scholarly journals 4D Printing: A Review on Recent Progresses

Micromachines ◽  
2020 ◽  
Vol 11 (9) ◽  
pp. 796 ◽  
Author(s):  
Honghui Chu ◽  
Wenguang Yang ◽  
Lujing Sun ◽  
Shuxiang Cai ◽  
Rendi Yang ◽  
...  

Since the late 1980s, additive manufacturing (AM), commonly known as three-dimensional (3D) printing, has been gradually popularized. However, the microstructures fabricated using 3D printing is static. To overcome this challenge, four-dimensional (4D) printing which defined as fabricating a complex spontaneous structure that changes with time respond in an intended manner to external stimuli. 4D printing originates in 3D printing, but beyond 3D printing. Although 4D printing is mainly based on 3D printing and become an branch of additive manufacturing, the fabricated objects are no longer static and can be transformed into complex structures by changing the size, shape, property and functionality under external stimuli, which makes 3D printing alive. Herein, recent major progresses in 4D printing are reviewed, including AM technologies for 4D printing, stimulation method, materials and applications. In addition, the current challenges and future prospects of 4D printing were highlighted.

Author(s):  
Denesh Mohan ◽  
Mohd Shaiful Sajab

The materials for additive manufacturing (AM) technology have grown substantially over the last few years to fulfill industrial needs. Despite that, the use of bio-based composites for improved mechanical properties and biodegradation is still not fully explored. This limits the universal expansion of AM-fabricated products due to the incompatibility of the products made from petroleum-derived resources. The development of naturally-derived polymers for AM materials is promising with the increasing number of studies in recent years owing to their biodegradation and biocompatibility. Cellulose is the most abundant biopolymer that possesses many favorable properties to be incorporated into AM materials, which have been continuously focused on in recent years. This critical review discusses the development of AM technologies and materials, cellulose-based polymers, cellulose-based three-dimensional (3D) printing filaments, liquid deposition modeling of cellulose, and four-dimensional (4D) printing of cellulose-based materials. Cellulose-based AM material applications and the limitations with future developments are also reviewed.


2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Xiaoyu Zhao ◽  
Ye Zhao ◽  
Ming-De Li ◽  
Zhong’an Li ◽  
Haiyan Peng ◽  
...  

AbstractPhotopolymerization-based three-dimensional (3D) printing can enable customized manufacturing that is difficult to achieve through other traditional means. Nevertheless, it remains challenging to achieve efficient 3D printing due to the compromise between print speed and resolution. Herein, we report an efficient 3D printing approach based on the photooxidation of ketocoumarin that functions as the photosensitizer during photopolymerization, which can simultaneously deliver high print speed (5.1 cm h−1) and high print resolution (23 μm) on a common 3D printer. Mechanistically, the initiating radical and deethylated ketocoumarin are both generated upon visible light exposure, with the former giving rise to rapid photopolymerization and high print speed while the latter ensuring high print resolution by confining the light penetration. By comparison, the printed feature is hard to identify when the ketocoumarin encounters photoreduction due to the increased lateral photopolymerization. The proposed approach here provides a viable solution towards efficient additive manufacturing by controlling the photoreaction of photosensitizers during photopolymerization.


2020 ◽  
Vol 11 (46) ◽  
pp. 7316-7329
Author(s):  
Joël Monti ◽  
Eva Blasco

Herein, recent developments in the 3D printing of materials with structural hierarchy and their future prospects are reviewed. It is shown that increasing the extent of ordering, is essential to access novel properties and functionalities.


Materials ◽  
2021 ◽  
Vol 14 (12) ◽  
pp. 3149
Author(s):  
Angelika Zaszczyńska ◽  
Maryla Moczulska-Heljak ◽  
Arkadiusz Gradys ◽  
Paweł Sajkiewicz

Tissue engineering (TE) scaffolds have enormous significance for the possibility of regeneration of complex tissue structures or even whole organs. Three-dimensional (3D) printing techniques allow fabricating TE scaffolds, having an extremely complex structure, in a repeatable and precise manner. Moreover, they enable the easy application of computer-assisted methods to TE scaffold design. The latest additive manufacturing techniques open up opportunities not otherwise available. This study aimed to summarize the state-of-art field of 3D printing techniques in applications for tissue engineering with a focus on the latest advancements. The following topics are discussed: systematics of the available 3D printing techniques applied for TE scaffold fabrication; overview of 3D printable biomaterials and advancements in 3D-printing-assisted tissue engineering.


Author(s):  
Morteza Vatani ◽  
Faez Alkadi ◽  
Jae-Won Choi

A novel additive manufacturing algorithm was developed to increase the consistency of three-dimensional (3D) printed curvilinear or conformal patterns on freeform surfaces. The algorithm dynamically and locally compensates the nozzle location with respect to the pattern geometry, motion direction, and topology of the substrate to minimize lagging or leading during conformal printing. The printing algorithm was implemented in an existing 3D printing system that consists of an extrusion-based dispensing module and an XYZ-stage. A dispensing head is fixed on a Z-axis and moves vertically, while the substrate is installed on an XY-stage and moves in the x–y plane. The printing algorithm approximates the printed pattern using nonuniform rational B-spline (NURBS) curves translated directly from a 3D model. Results showed that the proposed printing algorithm increases the consistency in the width of the printed patterns. It is envisioned that the proposed algorithm can facilitate nonplanar 3D printing using common and commercially available Cartesian-type 3D printing systems.


