C. The variation of dielectric relaxation time with the mole fraction of TMU in the whole concentration range of the binary mixtures was found to be non-monotonic. The solute-solute and solute-solvent type of molecular associations may be proposed based upon above observations. Using Eyring rate equations the energy parameters ΔH, ΔF, and ΔS for the dielectric relaxation process and the viscous flow process have been calculated at the given temperatures. It is found from the comparison of energy parameters that, just like the viscous flow process, the dielectric relaxation process can also be treated as a rate process.

Charge transport in thin layers of ferroelectric Hf0.5Zr0.5O2

2016 ◽  
Vol 45 (5) ◽  
pp. 350-356 ◽  
Author(s):  
O. M. Orlov ◽  
D. R. Islamov ◽  
A. G. Chernikova ◽  
M. G. Kozodaev ◽  
A. M. Markeev ◽  
...  
Keyword(s):  
Charge Transport ◽  
Thin Layers

35Cl NQR and Molecular Motion in Solid C6X5Cl (X = H, F)

1992 ◽  
Vol 47 (1-2) ◽  
pp. 330-332 ◽  
Author(s):  
A. D. Gordeev ◽  
G. B. Soifer ◽  
A. P. Zhukov
Keyword(s):  
Relaxation Time ◽  
Molecular Motion ◽  
Lattice Relaxation ◽  
Lattice Relaxation Time ◽  
Activation Energies ◽  
Spin Lattice Relaxation ◽  
Melting Points ◽  
Spin Lattice Relaxation Time ◽  
Spin Lattice ◽  
35Cl Nqr

AbstractThe 35Cl NQR frequency and spin-lattice relaxation time of solid chlorobenzene and chloropentafluorobenzene at temperatures from 77 K to the melting points have been measured and explained by thermoactivated librations and reorientations of the molecules around the normal to their plane. The activation energies of these motions have been estimated

scholarly journals Towards intrinsic charge transport in monolayer molybdenum disulfide by defect and interface engineering

2014 ◽  
Vol 5 (1) ◽  
Author(s):  
Zhihao Yu ◽  
Yiming Pan ◽  
Yuting Shen ◽  
Zilu Wang ◽  
Zhun-Yong Ong ◽  
...  
Keyword(s):  
Charge Transport ◽  
Molybdenum Disulfide ◽  
Interface Engineering
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