scholarly journals SYNTHESIS NEW BIOCOMPOSITGE OF STARCH/NATURAL RUBBER BY USING EPOXIDIZED RUBBER AS A COMPATIBILIZER

2012 ◽  
Vol 15 (3) ◽  
pp. 27-36
Author(s):  
Mao Dang Nguyen ◽  
Thanh Duy Tran ◽  
Ngan Thi Kim Nguyen ◽  
Nhan Thuc Chi Ha ◽  
Huy Thuc Ha

The main component of Natural rubber (NR) is cis-1,4-poly isoprene a renewable natural elastomer produced from the latex of rubber tree. NR has many excellent properties, such as outstanding resilience, high strength, tear resistance and good process ability. Therefore, it is compounded with various chemicals and fillers like carbon black, clay, silica in suitable high concentration to achieve wide range properties having many applications in industries. However, as many synthetic polymers, NR needs a lot of time to be degraded and using carbon black as a filler could cause pollution and gives to the rubber a black color that has a significantly negative effect on products. The aim of the present work was to study the mechanical properties of bio based materials from thermoplastic starch (TPS), natural rubber and epoxidized natural rubber (ENR) used as a compatibilizer. The TPS/NR material was prepared by blending the plasticized starch with natural rubber latex and ENR in a Haake Rheomix 600 mixer. The morphology, mechanical and thermal properties of the material was investigated. The results show that the crystal structure of blend disappeared and thermal stability of material was not improved. Material had the best mechanical properties at TPS/NR ratio 30/70 with ENR content 15%wt.

2013 ◽  
Vol 821-822 ◽  
pp. 961-964 ◽  
Author(s):  
Dan Fan ◽  
Xiao Xue Liao ◽  
Shuang Quan Liao ◽  
Yan Fang Zhao ◽  
Jie Sun

Stable aqueous solution of purple carbon black (PCB) was prepared first and then added to prevulcanized natural rubber latex. The effects of the amount of PCB, silane coupling agent and the type of silane coupling agent on the mechanical properties of the vulcanized latex film were researched. The results show that the best mechanical properties were obtained when the vulcanized film was filled with 6 phr PCB modified by KH560. TG shows that thermal stability of the film with PCB modified by KH560 increased. DSC shows that the glass transition temperature of the film increased after adding PCB.


2014 ◽  
Vol 87 (2) ◽  
pp. 250-263 ◽  
Author(s):  
Sasidharan Krishnan ◽  
Rosamma Alex ◽  
Thomas Kurian

ABSTRACT A process for production of carbon black/silica/nanoclay ternary filler masterbatch from fresh natural rubber (NR) latex was standardized. The fillers, nanoclay, carbon black, and silica were incorporated in fresh NR latex by a modified coagulation process. The latex, mixed with filler dispersions, coagulated immediately on addition of acids. The coagulum containing fillers was dried at 70 °C in an air oven to get the latex filler masterbatch, which was further processed in the conventional way. The masterbatch compounds containing only silica/carbon black showed a higher level of vulcanization as compared with the corresponding dry mixes. The mechanical properties, such as tensile strength, modulus, tear strength, abrasion resistance, and hardness, increased with the proportion of nanoclay in the mixes up to 5 phr, and with a greater amount, the change was only marginal. Lower tan delta values were observed for all of the masterbatches containing nanoclay in the ranges of 3 to 10 phr compared with the control dry mix containing 25/25 carbon black/silica. The improvement in mechanical properties and dynamic properties shown by the masterbatches over the conventional mill-mixed compounds was attributed to factors related to filler dispersion, as evidenced from the data from dispersion analyzer images, X-ray diffractograms, and a higher level of vulcanization.


2021 ◽  
Author(s):  
Vitor Peixoto Klienchen de Maria ◽  
Fábio Paiva ◽  
Flávio Camargo Cabrera ◽  
Carlos Toshiyuki Hiranobe ◽  
Gabriel Deltrejo Ribeiro ◽  
...  

Abstract The present research aimed to develop natural rubber (NR) hybrid composites reinforced with treated ultrafine calcium carbonate/carbon black (CC/CB). The influence of CC/CB with various filler ratios (50/0, 40/10, 30/20, 20/30, 10/40 and 0/50) on mechanical properties and cure characteristics of the vulcanizates was investigated and their reinforcing efficiency was compared aiming to achieve the best ratio for CB partial substitution as compared to composites with CC and CB incorporated separately. The CC30/CB20 composites reached around to 17 MPa similar strength at break response compared to CC0/CB50 (16.83 MPa). Elongation at break increased 48% in relation to CC0/CB50. Hardness maintain similar values compare to high concentration of CB composites. Crosslink density results revealed similar chain number in rubber matrix representing better interaction between CC/CB. Scanning electron microscopy studies also reveal a good filler dispersion between filler particles and matrix. The results shown that the new material can be an alternative filler for partial substitution of CB conserving mechanical properties.


