scholarly journals Study of Archeometric Characteristics of a Panel Painted Icon Form XIXth Century

2013 ◽  
Vol 21 (2) ◽  
pp. 71-82 ◽  
Author(s):  
Raluca A. Cristache ◽  
Ion Sandu ◽  
Viorica Vasilache ◽  
Oana Cristache
Keyword(s):  
Physicochemical Analysis ◽  
Wood Panel ◽  
Pigment Layer ◽  
X Ray ◽  
Painting Materials ◽  
Ultramarine Blue ◽  
Xixth Century ◽  
The Right ◽  
Painting Layer ◽  
Scanning Electron

Abstract This study presents a physicochemical analysis on the orthodox icon “The grieving Mother” from XIXth century. The icon is made by an anonymus painter, in tempera pigments, on a lime wood support, Tillia cordata. God’s Mother is represented from one side, only the bust, with the head down, framed by a white border. The predominant colors of the icon are ultramarine blue, ocher, red-brown, with silver leaf. The edges of the panel were painted with tempera pigments as the border. On the right edge an inscription in blue ink, can be seen, but is unreadable. The painting layer has gaps, fissures, detachments, dirt, degraded and scaly varnish. The panel is made from a single board, transversally cut, without crossbeams. The study is based on the identification of some archeometric characteristics of the wood panel and of the pigment layer. To determin painting materials and the conservation state, Fourier Transform Infrared Spectroscopy (Micro-FTIR) and Scanning Electron Microscope coupled with Energy Dispersive X-ray spectroscopy (SEM-EDX) were employed. Using this methods we identify the pigments used and the state of degradation of the panel. The FTIR spectrum analysis showed that the pigment layer contains schellac varnish, ultramarine blue and dust, a conclusion supported by SEM-EDX analysis.

scholarly journals Physicochemical Analysis of the Polydimethylsiloxane Interlayer Influence on a Hydroxyapatite Doped with Silver Coating

2015 ◽  
Vol 2015 ◽  
pp. 1-10 ◽  
Author(s):  
C. L. Popa ◽  
A. Groza ◽  
P. Chapon ◽  
C. S. Ciobanu ◽  
R. V. Ghita ◽  
...  
Keyword(s):  
Electron Microscopy ◽  
Composite Layer ◽  
Optical Emission ◽  
Physicochemical Analysis ◽  
Crystalline Form ◽  
Emission Spectrometry ◽  
Silver Coating ◽  
X Ray Diffraction ◽  
X Ray ◽  
Scanning Electron

We investigate by different complementary methods the processes occurring when a polydimethylsiloxane film is used as interlayer for a silver doped hydroxyapatite coating. The X-ray diffraction and Fourier Transform Infrared Spectroscopy measurements show that the hydroxyapatite doped with silver is in a crystalline form and someSiO44-ions formation takes place at the surface and in the bulk of the new hydroxyapatite doped with silver/polydimethylsiloxane composite layer. The possibility ofSiO44-ions incorporation in the structure of silver doped hydroxyapatite by the mechanism ofSiO44-/PO43-ions substitution is analysed. The new formed silver doped hydroxyapatite/polydimethylsiloxane composite layer is compact, homogeneous, with no cracks as it was shown by Scanning Electron Microscopy and Glow Discharge Optical Emission Spectrometry.

Tobolocella levinae n. gen., n. sp., a cheilostome bryozoan from the late Maastrichtian of northern Kazakhstan: scanning electron microscope and micro-CT study

2019 ◽  
Vol 294 (1) ◽  
pp. 91-101 ◽  
Author(s):  
Anna V. Koromyslova ◽  
Alexey V. Pakhnevich ◽  
Petr V. Fedorov
Keyword(s):  
Electron Microscopy ◽  
Scanning Electron Microscopy ◽  
Electron Microscope ◽  
New Genus ◽  
Micro Ct ◽  
X Ray ◽  
Northern Kazakhstan ◽  
Ct Data ◽  
The Right ◽  
Scanning Electron

A cheilostome bryozoan Tobolocella levinae gen. et sp. nov. is described from a late Maastrichtian outcrop located on the right bank of the Tobol River in northern Kazakhstan. Its morphology is investigated in detail using combined scanning electron microscopy and X-ray micro-CT data. These studies reveal that colonies of this new genus generally consist of regularly arranged but morphologically different zooids: autozooids, T-zooids, and vicarious avicularia. The T-zooids first established in T. levinae gen. et sp. nov. are zooids with a modified cystid and can be interpreted as autozooidal polymorphs, if its polypide was identical to that of regular autozooids, or heterozooids, if its polypide was modified. The T-zooids probably can increase the distance between autozooidal polypides to improve their feeding efficiency.

