scholarly journals Physico-mechanical and water absorption properties of LDPE/cassava starch film

Author(s):  
Junaidah Jai ◽  
Siti Fatma Abd Karim ◽  
Nurul Asyikin Md Zaki ◽  
Rabiatul Adawiyah Abdol Aziz ◽  
Farhana Wahet ◽  
...  

Plastic waste is a global crisis, and Malaysia is the 8th worst country worldwide for plastic waste. With this trend, growing market demands for green product have imposed pressure on industries to find an alternative to petroleum-based plastic. Degradable plastic is introduced to overcome this limitation. The present work investigates degradable plastic film of low-density polyethylene incorporated with cassava starch (LDPE-CS). The compounding of the LDPE-CS was prepared via pre-mixing, blending, resin crushing, and film hot pressing. Film thickness, tensile strength, elongation, water absorption, and field test were conducted on the LDPE-CS and commercial LDPE (control). Experimental data of LDPE-CS and commercial LDPE films were evaluated and compared. Thickness of LDPE-CS film was 0.18 mm which was 51% thicker than the control film. Tensile strength and elongation of the LDPE-CS were 7.04 MPa and 5.39%, while control film was 12.77 MPa and 921.5%, respectively. The tensile strength and elongation of the LDPE-SC were significantly lower than the control film, which may be due to the weak interface between LDPE and starch. The water absorption test revealed that the LDPE-CS film absorbed water by 4.8%, which indicates its degradability in the water. The field test shows that the LDPE-CS is biodegradable and comparable with the commercial plant polybag in terms of its capability in planting. 

2018 ◽  
Vol 21 (2) ◽  
pp. 80-84 ◽  
Author(s):  
Retno Ariadi Lusiana ◽  
Vivi Dia Ahmad Sangkota ◽  
Sri Juari Santosa

Evaluation character of chitosan membrane-succinate / poly vinyl alcohol-poly ethylene glycol (PVA-PEG) were prepared in acetic acid solvent through a phase inversion method has been performed. The study began with the preparation of crosslinked chitosan compounds with succinic acid, followed by preparation into membrane by combining PVA-PEG. Character analysis of the resulting material using FTIR, EDX, TGA, water absorption test, tensile strength, membrane hydrophilicity. The ability of membrane permeation was tested against creatinine. The results showed that the succinate had reacted with chitosan. Chitosan modification through cross link and polymer alloys increases tensile strength and membrane strain of 1.7-2.5 x of pure chitosan membrane. In addition, the modified membrane also has higher water absorption and hydrophilicity values than the unmodified membrane, and this implies the ability of membrane-induced creatinine permeation. Permeable permeation values were 13.8% in chitosan, 24.84% on chitosan-succinate and 25% in chitosan-succinate / PVA-PEG. Chitosan-succinate membranes have the ability to use more than 4x repeated use.


2018 ◽  
Vol 33 (3) ◽  
pp. 289-304 ◽  
Author(s):  
Kuhananthan Nanthakumar ◽  
Chan Ming Yeng ◽  
Koay Seong Chun

This research covers the preparation of poly(lactic acid) (PLA)/sugarcane leaves fibre (SLF) biofilms via a solvent-casting method. The results showed that the tensile strength and Young’s modulus of PLA/SLF biofilms increased with the increasing of SLF content. Nevertheless, the elongation at break showed an opposite trend as compared to tensile strength and Young’s modulus of biofilms. Moreover, water absorption properties of PLA/SLF biofilms increased with the increasing of SLF content. In contrast, the tensile strength and Young’s modulus of biofilms were enhanced after bleaching treatment with hydrogen peroxide on SLF, but the elongation at break and water absorption properties of bleached biofilms were reduced due to the improvement of filler–matrix adhesion in biofilms. The tensile and water properties were further discussed using B-factor and Fick’s law, respectively. Furthermore, the functional groups of unbleached and bleached SLF were characterized by Fourier transform infrared analysis.


