Effect of gamma-irradiation on total organic carbon and trihalomethane formation potential

1990 ◽  
Author(s):  
Trupti N. Bhatt
1995 ◽  
Vol 31 (11) ◽  
pp. 195-201 ◽  
Author(s):  
S. E. Hrudey ◽  
P. M. Huck ◽  
M. J. Mitton ◽  
S. L. Kenefick

Biological water treatment has been shown to effectively remove biodegradable organic matter, chlorinated by-products and ozonation by-products from drinking water during a large pilot-scale study for the American Water Works Association Research Foundation using the North Saskatchewan River, at Edmonton. In addition to studying total organic carbon, assimilable organic carbon, chlorine demand, haloacetic acid formation potential, trihalomethane formation potential, adsorbable organic halide formation potential, chloral hydrate and aldehydes, this study used a flavour profile panel to follow the removal of odour through different process trains involving biological treatment during the annual spring runoff which has historically caused odour incidents in the water supply. Over the 5-week period of the study, the raw water was found to develop from a very mild grassy odour to a strong odour, variously characterized as septic, manure, musty, earthy and hay-like. The odour persisted and changed character to varying degrees through the various process trains under study. The results verified the futility of relying on a strictly oxidative treatment like ozone for odour removal as well as showing that biological treatment using granular activated carbon could produce an essentially odour-free effluent during a transient raw-water odour event.


2013 ◽  
Vol 13 (4) ◽  
pp. 1099-1108 ◽  
Author(s):  
Ekaterina Vasyukova ◽  
René Proft ◽  
Johanna Jousten ◽  
Irene Slavik ◽  
Wolfgang Uhl

A multidisciplinary approach was applied in this work to characterise natural organic matter and evaluate the performance of a full-scale waterworks treating organic-rich surface water. It was shown that the combination of the treatment processes considered efficiently removed the dissolved organic matter, including its specific fractions. Most of the dissolved organic carbon and nitrogen (DOC and DON), biodegradable DOC and DON, as well as assimilable organic carbon were removed by coagulation/sedimentation. However, the coagulation process was not likely to be optimised for the removal of all molecular weight compounds. The breakdown of high molecular weight compounds into others of low molecular weight, as well as the production of biodegradable organic matter during ozonation, proved to enhance their removal efficiency by subsequent biological activated carbon filtration. The specific trihalomethane formation potential decreased during treatment, indicating a decrease in reactivity of DOC with chlorine across the treatment train. Fractionation experiments demonstrated that high and medium molecular weight organics were likely to be the main precursors for the formation of trihalomethanes. However, other disinfection by-products (such as haloacetic acids) should also be controlled, as the chlorine demand pattern did not necessarily follow that of trihalomethane formation.


2008 ◽  
Vol 6 (1) ◽  
Author(s):  
Markus Heryanto Langsa

<p>Penelitian ini bertujuan untuk menentukan senyawa organik khususnya organic karbon terlarut (DOC) dari dua spesies daun tumbuhan (<em>wandoo eucalyptus </em>and <em>pinus radiate, conifer</em>) yang larut dalam air selama periode 5 bulan leaching eksperimen. Kecepatan melarutnya senyawa organic ditentukan secara kuantitatif dan kualitatif menggunakan kombinasi dari beberapa teknik diantaranya Total Organic Carbon (TOC) analyser, Ultraviolet-Visible (UV-VIS) spektrokopi dan pyrolysis-gas chromatography-mass spectrometry (Py-GC-MS).</p><p>Hasil analisis DOC dan UV menunjukkan peningkatan yang tajam dari kelarutan senyawa organic di awal periode pengamatan yang selanjutnya berkurang seiring dengan waktu secara eksponensial. Jumlah relatif senyawa organic yang terlarut tergantung pada luas permukaan, aktifitas mikrobiologi dan jenis sampel tumbuhan (segar atau kering) yang digunakan. Fluktuasi profil DOC dan UV<sub>254</sub> disebabkan oleh aktifitas mikrobiologi. Diperoleh bahwa daun kering lebih mudah terdegradasi menghasilkan senyawa organic dalam air dibandingkan dengan daun segar. Hasil pyrolysis secara umum menunjukkan bahwa senyawa hidrokarbon aromatic dan fenol (dan turunannya) lebih banyak ditemukan pada residue sampel setelah proses leaching kemungkinan karena adanya senyawa lignin atau aktifitas humifikasi mikrobiologi membuktikan bahwa senyawa-senyawa tersebut merupakan komponen penting dalam proses karakterisasi DOC.</p>


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