scholarly journals Continuous Synthesis of Doped Layered Double Hydroxides in a Meso-Scale Flow Reactor

2018 ◽  
Author(s):  
Polina Yaseneva ◽  
Nan An ◽  
Matt Finn ◽  
Nicholas Tidemann ◽  
Nicholas Jose ◽  
...  

Detailed characterisation of morphology of doped hydrotalcites as catalysts precursors. Trends of material stability, pore size distribution, particle size as a function of the nature of dopants. Data on the flow synthesis method and reproducibility of materials that can be attained by this method.

2018 ◽  
Author(s):  
Polina Yaseneva ◽  
Nan An ◽  
Matt Finn ◽  
Nicholas Tidemann ◽  
Nicholas Jose ◽  
...  

Detailed characterisation of morphology of doped hydrotalcites as catalysts precursors. Trends of material stability, pore size distribution, particle size as a function of the nature of dopants. Data on the flow synthesis method and reproducibility of materials that can be attained by this method.


Fractals ◽  
2014 ◽  
Vol 22 (03) ◽  
pp. 1440009 ◽  
Author(s):  
MIGUEL ANGEL MARTÍN ◽  
FRANCISCO J. MUÑOZ ◽  
MIGUEL REYES ◽  
F. JAVIER TAGUAS

A 2D computer simulation method of random packings is applied to sets of particles generated by a self-similar uniparametric model for particle size distributions (PSDs) in granular media. The parameter p which controls the model is the proportion of mass of particles corresponding to the left half of the normalized size interval [0,1]. First the influence on the total porosity of the parameter p is analyzed and interpreted. It is shown that such parameter, and the fractal exponent of the associated power scaling, are efficient packing parameters, but this last one is not in the way predicted in a former published work addressing an analogous research in artificial granular materials. The total porosity reaches the minimum value for p = 0.6. Limited information on the pore size distribution is obtained from the packing simulations and by means of morphological analysis methods. Results show that the range of pore sizes increases for decreasing values of p showing also different shape in the volume pore size distribution. Further research including simulations with a greater number of particles and image resolution are required to obtain finer results on the hierarchical structure of pore space.


Agronomy ◽  
2019 ◽  
Vol 9 (4) ◽  
pp. 165 ◽  
Author(s):  
Sara de Jesus Duarte ◽  
Bruno Glaser ◽  
Carlos Pellegrino Cerri

The application of biochar is promising for improving the physical, chemical and hydrological properties of soil. However, there are few studies regarding the influence of biochar particle size. This study was conducted to evaluate the effect of biochar size on the physical, chemical and hydrological properties in sandy and loamy tropical soils. For this purpose, an incubation experiment was conducted in the laboratory with eight treatments (control (only soil), two soils (loamy and sandy soil), and three biochar sizes (<0.15 mm; 0.15–2 mm and >2 mm)). Analyses of water content, bulk density, total porosity, pore size distribution, total carbon (TC) and total N (TN) were performed after 1 year of soil–biochar-interactions in the laboratory. The smaller particle size <0.15 mm increased water retention in both soils, particularly in the loamy soil. Bulk density slightly decreased, especially in the loamy soil when biochar > 2 mm and in the sandy soil with the addition of 0.15–2 mm biochar. Porosity increased in both soils with the addition of biochar in the range of 0.15–2 mm. Smaller biochar particles shifted pore size distribution to increased macro and mesoporosity in both soils. Total carbon content increased mainly in sandy soil compared to control treatment; the highest carbon amount was obtained in the biochar size 0.15–2 mm in loamy soil and <0.15 mm in sandy soil, while the TN content and C:N ratio increased slightly with a reduction of the biochar particle size in both soils. These results demonstrate that biochar particle size is crucial for water retention, water availability, pore size distribution, and C sequestration.


Soil Research ◽  
1971 ◽  
Vol 9 (1) ◽  
pp. 21 ◽  
Author(s):  
LAG Aylmore ◽  
M Karim ◽  
JP Quirk

The effect of variations in physical form such as particle size and mixing with other materials, on the rate of dissolution of sulphate and phosphate from solid fertilizers, has been investigated. It is apparent from these results that the degree of subdivision of a solid fertilizer is particularly important in determining its susceptibility to leaching. It has been demonstrated that leaching of sulphate is appreciably restricted when the granule size is 2 mm or greater in diameter. Except when leached immediately after application, the retention of phosphate is determined largely by 'reversion' to the relatively insoluble dicalcium phosphate form. combination of sulphate with phosphate in superphosphate or the addition of various additives to gypsum markedly reduces the rate of sulphate leaching in comparison to pure gypsum. A comparison of pore size distribution suggests that pores within the intermediate range from approximately 500 A to 105 A play a significant part in the dissolution process.


2019 ◽  
Vol 358 ◽  
pp. 160-169 ◽  
Author(s):  
Prashanth Suresh Kumar ◽  
Leon Korving ◽  
Karel J. Keesman ◽  
Mark C.M. van Loosdrecht ◽  
Geert-Jan Witkamp

2008 ◽  
Vol 368-372 ◽  
pp. 1820-1822
Author(s):  
Zhao Hui Liu ◽  
Xiao Hua Gu ◽  
Zhao Cai Zhang ◽  
Dan Wang ◽  
Cui Yu Yin ◽  
...  

Mg-Al, Zn-Al, and Mg-Fe layered double hydroxides (LDHs) have been synthesized through a stepwise control route. In the stepwise control route, we controlled the state of Al or Fe composition as Al or Fe hydroxyl aqueous complexes in aqueous solution first, then dropwise Mg2+ or Zn2+ and OH - and keep procedure at constant pH value simultaneously at room temperature. The textural and structure properties of the resulting samples were characterized by XRD and TG-DTG. The results showed that products obtained by the stepwise control route were pure and highly crystalline LDHs. The particle size and size distribution was measured by DLLS.


2019 ◽  
Vol 360 ◽  
pp. 190-199 ◽  
Author(s):  
Polina Yaseneva ◽  
Nan An ◽  
Matt Finn ◽  
Nicholas Tiedemann ◽  
Nicholas Jose ◽  
...  

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