Modeling of a Fixed-Bed Reactor for the Production of Phthalic Anhydride

2011 ◽  
Vol 6 (1) ◽  
Author(s):  
Amir Rahimi ◽  
Sogand Hamidi
Keyword(s):  
Phthalic Anhydride ◽  
Fixed Bed ◽  
Tubular Reactor ◽  
Operating Conditions ◽  
Fixed Bed Reactor ◽  
Conversion Degree ◽  
Reactor Length ◽  
Reactor Temperature ◽  
Reported Data ◽  
Reactor Pressure

In this study, the performance of a fixed–bed tubular reactor for the production of phthalic anhydride is mathematically analyzed. The conversion degree and reactor temperature values are compared with the measured one in a tubular reactor applied in Farabi petrochemical unit in Iran as well as reported data in the literature for a pilot plate. The comparisons are satisfactory. The effects of some operating parameters including reactor length, feed temperature, reactor pressure, and existence of an inert in the catalytic bed are investigated. The optimum value of each parameter is determined on the basis of the corresponding operating conditions.

scholarly journals Effect of Temperature on Plasma-Assisted Catalytic Cracking of Palm Oil into Biofuels

2020 ◽  
Vol 9 (1) ◽  
pp. 107-112 ◽  
Author(s):  
I. Istadi ◽  
Teguh Riyanto ◽  
Luqman Buchori ◽  
Didi Dwi Anggoro ◽  
Roni Ade Saputra ◽  
...  
Keyword(s):  
Palm Oil ◽  
Catalytic Cracking ◽  
Plasma Reactor ◽  
Fixed Bed ◽  
Liquid Product ◽  
Fixed Bed Reactor ◽  
Effect Of Temperature ◽  
Catalytic Reactor ◽  
Catalytic Role ◽  
Reactor Temperature

Plasma-assisted catalytic cracking is an attractive method for producing biofuels from vegetable oil. This paper studied the effect of reactor temperature on the performance of plasma-assisted catalytic cracking of palm oil into biofuels. The cracking process was conducted in a Dielectric Barrier Discharge (DBD)-type plasma reactor with the presence of spent RFCC catalyst. The reactor temperature was varied at 400, 450, and 500 ºC. The liquid fuel product was analyzed using a gas chromatography-mass spectrometry (GC-MS) to determine the compositions. Result showed that the presenceof plasma and catalytic role can enhance the reactor performance so that the selectivity of the short-chain hydrocarbon produced increases. The selectivity of gasoline, kerosene, and diesel range fuels over the plasma-catalytic reactor were 16.43%, 52.74% and 21.25%, respectively, while the selectivity of gasoline, kerosene and diesel range fuels over a conventional fixed bed reactor was 12.07%, 39.07%, and 45.11%, respectively. The increasing reactor temperature led to enhanced catalytic role of cracking reaction,particularly directing the reaction to the shorter hydrocarbon range. The reactor temperature dependence on the liquid product components distribution over the plasma-catalytic reactor was also studied. The aromatic and oxygenated compounds increased with the reactor temperature.©2020. CBIORE-IJRED. All rights reserved

Methanol synthesis from CO2 and H2 in multi-tubular fixed-bed reactor and multi-tubular reactor filled with monoliths

2014 ◽  
Vol 92 (11) ◽  
pp. 2598-2608 ◽  
Author(s):  
Sofiane Arab ◽  
Jean-Marc Commenge ◽  
Jean-François Portha ◽  
Laurent Falk
Keyword(s):  
Methanol Synthesis ◽  
Fixed Bed ◽  
Tubular Reactor ◽  
Fixed Bed Reactor

Theoretical Investigations of Methane Conversion to Heavier Hydrocarbons in a Plasma Reactor

2012 ◽  
Vol 548 ◽  
pp. 153-159
Author(s):  
Mohammad Kazemeini ◽  
Masoud Habibi Zare ◽  
Nora Safabakhsh ◽  
Shadi Roshdi Ferdosi ◽  
Moslem Fattahi
Keyword(s):  
Methane Conversion ◽  
Plasma Reactor ◽  
Fixed Bed ◽  
Oxidative Coupling Of Methane ◽  
Operating Conditions ◽  
Fixed Bed Reactor ◽  
Plasma Process ◽  
Process Yield ◽  
Theoretical Investigations ◽  
Product And Process

In this study, mathematical modelling of oxidative coupling of methane (OCM) to C2hydrocarbons (C2H6and C2H4) over La2O3/CaO catalyst in a fixed-bed reactor operated under isothermal and non-isothermal conditions was investigated using the MATLAB program. In this process, methane and acetylene were the inputted feed and ethane, ethylene, propylene, propane, i-butane and n-butane were the output products. The amount of methane conversion obtained was 12.7% for the former feed however; if pure methane was inputted this conversion rose to 13.8%. Furthermore, the plasma process would enhance the conversion, selectivity towards desired product and process yield. A comparison between the thermal and the plasma process showed that the methane conversion and production yield in the plasma were higher than in the thermal process under the same operating conditions. Finally, the results of the catalytic OCM and methane conversion processes in the plasma phase were compared with one another.

