scholarly journals Remove of Humic Acid From Water Using Magnetite Nanoparticles

2020 ◽  
Vol 1 (4) ◽  
Author(s):  
M. Smiri ◽  
F. Guey ◽  
H. Chemingui ◽  
A. B. Dekhil ◽  
S. Elarbaoui ◽  
...  
Keyword(s):  
Humic Acid ◽  
Magnetite Nanoparticles ◽  
Fe3o4 Nanoparticles ◽  
Contact Time ◽  
Isotherm Models ◽  
Maximum Adsorption Capacity ◽  
Sorption Data ◽  
Equilibrium Data ◽  
Pseudo Second Order ◽  
Co Precipitation

Synthesis, characterization and application of iron oxide nanoparticles have received much attention in recent years due to their interesting chemical and physics properties. Magnetite (Fe3O4) nanoparticles were synthesed by chemical co-precipitation and characterized using X ray diffraction (XDR), Fourier transmission spectroscopy (FT-IR), dynamic light scattering and (DLS). Fe3O4 nanoparticles were successfully removed humic acid (HA) from water. The influence of pH, contact time, adsorbent nanoparticle doses and HA concentrations were analyzed. Maximum HA removal occurred at pH 6 (89.63%), 40 mg.L-1 of Magnetite (88.8%), 0.03g of HA (96.64%) and contact time of 20 min (94.37%). Sorption data fit pseudo-second order kinetics, indicated a chemical adsorption process. The Langmuir, Freundlich and Temkin adsorption isotherm models were applied to describe equilibrium data. Adsorption of HA on magnetite nanoparticles was well described by Temkin model. The maximum adsorption capacity was 128.23 mg.g-1. Fe3O4 nanoparticles were promising potential adsorbents for HA removal from water.

scholarly journals Utilization to Remove Pb (II) Ions from Aqueous Environments Using Waste Fish Bones by Ion Exchange

2014 ◽  
Vol 2014 ◽  
pp. 1-12 ◽  
Author(s):  
Bayram Kizilkaya ◽  
A. Adem Tekınay
Keyword(s):  
Aqueous Solutions ◽  
Adsorption Mechanism ◽  
Cost Effective ◽  
Isotherm Models ◽  
Maximum Adsorption Capacity ◽  
Fish Bones ◽  
Adsorption Capacities ◽  
Aqueous Environments ◽  
Equilibrium Data ◽  
Pseudo Second Order

Removal of lead (II) from aqueous solutions was studied by using pretreated fish bones as natural, cost-effective, waste sorbents. The effect of pH, contact time, temperature, and metal concentration on the adsorption capacities of the adsorbent was investigated. The maximum adsorption capacity for Pb (II) was found to be 323 mg/g at optimum conditions. The experiments showed that when pH increased, an increase in the adsorbed amount of metal of the fish bones was observed. The kinetic results of adsorption obeyed a pseudo second-order model. Freundlich and Langmuir isotherm models were applied to experimental equilibrium data of Pb (II) adsorption and the value ofRLfor Pb (II) was found to be 0.906. The thermodynamic parameters related to the adsorption process such asEa,ΔG°,ΔH°, andΔS° were calculated andEa,ΔH°, andΔS° were found to be 7.06, 46.01 kJ mol−1, and 0.141 kJ mol−1K−1for Pb (III), respectively.ΔH° values (46.01 kJmol−1) showed that the adsorption mechanism was endothermic. Weber-Morris and Urano-Tachikawa diffusion models were also applied to the experimental equilibrium data. The fish bones were effectively used as sorbent for the removal of Pb (II) ions from aqueous solutions.

