scholarly journals Modelowanie emisji podtlenku azotu i amoniaku w skali regionalnej oraz w Polsce

2018 ◽  
Vol 18(33) (2) ◽  
pp. 70-81
Author(s):  
Antoni Faber ◽  
Zuzanna Jarosz
Keyword(s):  
Organic Carbon ◽  
Emission Factor ◽  
Meteorological Data ◽  
N2o Emission ◽  
Ammonia Emission ◽  
N2o Emissions ◽  
Dndc Model ◽  
Cultivation Systems ◽  
Nh3 Emission ◽  
Direct Emission

The aim of the research was to verify the N2O direct and NH3 emission factors adopted in national inventories, and to estimate the direct and indirect N2O emissions in cultivation systems increasing carbon sequestration. Simulations were performed using the DNDC model for NUTS2 and Poland with the use of twenty-year series of meteorological data. It was found that the simulated direct emission of nitrous oxide for Poland was in line with the adopted emission factor. The simulated ammonia emission was greater than the assumed emission factor. Use in simulations of cultivation systems increasing the sequestration of organic carbon, such as conservation system and conventional system with manure fertilization, increased: surface leaching and runoff of nitrogen as well as direct and indirect N2O emission. The increase of these emissions must be compensated with an allowance increase in the amount of sequestered organic carbon in the soil if the greenhouse gas emissions balance is to be negative.

Emissions of the indirect greenhouse gases NH3 and NOx from Australian beef cattle feedlots

2008 ◽  
Vol 48 (2) ◽  
pp. 213 ◽  
Author(s):  
O. T. Denmead ◽  
D. Chen ◽  
D. W. T. Griffith ◽  
Z. M. Loh ◽  
M. Bai ◽  
...  
Keyword(s):  
Greenhouse Gases ◽  
Emission Factor ◽  
Production Systems ◽  
Agricultural Soils ◽  
N2o Emission ◽  
N2o Emissions ◽  
Oxides Of Nitrogen ◽  
Liquid Form ◽  
Nh3 Emission ◽  
N Compounds

Emissions of indirect greenhouse gases, notably the nitrogen gases ammonia (NH3) and the odd oxides of nitrogen (NOx), play important roles in the greenhouse story. Feedlots are intense, but poorly quantified, sources of atmospheric NH3 and although production of NOx is to be expected in feedlots, rates of NOx emission are virtually unknown. In the atmosphere, these gases are involved in several transformations, but eventually return to the earth in gaseous or liquid form and can then undergo further transformations involving the formation and emission of the direct greenhouse gas nitrous oxide (N2O). The IPCC Phase II guidelines estimate that indirect N2O emissions due to atmospheric deposition of N compounds formed from NH3 and NOx could be ~14% of the direct emissions from agricultural soils or from animal production systems. IPCC recommends that these indirect emissions be accounted for in making inventory estimates of N2O emission. This paper is a preliminary report of emissions of NH3 and NOx from two Australian feedlots determined with micrometeorological techniques. Emissions of nitrogen gases from both feedlots were dominated by emissions of NH3. The average NH3 emission rate over both feedlots in winter was 46 g N/animal.day, while that of NOx was less than 1% of that rate at 0.36 g N/animal.day. It was apparent that NH3 release was governed by the wetness of the surface. Rates of emission from the feedlot with the wetter surface were almost three times those from the other. The IPCC default emission factor for the combined emission of NH3 and NOx from livestock is 0.2 kg N/kg N excreted, but in our work, the emission factor was 0.59 kg N/kg N excreted. Potential emissions of N2O due to NH3 and NOx deposition were estimated to be of the same magnitude as the direct N2O emissions, the sum of direct and potential indirect amounting to ~3 g N2O-N/animal.day. If applied nationally, this would represent a contribution of N2O from Australian feedlots of 533Gg CO2-e or 2.2% of all Australian N2O emissions.

scholarly journals Major Elements to Consider in Developing Ammonia Emission Factor at Municipal Solid Waste (MSW) Incinerators

2021 ◽  
Vol 13 (4) ◽  
pp. 2197
Author(s):  
Seongmin Kang ◽  
Joonyoung Roh ◽  
Eui-chan Jeon
Keyword(s):  
Municipal Solid Waste ◽  
Solid Waste ◽  
Emission Factor ◽  
Waste Incineration ◽  
Emission Factors ◽  
Major Elements ◽  
Ammonia Emission ◽  
Nh3 Emission ◽  
The Difference ◽  
The One

