Cellulose-Based Polymers in Additive Manufacturing

The materials for additive manufacturing (AM) technology have grown substantially over the last few years to fulfill industrial needs. Despite that, the use of bio-based composites for improved mechanical properties and biodegradation is still not fully explored. This limits the universal expansion of AM-fabricated products due to the incompatibility of the products made from petroleum-derived resources. The development of naturally-derived polymers for AM materials is promising with the increasing number of studies in recent years owing to their biodegradation and biocompatibility. Cellulose is the most abundant biopolymer that possesses many favorable properties to be incorporated into AM materials, which have been continuously focused on in recent years. This critical review discusses the development of AM technologies and materials, cellulose-based polymers, cellulose-based three-dimensional (3D) printing filaments, liquid deposition modeling of cellulose, and four-dimensional (4D) printing of cellulose-based materials. Cellulose-based AM material applications and the limitations with future developments are also reviewed.

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4D Printing: A Review on Recent Progresses

Micromachines ◽

10.3390/mi11090796 ◽

2020 ◽

Vol 11 (9) ◽

pp. 796 ◽

Cited By ~ 1

Author(s):

Honghui Chu ◽

Wenguang Yang ◽

Lujing Sun ◽

Shuxiang Cai ◽

Rendi Yang ◽

...

Keyword(s):

Additive Manufacturing ◽

3D Printing ◽

Three Dimensional ◽

Complex Structures ◽

Future Prospects ◽

4D Printing ◽

Stimulation Method ◽

Shape Property ◽

External Stimuli

Since the late 1980s, additive manufacturing (AM), commonly known as three-dimensional (3D) printing, has been gradually popularized. However, the microstructures fabricated using 3D printing is static. To overcome this challenge, four-dimensional (4D) printing which defined as fabricating a complex spontaneous structure that changes with time respond in an intended manner to external stimuli. 4D printing originates in 3D printing, but beyond 3D printing. Although 4D printing is mainly based on 3D printing and become an branch of additive manufacturing, the fabricated objects are no longer static and can be transformed into complex structures by changing the size, shape, property and functionality under external stimuli, which makes 3D printing alive. Herein, recent major progresses in 4D printing are reviewed, including AM technologies for 4D printing, stimulation method, materials and applications. In addition, the current challenges and future prospects of 4D printing were highlighted.

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Property Enhancement of Carbon Fiber-Reinforced Polylactic Acid Composites Prepared by Fused-Deposition Modeling

Advances in Computer and Electrical Engineering - Handbook of Research on Recent Developments in Electrical and Mechanical Engineering ◽

10.4018/978-1-7998-0117-7.ch017 ◽

2020 ◽

pp. 455-478

Author(s):

Pravin R. Kubade ◽

Hrushikesh B. Kulkarni ◽

Vinayak C. Gavali

Keyword(s):

Mechanical Properties ◽

Additive Manufacturing ◽

Carbon Fiber ◽

Polylactic Acid ◽

Fused Deposition Modeling ◽

Three Dimensional ◽

Fiber Reinforced ◽

Fused Deposition ◽

Deposition Modeling ◽

Properties Of Composites

Additive Manufacturing or three-dimensional printing refers to a process of building lighter, stronger three-dimensional parts, manufactured layer by layer. Additive manufacturing uses a computer and CAD software which passes the program to the printer to build the desired shape. Metals, thermoplastic polymers, and ceramics are the preferred materials used for additive manufacturing. Fused deposition modeling is one additive manufacturing technique involving the use of thermoplastic polymer for creating desired shape. Carbon fibers can be added into polymer to strengthen the composite without adding additional weight. Present work deals with the manufacturing of Carbon fiber-reinforced Polylactic Acid composites prepared using fused deposition modeling. Mechanical and thermo-mechanical properties of composites are studied as per ASTM standards and using sophisticated instruments. It is observed that there is enhancement in thermo-mechanical properties of composites due to addition reinforcement which is discussed in detail.

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Efficient 3D printing via photooxidation of ketocoumarin based photopolymerization

Nature Communications ◽

10.1038/s41467-021-23170-4 ◽

2021 ◽

Vol 12 (1) ◽

Author(s):

Xiaoyu Zhao ◽

Ye Zhao ◽

Ming-De Li ◽

Zhong’an Li ◽

Haiyan Peng ◽

...

Keyword(s):

Additive Manufacturing ◽

3D Printing ◽

Visible Light ◽

Light Exposure ◽

Three Dimensional ◽

3D Printer ◽

Light Penetration ◽

Viable Solution

AbstractPhotopolymerization-based three-dimensional (3D) printing can enable customized manufacturing that is difficult to achieve through other traditional means. Nevertheless, it remains challenging to achieve efficient 3D printing due to the compromise between print speed and resolution. Herein, we report an efficient 3D printing approach based on the photooxidation of ketocoumarin that functions as the photosensitizer during photopolymerization, which can simultaneously deliver high print speed (5.1 cm h−1) and high print resolution (23 μm) on a common 3D printer. Mechanistically, the initiating radical and deethylated ketocoumarin are both generated upon visible light exposure, with the former giving rise to rapid photopolymerization and high print speed while the latter ensuring high print resolution by confining the light penetration. By comparison, the printed feature is hard to identify when the ketocoumarin encounters photoreduction due to the increased lateral photopolymerization. The proposed approach here provides a viable solution towards efficient additive manufacturing by controlling the photoreaction of photosensitizers during photopolymerization.