Sorption of Uranium (VI) From Aqueous Solution Using Nanomagnetite Particles; Singly and Coated With Humic Acid

2021 ◽  
Author(s):  
Ismail Mohamed Ahmed ◽  
Aly A. Helal ◽  
Rasha Gamal ◽  
Salah aboEinien ◽  
Abdullah A. Helal
Keyword(s):  
Aqueous Solution ◽  
Humic Acid ◽  
Magnetite Nanoparticles ◽  
Kinetic Data ◽  
Contact Time ◽  
Organic Coating ◽  
Langmuir Model ◽  
Sorption Kinetic ◽  
Maximum Capacity ◽  
Pseudo Second Order

Abstract Magnetite nanoparticles (Fe3O4) and humic acid coated magnetite nanoparticles (Fe3O4/HA) were investigated for the removal of U(VI) from aqueous solution. Batch sorption experiments were studied as a function contact time, adsorbent mass, U(VI) concentration and pH. The sorption kinetic data follow the pseudo-second order while the isotherms are found to obey Langmuir model with maximum capacity (Qmax) of 230, 196 mg/g for Fe3O4 and Fe3O4/HA, respectively. The study reveals that humic acid decreases the sorption capacity due to the formation of a polyanionic organic coating and thus altering the surface properties of the particles and reduces the magnetite aggregation and stabilizes the magnetite suspension.

scholarly journals Preparation of a novel Fe3O4/HCO composite adsorbent and the mechanism for the removal of antimony (III) from aqueous solution

2019 ◽  
Vol 9 (1) ◽  
Author(s):  
Jun Zhang ◽  
Ren-jian Deng ◽  
Bo-zhi Ren ◽  
Baolin Hou ◽  
Andrew Hursthouse
Keyword(s):  
Dominant Role ◽  
Second Order ◽  
Maximum Adsorption Capacity ◽  
Isothermal Adsorption ◽  
Batch Tests ◽  
Equilibrium Data ◽  
Langmuir Isotherm Model ◽  
Pseudo Second Order ◽  
Co Precipitation ◽  
Optical Polishing

Abstract A novel adsorbent (Fe3O4/HCO) was prepared via co-precipitation from a mix of ferriferrous oxide and a Ce-rich waste industrial sludge recovered from an optical polishing activity. The effect of system parameters including reaction time, pH, dose, temperature as well as initial concentration on the adsorption of Sb(III) were investigated by sequential batch tests. The Sb(III)/Fe3O4/HCO system quickly reached adsorption equilibrium within 2 h, was effective over a wide pH (3–7) and demonstrated excellent removal at a 60 mg/L Sb(III) concentration. Three isothermal adsorption models were assessed to describe the equilibrium data for Sb(III) with Fe3O4/HCO. Compared to the Freundlich and dubinin-radushkevich, the Langmuir isotherm model showed the best fit, with a maximum adsorption capacity of 22.853 mg/g, which exceeds many comparable absorbents. Four kinetic models, Pseudo-first-order, Pseudo-second-order, Elovich and Intra-particle, were used to fit the adsorption process. The analysis showed that the mechanism was pseudo-second-order and chemical adsorption played a dominant role in the adsorption of Sb(III) by Fe3O4/HCO (correlation coefficient R2 = 0.993). Thermodynamic calculations suggest that adsorption of Sb(III) ions was endothermic, spontaneous and a thermodynamically feasible process. The mechanism of the adsorption of Sb(III) on Fe3O4/HCO could be described by the synergistic adsorption of Sb (III) on Fe3O4, FeCe2O4 and hydrous ceric oxide. The Fe3O4/HCO sorbent appears to be an efficient and environment-friendly material for the removal of Sb(III) from wastewater.

Chromium (VI) adsorption onto activated sulfate lignin

2009 ◽  
Vol 4 (2) ◽  
Author(s):  
Nassima Tazrouti ◽  
Moussa Amrani
Keyword(s):  
Adsorption Capacity ◽  
Contact Time ◽  
Analytical Data ◽  
Order Equation ◽  
Second Order ◽  
Isotherm Models ◽  
Maximum Adsorption Capacity ◽  
Adsorption Model ◽  
Chromium Vi ◽  
Pseudo Second Order

