scholarly journals Exceptional Mechanical Properties and Heat Resistance of Photocurable Bismaleimide Ink for 3D Printing

Materials ◽  
2021 ◽  
Vol 14 (7) ◽  
pp. 1708
Author(s):  
Wenqiang Hua ◽  
Qilang Lin ◽  
Bo Qu ◽  
Yanyu Zheng ◽  
Xiaoying Liu ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
3D Printing ◽  
Heat Resistance ◽  
Three Dimensional ◽  
Mechanical And Thermal Properties ◽  
Amino Group ◽  
Building Models ◽  
Fast Processing ◽  
Forming Precision ◽  
Complex Structural

Photosensitive resins used in three-dimensional (3D) printing are characterized by high forming precision and fast processing speed; however, they often possess poor mechanical properties and heat resistance. In this study, we report a photocurable bismaleimide ink with excellent comprehensive performance for stereolithography (SLA) 3D printing. First, the main chain of bismaleimide with an amino group (BDM) was synthesized, and then, the glycidyl methacrylate was grafted to the amino group to obtain the bismaleimide oligomer with an unsaturated double bond. The oligomers were combined with reaction diluents and photo-initiators to form photocurable inks that can be used for SLA 3D printing. The viscosity and curing behavior of the inks were studied, and the mechanical properties and heat resistance were tested. The tensile strength of 3D-printed samples based on BDM inks could reach 72.6 MPa (166% of that of commercial inks), glass transition temperature could reach 155 °C (205% of that of commercial inks), and energy storage modulus was 3625 MPa at 35 °C (327% of that of commercial inks). The maximum values of T-5%, T-50%, and Tmax of the 3D samples printed by BDM inks reached 351.5, 449.6, and 451.9 °C, respectively. These photocured BDM inks can be used to produce complex structural components and models with excellent mechanical and thermal properties, such as car parts, building models, and pipes.

scholarly journals An Overview on the Rheology, Mechanical Properties, Durability, 3D Printing, and Microstructural Performance of Nanomaterials in Cementitious Composites

Materials ◽  
2021 ◽  
Vol 14 (11) ◽  
pp. 2950
Author(s):  
Hongwei Song ◽  
Xinle Li
Keyword(s):  
Mechanical Properties ◽  
3D Printing ◽  
Three Dimensional ◽  
Cementitious Materials ◽  
Research Area ◽  
Cementitious Composites ◽  
Split Tensile Strength ◽  
Contour Crafting ◽  
Wide Range ◽  
Active Research

The most active research area is nanotechnology in cementitious composites, which has a wide range of applications and has achieved popularity over the last three decades. Nanoparticles (NPs) have emerged as possible materials to be used in the field of civil engineering. Previous research has concentrated on evaluating the effect of different NPs in cementitious materials to alter material characteristics. In order to provide a broad understanding of how nanomaterials (NMs) can be used, this paper critically evaluates previous research on the influence of rheology, mechanical properties, durability, 3D printing, and microstructural performance on cementitious materials. The flow properties of fresh cementitious composites can be measured using rheology and slump. Mechanical properties such as compressive, flexural, and split tensile strength reveal hardened properties. The necessary tests for determining a NM’s durability in concrete are shrinkage, pore structure and porosity, and permeability. The advent of modern 3D printing technologies is suitable for structural printing, such as contour crafting and binder jetting. Three-dimensional (3D) printing has opened up new avenues for the building and construction industry to become more digital. Regardless of the material science, a range of problems must be tackled, including developing smart cementitious composites suitable for 3D structural printing. According to the scanning electron microscopy results, the addition of NMs to cementitious materials results in a denser and improved microstructure with more hydration products. This paper provides valuable information and details about the rheology, mechanical properties, durability, 3D printing, and microstructural performance of cementitious materials with NMs and encourages further research.

scholarly journals Extrusion Based 3D Printing of Sustainable Biocomposites from Biocarbon and Poly(trimethylene terephthalate)

Molecules ◽  
2021 ◽  
Vol 26 (14) ◽  
pp. 4164
Author(s):  
Elizabeth Diederichs ◽  
Maisyn Picard ◽  
Boon Peng Chang ◽  
Manjusri Misra ◽  
Amar Mohanty
Keyword(s):  
Mechanical Properties ◽  
3D Printing ◽  
Surface Finish ◽  
Three Dimensional ◽  
Morphological Properties ◽  
Great Promise ◽  
Structural Components ◽  
Computer Aided ◽  
Trimethylene Terephthalate ◽  
Optimal Quantity

