Hydrodynamic Dispersion Coefficient of Urea in Silty Loam Soil

2019 ◽  
Vol 6 (04) ◽  
Author(s):  
RAM PAL ◽  
H C SHARMA ◽  
M IMTIYAZ
Keyword(s):  
Transport Phenomenon ◽  
Porous Medium ◽  
Contaminant Transport ◽  
Dispersion Coefficient ◽  
Hydrodynamic Dispersion ◽  
Soil Columns ◽  
Soil Medium ◽  
Adverse Health Effects ◽  
Silty Loam ◽  
Loam Soil

The modern theme of agriculture is not only to increase production but also to minimize undesirable environmental effects. Leaching of surface-applied fertilizer is the major source of groundwater pollution. Nitrogenous fertilizers are the most popular among the Indian farmers, which on leaching reach the groundwater in different forms (NH4-N, NO3-N, etc). NO3-N leaches faster than other types, remains in-reactive in groundwater, moves with the velocity of groundwater and contaminates it. Contamination arises when NO3-N accumulates in groundwater and consumed in high amount by humans and animals, may result in adverse health effects. For the study of contaminant transport phenomenon in porous medium, a general convection dispersion equation is used, in which dispersion coefficient is one of the primary parameters necessary to be determined for a particular soil. Keeping it in view a study was conducted to assess different available techniques to determine the dispersion coefficient with the help of soil columns having silty loam soil as soil medium. The value of the dispersion coefficient obtained for silty loam soil, by this method was equal to 0.00576 m2.

scholarly journals Modeling Contaminant Transport of Nitrate in Soil Column

2021 ◽  
Vol 5 (4) ◽  
pp. 471-485
Author(s):  
Anthony Chibuzo Ekeleme ◽  
Benjamin Nnamdi Ekwueme ◽  
Jonah Chukwuemeka Agunwamba
Keyword(s):  
Contaminant Transport ◽  
Dispersion Coefficient ◽  
Soil Column ◽  
Soil Columns ◽  
Modified Model ◽  
Agno3 Solution ◽  
The Difference ◽  
Experimental Values ◽  
Column Outlet ◽  
Chemical Contents

Soil forms solution when it is in contact with water or any liquid. This soil solution disperses into the ground in different parts, at different velocities. Hence, the chemical contents of the soil are leached gradually from soil with infiltrating water. Soil parameter characterizing this phenomenon is referred to as Solute dispersivity. The objective of this study is to model contaminant transport of nitrate in soil, calibrate and verify the model derived. Dispersion studies were performed in the laboratory using soil columns filled with silver nitrate (AgNO3) solution. Samples were collected from the column outlet at intervals of 5minutes and the dispersion coefficient calculated. The dispersion coefficient calculated was incorporated into existing Notordamojo’s model and solved. Results obtained from the research showed that the R2values ranging from 0.741 to 0.896 and 0.484 to 0.769 were obtained for the modified model and the existing Notordamojo’s model respectively. The model verified with the experimental data showed predicted transport was in close agreement with experimental values having coefficient of correlation (r) ranging from 0.86 to 0.98. The difference between the experimental and predicted results, when expressed as a percentage of the experimental value was less than 5%. The study has established that the modified model which accounted for variability in dispersion coefficient offered a better approach than the conventional one. Doi: 10.28991/esj-2021-01290 Full Text: PDF

scholarly journals Monitoring of acetochlor residues in soil and maize grain supported by the laboratory study

2014 ◽  
Vol 60 (No. 11) ◽  
pp. 496-500 ◽  
Author(s):  
M. Kucharski ◽  
M. Dziągwa ◽  
J. Sadowski
Keyword(s):  
Degradation Rate ◽  
Electron Capture Detection ◽  
Soil Medium ◽  
Degradation Data ◽  
Loamy Sand Soil ◽  
Maximum Residue Level ◽  
Time Period ◽  
Silty Loam ◽  
Loam Soil ◽  
Maize Grain