2021 ◽  
Vol 2021 ◽  
pp. 1-20 ◽  
Author(s):  
Dhinakaran Veeman ◽  
M. Swapna Sai ◽  
P. Sureshkumar ◽  
T. Jagadeesha ◽  
L. Natrayan ◽  
...  

As a technique of producing fabric engineering scaffolds, three-dimensional (3D) printing has tremendous possibilities. 3D printing applications are restricted to a wide range of biomaterials in the field of regenerative medicine and tissue engineering. Due to their biocompatibility, bioactiveness, and biodegradability, biopolymers such as collagen, alginate, silk fibroin, chitosan, alginate, cellulose, and starch are used in a variety of fields, including the food, biomedical, regeneration, agriculture, packaging, and pharmaceutical industries. The benefits of producing 3D-printed scaffolds are many, including the capacity to produce complicated geometries, porosity, and multicell coculture and to take growth factors into account. In particular, the additional production of biopolymers offers new options to produce 3D structures and materials with specialised patterns and properties. In the realm of tissue engineering and regenerative medicine (TERM), important progress has been accomplished; now, several state-of-the-art techniques are used to produce porous scaffolds for organ or tissue regeneration to be suited for tissue technology. Natural biopolymeric materials are often better suited for designing and manufacturing healing equipment than temporary implants and tissue regeneration materials owing to its appropriate properties and biocompatibility. The review focuses on the additive manufacturing of biopolymers with significant changes, advancements, trends, and developments in regenerative medicine and tissue engineering with potential applications.


Materials ◽  
2020 ◽  
Vol 13 (20) ◽  
pp. 4534 ◽  
Author(s):  
Elżbieta Bogdan ◽  
Piotr Michorczyk

This paper describes the process of additive manufacturing and a selection of three-dimensional (3D) printing methods which have applications in chemical synthesis, specifically for the production of monolithic catalysts. A review was conducted on reference literature for 3D printing applications in the field of catalysis. It was proven that 3D printing is a promising production method for catalysts.


Science ◽  
2019 ◽  
Vol 366 (6461) ◽  
pp. 105-109 ◽  
Author(s):  
Sourabh K. Saha ◽  
Dien Wang ◽  
Vu H. Nguyen ◽  
Yina Chang ◽  
James S. Oakdale ◽  
...  

High-throughput fabrication techniques for generating arbitrarily complex three-dimensional structures with nanoscale features are desirable across a broad range of applications. Two-photon lithography (TPL)–based submicrometer additive manufacturing is a promising candidate to fill this gap. However, the serial point-by-point writing scheme of TPL is too slow for many applications. Attempts at parallelization either do not have submicrometer resolution or cannot pattern complex structures. We overcome these difficulties by spatially and temporally focusing an ultrafast laser to implement a projection-based layer-by-layer parallelization. This increases the throughput up to three orders of magnitude and expands the geometric design space. We demonstrate this by printing, within single-digit millisecond time scales, nanowires with widths smaller than 175 nanometers over an area one million times larger than the cross-sectional area.


Polymers ◽  
2020 ◽  
Vol 12 (12) ◽  
pp. 2900
Author(s):  
Alyaa Mohammed ◽  
Nihad Tareq Khshain Al-Saadi

One of the considerable challenges in the design of cementitious mixtures for additive manufacturing/three-dimensional (3D) printing applications is achieving both suitable fresh properties and significant mechanical strengths. This paper presents the use of graphene oxide (GO) as a promising nano reinforcement material with the potential to improve the printing feasibility and quality of a 3D printed cementitious matrix. Additionally, in this study, a viscosity modifying agent (VMA) was employed as a chemical additive to attain the required consistency and flow. The printed mixture was fabricated using various cementitious materials and waste materials. This study investigated the impact of GO and VMA on the enhancement of the 3D printing of cementitious composites through several tests. A flow test was conducted using the flow table test. The results showed a high fluidity and practical consistency, which are essential for nozzle pumping and accurateness in printed shapes. Furthermore, the bleeding test showed minimal bleeding up to hardening, and a considerable self-cleaning ability was noted during handling when conducting examinations of fresh properties. For hardened properties, the mechanical strengths were exceptionally high, especially at early ages, which is crucial for the stability of sequence layers of printed composites. The tensile strengths were 3.77, 10.5, 13.35, and 18.83 MPa at 1, 3, 7, and 28 days, respectively, and the compressive strengths were 25.1, 68.4, 85.6, and 125.4 MPa at 1, 3, 7, and 28 days, respectively. The test results showed the effectiveness of the fabricated cementitious mixture design method for meeting the requirements for 3D concrete printing applications.


2021 ◽  
Vol 11 (18) ◽  
pp. 8545
Author(s):  
So-Ree Hwang ◽  
Min-Soo Park

Additive manufacturing, commonly called 3D printing, has been studied extensively because it can be used to fabricate complex structures; however, polymer-based 3D printing has limitations in terms of implementing certain functionalities, so it is limited in the production of conceptual prototypes. As such, polymer-based composites and multi-material 3D printing are being studied as alternatives. In this study, a DLP 3D printer capable of printing multiple composite materials was fabricated using a movable separator and structures with various properties were fabricated by selectively printing two composite materials. After the specimen was fabricated based on the ASTM, the basic mechanical properties of the structure were compared through a 3-point bending test and a ball rebound test. Through this, it was shown that structures with various mechanical properties can be fabricated using the proposed movable-separator-based DLP process. In addition, it was shown that this process can be used to fabricate anisotropic structures, whose properties vary depending on the direction of the force applied to the structure. By fabricating multi-joint grippers with varying levels of flexibility, it was shown that the proposed process can be applied in the fabrication of soft robots as well.


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