scholarly journals The Compressive Strength and Microstructure of Alkali-Activated Binary Cements Developed by Combining Ceramic Sanitaryware with Fly Ash or Blast Furnace Slag

Minerals ◽  
2018 ◽  
Vol 8 (8) ◽  
pp. 337 ◽  
Author(s):  
Juan Cosa ◽  
Lourdes Soriano ◽  
María Borrachero ◽  
Lucía Reig ◽  
Jordi Payá ◽  
...  
Keyword(s):  
Compressive Strength ◽  
Blast Furnace ◽  
Fly Ash ◽  
Blast Furnace Slag ◽  
Calcium Content ◽  
Partial Replacement ◽  
Alkali Activation ◽  
High Calcium ◽  
Furnace Slag ◽  
Alkali Activated

The properties of a binder developed by the alkali-activation of a single waste material can improve when it is blended with different industrial by-products. This research aimed to investigate the influence of blast furnace slag (BFS) and fly ash (FA) (0–50 wt %) on the microstructure and compressive strength of alkali-activated ceramic sanitaryware (CSW). 4 wt % Ca(OH)2 was added to the CSW/FA blended samples and, given the high calcium content of BFS, the influence of BFS was analyzed with and without adding Ca(OH)2. Mortars were used to assess the compressive strength of the blended cements, and their microstructure was investigated in pastes by X-ray diffraction, thermogravimetry, and field emission scanning electron microscopy. All the samples were cured at 20 °C for 28 and 90 days and at 65 °C for 7 days. The results show that the partial replacement of CSW with BFS or FA allowed CSW to be activated at 20 °C. The CSW/BFS systems exhibited better mechanical properties than the CSW/FA blended mortars, so that maximum strength values of 54.3 MPa and 29.4 MPa were obtained in the samples prepared with 50 wt % BFS and FA, respectively, cured at 20 °C for 90 days.

Experimental Study on Compound Binding Material of Alkali Activated Metakaolin and Ground Granulated Blast Furnace Slag

2011 ◽  
Vol 287-290 ◽  
pp. 1275-1279
Author(s):  
Yong Jia He ◽  
Lin Nu Lu ◽  
Shu Guang Hu
Keyword(s):  
Compressive Strength ◽  
Blast Furnace ◽  
Blast Furnace Slag ◽  
Hydration Product ◽  
Alkali Activation ◽  
Granulated Blast Furnace Slag ◽  
Binding Material ◽  
Measurement Results ◽  
Furnace Slag ◽  
Alkali Activated

Compound binding material was prepared by the alkali activation of metakaolin and ground granulated blast furnace slag. Hydration product components, microstructure and mechanical properties of the hardened paste were investigated by IR, XRD, SEM, MIP, and compressive strength measurement. Results indicated that hydration products included C-S-H and geopolymer, and both of them were amorphous although there were differences in their structure and morphology. When the dosage of slag was less than 50%, the compressive strength of hardened paste increased as the dosage increased, which was mainly because C-S-H produced by the reaction of GGBFS and alkali filled void in geopolymer phase, and part of unreacted slag particles acting as microaggregate to prevent from extension of microcrack in the hardened paste, so the porosity of hardened paste decreased and compressive strength increased.

The Leachability of Heavy Metals from Alkali-Activated Fly Ash and Blast Furnace Slag Matrices

2016 ◽  
Vol 851 ◽  
pp. 141-146
Author(s):  
Jan Koplík ◽  
Miroslava Smolková ◽  
Jakub Tkacz
Keyword(s):  
Mechanical Properties ◽  
Heavy Metals ◽  
Blast Furnace ◽  
Fly Ash ◽  
Blast Furnace Slag ◽  
Inductively Coupled Plasma ◽  
Emission Spectrometry ◽  
Alkali Activation ◽  
Furnace Slag ◽  
Alkali Activated