The purpose of this work was to evaluate the acetochlor degradation rate in soils and investigate acetochlor contamination of maize grains and soil. Two kinds of soil: medium silty loam (soil A) and heavy loamy sand (soil B) were collected for the laboratory experiment. The degradation data were plotted. Good linearity was found between logarithmic concentration of acetochlor residues and time, indicating first-order rates of degradation. The t<sub>1/2</sub> values varied from 10.5 days for soil A to 15.1 days for soil B. The degradation rate depends on the soil properties. In the soil A (higher content of clay and organic carbon) the t<sub>1/2</sub> value was shorter than in the soil B. Monitoring tests were carried out during the 2010&ndash;2012 time period on maize fields located in the south-western Poland. Soil and maize grain samples were collected at harvest time. The determination of acetochlor residues was conducted using gas chromatography with electron capture detection. Based on the analysis of a total of 124 environmental samples, acetochlor residues were detected in 17.4% of soil and 8.1% of maize grain samples. None of the examined samples showed a herbicide concentration exceeding the maximum residue level.

Chloride and Lithium Transport in Large Arrays of Undisturbed Silt Loam and Sandy Loam Soil Columns

2004 ◽  
Vol 3 (1) ◽  
pp. 316
Author(s):  
M. Saleem Akhtar ◽  
Tammo S. Steenhuis ◽  
Brian K. Richards ◽  
Murray B. McBride
Keyword(s):  
Sandy Loam ◽  
Sandy Loam Soil ◽  
Silt Loam ◽  
Soil Columns ◽  
Lithium Transport ◽  
Loam Soil

scholarly journals Aggregate stability and associated C and N in a silty loam soil as affected by organic material inputs

2015 ◽  
Vol 14 (4) ◽  
pp. 774-787 ◽  
Author(s):  
Pan LONG ◽  
Peng SUI ◽  
Wang-sheng GAO ◽  
Bin-bin WANG ◽  
Jian-xiong HUANG ◽  
...  
Keyword(s):  
Organic Material ◽  
Aggregate Stability ◽  
Silty Loam ◽  
Loam Soil ◽  
C And N

scholarly journals A short-term comparison of organic v. conventional agriculture in a silty loam soil using two organic amendments

2008 ◽  
Vol 146 (6) ◽  
pp. 677-687 ◽  
Author(s):  
J. F. HERENCIA ◽  
J. C. RUIZ ◽  
S. MELERO ◽  
P. A. GARCIA GALAVÍS ◽  
C. MAQUEDA
Keyword(s):  
Organic Farming ◽  
Crop Yields ◽  
Organic Amendments ◽  
Chemical Properties ◽  
Soil Nutrient ◽  
Short Term ◽  
Organic System ◽  
Conventional Agriculture ◽  
Silty Loam ◽  
Loam Soil

SUMMARYThe transition from conventional to organic farming is accompanied by changes in soil chemical properties and processes that could affect soil fertility. The organic system is very complex and the present work carries out a short-term comparison of the effects of organic and conventional agriculture on the chemical properties of a silty loam soil (Xerofluvent) located in the Guadalquivir River Valley, Seville, Spain, through a succession of five crop cycles over a 3-year period. Crop rotation and varieties were compared in a conventional system using inorganic fertilizer and two organic systems using either plant compost or manure. At the end of the study, organic farming management resulted in higher soil organic carbon (OC), N and available P, K, Fe and Zn. The available Mn and especially Cu values did not show significant differences. In general, treatment with manure resulted in more rapid increases in soil nutrient values than did plant compost, which had an effect on several crop cycles later. The present study demonstrated that the use of organic composts results in an increase in OC and the storage of nutrients, which can provide long-term fertility benefits. Nevertheless, at least 2–3 years of organic management are necessary, depending on compost characteristics, to observe significant differences. Average crop yields were 23% lower in organic crops. Nevertheless, only two crops showed statistically significant differences.

scholarly journals Temperature effect in potassium and nitrate ions in soil transport

2008 ◽  
Vol 28 (3) ◽  
pp. 438-447 ◽  
Author(s):  
Adriano D. M. A. Gonçalves ◽  
Jarbas H. Miranda ◽  
Paulo Rossi ◽  
José F. G. Sabadin ◽  
Marcos Y. Kamogawa
Keyword(s):  
Porous Medium ◽  
Dispersion Coefficient ◽  
Potassium Nitrate ◽  
Positive Influence ◽  
Retardation Factor ◽  
Nitrate Transport ◽  
Transport Parameters ◽  
Medium Temperature ◽  
Soil Transport ◽  
Solute Dynamics

