scholarly journals Quench dynamics in spin crossover induced by high pressure

Open Physics ◽  
2013 ◽  
Vol 11 (7) ◽  
Author(s):  
Alexander Nesterov ◽  
Sergey Ovchinnikov ◽  
Grigorii Iaroshenko
Keyword(s):  
High Pressure ◽  
Quantum System ◽  
High Spin ◽  
Spin Crossover ◽  
Static Pressure ◽  
Pulse Velocity ◽  
Time Dependent ◽  
System State ◽  
Final State ◽  
Quench Dynamics

AbstractIn this paper we have analytically and numerically studied the dynamics of spin crossover induced by time-dependent pressure. We show that quasi static pressure, with a slow dependence on time, yields a spin crossover leading to transition from the high spin (HS) quantum system state to the low spin (LS) state. However, quench dynamics under shockwave load are more complicated. The final state of the system depends on the amplitude and pulse velocity, resulting in the mixture of the HS and LS states.

The Flexibility of Long Chain Substituents Influences Spin-Crossover in Isomorphous Lipid Bilayer Crystals

2021 ◽  
Author(s):  
Iurii Galadzhun ◽  
Rafal Kulmaczewski ◽  
Namrah Shahid ◽  
Oscar Cespedes ◽  
Mark J Howard ◽  
...  
Keyword(s):  
Lipid Bilayer ◽  
High Spin ◽  
Room Temperature ◽  
Spin Crossover ◽  
Pyridine Derivatives ◽  
Long Chain

[Fe(bpp)2][BF4]2 (bpp = 2,6-di{pyrazol-1-yl}pyridine) derivatives bearing a bent geometry of hexadec-1-ynyl or hexadecyl substituents pyrazole are isomorphous, and high-spin at room temperature. However, only the latter compound undergoes an abrupt,...

scholarly journals Equivalence between Redfield- and master-equation approaches for a time-dependent quantum system and coherence control

2011 ◽  
Vol 83 (6) ◽  
Author(s):  
D. O. Soares-Pinto ◽  
M. H. Y. Moussa ◽  
J. Maziero ◽  
E. R. deAzevedo ◽  
T. J. Bonagamba ◽  
...  
Keyword(s):  
Master Equation ◽  
Quantum System ◽  
Time Dependent

A time-dependent model for high-pressure discharges in narrow ablative capillaries

1993 ◽  
Vol 50 (1) ◽  
pp. 51-70 ◽  
Author(s):  
D. Zoler ◽  
S. Cuperman ◽  
J. Ashkenazy ◽  
M. Caner ◽  
Z. Kaplan
Keyword(s):  
High Pressure ◽  
Equation Of State ◽  
Time Dependent ◽  
Dimensional Model ◽  
Plasma Sources ◽  
One Dimensional ◽  
Space And Time ◽  
Dependent Model ◽  
Energy Equations ◽  
Time Dependent Model

A time-dependent quasi-one-dimensional model is developed for studying high- pressure discharges in ablative capillaries used, for example, as plasma sources in electrothermal launchers. The main features of the model are (i) consideration of ablation effects in each of the continuity, momentum and energy equations; (ii) use of a non-ideal equation of state; and (iii) consideration of space- and time-dependent ionization.

Influence of Turbulent Flow Characteristics and Coherent Vortices on the Pressure Recovery of Annular Diffusers: Part A — Experimental Results

2015 ◽  
Author(s):  
Marcus Kuschel ◽  
Bastian Drechsel ◽  
David Kluß ◽  
Joerg R. Seume
Keyword(s):  
Boundary Layer ◽  
High Pressure ◽  
Static Pressure ◽  
Turbulent Transport ◽  
Axial Flow ◽  
Pressure Recovery ◽  
Turbulence Structure ◽  
Reynolds Stresses ◽  
Wide Range ◽  
Operating Points

Exhaust diffusers downstream of turbines are used to transform the kinetic energy of the flow into static pressure. The static pressure at the turbine outlet is thus decreased by the diffuser, which in turn increases the technical work as well as the efficiency of the turbine significantly. Consequently, diffuser designs aim to achieve high pressure recovery at a wide range of operating points. Current diffuser design is based on conservative design charts, developed for laminar, uniform, axial flow. However, several previous investigations have shown that the aerodynamic loading and the pressure recovery of diffusers can be increased significantly if the turbine outflow is taken into consideration. Although it is known that the turbine outflow can reduce boundary layer separations in the diffuser, less information is available regarding the physical mechanisms that are responsible for the stabilization of the diffuser flow. An analysis using the Lumley invariance charts shows that high pressure recovery is only achieved for those operating points in which the near-shroud turbulence structure is axi-symmetric with a major radial turbulent transport component. This turbulent transport originates mainly from the wake and the tip vortices of the upstream rotor. These structures energize the boundary layer and thus suppress separation. A logarithmic function is shown that correlates empirically the pressure recovery vs. the relevant Reynolds stresses. The present results suggest that an improved prediction of diffuser performance requires modeling approaches that account for the anisotropy of turbulence.