2015 ◽  
Vol 659 ◽  
pp. 404-408 ◽  
Author(s):  
Karndarthip Kuntanoo ◽  
Sarunya Promkotra ◽  
Pakawadee Kaewkannetra

Polyhydroxybutyrate-co-hydroxyvalerate (PHBV) is mixed with natural rubber latex to make better mechanical properties of PHBV. The various ratios between PHBV and natural rubber latex are examined to improve their mechanical properties. The PHBV are solid, easily broken, while natural rubber is excessive elastic materials. Concentrations of the employed PHBV solution are 1, 2, and 3 (%w/v). The mixtures of this solution to natural rubber latex are fabricated the biofilms in three different ratios, 4:6, 5:5, and 6:4, respectively. The films are characterized by electron microscope, universal testing machine, and differential scanning calorimetry (DSC). The electron micrographs of the mixed films and unmixed PHBV yield the lowest void distributions in 3%w/v PHBV. For mechanical properties, the averaged elastic moduli of 1, 2, and 3 (%w/v PHBV) mixed films are 773, 955 and 1,008 kPa, respectively. Their tensile strengths increase with increasing the PHBV concentrations. A similar trend is also found in elastic modulus. The crystallization and melting behavior of pure PHBV and the mixed films are examined by DSC. Melting transition temperatures of pure PHBV exhibit two melting peaks at 154°C and 173°C. In addition, the melting peaks of the mixed films remain in the range of 152-156°C and 168-171°C, respectively. According to their morphology, void distributions reduce twice, compared to the unmixed PHBV. Mechanical properties and thermal analysis indicate that the mixed PHBV can be improved their properties with more resilient and wide range temperature than usual.


2007 ◽  
Vol 344 ◽  
pp. 143-150 ◽  
Author(s):  
Gianluca Buffa ◽  
Livan Fratini ◽  
Marion Merklein ◽  
Detlev Staud

Tight competition characterizing automotive industries in the last decades has determined a strong research effort aimed to improve utilized processes and materials in sheet stamping. As far as the latter are regarded light weight alloys, high strength steels and tailored blanks have been increasingly utilized with the aim to reduce parts weight and fuel consumptions. In the paper the mechanical properties and formability of tailored welded blanks made of a precipitation hardenable aluminum alloy but with different sheet thicknesses, have been investigated: both laser welding and friction stir welding have been developed to obtain the tailored blanks. For both welding operations a wide range of the thickness ratios has been considered. The formability of the obtained blanks has been characterized through tensile tests and cup deep drawing tests, in order to show the formability in dependency of the stress condition; what is more mechanical and metallurgical investigations have been made on the welded joints.


2021 ◽  
Vol 904 ◽  
pp. 441-446
Author(s):  
Nuchnapa Tangboriboon ◽  
Sarun Muntongkaw ◽  
Sompratthana Pianklang

Adding 0, 20, and 50 wt% natural-rubber latex compound into the plaster ceiling matrix affected to increase the physical-mechanical-thermal performance properties of plaster ceiling composites. Adding 50 wt% natural rubber latex compound into plaster composites can increase the superior adhesion of the nail-tensile resistance equal to 57.54 N and decrease thermal conductivity equal to 0.0634 W/m.K. In addition, adding natural rubber latex compounds into plaster composites can reduce water solubility, brittleness, impact, and cost of energy consumption due to the exterior temperature. Adequate thermal insulation for roofing, ceiling, and wall systems also reduces radiative losses that chill occupants in cold weather, and reduce interior surface temperatures in the summer, thereby optimizing the comfort of building occupants. The mechanical and thermal properties of plaster composites were investigated by using a Universal Testing Machine (UTM) and heat flow meter, respectively, measured according to TIS 1211-50, TIS 219-2522, and ASTM C518.


2018 ◽  
Vol 157 ◽  
pp. 02052 ◽  
Author(s):  
Krzysztof Talaśka ◽  
Dominik Wojtkowiak

Due to the wide range of application for belt conveyors, engineers look for many different combinations of mechanical properties of conveyor and transmission belts. It can be made by creating multilayer or fibre reinforced composite materials from base thermoplastic or thermosetting polymers. In order to gain high strength with proper elasticity and friction coefficient, the core of the composite conveyor belt is made of polyamide film core, which can be combined with various types of polymer fabrics, films or even rubbers. In this paper authors show the complex model of multilayer composite belt with the polyamide core, which can be used in simulation analyses. The following model was derived based on the experimental research, which consisted of tensile, compression and shearing tests. In order to achieve the most accurate model, proper simulations in ABAQUS were made and then the results were compared with empirical mechanical characteristics of a conveyor belt. The main goal of this research is to fully describe the perforation process of conveyor and transmission belts for vacuum belt conveyors. The following model will help to develop design briefs for machines used for mechanical perforation.


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