NH3 is one of the major substances contributing to the secondary generation of PM2.5; therefore, management is required. In Korea, the management of NH3 is insufficient, and the emission factor used by EPA is the same as the one used when calculating emissions. In particular, waste incineration facilities do not currently calculate NH3 emissions. In the case of combustion facilities, the main ammonia emission source is the De-NOx facility, and, in the case of a power plant with a De-NOx facility, NH3 emission is calculated. Therefore, in the case of a Municipal Solid Waste (MSW) incinerator with the same facility installed, it is necessary to calculate NH3 emissions. In this study, the necessity of developing NH3 emission factors for an MSW incinerator and calculating emission was analyzed. In addition, elements to be considered when developing emission factors were analyzed. The study found that the NH3 emission factors for each MSW incinerator technology were calculated as Stoker 0.010 NH3 kg/ton and Fluidized Beds 0.004 NH3 kg/ton, which was greater than the NH3 emission factor 0.003 NH3 kg/ton for the MSW incinerator presented in EMEP/EEA (2016). As a result, it was able to identify the need for the development of NH3 emission factors in MSW incinerators in Korea. In addition, the statistical analysis of the difference between the incineration technology of MSW and the NH3 emission factor by the De-NOx facility showed a difference in terms of both incineration technology and De-NOx facilities, indicating that they should be considered together when developing the emission factor. In addition to MSW, it is believed that it will be necessary to review the development of emission factors for waste at workplaces and incineration facilities of sewage sludge.

scholarly journals Groundwater N<sub>2</sub>O emission factors of nitrate-contaminated aquifers as derived from denitrification progress and N<sub>2</sub>O accumulation

2008 ◽  
Vol 5 (5) ◽  
pp. 1215-1226 ◽  
Author(s):  
D. Weymann ◽  
R. Well ◽  
H. Flessa ◽  
C. von der Heide ◽  
M. Deurer ◽  
...  
Keyword(s):  
Emission Factor ◽  
Noble Gas ◽  
N2o Emission ◽  
Emission Factors ◽  
N2o Emissions ◽  
Northern Germany ◽  
Stable Component ◽  
Sand And Gravel ◽  
First Time ◽  
Ipcc Default

Abstract. We investigated the dynamics of denitrification and nitrous oxide (N2O) accumulation in 4 nitrate (NO−3) contaminated denitrifying sand and gravel aquifers of northern Germany (Fuhrberg, Sulingen, Thülsfelde and Göttingen) to quantify their potential N2O emission and to evaluate existing concepts of N2O emission factors. Excess N2 – N2 produced by denitrification – was determined by using the argon (Ar) concentration in groundwater as a natural inert tracer, assuming that this noble gas functions as a stable component and does not change during denitrification. Furthermore, initial NO−3 concentrations (NO−3 that enters the groundwater) were derived from excess N2 and actual NO−3 concentrations in groundwater in order to determine potential indirect N2O emissions as a function of the N input. Median concentrations of N2O and excess N2 ranged from 3 to 89 μg N L−1 and from 3 to 10 mg N L−1, respectively. Reaction progress (RP) of denitrification was determined as the ratio between products (N2O-N + excess N2) and starting material (initial NO−3 concentration) of the process, characterizing the different stages of denitrification. N2O concentrations were lowest at RP close to 0 and RP close to 1 but relatively high at a RP between 0.2 and 0.6. For the first time, we report groundwater N2O emission factors consisting of the ratio between N2O-N and initial NO−3-N concentrations (EF1). In addition, we determined a groundwater emission factor (EF2) using a previous concept consisting of the ratio between N2O-N and actual NO−3-N concentrations. Depending on RP, EF(1) resulted in smaller values compared to EF(2), demonstrating (i) the relevance of NO−3 consumption and consequently (ii) the need to take initial NO−3-N concentrations into account. In general, both evaluated emission factors were highly variable within and among the aquifers. The site medians ranged between 0.00043–0.00438 for EF(1) and 0.00092–0.01801 for EF(2), respectively. For the aquifers of Fuhrberg and Sulingen, we found EF(1) median values which are close to the 2006 IPCC default value of 0.0025. In contrast, we determined significant lower EF values for the aquifers of Thülsfelde and Göttingen. Summing the results up, our study supports the substantial downward revision of the IPCC default EF5-g from 0.015 (1997) to 0.0025 (2006).