The Fixed Bed Reaction of Residual Natural Rubber for Oil Production by Pyrolysis Process

2014 ◽  
Vol 931-932 ◽  
pp. 225-230
Author(s):  
Khanita Kamwilaisak ◽  
Mallika Thabuot
Keyword(s):  
Particle Size ◽  
Pyrolysis Temperature ◽  
Fixed Bed ◽  
Maximum Amount ◽  
Operating Conditions ◽  
Fixed Bed Reactor ◽  
Pyrolysis Process ◽  
Pyrolysis Reaction ◽  
Benzenedicarboxylic Acid ◽  
Chemical Feedstock

The aim of this study is to use pyrolysis reaction to produce oil product as a fuel or chemical feedstock. The fixed bed reactor was used as a pyrolysis system. The pyrolysis reaction of residual para rubber was operated in the absence of catalyse. The operating conditions such as particle size (0.5 and 1.0 cm3) and pyrolysis temperature (500, 550 and 600 OC) were studied under N2 conditions and retention time 90 min. The result shows the para rubber size 1.0 cm3 can be produced liquid phase more than of para rubber size of 0.5 cm3. The optimised condition with the highest oil yield was at 550OC with rubber size of 1.0 cm3. The percentage of the product was 60% of liquid, 35% of gas and 5% of solid (char). Furthermore, the FTIR result can be presented the supported evidence that the transformation of aliphatic contents to be aromatic contents was increased with increased temperature. Also, GCMS analysis was used for the identification and quantification of the product. It was found 5 major products that can be used as a chemical feedstock. The maximum amount of component was 2-Benzenedicarboxylic acid, diisooctyl ester (Isooctyl phthalate) with 22.08%. This is a plasticizer with higher cost than fuel.

Utilisation of Biogas From an Urban Sewage Treatment Plant in a Solid Oxide Fuel Cell

2010 ◽  
Author(s):  
Andrea Lanzini ◽  
Pierluigi Leone ◽  
Massimo Santarelli
Keyword(s):  
Sewage Treatment ◽  
Fixed Bed ◽  
Sewage Treatment Plant ◽  
Treatment Plant ◽  
Cell Voltage ◽  
Operating Conditions ◽  
Fixed Bed Reactor ◽  
Urban Sewage ◽  
Anode Degradation ◽  
Anode Supported Cell

A biogas coming from anaerobic digestion of urban sewage has been used to feed a SOFC planar anode-supported cell. The sewage is produced from the urban area of Torino (IT), and eventually collected and treated by SMAT (the municipal company managing the potable and waste water of the city). The biogas is produced by the thermophilic fermentation of the sludge which remains after the several treatments the sewage goes through in the above-mentioned plant. The biogas is of a high quality: it has on average a a methane content around 65% (the balance being essentially CO2), and the only significant impurity measured is H2S in a range of 70–80 ppm. The as-produced biogas has been used for feeding a planar Ni-YSZ anode-supported SOFC with a LSCF cathode. The biogas desulphurization was accomplished flowing the gas in a fixed-bed reactor, filled with activated. The fuel processing with POX has been assessed to avoid carbon deposition into the Ni-YSZ anode and convert the CH4 into H2 and CO. Short tests to check for eventual anode degradation were performed under typical operating conditions. The cell voltage was always stable under load with the tested mixtures. A cell electrical efficiency around 45% has been measured at 800°C and 80% FU. System simulations have performed as well to assess the whole system configuration under a biogas feeding. Optimization routines have been implemented to predict the best net AC efficiency achievable by a SOFC system running on biogas. Additional considerations on the management of poor LHV biogas mixture have been also assessed, showing how dry-reforming of CH4 with the CO2 already available in the biogas stream would be an excellent option needed to be investigated with further detail in the next future.

scholarly journals Kinetic Study Based on the Carbide Mechanism of a Co-Pt/γ-Al2O3 Fischer–Tropsch Catalyst Tested in a Laboratory-Scale Tubular Reactor