The ability of alkali-activated materials (AAMs) to fix and immobilize heavy metals was investigated. Two raw materials were used to prepare alkali-activated matrices – high-temperature fly ash and blast furnace slag (BFS). NaOH served as an alkaline activator. Two heavy metals (Mn, Ni) were added in different amounts to find out the influence of dosage of heavy metal on the mechanical properties of the matrices and the leachability. Leachability was measured as concentration of heavy metals in leachates (ČSN EN 12457-4) by inductively coupled plasma/optical emission spectrometry (ICP/OES). Structure of prepared matrices was characterized by scanning electron microscopy (SEM). Increasing of addition of heavy metals led to decrease of mechanical properties of matrices. The leaching tests showed, that both matrices can immobilize Mn and Ni in dosages of 0.1 – 2,5%. Higher dosages caused deterioration of the matrices and increased the leachability. After alkali activation both heavy metals were transformed into the form of insoluble salts.

scholarly journals Evolution of Mechanical Properties with Time of Fly-Ash-Based Geopolymer Mortars under the Effect of Granulated Ground Blast Furnace Slag Addition

Energies ◽  
2020 ◽  
Vol 13 (5) ◽  
pp. 1135 ◽  
Author(s):  
Mateusz Sitarz ◽  
Izabela Hager ◽  
Marta Choińska
Keyword(s):  
Compressive Strength ◽  
Blast Furnace ◽  
Fly Ash ◽  
Modulus Of Elasticity ◽  
Blast Furnace Slag ◽  
Energy Savings ◽  
Pulse Velocity ◽  
Partial Replacement ◽  
Granulated Blast Furnace Slag ◽  
Furnace Slag

Geopolymers are considered to alternatives to Portland cement, providing an opportunity to exploit aluminosilicate wastes or co-products with promising performances in the construction sector. This research is aimed at investigating the strength of fly-ash-geopolymers of different ages. The effect of granulated blast furnace slag (GGBFS) as a partial replacement of fly ash (FA) on the tensile (ft) and compressive strength (fc), as well as the modulus of elasticity, is investigated. The main advantage of the developed geopolymer mixes containing GGBFS is their ability to set and harden at room temperature with no need for heating to obtain binding properties, reducing the energy consumption of their production processes. This procedure presents a huge advantage over binders requiring heat curing, constituting a significant energy savings and reduction of CO2 emissions. It is found that the development of strength strongly depends on the ratio of fly-ash to granulated blast furnace slag. With the highest amount of GGBFS, the compressive strength of geopolymers made of fly-ash reached 63 MPa after 28 days of curing at ambient temperature. The evolution of compressive strength with time is correlated with the development of ultrasound pulse velocity methods, which are used to evaluate maturity. The modulus of elasticity changes with strength and the relationship obtained for the geopolymer is presented on the basis of typical models used for cement-based materials. The tensile to compressive strength ratios of the tested geopolymers are identified as higher than for cementitious binders, and the ft(fc) relationship is juxtaposed with dependencies known for cement binders, showing that the square root function gives the best fit to the results.

Immobilization of Sr2+, Bi3+ and Zn2+ in Alkali-Activated Materials Based on Blast Furnace Slag and Fly Ash

2018 ◽  
Vol 761 ◽  
pp. 15-18 ◽  
Author(s):  
Jan Koplík ◽  
Tomáš Solný ◽  
Lukáš Kalina ◽  
Jiří Másilko
Keyword(s):  
Blast Furnace ◽  
Fly Ash ◽  
Blast Furnace Slag ◽  
Alkali Activation ◽  
Alkaline Activator ◽  
Insoluble Compounds ◽  
Furnace Slag ◽  
Alkali Activated ◽  
State Of Metals

It is well known, that alkali-activated materials (AAMs) are suitable for immobilization of heavy metals and other hazardous materials. This study is focused on the characterization of inhibition of three metals – Sr2+, Bi3+and Zn2+in alkali-activated matrices. Two type of matrices were prepared – alkali-activated blast furnace slag (BFS) and alkali-activated fly ash (FA). Sodium water glass was used as alkaline activator. The ability of these matrices to fix the metals were proved by leaching tests. Compressive strength was measured to characterize mechanical properties of the matrices. Scanning electron microscopy (SEM) equipped with energy dispersive X-ray spectroscopy (EDS) was used to examine distribution and chemical state of metals within the matrices. The observed metals mainly formed the insoluble compounds after alkali activation.