Three-dimensional (3D) printing manufactures intricate computer aided designs without time and resource spent for mold creation. The rapid growth of this industry has led to its extensive use in the automotive, biomedical, and electrical industries. In this work, biobased poly(trimethylene terephthalate) (PTT) blends were combined with pyrolyzed biomass to create sustainable and novel printing materials. The Miscanthus biocarbon (BC), generated from pyrolysis at 650 °C, was combined with an optimized PTT blend at 5 and 10 wt % to generate filaments for extrusion 3D printing. Samples were printed and analyzed according to their thermal, mechanical, and morphological properties. Although there were no significant differences seen in the mechanical properties between the two BC composites, the optimal quantity of BC was 5 wt % based upon dimensional stability, ease of printing, and surface finish. These printable materials show great promise for implementation into customizable, non-structural components in the electrical and automotive industries.

scholarly journals Effect of Selected Commercial Plasticizers on Mechanical, Thermal, and Morphological Properties of Poly(3-hydroxybutyrate)/Poly(lactic acid)/Plasticizer Biodegradable Blends for Three-Dimensional (3D) Print

Materials ◽  
2018 ◽  
Vol 11 (10) ◽  
pp. 1893 ◽  
Author(s):  
Přemysl Menčík ◽  
Radek Přikryl ◽  
Ivana Stehnová ◽  
Veronika Melčová ◽  
Soňa Kontárová ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Lactic Acid ◽  
Thermal Properties ◽  
Three Dimensional ◽  
Poly Lactic Acid ◽  
Mechanical And Thermal Properties ◽  
Modulated Differential Scanning Calorimetry ◽  
3D Print ◽  
3D Printed ◽  
Biodegradable Blends

This paper explores the influence of selected commercial plasticizers structure, which are based on esters of citric acid, on mechanical and thermal properties of Poly(3-hydroxybutyrate)/Poly(lactic acid)/Plasticizer biodegradable blends. These plasticizers were first tested with respect to their miscibility with Poly(3-hydroxybutyrate)/Poly(lactic acid) (PHB/PLA) blends using a kneading machine. PHB/PLA/plasticizer blends in the weight ratio (wt %) of 60/25/15 were then prepared by single screw and corotating meshing twin screw extruders in the form of filament for further three-dimensional (3D) printing. Mechanical, thermal properties, and shape stability (warping effect) of 3D printed products can be improved just by the addition of appropriate plasticizer to polymeric blend. The goal was to create new types of eco-friendly PHB/PLA/plasticizers blends and to highly improve the poor mechanical properties of neat PHB/PLA blends (with majority of PHB) by adding appropriate plasticizer. Mechanical properties of plasticized blends were then determined by the tensile test of 3D printed test samples (dogbones), as well as filaments. Measured elongation at break rapidly enhanced from 21% for neat non-plasticized PHB/PLA blends (reference) to 328% for best plasticized blends in the form of filament, and from 5% (reference) to 187% for plasticized blends in the form of printed dogbones. The plasticizing effect on blends was confirmed by Modulated Differential Scanning Calorimetry. The study of morphology was performed by the Scanning Electron Microscopy. Significant problem of plasticized blends used to be also plasticizer migration, therefore the diffusion of plasticizers from the blends after 15 days of exposition to 110 °C in the drying oven was investigated as their measured weight loss. Almost all of the used plasticizers showed meaningful positive softening effects, but the diffusion of plasticizers at 110 °C exposition was quite extensive. The determination of the degree of disintegration of selected plasticized blend when exposed to a laboratory-scale composting environment was executed to roughly check the “biodegradability”.

scholarly journals Parameters Affecting the Mechanical Properties of Three-Dimensional (3D) Printed Carbon Fiber-Reinforced Polylactide Composites

Polymers ◽  
2020 ◽  
Vol 12 (11) ◽  
pp. 2456
Author(s):  
Demei Lee ◽  
Guan-Yu Wu
Keyword(s):  
Mechanical Properties ◽  
Carbon Fiber ◽  
3D Printing ◽  
Three Dimensional ◽  
Fused Deposition Modelling ◽  
Layer By Layer ◽  
Fused Deposition ◽  
Bed Temperature ◽  
3D Printed ◽  
The Impact