scholarly journals Mitigation of CO2 and N2O Emission from Cabbage Fields in Korea by Optimizing Tillage Depth and N-Fertilizer Level: DNDC Model Simulation under RCP 8.5 Scenario

2019 ◽  
Vol 11 (21) ◽  
pp. 6158 ◽  
Author(s):  
Wonjae Hwang ◽  
Minseok Park ◽  
Kijong Cho ◽  
Jeong-Gyu Kim ◽  
Seunghun Hyun
Keyword(s):  
Model Simulation ◽  
Supply And Demand ◽  
N2o Emission ◽  
Economic Losses ◽  
Change Scenario ◽  
N2o Emissions ◽  
Low Carbon ◽  
Farming Practices ◽  
Dndc Model ◽  
Tillage Depth

In this study, we applied the Denitrification and Decomposition model to predict the greenhouse gas (GHGs; CO2 and N2O) emissions and cabbage yields from 8072 cabbage fields in Korea in the 2020s and 2090s. Model outputs were evaluated as a function of tillage depth (T1, T2, and T3 for 10, 20, and 30 cm) and fertilizer level (F1, F2, and F3 for 100, 200, and 400 kg N ha−1) under the Representative Concentration Pathways 8.5 climate change scenario. For both time periods, CO2 emissions increased with tillage depth, and N2O emissions were predominantly influenced by the level of applied N-fertilizers. Both cabbage yields and GHGs fluxes were highest when the T3F3 farming practice was applied. Under current conventional farming practices (T1F3), cabbage yield was projected at 64.5 t ha−1 in the 2020s, which was close in magnitude to the predicted cabbage demand. In the 2090s, the predicted cabbage supply by the same practice far exceeded the projected demand at 28.9 t ha−1. Cabbage supply and demand were balanced and GHGs emissions reduced by 19.6% in the 2090s when 94% of the total cabbage farms adopted low carbon-farming practices (e.g., reducing fertilizer level). Our results demonstrate the large potential for Korean cabbage farms to significantly contribute towards the mitigation of GHGs emissions through the adoption of low-carbon farming practices. However, in order to incentivize the shift towards sustainable farming, we advise that lower yield and potential economic losses in farmlands from adopting low-carbon practices should be appropriately compensated by institutional policy.

Nitrous oxide emission from two acidic soils as affected by dolomite application

Soil Research ◽  
2014 ◽  
Vol 52 (8) ◽  
pp. 841 ◽  
Author(s):  
Muhammad Shaaban ◽  
Qian Peng ◽  
Shan Lin ◽  
Yupeng Wu ◽  
Jinsong Zhao ◽  
...  
Keyword(s):  
Nitrous Oxide ◽  
Microbial Biomass ◽  
Organic Carbon ◽  
Soil Ph ◽  
Microbial Biomass Carbon ◽  
Rice Paddy ◽  
N2o Emission ◽  
N2o Emissions ◽  
Biomass Carbon ◽  
Acidic Soils

The effect of dolomite (CaMg(CO3)2) application on nitrous oxide (N2O) emission was examined in a laboratory study with soil from a rice paddy–rapeseed rotation (PR soil, pH 5.25) and from a rice paddy–fallow–flooded rotation soil (PF soil, pH 5.52). The soils were treated with 0, 0.5 (L) and 1.5 (H) g dolomite 100 g–1 soil. Results showed that N2O emissions were higher in control treatments (untreated dolomite) in both soils. Application of dolomite decreased N2O emissions significantly (P ≤ 0.001) as soil pH increased in both soils. The H treatment was more effective than the L treatment for the reduction of N2O emissions. The H treatment decreased the cumulative N2O emissions by up to 73.77% in PR soil and 64.07% in PF soil compared with the control. The application of dolomite also affected concentrations of dissolved organic carbon, microbial biomass carbon, ammonium and nitrate in soils, which related to N2O emission. The results suggest that dolomite not only counteracts soil acidification but also has the potential to mitigate N2O emissions in acidic soils.

scholarly journals Ammonia emission measurements of an intensively grazed pasture

2018 ◽  
Author(s):  
Karl Voglmeier ◽  
Markus Jocher ◽  
Christoph Häni ◽  
Christof Ammann
Keyword(s):  
Dairy Cows ◽  
Emission Factor ◽  
Ambient Air ◽  
Ammonia Emission ◽  
Large Uncertainty ◽  
Protein Balance ◽  
Grazing Season ◽  
Measurement Campaign ◽  
Grazed Pasture ◽  
Nh3 Emission