Catalysts ◽  
2019 ◽  
Vol 9 (9) ◽  
pp. 717 ◽  
Author(s):  
Marco Marchese ◽  
Niko Heikkinen ◽  
Emanuele Giglio ◽  
Andrea Lanzini ◽  
Juha Lehtonen ◽  
...  
Keyword(s):  
Carbon Number ◽  
Fixed Bed ◽  
Tubular Reactor ◽  
Fixed Bed Reactor ◽  
Molar Ratio ◽  
Fischer Tropsch ◽  
Mechanism Model ◽  
Conversion Level ◽  
Temperature Programmed ◽  
Xrd Techniques

A Co-Pt/γ-Al2O3 catalyst was manufactured and tested for Fischer–Tropsch applications. Catalyst kinetic experiments were performed using a tubular fixed-bed reactor system. The operative conditions were varied between 478 and 503 K, 15 and 30 bar, H2/CO molar ratio 1.06 and 2.11 at a carbon monoxide conversion level of about 10%. Several kinetic models were derived, and a carbide mechanism model was chosen, taking into account an increasing value of termination energy for α-olefins with increasing carbon numbers. In order to assess catalyst suitability for the determination of reaction kinetics and comparability to similar Fischer–Tropsch Synthesis (FTS) applications, the catalyst was characterized with gas sorption analysis, temperature-programmed reduction (TPR), and X-ray diffraction (XRD) techniques. The kinetic model developed is capable of describing the intrinsic behavior of the catalyst correctly. It accounts for the main deviations from the typical Anderson-Schulz-Flory distribution for Fischer–Tropsch products, with calculated activation energies and adsorption enthalpies in line with values available from the literature. The model suitably predicts the formation rates of methane and ethylene, as well as of the other α-olefins. Furthermore, it properly estimates high molecular weight n-paraffin formation up to carbon number C80.

scholarly journals Integrated Ozonation-Enzymatic Hydrolysis Pretreatment of Sugarcane Bagasse: Enhancement of Sugars Released to Expended Ozone Ratio

Processes ◽  
2020 ◽  
Vol 8 (10) ◽  
pp. 1274 ◽  
Author(s):  
Daryl Rafael Osuna-Laveaga ◽  
Octavio García-Depraect ◽  
Ramiro Vallejo-Rodríguez ◽  
Alberto López-López ◽  
Elizabeth León-Becerril
Keyword(s):  
Enzymatic Hydrolysis ◽  
Sugarcane Bagasse ◽  
Fixed Bed ◽  
Operating Conditions ◽  
Fixed Bed Reactor ◽  
Particle Sizes ◽  
Combined Effects ◽  
Sugar Release ◽  
The Relationship ◽  
Ozonation Process

The combined effects of three key ozonation process parameters on the integrated ozonation-enzymatic hydrolysis pretreatment of sugarcane bagasse (SCB) were investigated, with emphasis on the relationship between sugar release and ozone consumption. A lab-scale fixed bed reactor was employed for ozonation at varying ozone doses (50, 75 and 100 mg O3/g SCB), particle sizes (420, 710 and 1000 µm) and moisture contents (30, 45 and 60% w/w) in multifactorial experiments, keeping a residence time of 30 min. The ozonated SCB showed a reduction in the content of acid-insoluble lignin from 26.6 down to 19.1% w/w, while those of cellulose and hemicellulose were retained above 45.5 and 13.6% w/w, with recoveries of 100–89.9 and 83.5–72.7%, respectively. Ozone-assisted enzymatic hydrolysis allowed attaining glucose and xylose yields as high as 45.0 and 37.8%, respectively. The sugars released/ozone expended ratio ranged between 2.3 and 5.7 g sugars/g O3, being the higher value achieved with an applied ozone input of 50 mg O3/g SCB and SCB with 420 µm particle size and 60% moisture. Such operating conditions led to efficient ozone utilization (<2% unreacted ozone) with a yield of 0.29 g sugars/g SCB. Overall, the amount of sugars released relative to the ozone consumed was improved, entailing an estimated cost of ozonation of USD 34.7/ton of SCB, which could enhance the profitability of the process.

Effect of Reactor Temperature on Pyrolysis of Lignocellulosic Medical Waste in a Fixed Bed Reactor

2019 ◽  
Vol 15 (15) ◽  
Author(s):  
Pious O. Okekunle ◽  
Olukunle E. Itabiyi ◽  
Emmanuel O. Olafimihan ◽  
Sunday O. Adetola ◽  
Oluremilekun R. Oyetunji ◽  
...  
Keyword(s):  
Fixed Bed ◽  
Medical Waste ◽  
Fixed Bed Reactor ◽  
Reactor Temperature
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