scholarly journals INFLUENCE OF GRAM-NEGATIVE STRAIN KLEBSIELLA OXYTOCA ON BIOCORROSION

Author(s):  
Chitra S ◽  
Anand B

Several studies of biofilms must accept that biofilms may develop in an enormous number of environments. This biofilm forms colonization on the solid surfaces by extracellular polysaccharides (EPSs) secreted by the microbial cells. The EPSs secreted by microbial cell stimulate corrosion in the engineered materials due to the presence of polyanionic neutral macromolecules. Many techniques have been described measuring and inhibiting microbiologically influenced corrosion; however, none has been accepted as an industry standard. This is because the risks posed to the marine biosphere due to the use of antifouling inhibitors. Recently, a large amount of literature has been edited on the influence of toxic biocides on non-targeted organisms in the marine environment are most likely. It has been shown that the modifications of antifouling inhibitors by the non-toxic drugs can reduce microbial adhesion and some disentangle effects toward the environment. Hence, in this paper, the inhibition effect of neomycin trisulfate on the Klebsiella oxytoca on mild steel corrosion has been investigated using weight loss measurement, electrochemical impedance spectroscopy, Fourier-transform infrared, and scanning electron microscopy (SEM). These studies have shown that neomycin trisulfate shows better inhibition toward the microbe. The agreement with the experimental data was also found to be satisfactory. Further, surface morphological examination through SEM confirms that the inhibitor inhibits the microbes by blocking the EPS

2011 ◽  
Vol 66-68 ◽  
pp. 540-544 ◽  
Author(s):  
Ahmed Y. Musa ◽  
Abdul Amir H. Kadhum ◽  
Abu Bakar Mohamad ◽  
Mohd Sobri Takriff

The organic material named 4-amino-5-phenyl-4H-1, 2, 4-trizole-3-thiol (APTT) was studied as inhibitor for mild steel corrosion in 1.0 M HCl at 30 °C. The effects of turbulent flow on the inhibition process were characterized using open circuit potential (OCP), potentiodynamic polarization, electrochemical impedance spectroscopy (EIS) and scanning electron microscopy (SEM). Turbulent flow condition experiments were simulated by Rotating Cylinder Electrode (RCE). Results obtained from changes of open circuit potential (OCP) with immersion time, potentiodynamic polarization, and impedance measurements all are in good agreement and indicated that the formation and the development of the inhibitor film were flow rate dependence. The scanning electron micrograph confirmed film structure is dependence of flow condition.


2013 ◽  
Vol 2013 ◽  
pp. 1-9 ◽  
Author(s):  
M. K. Pavithra ◽  
T. V. Venkatesha ◽  
M. K. Punith Kumar

The corrosion inhibition effect of Rabeprazole sulfide (RS) on mild steel in 1 M hydrochloric acid (HCl) was investigated using weight loss, potentiodynamic polarization, electrochemical impedance spectroscopy (EIS), and chronoamperometric measurements. Protection efficiency of RS increases with the concentration and decreases with the rise in temperature. Adsorption of RS on mild steel surface in 1 M HCl follows Langmuir adsorption isotherm. The kinetic and thermodynamic parameters governing the adsorption process were calculated and discussed. The polarization results suggest that RS performed as an excellent mixed-type inhibitor for mild steel corrosion in 1 M HCl.


2011 ◽  
Vol 8 (s1) ◽  
pp. S53-S60 ◽  
Author(s):  
M. Vishnudevan

The inhibition efficiency of mild steel corrosion in HCl acidic solution containing various concentrations of mixed inhibitors were evaluated by conducting Tafel polarization and electrochemical impedance studies. The mixed inhibitors used in this present investigation were trisodium citrate and sodium benzoate. In this present investigation 0.01 N to 0.1 N concentrations of HCl was used at 30°C. Sodium benzoate present in the mixed inhibitive system enhanced the inhibition efficiency through chemisorptions. The maximum inhibition efficiency ( 95.4%) was obtained for the mixed inhibitive system containing 0.05 M citrate and 0.5 M benzoate in 0.1 N HCl.


2014 ◽  
Vol 10 (3) ◽  
pp. 2388-2402 ◽  
Author(s):  
M.P. Chakravarthy ◽  
Dr. K. N. Mohana ◽  
C.B. Pradeep Kumar

Dapsone derivatives Viz., 4, 4’-sulfonylbis(N-((1H-pyrrol-2-yl)methylene)aniline) (SBPMA) and 2-dimethylamino-5-[(4-{4-[(4-dimethylamino-benzylidene)-amino]-benzenesulfonyl}-phenylimino)-methyl]-benzene (DBBPB), a new class of corrosion inhibitors have been synthesized and their corrosion inhibition efficiency on mild steel in 0.5 M H2SO4 was investigated by mass loss,  Tafel polarization and AC impedance measurements. Potentiodynamic polarization studies showed that, these compounds behave as mixed type of corrosion inhibitors. The adsorption process was found to obey Langmuir isotherm model. Electrochemical impedance spectroscopy (EIS) studies revealed that polarization resistance (RP) increases and double layer capacitance (Cdl) decreases as the concentration of the inhibitors increases. Various thermodynamic parameters for the adsorption of inhibitors on mild steel were computed and discussed. FTIR, EDX and SEM analyses were performed to study the film persistency of the inhibitors.