Abstract. The quantification of ammonia (NH3) emissions in ambient air conditions is still a challenge and the corresponding emission factor for grazed pastures have therefore a large uncertainty. This study presents NH3 emission measurements of two pasture systems in western Switzerland over the entire grazing season 2016. During the measurement campaign, each pasture system was grazed by 12 dairy cows in an intensive rotational management. The cow herds on the two pastures differed in the energy to protein balance of the diet. NH3 concentrations were measured upwind and downwind of a grazed sub plot with line integrating open path instruments that were able to retrieve small horizontal concentration differences (

Estimating a nitrous oxide emission factor for animal urine from some New Zealand pastoral soils

Soil Research ◽  
2003 ◽  
Vol 41 (3) ◽  
pp. 381 ◽  
Author(s):  
Cecile A. M. de Klein ◽  
Louise Barton ◽  
Robert R. Sherlock ◽  
Zheng Li ◽  
Roger P. Littlejohn
Keyword(s):  
Nitrous Oxide ◽  
New Zealand ◽  
Emission Factor ◽  
N2o Emission ◽  
Emission Factors ◽  
N2o Emissions ◽  
Drainage Class ◽  
Background Levels ◽  
Cow Urine ◽  
N2o Emission Factor

The Intergovernmental Panel on Climate Change methodology estimates that over 50% of total nitrous oxide (N2O) emissions in New Zealand derive from animal excreta-N deposited during grazing. The emission factor for excreta-N as used by this methodology has an important impact on New Zealand's total N2O inventory. The objectives of this study were to refine the N2O emission factor for urine by simultaneously measuring N2O emissions from 5 pastoral soils of different drainage class, in 3 different regions in New Zealand following a single application of urine; plus test various aspects of the soil cover method for determining emission factors. Cow urine and synthetic urine was applied to pastoral soils in autumn 2000 and N2O emissions were measured using closed flux chambers at regular intervals for 4–18 months following application. The N2O emission factors for cow urine estimated for the first 4 months after urine application varied greatly depending on rainfall and soil drainage class, and ranged from 0.3 to 2.5% of the urine-N applied, suggesting that adopting a single emission factor for New Zealand may be inappropriate. The largest emission factor was found in a poorly drained soil, and the lowest emission factor was found in a well-drained stony soil. Ongoing measurements on one of the soils resulted in an increase in emission factors as the N2O emissions had not reached background levels 4 months after urine application. To characterise urine-induced N2O emissions, we recommend measurements continue until N2O emissions from urine-amended soil return to background levels. Furthermore, we recommend using real animal urine rather than synthetic urine in studies when determining the N2O emission factor for urine.

scholarly journals Ammonia Emission Characteristics and Emission Factor of Municipal Solid Waste Incineration Plant

2020 ◽  
Vol 12 (18) ◽  
pp. 7309
Author(s):  
Seongmin Kang ◽  
Jiyun Woo ◽  
Eui-chan Jeon
Keyword(s):  
Municipal Solid Waste ◽  
Solid Waste ◽  
Emission Factor ◽  
Waste Treatment ◽  
Waste Incineration ◽  
Air Pollutant ◽  
Pollutant Emission ◽  
Ammonia Emission ◽  
Activity Data ◽  
Nh3 Emission

This study aims to analyze whether ammonia emission occurs when municipal solid waste (MSW) is incinerated. In cases where ammonia is emitted, we aim to develop an emission factor, calculate annual emission amounts by utilizing activity data (waste incineration amount) applied in air pollutant emission calculations for the waste combustion in Korea, and investigate whether there is a need for emission calculation. As a result of the study, the ammonia emission factor of the MSW incineration facility to be studied was 0.0091 kgNH3/ton, which was 3 times higher than the emission factor in Europe. In the case of emissions, a randomly developed emission factor was applied to confirm the necessity of development of the emission factor, and as a result of the application, it was found to be 22 NH3 ton/year, which is the same number as the annual NH3 emission of the entire waste treatment sector in 2016. Therefore, we believe that MSW incinerator facilities should be recognized as one of the major NH3 omitted emission sources. Moreover, it is evident that there is a need for an NH3 emission factor and emission calculations that reflect the characteristics of Korea.

scholarly journals TransCom N<sub>2</sub>O model inter-comparison – Part 2: Atmospheric inversion estimates of N<sub>2</sub>O emissions