Activated lignin having surface area of 1023 m2.g-1 has been prepared from sulfate lignin that was treated by 30 % H2O2 and carbonized at 300 °C in order to test the chromium (VI) adsorption from aqueous solution. The influence of contact time, pH, initial concentration of adsorbent and adsorbate and temperature on the adsorption capacity were investigated. The maximum removal of Cr(VI) was found to be 92,36 % at pH=2 and contact time of 80 min. Optimal concentration of lignin and Cr(VI) were found to be 3.8 g.l-1 and 180 mg.l-1, respectively. The adsorption kinetics was tested pseudo-first-order and pseudo-second-order equation. The analytical data were fitted well in a pseudo-second-order equation and the rate of removal of chromium was found to speed up with increasing temperature. Activation energy for the adsorption process was found to be 18.19 Kj.mol-1. The Langmuir and Freundlich adsorption isotherm models were applied to describe the isotherm and isotherm constants for the adsorption of Cr (VI) on lignin. These constants and correlation coefficients of the isotherm models were calculated and compared. Results indicated that Cr (VI) uptake could be described by the Langmuir adsorption model. The maximum adsorption capacity (qm) of Cr (VI) on lignin was 75.75 mg.g-1 at temperature of 40°C. The dimensionless equilibrium parameter (RL) signified a favorable adsorption of Cr (VI) on lignin and was found between 0.0601 and 0.818 (0<RL<1). The thermodynamic parameters like ΔG°, ΔS° and ΔH° were calculated and it has been found that the reaction was spontaneous and endothermic in nature. This study indicates that lignin has the potential to become an effective and economical adsorbent for removal Cr (VI) from the waste water.

scholarly journals Removal of acridine orange dye from aqueous solution by adsorption onto dried sugar beet pulp

2017 ◽  
pp. 307-314
Author(s):  
Vesna Vucurovic ◽  
Vladimir Puskas ◽  
Uros Miljic
Keyword(s):  
Sugar Beet ◽  
Acridine Orange ◽  
Low Cost ◽  
Sugar Beet Pulp ◽  
Isotherm Models ◽  
Maximum Adsorption Capacity ◽  
Solution Ph ◽  
Equilibrium Data ◽  
Beet Pulp ◽  
Pseudo Second Order

A simple, low cost, and effective method for the removal of acridine orange (AO), a mutagenic cationic dye, from aqueous model solutions by adsorption onto dried sugar beet pulp (SBP) was evaluated in the present study. The AO removal was enhanced along with the increase of the initial solution pH and dye concentration. It was found that the adsorption process closely follows a pseudo-second-order chemisorption kinetics. The obtained equilibrium data obey both the Freundlich and Langmuir isotherm models. The SBP was proved to be very promising adsorbent for AO removal. Maximum adsorption capacity of the Langmuir monolayer of SBP for AO was found to be 5.37, 34.6, 89.62, 144.53 and 324.58 mg/g, at 25?C for the solution pH of 2, 4, 5, 6, and 8, respectively.

scholarly journals Application of modified clay for removal of phenol and PO43− ions from aqueous solutions

2017 ◽  
Vol 35 (7-8) ◽  
pp. 692-699 ◽  
Author(s):  
Agnieszka Gładysz-Płaska
Keyword(s):  
Kinetic Studies ◽  
Order Reaction ◽  
Isotherm Models ◽  
Maximum Adsorption Capacity ◽  
Second Order Reaction ◽  
Modified Clay ◽  
Ph Values ◽  
Simultaneous Adsorption ◽  
Equilibrium Data ◽  
Pseudo Second Order

Simultaneous adsorption of phenol and phosphate(V) ions on the surfactant-modified clay from the binary mixture was studied and compared with the single phenol or phosphate(V) sorption. The maximum adsorption capacity of hexadecyltrimethylammonium–bentonite was 18.8 mg/g for phenol and 38.5 mg/g for phosphate(V) at simultaneous adsorption of both of them. The optimal pH values of adsorption on hexadecyltrimethylammonium–bentonite was found to be 7.0 and >7 for phosphate(V) and phenol, respectively. The kinetic studies showed that the adsorption followed a pseudo-second-order reaction for both. The equilibrium data were analyzed using the Langmuir, Freundlich, Temkin, and Dubinin-Radushkevich isotherm models.

