Фотополимеризация в слоях фуллерена молекулярного донорно-акцепторного комплекса \Pt(nPr-=SUB=-2-=/SUB=-dtc)-=SUB=-2-=/SUB=-\·(C-=SUB=-60-=/SUB=-)-=SUB=-2-=/SUB=-
AbstractWe measured Raman spectra in crystals of molecular donor–acceptor fullerene complexes { Me ( n Pr_2 dtc )_2} · (C_60)_2 ( Me = Ni, Cu, Pt). In the spectra of the {Pt( n Pr_2 dtc )_2} · (C_60)_2 complex under prolonged irradiation with a laser with λ = 532 nm, characteristic changes in the photopolymerization of fullerene are observed, associated with the splitting of degenerate phonon Hg modes and softening of Ag modes of the C_60 molecule. The kinetics of photopolymerization under conditions of weak irradiation at room temperature is studied. It was found that thermal destruction of the photopolymer with increasing temperature leads to a decrease in its concentration in the final photopolymerization product. The kinetics of thermal destruction is described by the Arrhenius equation, with the activation energy E _A of (0.68 ± 0.03) eV; the dimers are destructed to a concentration of 1% within 15 min at ~114°C.