2014 ◽  
Vol 14 (12) ◽  
pp. 6177-6194 ◽  
Author(s):  
R. L. Thompson ◽  
K. Ishijima ◽  
E. Saikawa ◽  
M. Corazza ◽  
U. Karstens ◽  
...  
Keyword(s):  
Meteorological Data ◽  
N2o Emission ◽  
Inversion Method ◽  
N2o Emissions ◽  
Observation Data ◽  
High Latitudes ◽  
Data Set ◽  
The Mean ◽  
The Tropics ◽  
Atmospheric Inversion

Abstract. This study examines N2O emission estimates from five different atmospheric inversion frameworks based on chemistry transport models (CTMs). The five frameworks differ in the choice of CTM, meteorological data, prior uncertainties and inversion method but use the same prior emissions and observation data set. The posterior modelled atmospheric N2O mole fractions are compared to observations to assess the performance of the inversions and to help diagnose problems in the modelled transport. Additionally, the mean emissions for 2006 to 2008 are compared in terms of the spatial distribution and seasonality. Overall, there is a good agreement among the inversions for the mean global total emission, which ranges from 16.1 to 18.7 TgN yr−1 and is consistent with previous estimates. Ocean emissions represent between 31 and 38% of the global total compared to widely varying previous estimates of 24 to 38%. Emissions from the northern mid- to high latitudes are likely to be more important, with a consistent shift in emissions from the tropics and subtropics to the mid- to high latitudes in the Northern Hemisphere; the emission ratio for 0–30° N to 30–90° N ranges from 1.5 to 1.9 compared with 2.9 to 3.0 in previous estimates. The largest discrepancies across inversions are seen for the regions of South and East Asia and for tropical and South America owing to the poor observational constraint for these areas and to considerable differences in the modelled transport, especially inter-hemispheric exchange rates and tropical convective mixing. Estimates of the seasonal cycle in N2O emissions are also sensitive to errors in modelled stratosphere-to-troposphere transport in the tropics and southern extratropics. Overall, the results show a convergence in the global and regional emissions compared to previous independent studies.

Nitrous oxide emission factor from cattle urine and dung in native grassland of the Pampa biome, South Brazil

Soil Research ◽  
2020 ◽  
Vol 58 (2) ◽  
pp. 198 ◽  
Author(s):  
Janquieli Schirmann ◽  
Diego Fernandes de Bastos ◽  
Douglas Adams Weiler ◽  
Murilo G. Veloso ◽  
Jeferson Dieckow ◽  
...  
Keyword(s):  
Nitrous Oxide ◽  
Emission Factor ◽  
Live Weight ◽  
N2o Emission ◽  
N2o Emissions ◽  
Native Grassland ◽  
Tier 1 ◽  
N2o Fluxes ◽  
The Impact ◽  
South Brazil

Native grassland supports extensive livestock production in the Pampas of South America, but the impact of cattle excreta on nitrous oxide (N2O) emissions remains unknown in this biome. The objective of this study was to determine the N2O emission factor (EF-N2O, % of N applied that is emitted as N2O) for urine and dung from beef cattle grazing on native grasslands. A field trial was conducted under low and moderate forage allowances (FA4 and FA12; i.e. 4 and 12 kg dry matter/100 kg live weight respectively) during the 30th year of a long-term grassland experiment on a Typic Paleudult in South Brazil. Urine and dung were applied onto separate patches, at rates equivalent to one average urination or defecation; and N2O fluxes were monitored with closed static chambers over 338 days. In adjacent microplots receiving the same excreta treatment, water-filled pore space, nitrate, ammonium and extractable dissolved organic carbon were monitored in the top 0.1 m of soil. Averaged across the forage allowances, daily soil N2O fluxes were low in the control without excreta (1.3 g N ha–1), but increased upon application of dung (3.8 g N ha–1) and urine (66 g N ha–1). The annual N2O emission and the EF-N2O for urine were greater under FA12 than FA4, but no difference was observed for dung. The positive relationships between N2O-N emissions and ammonium intensity and nitrate intensity suggest that N2O may have been produced concurrently by nitrification, nitrifier/denitrification and denitrification. On average, the EF-N2O was almost 10 times higher for urine than for dung (0.74% vs 0.08%), both much lower than the IPCC’s Tier 1 default value of 2%. Our findings reinforce the need for disaggregating the EF-N2O for urine and dung and of revising the IPCC’s Tier 1 EF-N2O.

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