scholarly journals Cr6+ adsorption by modified vermiculite

2020 ◽  
Author(s):  
Valeria Medoro ◽  
Celia Marcos Pascual ◽  
Giacomo Ferretti ◽  
Giulio Galamini ◽  
Massimo Coltorti
Keyword(s):  
Earth Sciences ◽  
Inductively Coupled Plasma ◽  
Contact Time ◽  
Second Order ◽  
Isotherm Models ◽  
Maximum Adsorption Capacity ◽  
Order Kinetic ◽  
Experimental Conditions ◽  
X Ray ◽  
Pseudo Second Order

<p><strong>Abstract</strong>: <strong>Cr<sup>6+</sup> adsorption by modified vermiculite</strong></p><p><strong> </strong></p><p>Valeria Medoro- University of Ferrara , Department of Physics and Earth Sciences, Italy</p><p>Celia Marcos Pascual-University of Oviedo, Department of Geology, Spain</p><p>Giacomo Ferretti- University of Ferrara , Department of Physics and Earth Sciences, Italy</p><p>Giulio Galamini- University of Ferrara , Department of Physics and Earth Sciences, Italy</p><p>Massimo Coltorti- University of Ferrara , Department of Physics and Earth Sciences, Italy</p><p> </p><p>This work aimed at investigating the adsorption of Cr<sup>6+</sup> in water by exfoliated vermiculite. The adsorbant tested in this experiment was a vermiculite (from China) which has been subjected to heating at 1000 °C for 1 minute, resulting in an exfoliated vermiculite.</p><p>Three effects were studied: 1) contact time; 2) initial concentracion of Cr<sup>6+</sup>; 3) adsorbent mass. Samples were analysed by X Ray Fluorescence (XRF), X Ray Diffraction (XRD) and the solutions with Inductively Coupled Plasma Mass Spectrometry (ICP-MS) to quantify the adsorbed Cr<sup>6+</sup> by the vermiculite.</p><p>Results from XRD diffraction showed a conversion of vermiculite into flogopite  after heating at 1000°C for 1 minute because of: 1) high content of potassium, 2) dehydration and 3) structural re-ordering; after the contact of vermiculite with Cr<sup>6+</sup>, the mineral structure did not change. The adsorption of Cr<sup>6+</sup> was studied by Langmuir, Freundlich and Dubinin-Kaganer-Radushkevich (DKR) isotherm models. DKR model, indicative of a cooperative process, described adsorption equilibrium better than the other two models and the maximum adsorption capacity obtained was of 2.81 mol/g. Kinetic was studied using pseudo-first and pseudo-second order kinetic models, with a better description of the process by pseudo-second order model with correlation coefficient almost unitary (R<sup>2</sup>=0.9984; other kinetic parameters were k<sub>2</sub>=0.0015 and the absorption initial rate of 0.2x10<sup>-8</sup> mg g<sup>-1</sup> h<sup>-1</sup>). </p><p>The present study demonstrates the effectiveness of modified vermiculite adsorbents for the treatment of hexavalent chromium-contaminated waters and that its adsorption depends on the experimental conditions (such as contact time, initial concentracion of Cr<sup>6+</sup> and adsorbent mass).</p>

Evaluation of the possible use of a Bulgarian clinoptilolite for removing strontium from water media

Clay Minerals ◽  
2015 ◽  
Vol 50 (1) ◽  
pp. 55-64 ◽  
Author(s):  
N. Lihareva ◽  
O. Petrov ◽  
Y. Tzvetanova ◽  
M. Kadiyski ◽  
V.A. Nikashina
Keyword(s):  
Second Order ◽  
Isotherm Models ◽  
Sorption Data ◽  
Water Media ◽  
Effects Of Ph ◽  
Equilibrium Data ◽  
Intra Particle Diffusion ◽  
Pseudo Second Order ◽  
Na Ions ◽  
Natural Clinoptilolite

AbstractThe sorption of Sr2+ ions by natural clinoptilolite was investigated using the batch method. The effects of pH, contact time and strontium concentrations were tested and the optimal conditions for sorption were determined. The process was very fast initially and equilibrium was reached within 24 h. Kinetic sorption data were fitted to pseudo-first-order, pseudo-second-order and intra-particle diffusion models. The simple pseudo-second-order rate model provides good agreement with the experimental data for Sr2+ uptake. The respective rate constants, k2, calculated at different initial Sr2+ concentrations, were obtained. The equilibrium data were analysed by applying the Langmuir, Freundlich and Dubinin–Raduchkevich isotherm models. The Langmuir model describes the observed Sr2+ uptake most accurately and the value of the monolayer sorption capacity is 32.81 mg Sr2+/g. The effect of Na+ ions and the effectiveness of uptake from low saline groundwater simulated solutions were also studied and discussed.

