scholarly journals Effect of Admixtures on Durability Characteristics of Fly Ash Alkali-activated Material

2020 ◽  
Vol 4 (6) ◽  
pp. 493-502
Author(s):  
Lukáš Procházka ◽  
Jana Boháčová
Keyword(s):  
Compressive Strength ◽  
Blast Furnace ◽  
Fly Ash ◽  
Flexural Strength ◽  
Frost Resistance ◽  
Granulated Slag ◽  
Furnace Slag ◽  
Alkali Activated ◽  
Reference Mixture ◽  
Denitrification Process

This paper deals with the possibility of partial replacement of blast furnace slag with fly ash and fly ash after denitrification by SNCR method in alkali-activated materials based on granulated blast furnace slag. The aim of this paper is to verify the effect of fly ash on properties of alkali-activated materials based on blast furnace granulated slag. Frost resistance and resistance to aggressive environments, represented by demineralized water were tested. The reference mixture was based on blast furnace granulated slag activated by sodium water glass with silicate modulus of 2. Mixtures with an ash content of 10, 20, and 30% were then compared with the reference mixture. The influence of the denitrification process on fly ash and its use in mixed alkali activated materials was also compared. As a part of the experiment, alkali-activated pastes were also prepared. Infrared spectroscopy with Furier transformation was subsequently determined on these pastes. The reference mixture achieved the highest compressive strength in the experiment and the strength decreased with increasing amount of fly ash. In terms of flexural strength, the highest values were reached for mixtures with 10% slag replacement by fly ash. In the case of frost resistance, the significant increase of flexural strength, which was 50% for the reference mixture, is particularly interesting. For compressive strength, the frost resistance coefficient ranged from 0.95 to 1.00. In the case of resistance to aggressive environments, no differences were observed in the compressive strength, on the other hand, flexural strength decrease of up to 20% was detected for 10 and 20 percent replacement of slag with fly ash that did not undergo denitrification. Monitored properties did not show any negative effect of the denitrification process on fly ash properties. Infrared spectroscopy identified the main hydration product in the region of 945 cm-1which is a C-(A)-S-H gel and in combined mixtures with fly ash also N-A-S-H gel. Doi: 10.28991/esj-2020-01247 Full Text: PDF

scholarly journals The Compressive Strength and Microstructure of Alkali-Activated Binary Cements Developed by Combining Ceramic Sanitaryware with Fly Ash or Blast Furnace Slag

Minerals ◽  
2018 ◽  
Vol 8 (8) ◽  
pp. 337 ◽  
Author(s):  
Juan Cosa ◽  
Lourdes Soriano ◽  
María Borrachero ◽  
Lucía Reig ◽  
Jordi Payá ◽  
...  
Keyword(s):  
Compressive Strength ◽  
Blast Furnace ◽  
Fly Ash ◽  
Blast Furnace Slag ◽  
Calcium Content ◽  
Partial Replacement ◽  
Alkali Activation ◽  
High Calcium ◽  
Furnace Slag ◽  
Alkali Activated

The properties of a binder developed by the alkali-activation of a single waste material can improve when it is blended with different industrial by-products. This research aimed to investigate the influence of blast furnace slag (BFS) and fly ash (FA) (0–50 wt %) on the microstructure and compressive strength of alkali-activated ceramic sanitaryware (CSW). 4 wt % Ca(OH)2 was added to the CSW/FA blended samples and, given the high calcium content of BFS, the influence of BFS was analyzed with and without adding Ca(OH)2. Mortars were used to assess the compressive strength of the blended cements, and their microstructure was investigated in pastes by X-ray diffraction, thermogravimetry, and field emission scanning electron microscopy. All the samples were cured at 20 °C for 28 and 90 days and at 65 °C for 7 days. The results show that the partial replacement of CSW with BFS or FA allowed CSW to be activated at 20 °C. The CSW/BFS systems exhibited better mechanical properties than the CSW/FA blended mortars, so that maximum strength values of 54.3 MPa and 29.4 MPa were obtained in the samples prepared with 50 wt % BFS and FA, respectively, cured at 20 °C for 90 days.

Effect of the Combined Using of Fly Ash and Granulated Blast Furnace Slag on Properties of Cementless Alkali-Activated Mortar

2011 ◽  
Vol 287-290 ◽  
pp. 916-921
Author(s):  
Kyung Taek Koh ◽  
Gum Sung Ryu ◽  
Si Hwan Kim ◽  
Jang Hwa Lee
Keyword(s):  
Compressive Strength ◽  
Blast Furnace ◽  
Fly Ash ◽  
Blast Furnace Slag ◽  
Curing Temperature ◽  
Mixture Ratio ◽  
Granulated Blast Furnace Slag ◽  
Alkaline Activator ◽  
Furnace Slag ◽  
Alkali Activated

This paper examines the effects of the mixture ratio of fly ash/slag, the type of alkaline activators and curing conditions on the workability, compressive strength and microstructure of cementless alkali-activated mortar. The investigation showed that the mixture ratio of fly ash/slag and the type of alkaline activator have significant influence on the workability and strength, whereas the curing temperature has relatively poor effect. An alkali-activated mortar using a binder composed of 50% of fly ash and 50% of granulated blast furnace slag and alkaline activator made of 9M NaOH and sodium silicate in proportion of 1:1 is seen to be able to develop a compressive strength of 65 MPa at age of 28 days even when cured at ambient temperature of 20°C.