2018 ◽  
Vol 55 (5B) ◽  
pp. 103
Author(s):  
Bui Thi Thanh Huyen

This paper deals with the effect of anion groups (SO42- and Cl-) on inhibition behaviours of Vietnam orange peel essential oil (OPE) for corrosion process of mild steel in acidic media. The electrochemical techniques (potentiodynamic, electrochemical impedance spectroscopy (EIS)), weight loss and scanning electron microscopy (SEM) analyses are used in this study. The results show that anion groups do not affect the inhibition mechanism of OPE. The OPE ­behaves as mixed inhibitor for mild steel corrosion in both 1N HCl and H2SO4 acid. The inhibition efficiency of OPE in 1N HCl is greater than that in 1N H2SO4 which implies that the adsorption of the inhibitor is influenced by the nature of anions in acidic solutions. Moreover, the OPE inhibits both general and pitting corrosion for mild steel in the acidic media. 


2019 ◽  
Vol 233 (11) ◽  
pp. 1553-1569 ◽  
Author(s):  
Rola N. Tabesh ◽  
Ashraf Moustafa Abdel-Gaber ◽  
Hassan H. Hammud ◽  
Rami Al-Oweini

Abstract The ligands 1,10-phenanthroline, (P) and para-aminobenzoate, (B); as well as their corresponding MnPB complex [bis-(dimanganese di-μ-paraaminobenzoate dichloro diphenanthroline)] have been investigated as inhibitors of mild steel corrosion in H2SO4 (0.5 M) solutions via potentiodynamic and electrochemical impedance spectroscopy techniques. Stability of the prepared complex was examined by UV-visible spectroscopy. The corrosion inhibition, thermodynamics, and adsorptive properties obtained have shown that MnPB complex has remarkable effects in the acidic solutions. Theoretical fitting of different adsorption isotherms such as Langmuir, Flory–Huggins, and the kinetic-thermodynamic models were tested and the thermodynamic activation parameters were calculated. The data revealed that the corrosion inhibition mechanism of mild steel in acidic solutions by the MnPB complex goes via physicochemical adsorption.


2019 ◽  
Vol 66 (5) ◽  
pp. 544-555 ◽  
Author(s):  
Ilham Elazhary ◽  
My Rachid Laamari ◽  
Aziz Boutouil ◽  
Lahoucine Bahsis ◽  
Mohammadine El Haddad ◽  
...  

Purpose This paper aims to study the corrosion inhibition of Methyl 2-(benzamido)-2-(4-phenyl-1H-1,2,3-triazol-1-yl) acetate (MBPTA) and Methyl 2-(benzamido)-2-(4-p-tolyl-1H-1,2,3-triazol-1-yl) acetate (MBTTA) in 1 M H2SO4 solution at 25 °C. Design/methodology/approach The authors have used weight loss measurements, electrochemical impedance spectroscopy (EIS), potentiodynamic polarization, FT-IR, quantum chemical calculations and scanning electron microscopy (SEM) techniques. Findings The polarization measurements indicate that both compounds are mixed type inhibitors, and that MBTTA is more effective than MBPTA. The effect of temperature on the corrosion behavior using optimal concentration of MBTTA and MBPTA was studied in the temperature range 298-328 K. SEM was used to examine the morphology of the metal surface. Thermodynamic parameters were calculated and discussed. Monte Carlo simulations were applied to lookup for the most stalls configuration and adsorption energy for the interaction of inhibitors on Fe (1 1 1) interface. The difference in inhibition efficiencies between the two organic inhibitors can be clearly explained in terms of frontier molecular orbital theory. Originality/value The authors report on the comparative inhibiting effect of two new 1,4-disubstituted 1,2,3-triazoles, namely Methyl 2-(benzamido)-2-(4-phenyl-1H-1,2,3-triazol-1-yl) acetate (MBPTA) and Methyl 2-(benzamido)-2-(4-p-tolyl-1H-1, 2, 3-triazol-1-yl) acetate (MBTTA) on mild steel corrosion in 1 M H2SO4 solution.


2017 ◽  
Vol 64 (1) ◽  
pp. 23-35 ◽  
Author(s):  
Mohammed Elalaoui Belghiti ◽  
Ayssar Nahlé ◽  
Abdeslam Ansari ◽  
Yasser Karzazi ◽  
S. Tighadouini ◽  
...  

Purpose This paper aims to study the inhibition effect of 2-pyridinealdazine on the corrosion of mild steel in an acidic medium. The inhibition effect was studied using weight loss, electrochemical impedance spectroscopy, and Tafel polarization measurements. Design/methodology/approach Weight loss measurements, potentiodynamic tests, electrochemical impedance spectroscopy, X-ray diffraction and spectral and conformational isomers analysis of A (E-PAA) and B (Z-PAA) were performed were investigated. Findings 2-pyridinealdazine (PAA) acts as a good inhibitor for the corrosion of steel in 2.0 M H3PO4. The inhibition efficiency increases with an increase in inhibitor concentration but decreases with an increase in temperature. Originality/value This paper is intended to be added to the family of azines which are highly efficient inhibitors and can be used in the area of corrosion prevention and control.


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