Studying adsorption of methylene blue onto chitosan – mangetite composite

2021 ◽  
Vol 11 (1) ◽  
pp. 60-66
Author(s):  
Quy Bui Minh ◽  
Oanh Do Thi ◽  
Vinh Nguyen Dinh ◽  
Linh Nguyen Thi Ngoc ◽  
Hoa Nguyen Thi Hong ◽  
...  
Keyword(s):  
Methylene Blue ◽  
Diffraction Method ◽  
Precipitation Method ◽  
Isotherm Models ◽  
Maximum Adsorption Capacity ◽  
Order Kinetic ◽  
Order Kinetic Model ◽  
Pseudo Second Order ◽  
Co Precipitation ◽  
Microscopy Techniques

The chitosan/mangetite composite in the mass ratio chitosan:mangetite of 9:1 (CM91) was synthesised by co-precipitation method. The characteristics of the chitosan/mangetite composite was estimated by X-ray diffraction method (XRD) and scanning electron microscopy techniques (SEM). The methylene blue adsorption ability onto CM91 composite was well at value pH 9, equilibrium contact time of 20 minutes. The experimental adsorption data fitted into pseudo–Langmuir adsorption isotherm models. The adsorption followed pseudo-second order kinetic model very well. The maximum adsorption capacity of that composite which caculated by Langmuir equation was 94,18 mg/g.

Chromium (VI) Adsorption on Activated Lignin

2009 ◽  
Vol 4 (1) ◽  
Author(s):  
Nassima Tazerouti ◽  
Moussa Amrani
Keyword(s):  
Adsorption Isotherm ◽  
Adsorption Capacity ◽  
Contact Time ◽  
Analytical Data ◽  
Correlation Coefficients ◽  
Second Order ◽  
Isotherm Models ◽  
Maximum Adsorption Capacity ◽  
Chromium Vi ◽  
Pseudo Second Order

Activated lignin, having a surface area of 1023 m2 g-1, has been prepared from lignin sulfate that was treated by 30% H2O2 and carbonized at 300°C in order to test the chromium (VI) adsorption from aqueous solution. The influence of contact time, pH, initial concentration of adsorbent and adsorbate and temperature on the adsorption capacity was investigated. The maximum removal of Cr(VI) was found to be 92.36% at pH=2 and a contact time of 80 min. Optimal concentration of lignin and Cr(VI) was found to be 3.8 gL-1 and 180mg L-1, respectively. The adsorption kinetics was examined with pseudo-first-order and pseudo-second-order equations. The analytical data fit well to the pseudo-second-order equation, and the rate of removal of chromium was found to speed up by increasing the temperature. Activation energy for the adsorption process was found to be 18.19 KJ mol-1. The Langmuir-Freundlich adsorption isotherm models were applied to describe the isotherm and its constants for the adsorption of Cr(VI) on lignin. These constants and correlation coefficients of the isotherm models were calculated and compared with each other. Results indicated that Cr(VI) uptake could be described by the Langmuir adsorption isotherm. The maximum adsorption capacity (qmax) of Cr(VI) on lignin was 75.75 mg g-1 at a temperature of 40°C. The dimensionless equilibrium parameter (RL) signified a favorable adsorption of Cr(VI) on lignin and was found to be between 0.0601 and 0.818 (0L<1). The thermodynamic parameters such as ?G°, ?S°, and ?H° were calculated and it has been found that the reaction was spontaneous and endothermic in nature. This study indicates that lignin has the potential to become an effective and economical adsorbent for the removal of Cr(VI) from waste water.

Sign in / Sign up

Export Citation Format

Share Document