Relationships among trihalomethane formation potential, organic carbon and lake enrichment

1989 ◽  
Vol 61 (3) ◽  
pp. 199-209 ◽  
Author(s):  
Joseph A. Arruda ◽  
Carla H. Fromm
1995 ◽  
Vol 31 (11) ◽  
pp. 195-201 ◽  
Author(s):  
S. E. Hrudey ◽  
P. M. Huck ◽  
M. J. Mitton ◽  
S. L. Kenefick

Biological water treatment has been shown to effectively remove biodegradable organic matter, chlorinated by-products and ozonation by-products from drinking water during a large pilot-scale study for the American Water Works Association Research Foundation using the North Saskatchewan River, at Edmonton. In addition to studying total organic carbon, assimilable organic carbon, chlorine demand, haloacetic acid formation potential, trihalomethane formation potential, adsorbable organic halide formation potential, chloral hydrate and aldehydes, this study used a flavour profile panel to follow the removal of odour through different process trains involving biological treatment during the annual spring runoff which has historically caused odour incidents in the water supply. Over the 5-week period of the study, the raw water was found to develop from a very mild grassy odour to a strong odour, variously characterized as septic, manure, musty, earthy and hay-like. The odour persisted and changed character to varying degrees through the various process trains under study. The results verified the futility of relying on a strictly oxidative treatment like ozone for odour removal as well as showing that biological treatment using granular activated carbon could produce an essentially odour-free effluent during a transient raw-water odour event.


2013 ◽  
Vol 13 (4) ◽  
pp. 1099-1108 ◽  
Author(s):  
Ekaterina Vasyukova ◽  
René Proft ◽  
Johanna Jousten ◽  
Irene Slavik ◽  
Wolfgang Uhl

A multidisciplinary approach was applied in this work to characterise natural organic matter and evaluate the performance of a full-scale waterworks treating organic-rich surface water. It was shown that the combination of the treatment processes considered efficiently removed the dissolved organic matter, including its specific fractions. Most of the dissolved organic carbon and nitrogen (DOC and DON), biodegradable DOC and DON, as well as assimilable organic carbon were removed by coagulation/sedimentation. However, the coagulation process was not likely to be optimised for the removal of all molecular weight compounds. The breakdown of high molecular weight compounds into others of low molecular weight, as well as the production of biodegradable organic matter during ozonation, proved to enhance their removal efficiency by subsequent biological activated carbon filtration. The specific trihalomethane formation potential decreased during treatment, indicating a decrease in reactivity of DOC with chlorine across the treatment train. Fractionation experiments demonstrated that high and medium molecular weight organics were likely to be the main precursors for the formation of trihalomethanes. However, other disinfection by-products (such as haloacetic acids) should also be controlled, as the chlorine demand pattern did not necessarily follow that of trihalomethane formation.


1992 ◽  
Vol 27 (1) ◽  
pp. 185-202
Author(s):  
C.R. Erland Jansson

Abstract The UVOX process was developed to reduce the high concentrations of trihalomethanes, a potentially hazardous disinfection by-product found in a surface water supply for a community in northeastern Saskatchewan. Pilot plant tests were conducted at a throughput of 1.25 l/s utilizing UV to produce hydroxyl radicals from photolysis of H2O2 with air cooled UV units. These tests continued through 1985 andl986 to provide operational data for all seasons of the year. Test results indicated that the UVOX process was effective in reducing trihalomethane formation potential to very low levels. Recent concerns have also centred on the biocidal effectivenesss of disinfectants, particularly when applied to inactivation of resistant species of microogranisms, such as the cysts of Giardia lamblia. The UVOX process in a single pass configuration slightly enhanced the ability of UV to inactivate Giardia cysts.


2015 ◽  
Vol 16 (2) ◽  
pp. 305-313 ◽  
Author(s):  
Euis Nurul Hidayah ◽  
Yung-Chen Chou ◽  
Hsuan-Hsien Yeh

In this study high performance size exclusion chromatography (HPSEC) was used to compare an ultrafiltration (UF) membrane and alum coagulation for their capacity to remove different fractions of natural organic matter (NOM) from water. At the same time, the removal of disinfection by-product (DBP) precursors, as measured by trihalomethane formation potential (THMFP) and haloacetic acid formation potential (HAAFP), was also detected. The results show that the UF membrane mainly removed the aliphatic biopolymer fraction, while alum coagulation mainly removed the humic substances fraction. The results of DBP precursor analysis show that more THMFP was removed by the UF membrane than HAAFP, while the reverse was true for alum coagulation. It is conjectured that the aliphatic biopolymer fraction is the major precursor for trihalomethanes (THMs), while the humic substances fraction is the major precursor for haloacetic acids (HAAs).


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