scholarly journals OPTIMIZATION OF INORGANIC COMPONENTS OF FIRE PROTECTIVE VARNISH FOR WOOD

Author(s):  
Yu. Tsapko ◽  
◽  
А. Tsapko ◽  
O. Bondarenko ◽  
V. Lomaha ◽  
...  

Abstract. The processes of creation of fire-retardant varnish for wood consisting of a mixture of inorganic and polymeric substances are investigated in the work. It is established that the optimization of the inorganic component leads to a directional ratio of mineral acids and urea capable of effective fire protection of the material. Studies have shown that at the initial temperature of gaseous combustion products T = 68 °C, when exposed to the radiation panel, the untreated sample ignited after 146 s, the flame spread over the entire surface, instead, the sample fire-protected varnish did not ignite, the maximum temperature was 105 °C. In this case, as evidenced by the results of heat resistance, there is a change in the structure of the protective film of the coating. The thickness of the protective layer increases due to the decomposition of the composition, which leads to inhibition of oxidation in the gas and condensed phase, change the direction of decomposition towards the formation of non-combustible gases and combustible coke residue, reduce material combustion and increase flammability index. The coating under the influence of high temperature promotes the formation of a heat-insulating layer of coke, which prevents burning and the passage of high temperature to the material, which is confirmed by the absence of the process of ignition of fire-retardant wood. Features of braking of process of ignition and distribution of a flame of the wood processed by a varnish which consist in several aspects are established. This is the formation of a heat-insulating layer of coke, which prevents burning and the passage of high temperatures to the material, which is confirmed by the absence of the process of ignition of fire-retardant reeds. This indicates the possibility of targeted control of high temperature transfer processes to organic material through the use of special coatings for wood products.

2020 ◽  
Vol 11 (3) ◽  
Author(s):  
V. V. Lomaha ◽  
O. Yu. Tsapko ◽  
Yu. V. Tsapko ◽  
O. P. Bondarenko

Reducing the fire prevention of timber is not only an economic task, but also has a social and environmental focus. From economic, technological and environmental perspective, an important problem in ensuring the viability and safe operation of construction sites is the development of fire-retardant coatings for wooden structures. The construction is increasingly looking for new highly effective means of fire protection of wood and wood products which should not only ensure the standardized fire resistance of wood, but also to maintain its operational parameters to solve environmental safety and durability. Studies of the effect of the radiation panel on the ignition of the wood sample have set the parameters of the flame ignition, which makes it possible to influence this process. It is proved that they consist in the formation of a layer of organic material on the surface, which provides heating to a critical temperature, when the intensive decomposition of the material begins with the release of the required amount of combustible gases and their ignition. This makes it possible to determine the effect of fire protection and the properties of protective compositions on the process of slowing down the rate of burning of wood. Experimental studies have confirmed that the untreated sample of wood, under the thermal action of the radiation panel has taken up, the flames spread over the entire surface, which led to its combustion. The application of a fire retardant varnish under the influence of temperature leads to a layer of foam coke and inhibition of heat transfer of high-temperature flame to the material and its ignition. Thanks to this, it became possible to determine the conditions for changing the parameters of combustion and braking during fire protection of wood, by forming a barrier for thermal conductivity. Thus, there is reason to argue for the possibility of directional control of the processes of fire protection of wood by the use of fireproof coatings that can form a protective layer on the surface of the material, which slows down the rate of burning of wood.


Alloy Digest ◽  
1974 ◽  
Vol 23 (2) ◽  

Abstract MANIFLEX-FM is a free-machining chromium-nickel austenitic stainless steel which offers excellent high-temperature strength and hardness with good corrosion resistance to combustion products. It is widely used exhaust components in automotive engines. This datasheet provides information on composition, physical properties, elasticity, and tensile properties. It also includes information on high temperature performance and corrosion resistance as well as forming, heat treating, machining, and joining. Filing Code: SS-291. Producer or source: Carpenter.