Nondestructive analysis of a painting, a national treasure in Japan

2007 ◽  
Vol 22 (2) ◽  
pp. 126-129 ◽  
Author(s):  
Yasuhiro Hayakawa ◽  
Seiji Shirono ◽  
Sadatoshi Miura ◽  
Tomohide Matsushima ◽  
Tokugo Uchida
Keyword(s):  
High Resolution ◽  
Digital Imaging ◽  
Nondestructive Analysis ◽  
X Ray ◽  
Painting Materials ◽  
Materials Used ◽  
The Right ◽  
Folding Screens

The painting materials and drawing techniques of a pair of two-panel folding screens entitled Red and White Plum Blossoms by Ogata Korin, a national treasure in Japan, were investigated directly and nondestructively by XRF, X-ray radiography, and high resolution digital imaging. Several assumptions were made about the materials used in the red and white plum trees drawn on the right and left screens, respectively, and the river drawn at the center. By the present investigation, the materials used for the paintings were revealed, and some of them contradicted what have been previously believed.

scholarly journals Identification of Lithol Red Synthetic Organic Pigment Reveals the Cause of Paint Layer Degradation on the Lazar Vozarević Painting “Untitled” with Copper Plates

Heritage ◽  
2019 ◽  
Vol 2 (3) ◽  
pp. 2612-2624
Author(s):  
Vanja Jovanović ◽  
Suzana Erić ◽  
Philippe Colomban ◽  
Aleksandar Kremenović
Keyword(s):  
Electron Microscopy ◽  
Scanning Electron Microscopy ◽  
Visual Experience ◽  
Paint Layer ◽  
Organic Pigment ◽  
X Ray ◽  
Painting Materials ◽  
Micro Raman Spectroscopy ◽  
Synthetic Organic Pigment ◽  
Scanning Electron

Out of a total of 56 paintings in the collection of the Lazar Vozarević Gallery in Sremska Mitrovica, only one Lazar Vozarević painting from 1961, titled “Untitled”, has been subject to atypical degradation that has resulted in damage of completely atypical appearance. Such a problem had never before been noticed in Yugoslavian paintings of the 20th century. Discolored areas were found in various locations on the paint layer of the painting “Untitled” (especially on the lower and central parts of the painting), which disturbed the visual experience of the artistic work. To discover the cause of this discoloration, the composition of the paint layer was investigated, with the assumption that the true cause of degradation was hidden therein. Moreover, this painting belongs to a specific period in Vozarević’s activity, characterized by the use of non-traditional painting materials. To identify pigments from the highly degraded painting “Untitled”, scanning electron microscopy coupled with energy dispersive X-ray spectrometry (SEM/EDS) and micro-Raman spectroscopy were applied. Lithol red, a synthetic organic pigment known to give paintings a red tone, was identified as the main reason for the painting’s degradation. Lithol red is not only highly light-sensitive but is also chemically unstable, toxic, and sensitive to heat.

scholarly journals Polypropylene Graft Poly(Methyl Methacrylate) Graft Poly(N-Vinylimidazole) as a Smart Material for pH-Controlled Drug Delivery

2021 ◽  
Author(s):  
Felipe López-Saucedo ◽  
Jesús Eduardo López-Barriguete ◽  
Guadalupe Gabriel Flores-Rojas ◽  
Sharemy Gómez-Dorantes ◽  
Emilio Bucio
Keyword(s):  
Antimicrobial Activity ◽  
Methyl Methacrylate ◽  
Gamma Rays ◽  
Photoelectron Spectroscopy ◽  
Controlled Drug Delivery ◽  
Controlled Drug Release ◽  
Physicochemical Analysis ◽  
X Ray ◽  
Simultaneous Irradiation ◽  
Scanning Electron

Surface modification of polypropylene (PP) films is achieved using gamma-irradiation-induced grafting to proffer with antimicrobial activity. The copolymer was obtained through a versatile two-step route; pristine PP is exposed to gamma rays and grafted using methyl methacrylate (MMA), then N-vinylimidazole (NVI) is grafted onto the copolymer PP-g-MMA by simultaneous irradiation. The characterization included Fourier-Transform Infrared Spectroscopy (FTIR), Scanning Electron Microscope (SEM), Thermogravimetric Analysis (TGA), X-ray Photoelectron Spectroscopy (XPS), and physicochemical analysis of swelling and contact angle. The copolymer (PP-g-MMA)-g-NVI was loaded with vancomycin, and the drug released was quantified by UV-vis spectrophotometry at different pH. The surface of (PP-g-MMA)-g-NVI exhibited pH-responsiveness and moderate hydrophilicity, suitable properties for controlled drug release.