Three-dimensional (3D) printing is a manufacturing technology which creates three-dimensional objects layer-by-layer or drop-by-drop with minimal material waste. Despite the fact that 3D printing is a versatile and adaptable process and has advantages in establishing complex and net-shaped structures over conventional manufacturing methods, the challenge remains in identifying the optimal parameters for the 3D printing process. This study investigated the influence of processing parameters on the mechanical properties of Fused Deposition Modelling (FDM)-printed carbon fiber-filled polylactide (CFR-PLA) composites by employing an orthogonal array model. After printing, the tensile and impact strengths of the printed composites were measured, and the effects of different parameters on these strengths were examined. The experimental results indicate that 3D-printed CFR-PLA showed a rougher surface morphology than virgin PLA. For the variables selected in this analysis, bed temperature was identified as the most influential parameter on the tensile strength of CFR-PLA-printed parts, while bed temperature and print orientation were the key parameters affecting the impact strengths of printed composites. The 45° orientation printed parts also showed superior mechanical strengths than the 90° printed parts.

scholarly journals Mechanical and Thermal Properties of Polyurethane Materials and Inflated Insulation Chambers

Materials ◽  
2021 ◽  
Vol 14 (6) ◽  
pp. 1541
Author(s):  
Goran Čubrić ◽  
Ivana Salopek Čubrić ◽  
Dubravko Rogale ◽  
Snježana Firšt Rogale
Keyword(s):  
Mechanical Properties ◽  
Thermal Properties ◽  
Heat Resistance ◽  
Winter Season ◽  
Thermal Characteristics ◽  
Football Players ◽  
Mechanical And Thermal Properties ◽  
Cold Environment ◽  
Target Groups ◽  
Intelligent Clothing

Evaluating mechanical and thermal characteristics of garment systems or their segments is important in an attempt to provide optimal or at least satisfying levels of comfort and safety, especially in the cold environment. The target groups of users may be athletes engaged in typical sports that are trained in the cold, as well as football players that play matches and train outdoors during the winter season. Previous studies indicated an option to substitute the inner layers of an intelligent garment with polyurethane inflated chambers (PIC) to increase and regulate thermal insulation. In this paper, the authors investigate the mechanical properties of polyurethane material with and without ultrasonic joints. Furthermore, they investigate the potential of designed PICs in terms of efficiency and interdependence of air pressure and heat resistance. The results indicated that an inflated PIC with four diagonal ultrasonic joints has the highest ability to maintain the optimal thermal properties of an intelligent clothing system. The influence of direction and number of ultrasonic joints on the mechanical properties of polyurethane material is confirmed, especially in terms of compression resilience and tensile energy.

scholarly journals Intact Fibrillated 3D-Printed Cellulose Macrofibrils/CaCO3 for Controlled Drug Delivery

Polymers ◽  
2021 ◽  
Vol 13 (12) ◽  
pp. 1912
Author(s):  
Denesh Mohan ◽  
Zee Khai Teong ◽  
Mohd Shaiful Sajab ◽  
Nur Hidayatul Nazirah Kamarudin ◽  
Hatika Kaco
Keyword(s):  
Mechanical Properties ◽  
3D Printing ◽  
Three Dimensional ◽  
Volumetric Flow Rate ◽  
Homogeneous Distribution ◽  
Therapeutic Drug ◽  
Burst Release ◽  
Drug Release Profile ◽  
Precipitated Calcium Carbonate ◽  
Cellulose Fibrils

The tendency to use cellulose fibrils for direct ink writing (DIW) of three-dimensional (3D) printing has been growing extensively due to their advantageous mechanical properties. However, retaining cellulose in its fibrillated forms after the printing process has always been a challenge. In this study, cellulose macrofibrils (CMFs) from oil palm empty fruit bunch (OPEFB) fibers were partially dissolved for consistent viscosity needed for DIW 3D printing. The printed CMF structure obtained from optimized printing profiles (volumetric flow rate, Qv = 9.58 mm/s; print speed, v = 20 mm/s), exhibited excellent mechanical properties (tensile strength of 66 MPa, Young’s modulus of 2.16 GPa, and elongation of 8.76%). The remarkable structural and morphological effects of the intact cellulose fibrils show a homogeneous distribution with synthesized precipitated calcium carbonate (CaCO3) nanoparticles. The shear-aligned CMF/CaCO3 printed composite exhibited a sustained therapeutic drug release profile that can reduce rapid release that has adverse effects on healthy cells. In comparison with the initial burst release of 5-fluorouracil (5-FU) by CaCO3, the controlled release of 5-fluorouracil can be varied (48 to 75%) with the composition of CMF/CaCO3 allowing efficient release over time.