2013 ◽  
Vol 421 ◽  
pp. 290-295
Author(s):  
Mohammad Taib Mohamad Nurul Azman ◽  
Abu Kassim Masitah ◽  
Ariff Jamaludin Mohd ◽  
Ismail Tayibbah

This research investigated the tensile and water absorption properties of kenaf fibre mat/polyester composites. Treatment using acetylation method has been introduced to improve the properties of product manufactured. The effects of acetylation treatment with three variations of time that were 1, 4 and 24 hours on the kenaf fibre mats were investigated. The MOE of the tensile of treated fibre mat/polyester composite for 1 hour was the highest with value 4589.61 MPa. The tensile strength of treated fibre mat/polyester composite for 4 hours was the highest with value 0.6213 MPa. For water absorption test, the results showed that fibre mat/polyester composite with treatment duration for 1 hour had the lowest water absorption that was 1.23% compared with treatment duration for 4 hours and 24 hours. For overall it can be concluded that the treatment duration of 1 hour was recommended for acetylation method when compared with 4 hours and 24 hours duration treatments. Using acetylation treatment on the kenaf fibre mat/polyester composites was showed improvement on composite and was recommended in short duration of treatment.


2021 ◽  
Vol 5 (1) ◽  
pp. 22
Author(s):  
S. Sigit Udjiana ◽  
Sigit Hadiantoro ◽  
Noor Isnaini Azkiya

Pada penelitian ini biji durian digunakan sebagai sumber pati dalam pembuatan plastik biodegradable. Penelitian ini bertujuan untuk mengetahui pengaruh jenis dan jumlah filler terhadap sifat biodegradable, sifat mekanik dan sifat water absorbtion pada plastik biodegradable berbasis pati biji buah durian. Plasticizer yang digunakan dalam penelitian ini adalah sorbitol  40%, sedangkan filler yang digunakan adalah Kalsium silikat (Ca2SiO4) dan Kalsium karbonat (CaCO3) dengan variable konsentrasi 2%, 4%, 6%, dan 8%. Dari hasil penelitian, diperoleh % yield dari pati biji buah durian sebesar 34,57%. Hasil dari plastik biodegradable terbaik dengan karakteristik transparan, tidak ada gelembung, lentur serta permukaan yang halus diperoleh pada variabel penambahan filler kalsium karbonat 4%. Hasil uji bio-degradasi paling mendekati standard ASTM D6400 diperoleh pada variabel kalsium karbonat 2%. Pada Uji water absorption hasil terbaik dicapai pada variabel kalsium silikat 8%. Uji tarik hasil terbaik diperoleh pada variabel kalsium silikat 6%.In this study, durian seeds were used as a source of starch in making biodegradable plastics. This study aims to determine the effect of the type and amount of filler on biodegradable properties, mechanical properties, and water absorption properties of biodegradable plastics based on durian fruit starch. The plasticizer used in this study was sorbitol 40%, while the filler used was Calcium silicate (Ca2SiO4) and Calcium carbonate (CaCO3) with variable concentrations of 2%, 4%, 6%, and 8%.. From the research results, the% yield of durian seed starch was 34.57%. The results of the best biodegradable plastic with the characteristics of transparent, no bubbles, flexible and smooth surface were obtained with the addition of 4% calcium carbonate filler variables. The bio-degradation test results closest to the ASTM D6400 standard were obtained in the 2% calcium carbonate variable. In the water absorption test, the best results were achieved at the 8% calcium silicate variable. The best tensile test results were obtained in the 6% calcium silicate variable.


2003 ◽  
Vol 55 (11) ◽  
pp. 504-510 ◽  
Author(s):  
Fábio D. S. Larotonda ◽  
Kátia S. Matsui ◽  
Sabrina S. Paes ◽  
João Borges Laurindo

2018 ◽  
Vol 280 ◽  
pp. 368-373
Author(s):  
R.J. Walster ◽  
A.R. Rozyanty ◽  
A.W.M. Kahar ◽  
Luqman Musa

Cassava starch (CS) films filled with different loading of kenaf core fiber (KCF) were prepared and tested. Three testing were carried out; tensile test, water absorption test, and oil absorption test. The tensile test showed an increase in stiffness of the modulus as the loading of KCF increased. Additionally, the increase of KCF loading also increased the amount of water and oil absorbed by the films.