Properties of GGBFS-Based Pervious Concrete Containing Fly Ash and Silica Fume

2017 ◽  
Vol 266 ◽  
pp. 278-282 ◽  
Author(s):  
Jul Endawati
Keyword(s):  
Compressive Strength ◽  
Blast Furnace ◽  
Fly Ash ◽  
Flexural Strength ◽  
Silica Fume ◽  
Blast Furnace Slag ◽  
Aggregate Size ◽  
Pervious Concrete ◽  
Fine Aggregate ◽  
Furnace Slag

Pervious concrete primarily is used as a means of storm water management. Taking into consideration the environment issues, the binder can also be formed by partially replaced Portland cement by cementitious materials, such as blast furnace slag fine powder, fly ash and silica fume. The combination of the binder materials was determined based on previous work, which composed of 56% Portland Composite Cement, 15% fly ash Type F, 26% air-cooled blast furnace slag from a local steel Industry and 3% condensed silica fume. The compressive strength of specimens with coarser aggregate was lower compared with the control pervious concrete, but still within the range of the requirement compressive strength according to ACI 522R-2010. The difference of the aggregate size affected the enhancement of the compressive strength. The flexural strength of pervious concrete with aggregate size of 9.5mm-12.5mm tend to be higher compared with that of pervious concrete with smaller aggregate size. Furthermore, the addition of 6% natural fine aggregate while applying higher water/cement ratio could be a contribution to the enhancement of the compressive and the flexural strength.

scholarly journals Physical and Chemical Relationships in Accelerated Carbonation Conditions of Alkali-Activated Cement Based on Type of Binder and Alkali Activator

Polymers ◽  
2021 ◽  
Vol 13 (4) ◽  
pp. 671
Author(s):  
Yuto Yamazaki ◽  
Jihoon Kim ◽  
Keisuke Kadoya ◽  
Yukio Hama
Keyword(s):  
Compressive Strength ◽  
Blast Furnace ◽  
Fly Ash ◽  
Blast Furnace Slag ◽  
Accelerated Carbonation ◽  
Chemical Changes ◽  
Physical Changes ◽  
Physical And Chemical ◽  
Furnace Slag ◽  
Alkali Activated

Alkali-activated cements prepared from aluminosilicate powders, such as blast furnace slag and fly ash, are rapidly attracting attention as alternatives to cement because they can significantly reduce CO2 emissions compared to conventional cement concrete. In this study, we investigated the relationship between the physical and chemical changes by accelerated carbonation conditions of alkali-activated cements. Alkali-activated cements were prepared from binders composed of blast furnace slag and fly ash as well as alkali activators sodium silicate and sodium hydroxide. Physical changes were analyzed from compressive strength, pH, and neutralization depth, and chemical changes were analyzed from XRD, TG-DTG, and 29Si MAS NMR. The C–(N)–A–S–H structure is noted to change via carbonation, and the compressive strength is observed to decrease. However, in the case of Na-rich specimens, the compressive strength does not decrease by accelerated carbonation. This work is expected to contribute to the field of alkali-activated cements in the future.

scholarly journals Comparison of the strength development of binary and ternary cements containing perlite powder

2020 ◽  
Vol 15 (1) ◽  
pp. 47-57
Author(s):  
Alena Sičáková ◽  
Erika Figmigová ◽  
Matej Špak
Keyword(s):  
Compressive Strength ◽  
Blast Furnace ◽  
Fly Ash ◽  
Flexural Strength ◽  
Blast Furnace Slag ◽  
Time Development ◽  
Blended Cements ◽  
Granulated Blast Furnace Slag ◽  
Rate Of Increase ◽  
Furnace Slag

Abstract Currently, the consumption of blended cements is increasing all over the world. This is due to environmental, technical and economic reasons. Among the additives mixed with ordinary Portland cement, ground granulated blast furnace slag and fly ash are of particular significance. However, some regions may lack standard additives, and vice versa, may be rich in natural pozzolans. This paper is focused on the perlite as a natural pozzolanic material which is locally available. This study presents the results of the application of perlite as a component of blended cements in different proportions, representing binary and ternary compositions, and compares it with standard additives (fly ash and ground granulated blast furnace slag). The time development of both compressive and flexural strength, including results of 2, 7, 28 and 90-day testing, is analyzed. Perlite binders show acceptable time development of strengths, which is comparable to conventional blended binders based on ground granulated blast furnace slag and fly ash and do not constitute a technological barrier. With a higher dose of perlite, the time increase in flexural strength is slower, but the rate of increase in compressive strength does not change substantially. Flexural strength of 4.1–6.2 MPa and compressive strength of 18.8–38.5 MPa are sufficient for a number of practical applications and are expected to meet the required limits. An improvement of strengths in the later period (90 days) was also confirmed.