The Use of Advanced Analytical Techniques for Characterization of the Chemical, Physical, and Crystallographic Nature of a Surface

1973 ◽  
Vol 31 ◽  
pp. 132-133 ◽  
Author(s):  
R. E. Herfert
Keyword(s):  
Surface Characterization ◽  
Analytical Techniques ◽  
X Ray Diffraction ◽  
Depth Of Penetration ◽  
X Ray ◽  
The Past ◽  
Transmission Electron ◽  
Scanning Electron

Studies of the nature of a surface, either metallic or nonmetallic, in the past, have been limited to the instrumentation available for these measurements. In the past, optical microscopy, replica transmission electron microscopy, electron or X-ray diffraction and optical or X-ray spectroscopy have provided the means of surface characterization. Actually, some of these techniques are not purely surface; the depth of penetration may be a few thousands of an inch. Within the last five years, instrumentation has been made available which now makes it practical for use to study the outer few 100A of layers and characterize it completely from a chemical, physical, and crystallographic standpoint. The scanning electron microscope (SEM) provides a means of viewing the surface of a material in situ to magnifications as high as 250,000X.

Sem Studies of Co-Cr-Mo Surgical Implant Alloy Corrosion Behavior

1982 ◽  
Vol 40 ◽  
pp. 520-521
Author(s):  
Ann Chidester Van Orden ◽  
John L. Chidester ◽  
Anna C. Fraker ◽  
Pei Sung
Keyword(s):  
Electron Microscopy ◽  
Corrosion Behavior ◽  
Anodic Polarization ◽  
Saline Solution ◽  
Saturated Calomel Electrode ◽  
Physiological Saline ◽  
X Ray ◽  
Physiological Saline Solution ◽  
Scanning Electron

The influence of small variations in the composition on the corrosion behavior of Co-Cr-Mo alloys has been studied using scanning electron microscopy (SEM), energy dispersive x-ray analysis (EDX), and electrochemical measurements. SEM and EDX data were correlated with data from in vitro corrosion measurements involving repassivation and also potentiostatic anodic polarization measurements. Specimens studied included the four alloys shown in Table 1. Corrosion tests were conducted in Hanks' physiological saline solution which has a pH of 7.4 and was held at a temperature of 37°C. Specimens were mechanically polished to a surface finish with 0.05 µm A1203, then exposed to the solution and anodically polarized at a rate of 0.006 v/min. All voltages were measured vs. the saturated calomel electrode (s.c.e.).. Specimens had breakdown potentials near 0.47V vs. s.c.e.

Quantification of Silica Uptake by Alveolar Macrophages - An Emperical Scanning Electron Microprobe Method

1982 ◽  
Vol 40 ◽  
pp. 332-333
Author(s):  
V. V. Damiano ◽  
R. P. Daniele ◽  
H. T. Tucker ◽  
J. H. Dauber
Keyword(s):  
Quantitative Analysis ◽  
Alveolar Macrophages ◽  
Bulk Sample ◽  
Silica Particles ◽  
Empirical Method ◽  
Phagocytic Cells ◽  
Calibration Standards ◽  
X Ray ◽  
Accurate Quantitative Analysis ◽  
Scanning Electron

An important example of intracellular particles is encountered in silicosis where alveolar macrophages ingest inspired silica particles. The quantitation of the silica uptake by these cells may be a potentially useful method for monitoring silica exposure. Accurate quantitative analysis of ingested silica by phagocytic cells is difficult because the particles are frequently small, irregularly shaped and cannot be visualized within the cells. Semiquantitative methods which make use of particles of known size, shape and composition as calibration standards may be the most direct and simplest approach to undertake. The present paper describes an empirical method in which glass microspheres were used as a model to show how the ratio of the silicon Kα peak X-ray intensity from the microspheres to that of a bulk sample of the same composition correlated to the mass of the microsphere contained within the cell. Irregular shaped silica particles were also analyzed and a calibration curve was generated from these data.

Identification of calcium oxalate crystals in dried or fixed tobacco leaf

1984 ◽  
Vol 42 ◽  
pp. 288-289
Author(s):  
Vicki L. Baliga ◽  
Mary Ellen Counts
Keyword(s):  
Electron Microscopy ◽  
Scanning Electron Microscopy ◽  
Calcium Oxalate ◽  
Growth And Development ◽  
Polarized Light ◽  
Calcium Oxalate Crystals ◽  
X Ray Diffraction ◽  
X Ray ◽  
Transmission Electron ◽  
Scanning Electron

Calcium is an important element in the growth and development of plants and one form of calcium is calcium oxalate. Calcium oxalate has been found in leaf seed, stem material plant tissue culture, fungi and lichen using one or more of the following methods—polarized light microscopy (PLM), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and x-ray diffraction.Two methods are presented here for qualitatively estimating calcium oxalate in dried or fixed tobacco (Nicotiana) leaf from different stalk positions using PLM. SEM, coupled with energy dispersive x-ray spectrometry (EDS), and powder x-ray diffraction were used to verify that the crystals observed in the dried leaf with PLM were calcium oxalate.

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