Jurnal PenSil ◽  
2021 ◽  
Vol 10 (3) ◽  
pp. 166-176
Author(s):  
Melinda Putri Haryani ◽  
Kusno Adi Sambowo ◽  
Anisah

Abstrak Penelitian ini bertujuan untuk mengetahui pengaruh dari pemanfaatan limbah plastik PET, limbah plastik PP dan tanah diatomae sebagai bahan pengganti pasir sehingga dapat diketahui mutu yang mampu dicapai dan kesesuaiannya dengan SNI 03-0691-1996 mengenai paving block secara fisis maupun mekanis. Penelitian ini menggunakan metode eksperimen dengan benda uji paving block menggunakan limbah plastik PET, limbah plastik PP dan tanah diatomae sebagai bahan pengganti pasir dalam populasinya terdapat 5 presentase yaitu 0% (control), 5%, 10%, 15%, dan 20% dengan jumlah benda uji setiap variasi adalah 14 buah. Benda uji pada penelitian ini berukuran 210 mm x 105 mm x 80 mm berbentuk balok yang dicetak menggunakan mesin press vibrator. Setelah selesai pencetakan, benda uji dilakukan perawatan (curing) di dalam bak air selama ±28 hari. Kemudian dilakukan pengujian untuk mengetahui mutu benda uji sesuai dengan SNI 03-0691-1996 mengenai paving block, berupa uji tampak dan ukuran, uji kuat tekan, uji daya serap air, dan uji ketahanan terhadap Natrium Sulfat. Berdasarkan penelitian yang telah dilakukan, diperoleh hasil kuat tekan pada substitusi agregat halus buatan dengan variasi 0% (control), 5%, 10%, 15%, dan 20% berturut-turut 17,708 Mpa (Mutu B), 18,479 Mpa (Mutu B), 18,722 Mpa (Mutu B), 17,936 Mpa (Mutu B), dan 14,749 Mpa (Mutu C). Pada uji daya serap air hanya paving block dengan variasi 20% yang masuk ke dalam mutu C, kemudian pada pengujian ketahanan aus seluruh benda uji masuk ke dalam mutu A. Sementara untuk uji ketahanan terhadap Natrium Sulfat, hanya variasi 0% dan 5% yang tidak lolos uji. Dari hasil pengujian menunjukan bahwa penggunaan limbah plastik PET, limbah plastik PP, dan tanah diatomae sebagai agregat halus buatan yang disubstitusi ke agregat halus alami pada variasi 10% mampu mencapai mutu B yang digunakan sebagai peralatan parkir. Kata kunci: Limbah Plastik PET, Limbah Plastik PP, Tanah Diatomae, Agregat Halus, Paving Block, SNI 03-0691-1996   Abstract This study aims to determine the effect of the utilization of PET plastic waste, PP plastic waste and diatomaceous earth as a substitute for sand so that the quality that can be achieved and its conformity with SNI 03-0691-1996 regarding paving blocks physically and mechanically can be determined. This study uses an experimental method with paving block specimens using plastic as a substitute for sand in the population there are 5 percentages, namely 0% (control), 5%, 10%, 15% and 20% with the number of specimens for each variation is 14 pieces. The test object in this study measuring 210 mm x 105 mm x 80 mm in the form of a block printed using a vibrator press machine. After completion of printing, the specimens were treated (cured) in a water bath for ±28 days. Then a test was carried out to determine the quality of the test object in accordance with SNI 03-0691-1996 regarding paving blocks, in the form of appearance and size test, compressive strength test, water absorption test, and resistance test to Sodium Sulfate. Based on the research that has been done, the results of the compressive strength of artificial fine aggregate substitution with variations of 0% (control), 5%, 10%, 15% and 20% respectively 17.708 Mpa (Quality B), 18.479 Mpa (Quality B) , 18,722 Mpa (Quality B), 17,936 Mpa (Quality B), and 14,749 Mpa (Quality C). In the water absorption test, only paving blocks with a variation of 20% were categorized as C quality, then all the paving block are included in quality A in wear resistance testing. Meanwhile, for the sodium sulfate resistance test, only 0% and 5% variations did not pass the test. The test results show that the use of PET plastic waste, PP plastic waste, and diatomaceous earth as artificial fine aggregate which is substituted for natural fine aggregate at a variation of 10% is able to achieve B quality which is used as parking equipment. Keywords: Waste PET Plastic, PP Plastic Waste, Diatomaceous Earth, Fine Aggregate, Paving Block, SNI 03-0691-1996