Effect of the Combined Using of Fly Ash and Granulated Blast Furnace Slag on Properties of Cementless Alkali-Activated Mortar

2011 ◽  
Vol 287-290 ◽  
pp. 916-921
Author(s):  
Kyung Taek Koh ◽  
Gum Sung Ryu ◽  
Si Hwan Kim ◽  
Jang Hwa Lee
Keyword(s):  
Compressive Strength ◽  
Blast Furnace ◽  
Fly Ash ◽  
Blast Furnace Slag ◽  
Curing Temperature ◽  
Mixture Ratio ◽  
Granulated Blast Furnace Slag ◽  
Alkaline Activator ◽  
Furnace Slag ◽  
Alkali Activated

This paper examines the effects of the mixture ratio of fly ash/slag, the type of alkaline activators and curing conditions on the workability, compressive strength and microstructure of cementless alkali-activated mortar. The investigation showed that the mixture ratio of fly ash/slag and the type of alkaline activator have significant influence on the workability and strength, whereas the curing temperature has relatively poor effect. An alkali-activated mortar using a binder composed of 50% of fly ash and 50% of granulated blast furnace slag and alkaline activator made of 9M NaOH and sodium silicate in proportion of 1:1 is seen to be able to develop a compressive strength of 65 MPa at age of 28 days even when cured at ambient temperature of 20°C.

scholarly journals Effect of Polypropylene Fiber, GGBS and Fly Ash over the Strength Aspects of Concrete: A Critical Review

2021 ◽  
Vol 9 (VI) ◽  
pp. 978-983
Author(s):  
Khalid Bashir Mir
Keyword(s):  
Tensile Strength ◽  
Compressive Strength ◽  
Blast Furnace ◽  
Fly Ash ◽  
Blast Furnace Slag ◽  
Polypropylene Fiber ◽  
Synthetic Fiber ◽  
Partial Replacement ◽  
Granulated Blast Furnace Slag ◽  
Furnace Slag

In this review study the usage of three different kinds of constructional materials was discussed in detail. The three materials comprised of Ground Granulated Blast Furnace Slag, fly and polypropylene fiber. Ground Granulated Blast Furnace Slag is basically the slag derived after the quenching process of iron slag produced during the processing of iron in iron industry. Fly ash is the waste generated from the coal processing industries and is mainly used in the road constructions works. Polypropylene fiber is a synthetic fiber that has very high tensile strength and flexural strength. This fiber is also known as synthetic fiber as it is mainly used in the synthetic industry. Depending upon the results of previous studies over the usage of these materials various conclusions has been drawn which are as follows. The results of studies related to the usage of Ground Granulated Blast Furnace Slag as partial replacement of cement concluded that the most optimum usage percentage of Ground Granulated Blast Furnace Slag as partial replacement of cement was found to be between 20 percent and 30 percent and beyond this limit the strength of concrete was decreasing. The past studies related to the usage of fly ash as partial replacement of cement shoed that the most optimum usage percentage of fly ash was found to be between 15 percent to 20 percent and beyond this percentage the strength parameters of concrete such as compressive strength, flexural strength and split tensile strength starts declining up to a greater extent. The studies related to the usage of polypropylene fiber showed that the usage of this fiber increases the compressive strength of soil and the most optimum results were found between 1.0 percent to 1.5 percent usages of polypropylene fiber. Above this percentage there will be negative effect on the strength aspects and the compressive strength starts declining.

scholarly journals Physical and Chemical Relationships in Accelerated Carbonation Conditions of Alkali-Activated Cement Based on Type of Binder and Alkali Activator

Polymers ◽  
2021 ◽  
Vol 13 (4) ◽  
pp. 671
Author(s):  
Yuto Yamazaki ◽  
Jihoon Kim ◽  
Keisuke Kadoya ◽  
Yukio Hama
Keyword(s):  
Compressive Strength ◽  
Blast Furnace ◽  
Fly Ash ◽  
Blast Furnace Slag ◽  
Accelerated Carbonation ◽  
Chemical Changes ◽  
Physical Changes ◽  
Physical And Chemical ◽  
Furnace Slag ◽  
Alkali Activated