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Scientometric Review of Trends on the Mechanical Properties of Additive Manufacturing and 3D Printing

Journal of Materials Engineering and Performance ◽

10.1007/s11665-021-05524-7 ◽

2021 ◽

Author(s):

R. A. García-León ◽

J. A. Gómez-Camperos ◽

H. Y. Jaramillo

Keyword(s):

Mechanical Properties ◽

Additive Manufacturing ◽

3D Printing

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An Overview on the Rheology, Mechanical Properties, Durability, 3D Printing, and Microstructural Performance of Nanomaterials in Cementitious Composites

Materials ◽

10.3390/ma14112950 ◽

2021 ◽

Vol 14 (11) ◽

pp. 2950

Author(s):

Hongwei Song ◽

Xinle Li

Keyword(s):

Mechanical Properties ◽

3D Printing ◽

Three Dimensional ◽

Cementitious Materials ◽

Research Area ◽

Cementitious Composites ◽

Split Tensile Strength ◽

Contour Crafting ◽

Wide Range ◽

Active Research

The most active research area is nanotechnology in cementitious composites, which has a wide range of applications and has achieved popularity over the last three decades. Nanoparticles (NPs) have emerged as possible materials to be used in the field of civil engineering. Previous research has concentrated on evaluating the effect of different NPs in cementitious materials to alter material characteristics. In order to provide a broad understanding of how nanomaterials (NMs) can be used, this paper critically evaluates previous research on the influence of rheology, mechanical properties, durability, 3D printing, and microstructural performance on cementitious materials. The flow properties of fresh cementitious composites can be measured using rheology and slump. Mechanical properties such as compressive, flexural, and split tensile strength reveal hardened properties. The necessary tests for determining a NM’s durability in concrete are shrinkage, pore structure and porosity, and permeability. The advent of modern 3D printing technologies is suitable for structural printing, such as contour crafting and binder jetting. Three-dimensional (3D) printing has opened up new avenues for the building and construction industry to become more digital. Regardless of the material science, a range of problems must be tackled, including developing smart cementitious composites suitable for 3D structural printing. According to the scanning electron microscopy results, the addition of NMs to cementitious materials results in a denser and improved microstructure with more hydration products. This paper provides valuable information and details about the rheology, mechanical properties, durability, 3D printing, and microstructural performance of cementitious materials with NMs and encourages further research.

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Extrusion Based 3D Printing of Sustainable Biocomposites from Biocarbon and Poly(trimethylene terephthalate)

Molecules ◽

10.3390/molecules26144164 ◽

2021 ◽

Vol 26 (14) ◽

pp. 4164

Author(s):

Elizabeth Diederichs ◽

Maisyn Picard ◽

Boon Peng Chang ◽

Manjusri Misra ◽

Amar Mohanty

Keyword(s):

Mechanical Properties ◽

3D Printing ◽

Surface Finish ◽

Three Dimensional ◽

Morphological Properties ◽

Great Promise ◽

Structural Components ◽

Computer Aided ◽

Trimethylene Terephthalate ◽

Optimal Quantity

Three-dimensional (3D) printing manufactures intricate computer aided designs without time and resource spent for mold creation. The rapid growth of this industry has led to its extensive use in the automotive, biomedical, and electrical industries. In this work, biobased poly(trimethylene terephthalate) (PTT) blends were combined with pyrolyzed biomass to create sustainable and novel printing materials. The Miscanthus biocarbon (BC), generated from pyrolysis at 650 °C, was combined with an optimized PTT blend at 5 and 10 wt % to generate filaments for extrusion 3D printing. Samples were printed and analyzed according to their thermal, mechanical, and morphological properties. Although there were no significant differences seen in the mechanical properties between the two BC composites, the optimal quantity of BC was 5 wt % based upon dimensional stability, ease of printing, and surface finish. These printable materials show great promise for implementation into customizable, non-structural components in the electrical and automotive industries.

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Exceptional Mechanical Properties and Heat Resistance of Photocurable Bismaleimide Ink for 3D Printing

Materials ◽

10.3390/ma14071708 ◽

2021 ◽

Vol 14 (7) ◽

pp. 1708

Author(s):

Wenqiang Hua ◽

Qilang Lin ◽

Bo Qu ◽

Yanyu Zheng ◽

Xiaoying Liu ◽

...