Use of Ash after Denitrification as an Additive to Concrete Based on Alcali-Activated Slag

2021 ◽  
Vol 322 ◽  
pp. 78-83
Author(s):  
Lukáš Procházka ◽  
Jana Boháčová
Keyword(s):  
Blast Furnace ◽  
Fly Ash ◽  
Partial Replacement ◽  
Negative Effects ◽  
Concrete Mixtures ◽  
Granulated Slag ◽  
Activated Slag ◽  
Alkali Activated Concrete ◽  
Alkali Activated ◽  
Reference Mixture

This paper deals with the possibility of using fly ash after denitrification by the SNCR method a partial replacement in alkali-activated concrete based on blast furnace granulated slag. Previous research has verified the use of fly ash after denitrification in alkali-activated materials based on blast furnace granulated slag, and so far no negative effects on the properties of these mixtures have been found. The tests were performed on cement test specimens. As part of the preparation of concrete mixtures, two recipes were prepared. The first reference mixture contained only blast furnace granulated slag activated by sodium water glass with silicate modulus of 2. The second recipe was modified by replacing of 30% slag by fly ash after denitrification by SNCR method. Within the strength characteristics, the reference mixture always achieved better results. Very slow increases in strength were recorded for the mixture with 30% slag replacement by fly ash, when the compressive strength after 7 days of maturation was only 4.5 MPa.

Optimization of Concrete Porous Mix Using Slag as Substitute Material for Cement and Aggregates

2017 ◽  
Vol 865 ◽  
pp. 282-288 ◽  
Author(s):  
Jul Endawati ◽  
Rochaeti ◽  
R. Utami
Keyword(s):  
Compressive Strength ◽  
Blast Furnace ◽  
Fly Ash ◽  
Silica Fume ◽  
Blast Furnace Slag ◽  
Environmental Effect ◽  
Substitution Effect ◽  
Main Concern ◽  
Binder Material ◽  
Furnace Slag

In recent years, sustainability and environmental effect of concrete became the main concern. Substituting cement with the other cementitious material without decreasing mechanical properties of a mixture could save energy, reduce greenhouse effect due to mining, calcination and limestone refining. Therefore, some industrial by-products such as fly ash, silica fume, and Ground Iron Blast Furnace Slag (GIBFS) would be used in this study to substitute cement and aggregate. This substitution would be applied on the porous concrete mixture to minimize the environmental effect. Slag performance will be optimized by trying out variations of fly ash, silica fume, and slag as cement substitution material in mortar mixture. The result is narrowed into two types of substitution. First, reviewed from the fly ash substitution effect on binder material, highest compressive strength 16.2 MPa was obtained from mixture composition 6% fly ash, 3% silica fume and 17% grinding granular blast-furnace slag. Second, reviewed from slag types as cement substitution and silica fume substitution, highest compressive strength 15.2 MPa was obtained from mortar specimens with air-cooled blast furnace slag. It composed with binder material 56% Portland composite cement, 15% fly ash, 3% silica fume and 26% air-cooled blast furnace slag. Considering the cement substitution, the latter mixture was chosen.

scholarly journals Red Mud-Blast Furnace Slag-Based Alkali-Activated Materials

2021 ◽  
Vol 13 (20) ◽  
pp. 11298
Author(s):  
Alessio Occhicone ◽  
Mira Vukčević ◽  
Ivana Bosković ◽  
Claudio Ferone
Keyword(s):  
Compressive Strength ◽  
Blast Furnace ◽  
Red Mud ◽  
Blast Furnace Slag ◽  
Bauxite Residue ◽  
Sodium Silicate Solution ◽  
Silicate Solution ◽  
Waste Products ◽  
Furnace Slag ◽  
Alkali Activated

The aluminum Bayer production process is widespread all over the world. One of the waste products of the Bayer process is a basic aluminosilicate bauxite residue called red mud. The aluminosilicate nature of red mud makes it suitable as a precursor for alkali-activated materials. In this work, red mud was mixed with different percentages of blast furnace slag and then activated by sodium silicate solution at different SiO2/Na2O ratios. Obtained samples were characterized by chemical–physical analyses and compressive strength determination. Very high values of compressive strength, up to 50 MPa, even for high percentage of red mud in the raw mixture (70 wt.% of RM in powder mixture), were obtained. In particular, the higher compressive strength was measured for cubic samples containing 50 wt.% of RM, which showed a value above 70 MPa. The obtained mixtures were characterized by no or scarce environmental impact and could be used in the construction industry as an alternative to cementitious and ceramic materials.

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