2011 ◽  
Vol 418-420 ◽  
pp. 30-33 ◽  
Author(s):  
Huai Fang Wang ◽  
Hai Ning Lv ◽  
Jing Feng ◽  
Zhi Kai Wang

Collagen/cellulose films were made by the blend solutions of collagen, cellulose in this paper. To begin with, collagen and cellulose was dissolved in 1-allyl-3-methylimidazolium chloride ([Amim]Cl). The structure of the blend films was characterized by FTIR and XRD. The effects of weight ratio between the two polymers on light transmittance, tensile strength, elongation at break and water absorption of the film were studied. The results showed that there were strong interactions and good compatibility between collagen and cellulose in the film and the polymers have strongest interactions at the mixing ratio of 5:5. The blend films possess better properties such as mechanical and water absorption properties than those made of single polymer.


DYNA ◽  
2020 ◽  
Vol 87 (212) ◽  
pp. 31-37
Author(s):  
Pedro Alban Bolaños ◽  
Amanda Parra Campos ◽  
Hector Samuel Villada Castillo ◽  
Hugo Portela Guarín ◽  
German Antonio Arboleda Muñoz ◽  
...  

The aim of this study was to evaluate different formulations of a biodegradable black concentrate obtained from cassava starch and carbon black, on the mechanical properties, color, and water absorption of a film destined to the production of biodegradable bags for coffee seedlings. The modulus of elasticity, tensile strength and elongation properties is found to show significant variation due to the pigment, plasticizer, and lubricant concentration, both longitudinally and transversely of the film, the treatment being 40% pigment with the absence of plasticizer and lubricant for the pigment, which presented greater integrity in the mechanical properties evaluated in both directions. It is also noticeable that the different masterbatch formulations had an influence on the changes in the color parameters and weight gain of the film by the influence of water absorption.


2012 ◽  
Vol 18 (3) ◽  
pp. 416-425 ◽  
Author(s):  
Hadi Bahadori ◽  
Payam Hosseini

In this study, effects of replacing cement with colloidal amorphous silica nano-particles have been experimentally investigated on the physical and mechanical properties, durability and microstructure of concrete. Experimental results include workability, fresh concrete density, and hardened concrete properties like compressive strength at different ages of 3, 7, and 28-days, and also 28-days splitting tensile strength. Furthermore, influence of silica nano-particles on durability and microstructure of concrete for 28-days specimens was tested by conducting water absorption test, Scanning Electron Microscopy (SEM), and Energy Dispersive X-ray Analysis (EDAX), respectively. In order to study the effect of replacement of cement with silica nano-particles, specimens with 10%, 20%, and 30% cement reduction, and addition of 1%, 2%, and 3% silica nano-particles with respect to witness specimen were fabricated. Experimental results revealed that 20% reduction of cement combining 2% silica nano-particles and also 10% cement reduction combined with 1% silica nano-particles enhance the microstructure of concrete, despite unnoticeable compressive and tensile strength loss. By remarkable reduction of cement consumption and addition of silica nano-particles, strength almost remains constant and consequently decreasing the cement content will become possible. Also, in all specimens, increase in nano-particles content and decrease in cement usage contributed to workability loss. Therefore, applying super-plasticizers seems indispensible while using silica nano-particles. On the other side, according to water absorption test, concretes containing nanoparticles showed more appropriate durability.


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