Development of a Lifetime Pressure Sensitive Paint Procedure for High-Pressure Vane Testing

2021 ◽  
Author(s):  
Papa Aye N. Aye-Addo ◽  
Guillermo Paniagua ◽  
David G. Cuadrado ◽  
Lakshya Bhatnagar ◽  
Antonio Castillo Sauca ◽  
...  
Keyword(s):  
High Pressure ◽  
Test Section ◽  
Static Pressure ◽  
Pressure Field ◽  
Optical Measurements ◽  
Wall Region ◽  
Pressure Amplitude ◽  
Pressure Sensitive Paint ◽  
Suction Surface ◽  
Pressure Sensitive

Abstract Optical measurements based on fast response Pressure Sensitive Paint (PSP) provide enhanced spatial resolution of the pressure field. This paper presents laser lifetime PSP at 20 kHz, with precise calibrations, and results from a demonstration in an annular vane cascade. The laser lifetime PSP methodology is first evaluated in a linear wind tunnel with a converging-diverging nozzle followed by a wavy surface. This test section is fully optically accessible with maximum modularity. A data reduction procedure is proposed for the PSP calibration, and optimal pixel binning is selected to reduce the uncertainty. In the annular test section, laser lifetime PSP was used to measure the time-averaged static pressure field on a section of the suction surface of a high-pressure turbine vane. Tests were performed at engine representative conditions in the Purdue Big Rig for Annular Stationary Turbine Analysis module at the Purdue Experimental Turbine Aerothermal Lab. The 2-D pressure results showed a gradual increase of pressure in the spanwise and flow directions, corroborated with local static pressure taps and computational results. The variation in PSP thickness was measured as a contribution to the uncertainty. The discrete Fourier transform of the unsteady pressure signal showed increased frequency content in wind-on conditions compared to wind-off conditions at the mid-span and 30% span. Compared to the mid-span region, the hub end wall region had an increase in frequencies and pressure amplitude. This result was anticipated given the expected presence of secondary flow structures in the near hub region.

scholarly journals ANALYSIS OF THE TIME‐DEPENDENT BEHAVIOUR OF COMPOSITE CROSS‐SECTIONS BY LAPLACE‐TRANSFORM

2005 ◽  
Vol 11 (3) ◽  
pp. 203-209
Author(s):  
Erich Raue ◽  
Thorsten Heidolf
Keyword(s):  
Laplace Transform ◽  
Cross Sections ◽  
Composite Structures ◽  
Time Dependent ◽  
Time Interval ◽  
Final State ◽  
Long Time ◽  
Time Dependent Behaviour ◽  
Linear Differential ◽  
Dependent Behaviour

Composite structures consisting of precast and cast in‐situ concrete elements are increasingly common. These combinations demand a mechanical model which takes into account the time‐dependent behaviour and analysis of the different ages of the connected concrete components. The effect of creep and shrinkage of the different concrete components can be of relevance for the state of serviceability, as well as for the final state. The long‐time behaviour of concrete can be described by the rate‐of‐creep method, combined with a discretisation of time. The internal forces are described for each time interval using a system of linear differential equations, which can be solved by Laplace‐transform.

Optical Microscopy Imaging of the Thermally-Induced Spin Transition and Isothermal Multi-stepped Relaxation in a Low-Spin Stabilized Spin-Crossover Material

2021 ◽  
Author(s):  
Pradip Chakraborty ◽  
Mouhamadou Sy ◽  
Houcem Fourati ◽  
Maria Teresa Delgado Pérez ◽  
Mousumi Dutta ◽  
...  
Keyword(s):  
Optical Microscopy ◽  
High Spin ◽  
Spin Relaxation ◽  
Spin Crossover ◽  
Spin Transition ◽  
Host Lattice ◽  
Microscopy Imaging ◽  
Thermally Induced ◽  
Optical Microscopy Imaging

The thermal spin transition and the photo-induced high-spin → low-spin relaxation of the prototypical [Fe(ptz)6](BF4)2 spin-crossover compound (ptz = 1-propyltetrazole) diluted in the isostructural ruthenium host lattice [Ru(ptz)6](BF4)2, which stabilizes...

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