Alkali-activated cements prepared from aluminosilicate powders, such as blast furnace slag and fly ash, are rapidly attracting attention as alternatives to cement because they can significantly reduce CO2 emissions compared to conventional cement concrete. In this study, we investigated the relationship between the physical and chemical changes by accelerated carbonation conditions of alkali-activated cements. Alkali-activated cements were prepared from binders composed of blast furnace slag and fly ash as well as alkali activators sodium silicate and sodium hydroxide. Physical changes were analyzed from compressive strength, pH, and neutralization depth, and chemical changes were analyzed from XRD, TG-DTG, and 29Si MAS NMR. The C–(N)–A–S–H structure is noted to change via carbonation, and the compressive strength is observed to decrease. However, in the case of Na-rich specimens, the compressive strength does not decrease by accelerated carbonation. This work is expected to contribute to the field of alkali-activated cements in the future.

Hybrid Alkali Activated Concretes - Conception and Development for Practical Application

2016 ◽  
Vol 249 ◽  
pp. 3-7 ◽  
Author(s):  
Vlastimil Bílek ◽  
Jan Hurta ◽  
Petra Done ◽  
Libor Zidek ◽  
Tomas Zajdlik
Keyword(s):  
Blast Furnace ◽  
Fly Ash ◽  
Blast Furnace Slag ◽  
Mineral Admixtures ◽  
Alkali Activation ◽  
Granulated Blast Furnace Slag ◽  
Mineral Additions ◽  
New Type ◽  
Furnace Slag ◽  
Alkali Activated

Hybrid cements represent a relatively new type of binders which combine some of the advantages of Ordinary Portland Cement (OPC), the application of mineral admixtures and alkali activation. Hybrid cements represent blends containing a low portion of OPC and a high proportion of mineral additions (such as blast furnace slag, fly ash, metakaolin ....). The paper is focused on the study of properties of mortars prepared from hybrid cements. Mortars with hybrid cements were prepared for an evaluation of the effects of the dosage and the composition of alkali activator, the dosage of OPC and the ratio between ground granulated blast furnace slag and fly ash. The results make it possible to optimize the composition of hybrid alkali activated concretes.

Optimization of Concrete Porous Mix Using Slag as Substitute Material for Cement and Aggregates

2017 ◽  
Vol 865 ◽  
pp. 282-288 ◽  
Author(s):  
Jul Endawati ◽  
Rochaeti ◽  
R. Utami
Keyword(s):  
Compressive Strength ◽  
Blast Furnace ◽  
Fly Ash ◽  
Silica Fume ◽  
Blast Furnace Slag ◽  
Environmental Effect ◽  
Substitution Effect ◽  
Main Concern ◽  
Binder Material ◽  
Furnace Slag

In recent years, sustainability and environmental effect of concrete became the main concern. Substituting cement with the other cementitious material without decreasing mechanical properties of a mixture could save energy, reduce greenhouse effect due to mining, calcination and limestone refining. Therefore, some industrial by-products such as fly ash, silica fume, and Ground Iron Blast Furnace Slag (GIBFS) would be used in this study to substitute cement and aggregate. This substitution would be applied on the porous concrete mixture to minimize the environmental effect. Slag performance will be optimized by trying out variations of fly ash, silica fume, and slag as cement substitution material in mortar mixture. The result is narrowed into two types of substitution. First, reviewed from the fly ash substitution effect on binder material, highest compressive strength 16.2 MPa was obtained from mixture composition 6% fly ash, 3% silica fume and 17% grinding granular blast-furnace slag. Second, reviewed from slag types as cement substitution and silica fume substitution, highest compressive strength 15.2 MPa was obtained from mortar specimens with air-cooled blast furnace slag. It composed with binder material 56% Portland composite cement, 15% fly ash, 3% silica fume and 26% air-cooled blast furnace slag. Considering the cement substitution, the latter mixture was chosen.

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