2021 ◽  
Vol 5 (6) ◽  
pp. 144
Author(s):  
Klaudio Bari ◽  
Thozhuvur Govindaraman Loganathan

The research aim is to investigate the performance of novel enriched mineral fibres (Filava) in polysiloxane SLIRES H62 resin. Specimens were manufactured using a vacuum bagging process and oven cured at 250 °C. Specimens were prepared for flexural testing according to BS EN ISO 14125:1998 to obtain flexural strength, modulus, and elongation. The mechanical strength was compared to similar composites, with the aim of determining composite performance index. The flexural modulus (9.7 GPa), flexural strength (83 MPa), and flexural strain (2.9%) were obtained from a three-point bending test. In addition, the study investigates the thermal properties of the composite using a state-of-art Zwick Roell high temperature tensile rig. The results showed Filava/Polysiloxane Composites had an ultimate tensile strength 400 MPa, Young’s modulus 16 GPa and strain 2.5% at 1000 °C, and no smoke and ash were observed during pyrolysis. Ongoing research is currently taking place to use Filava-H62 in fire-retardant enclosure for lithium-ferro-phosphate Batteries used in electric trucks.


Micromachines ◽  
2021 ◽  
Vol 12 (2) ◽  
pp. 216
Author(s):  
Yongwei Li ◽  
Ting Liang ◽  
Cheng Lei ◽  
Qiang Li ◽  
Zhiqiang Li ◽  
...  

In this study, a preparation method for the high-temperature pressure sensor based on the piezoresistive effect of p-type SiC is presented. The varistor with a positive trapezoidal shape was designed and etched innovatively to improve the contact stability between the metal and SiC varistor. Additionally, the excellent ohmic contact was formed by annealing at 950 °C between Ni/Al/Ni/Au and p-type SiC with a doping concentration of 1018cm−3. The aging sensor was tested for varistors in the air of 25 °C–600 °C. The resistance value of the varistors initially decreased and then increased with the increase of temperature and reached the minimum at ~450 °C. It could be calculated that the varistors at ~100 °C exhibited the maximum temperature coefficient of resistance (TCR) of ~−0.35%/°C. The above results indicated that the sensor had a stable electrical connection in the air environment of ≤600 °C. Finally, the encapsulated sensor was subjected to pressure/depressure tests at room temperature. The test results revealed that the sensor output sensitivity was approximately 1.09 mV/V/bar, which is better than other SiC pressure sensors. This study has a great significance for the test of mechanical parameters under the extreme environment of 600 °C.


2020 ◽  
Vol 0 (10) ◽  
pp. 35-40
Author(s):  
S.I. Gertsyk ◽  
◽  
I.V. Belyakov ◽  

The formation probability of nitrogen oxides in combustion products of mixed blast-furnace and natural gases under different conditions of combustion was calculated. It has been found out that heating the air incoming into burners of high-temperature blast-furnaces sharply increases concentration of nitrogen oxides in combustion products (by 1.5-1.75 times). It was notices that in furnaces where temperature was less than 950-1000 °С, heating the air up to 400 °С increased NOx content in gases released to the atmosphere no more than by 20-23%, and oxide concentration was in limits of sanitary standards.


Author(s):  
Young Tae Moon ◽  
In Chul Ryu ◽  
Quan Zhou ◽  
Paul McMinn ◽  
Chan Y. Paik

During a severe accident with a vessel failure, corium relocates from the vessel into the reactor cavity (PWR) or pedestal (BWR) and accumulates on top of the cavity floor to form a corium pool. This corium pool is hot enough to cause a Molten Corium-Concrete Interaction (MCCI) that can ablate the concrete structure even if water is present on top of the corium. MCCI will also produce steam and other gases that increase containment pressure as well as generate combustible gases (Hydrogen and Carbon Monoxide). Current MAAP5* calculations with conservative assumptions have shown that the ablation depth in a basemat constructed of siliceous concrete can be larger than the depth of liner, even if the reactor cavity is flooded by water. To retain the melt in the containment and to cool the corium pool before the erosion reaches the liner plate, several approaches are being considered. One of these approaches is the installation of a protective layer on top of the concrete floor to retard MCCI. The purpose of this paper is to study the performance of different protective materials under postulated severe accident conditions. The candidates for the protective materials are refractory materials and limestone/limestone-common-sand (LCS) concrete. The refractory material was chosen based on the thermal performance and dissolution rate of the refractory material calculated by analytical calculations and also by MAAP5. Adding the refractory protective material protects the underlying concrete basemat from melting temporarily, so that water ingression into the surface of the corium is not initially affected by addition of the concrete material. *MAAP5 is an integrated severe accident code owned by the Electric Power Research Institute and developed by Fauske and Associates, LLC.