Keyword(s):

Mechanical Properties ◽

3D Printing ◽

Heat Resistance ◽

Three Dimensional ◽

Mechanical And Thermal Properties ◽

Amino Group ◽

Building Models ◽

Fast Processing ◽

Forming Precision ◽

Complex Structural

Photosensitive resins used in three-dimensional (3D) printing are characterized by high forming precision and fast processing speed; however, they often possess poor mechanical properties and heat resistance. In this study, we report a photocurable bismaleimide ink with excellent comprehensive performance for stereolithography (SLA) 3D printing. First, the main chain of bismaleimide with an amino group (BDM) was synthesized, and then, the glycidyl methacrylate was grafted to the amino group to obtain the bismaleimide oligomer with an unsaturated double bond. The oligomers were combined with reaction diluents and photo-initiators to form photocurable inks that can be used for SLA 3D printing. The viscosity and curing behavior of the inks were studied, and the mechanical properties and heat resistance were tested. The tensile strength of 3D-printed samples based on BDM inks could reach 72.6 MPa (166% of that of commercial inks), glass transition temperature could reach 155 °C (205% of that of commercial inks), and energy storage modulus was 3625 MPa at 35 °C (327% of that of commercial inks). The maximum values of T-5%, T-50%, and Tmax of the 3D samples printed by BDM inks reached 351.5, 449.6, and 451.9 °C, respectively. These photocured BDM inks can be used to produce complex structural components and models with excellent mechanical and thermal properties, such as car parts, building models, and pipes.

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Synthesis and properties of modified PBT for FDM

Rapid Prototyping Journal ◽

10.1108/rpj-12-2015-0197 ◽

2017 ◽

Vol 23 (4) ◽

pp. 804-810 ◽

Cited By ~ 2

Author(s):

Shiqing Cao ◽

Dandan Yu ◽

Weilan Xue ◽

Zuoxiang Zeng ◽

Wanyu Zhu

Keyword(s):

Mechanical Properties ◽

Impact Strength ◽

Fused Deposition Modeling ◽

Complex Structure ◽

Three Dimensional ◽

Sebacic Acid ◽

Wire Drawing ◽

Content Type ◽

Fused Deposition ◽

Deposition Modeling

Purpose The purpose of this paper is to prepare a new modified polybutylene terephalate (MPBT) for fused deposition modeling (FDM) to increase the variety of materials compatible with printing. And the printing materials can be used to print components with a complex structure and functional mechanical parts. Design/methodology/approach The MPBT, poly(butylene terephalate-co-isophthalate-co-sebacate) (PBTIS), was prepared for FDM by direct esterification and subsequent polycondensation using terephthalic acid (PTA), isophthalic acid (PIA), sebacic acid (SA) and 1,4-butanediol (BDO). The effects of the content of PIA (20-40 mol%) on the mechanical properties of PBTIS were investigated when the mole per cent of SA (αSA) is zero. The effects of αSA (0-7mol%) on the thermal, rheological and mechanical properties of PBTIS were investigated at nPTA/nPIA = 7/3. A desktop wire drawing and extruding machine was used to fabricate the filaments, whose printability and anisotropy were tested by three-dimensional (3D) printing experiments. Findings A candidate content of PIA introducing into PBT was obtained to be about 30 per cent, and the Izod notched impact strength of PBTIS increased with the increase of αSA. The results showed that the PBTIS (nPTA/nPIA = 7/3, αSA = 3-5mol%) is suitable for FDM. Originality/value New printing materials with good Izod notched impact strength were obtained by introducing PIA and SA (nPTA/nPIA = 7/3, αSA = 3-5 mol%) into PBT and their anisotropy are better than that of ABS.

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Advances in 3D Printing for Tissue Engineering

Materials ◽

10.3390/ma14123149 ◽

2021 ◽

Vol 14 (12) ◽

pp. 3149

Author(s):

Angelika Zaszczyńska ◽

Maryla Moczulska-Heljak ◽

Arkadiusz Gradys ◽

Paweł Sajkiewicz

Keyword(s):

Tissue Engineering ◽

Additive Manufacturing ◽

3D Printing ◽

Complex Structure ◽

Three Dimensional ◽

Computer Assisted ◽

Scaffold Fabrication ◽

Manufacturing Techniques ◽

Printing Techniques ◽

State Of Art

Tissue engineering (TE) scaffolds have enormous significance for the possibility of regeneration of complex tissue structures or even whole organs. Three-dimensional (3D) printing techniques allow fabricating TE scaffolds, having an extremely complex structure, in a repeatable and precise manner. Moreover, they enable the easy application of computer-assisted methods to TE scaffold design. The latest additive manufacturing techniques open up opportunities not otherwise available. This study aimed to summarize the state-of-art field of 3D printing techniques in applications for tissue engineering with a focus on the latest advancements. The following topics are discussed: systematics of the available 3D printing techniques applied for TE scaffold fabrication; overview of 3D printable biomaterials and advancements in 3D-printing-assisted tissue engineering.

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