When doing researches on solute dynamics in porous medium, the knowledge of medium characteristics and percolating liquids, as well as of external factors is very important. An important external factor is temperature and, in this sense, our purpose was determining potassium and nitrate transport parameters for different values of temperature, in miscible displacement experiments. Evaluated parameters were retardation factor (R), diffusion/dispersion coefficient (D) and dispersivity, at ambient temperature (25 up to 28 ºC), 40 ºC and 50 ºC. Salts used were potassium nitrate and potassium chlorate, prepared in a solution made up of 5 ppm nitrate and 2.000 ppm potassium, with Red-Yellow Latosol porous medium. Temperature exhibited a positive influence upon porous medium solution and upon dispersion coefficient.

scholarly journals Investigation of a parameter estimation method for contaminant transport in aquifers

2001 ◽  
Vol 3 (4) ◽  
pp. 203-213 ◽  
Author(s):  
Channa Rajanayaka ◽  
Don Kulasiri
Keyword(s):  
Experimental Data ◽  
Hydraulic Conductivity ◽  
Contaminant Transport ◽  
Dispersion Coefficient ◽  
Estimation Method ◽  
Longitudinal Dispersion ◽  
Longitudinal Dispersion Coefficient ◽  
System Noise ◽  
Estimated Parameters ◽  
Comparison Of The Results

Real world groundwater aquifers are heterogeneous and system variables are not uniformly distributed across the aquifer. Therefore, in the modelling of the contaminant transport, we need to consider the uncertainty associated with the system. Unny presented a method to describe the system by stochastic differential equations and then to estimate the parameters by using the maximum likelihood approach. In this paper, this method was explored by using artificial and experimental data. First a set of data was used to explore the effect of system noise on estimated parameters. The experimental data was used to compare the estimated parameters with the calibrated results. Estimates obtained from artificial data show reasonable accuracy when the system noise is present. The accuracy of the estimates has an inverse relationship to the noise. Hydraulic conductivity estimates in a one-parameter situation give more accurate results than in a two-parameter situation. The effect of the noise on estimates of the longitudinal dispersion coefficient is less compared to the effect on hydraulic conductivity estimates. Comparison of the results of the experimental dataset shows that estimates of the longitudinal dispersion coefficient are similar to the aquifer calibrated results. However, hydraulic conductivity does not provide a similar level of accuracy. The main advantage of the estimation method presented here is its direct dependence on field observations in the presence of reasonably large noise levels.

scholarly journals Numerical Modeling of Contaminant Transport with Spatially-Dependent Dispersion and Non-Linear Chemical Reaction

2007 ◽  
Vol 12 (3) ◽  
pp. 329-343 ◽  
Author(s):  
A. J. Chamkha
Keyword(s):  
Contaminant Transport ◽  
Chemical Reaction ◽  
Numerical Solutions ◽  
Dispersion Coefficient ◽  
Transport Model ◽  
Physical Parameters ◽  
Contaminant Concentration ◽  
Dimensionless Time ◽  
Polynomial Type ◽  
Special Cases

A one-dimensional advective-dispersive contaminant transport model with scale-dependent dispersion coefficient in the presence of a nonlinear chemical reaction of arbitrary order is considered. Two types of variations of the dispersion coefficient with the downstream distance are considered. The first type assumes that the dispersivity increases as a polynomial function with distance while the other assumes an exponentiallyincreasing function. Since the general problem is nonlinear and possesses no analytical solutions, a numerical solution based on an efficient implicit iterative tri-diagonal finitedifference method is obtained. Comparisons with previously published analytical and numerical solutions for special cases of the main transport equation are performed and found to be in excellent agreement. A parametric study of all physical parameters is conducted and the results are presented graphically to illustrate interesting features of the solutions. It is found that the chemical reaction order and rate coefficient have significant effects on the contaminant concentration profiles. Furthermore, the scale-dependent polynomial type dispersion coefficient is predicted to obtain significant changes in the contaminant concentration at all dimensionless time stages compared with the constant dispersion case. However, relatively smaller changes in the concentration level are predicted for the exponentially-increasing dispersion coefficient.

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