Author(s):  
Jianshu Lin ◽  
Hong Wang

A comprehensive analysis method is proposed to resolve the problem of simulating a complex thermo-flow with two kinds of distinct characteristic length in the dry gas seal, and a conjugated simulation of the complicated heat transfer and the gas film flow is carried out by using the commercial CFD software CFX. By using the proposed method, a three dimensional of velocity and pressure field in the gas film flow and the temperature distribution within the sealing rings are investigated for three kinds of film thickness, respectively. A comparison of thermo-hydrodynamics of the dry gas seals is conducted between the sealed gas of air and helium. The latter one is used in a helium circulator for High Temperature Gas-cooled Reactor (HTGR). From comparisons and discussions of a series of simulation results, it will be found that the comprehensive proposal is effective and simulation results are reasonable, and the maximum temperature rise in the dry gas seal is within the acceptable range of HTGR safety requirements.


Author(s):  
Stephen R. Swartz

Since the inception of the cyclone style boiler, industry has become accustomed to performing routine maintenance during every scheduled shutdown occurring 12 months to 18 months between cycles. These maintenance cycles are influenced by service factor, loading and the type design. The same problems exist in both the standard and super critical cyclones; severe deterioration of refractory and the anchoring pin studs. This paper focuses on one type of refractory failure mechanism caused by the anchoring pin studs. Most operators have found that the most effective means of applying refractory in this type situation is to “ram” the refractory in and around the anchoring pin studs thus creating a dense lining with maximum integrity. Coupled with proper application of anchoring pin studs and a special designed coating, typical volumetric expansion of the pin studs from corrosion attack and oxidation is eliminated thus extending the life of the refractory. This mechanism is discussed along with the results of the coating performance as it relates to extreme heat oxidation and thermal cycling in laboratory tests. A protective coating was developed using a nano-cored thermal spray wire technology that produces a uniform, adherent protective layer against high temperature corrosion and oxidation. The coating yields similar thermal conductivity as a bare stud thus experiencing excellent thermal cycle performance. This specially designed thermal spray coating is applied to standard 430 stainless steel pin studs thus providing the necessary barrier against aggressive high temperature environments while maintaining excellent heat conductivity. The coating has a high amount of tungsten (40+%) in a nickel matrix with greatly reduced oxides at the substrate and throughout the coating. With these attributes for the anchoring pin studs in mind, a newly designed stud was evaluated in heat oxidation tests up to 2000°F and thermal cycling test and compared to 430 stainless steel, chromized and Alloy 625. The new stud out-performed all others even in the as-welded condition. Further corrosion testing in ferric chloride (ASTM G48) showed them to be superior to Alloy 72 and Alloy 625 in the thermal spray and welded condition. Proper welding equipment and welding techniques are also discussed since weld continuity impacts overall performance of anchoring pin studs with refractory linings. A major test site will be examined in the spring of 2004 for it’s full effectiveness in service and will be documented in order that all data retrieved would be available to the entire industry.


2015 ◽  
Vol 4 (3) ◽  
pp. 37-55
Author(s):  
Yelena Vitalievna Volkova

The paper contains the results of the field experimental firings in fireplaces and in ovens made on the basis of Samara pottery experimental expedition (Dr N.P. Salugina is the leader of the expedition) in 2013. The author put forward two goals: one is to discover the basic knowledge on firing process with various kinds of fuel, and second is to find out the specific features to discern the vessels fired in fireplaces from the vessels fired in ovens. 20 vessels were prepared to the experiment. The first 10 pots were made of natural clay and the second 10 vessels were made of pottery paste (clay + grog + cow dung). Five simultaneous firings with various kinds of fuel were organized in fireplace and in oven. The author describes in detail the program, main steps, and maximum temperature of firings, the photos of the vessels, and the results of their analytical studies. After the experiments the author came to the next conclusions: firstly - there are absent the reliable features to distinguish the vessels fired in fireplace and in oven, secondly - there is one dependence between a kind pottery paste and a color of fired vessels and another relation between pottery paste and a degree of high-temperature baking of vessels.


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