A novel 3D-printable hydrogel with high mechanical strength and shape memory properties

2019 ◽  
Vol 7 (47) ◽  
pp. 14913-14922 ◽  
Author(s):  
Qiang Zhou ◽  
Kaixiang Yang ◽  
Jiaqing He ◽  
Haiyang Yang ◽  
Xingyuan Zhang
Keyword(s):  
Mechanical Properties ◽  
3D Printing ◽  
Mechanical Strength ◽  
Shape Memory ◽  
Three Dimensional ◽  
High Mechanical Strength ◽  
Shape Memory Properties ◽  
Potential Applications

The three-dimensional (3D)-printing of hydrogels with excellent mechanical properties has attracted extensive attention owing to their potential applications in many fields.

Printability assessment of psyllium husk (isabgol)/gelatin blends using rheological and mechanical properties

2020 ◽  
pp. 088532822097947
Author(s):  
Piyush Sunil Agarwal ◽  
Suruchi Poddar ◽  
Neelima Varshney ◽  
Ajay Kumar Sahi ◽  
Kiran Yellappa Vajanthri ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
3D Printing ◽  
Storage Modulus ◽  
Loss Tangent ◽  
Loss Modulus ◽  
Three Dimensional ◽  
Elastic Behavior ◽  
Flow Index ◽  
Plastic Behavior ◽  
Psyllium Husk

The primary goal of this study is to highlight the rheological and mechanical properties of a new blend composed of naturally-derived hydrogel materials- psyllium husk (PH) and gelatin (G) for its potential use in three-dimensional (3D) printing technology. The mixtures were prepared at various weight ratios of 100PH, 75PH + 25G and 50PH + 50G. A suitable selection of the printable ink was made based on the preliminary screening steps of manual filament drop test and layer stacking by 3D printing. Printing of the common features such as hexagon and square grids helped evaluating shape fidelity of the chosen ink. Although 50PH + 50G blend was found meeting most of the criteria for an ideal 3D printable ink, rheological and mechanical characterizations have been performed for all the ratios of polymeric blends. This study documents the correlation between various factors of rheology that should be taken into account while categorizing any biomaterial as a printable ink. Yield stress was measured as 18.59 ± 4.21 Pa, 268.74 ± 13.56 Pa and 109.16 ± 9.85 Pa for 50PH + 50G, 75PH + 25G and 100PH, respectively. Similarly, consistency index (K) and flow index (n) were calculated using the power law equation and found as 49.303 ± 4.17, 530.59 ± 10.92, 291.82 ± 10.53 and 0.275 ± 0.04, 0.05 ± 0.005, 0.284 ± 0.04 for 50PH + 50G, 75PH + 25G and 100PH, respectively. The loss modulus (G″) was observed dominating over storage modulus (G′) for 50PH + 50G, that depicts its liquid-like property; whereas storage modulus (G′) was found dominating in case of 75PH + 25G and 100PH, indicating their solid-like characteristics. In addition, the loss tangent value (tan δ) of 50PH + 50G was observed exceeding unity (1.05), supporting its plastic behavior, unlike 75PH + 25G (0.5) and 100PH (0.33) whose loss tangent values were estimated less than unity revealing their elastic behavior. Also, 50PH + 50G was found to have the highest mechanical strength amongst the three blends with a Young’s modulus of 9.170 ± 0.0881 kPa.

Fabrication, characterization, and application of polyester/wood flour composites

2017 ◽  
Vol 37 (7) ◽  
pp. 689-698 ◽  
Author(s):  
Chin-San Wu ◽  
Hsin-Tzu Liao
Keyword(s):  
Mechanical Properties ◽  
Antibacterial Activity ◽  
Thermal Properties ◽  
Composite Materials ◽  
3D Printing ◽  
Maleic Anhydride ◽  
Water Resistance ◽  
Wood Flour ◽  
Three Dimensional ◽  
Ester Formation

Abstract The mechanical properties, thermal properties, antibacterial activity, and fabrication of three-dimensional (3D) printing strips of composite materials containing polyhydroxyalkanoate (PHA) and wood flour (WF) were evaluated. Maleic anhydride (MA)-grafted PHA (PHA-g-MA) and WF were used to enhance the desired characteristics of these composites. The PHA-g-MA/WF composites had better mechanical properties than the PHA/WF composites did. This effect was attributed to a greater compatibility between the grafted polyester and WF. Additionally, the PHA-g-MA/WF composites provided higher quality 3D printing strips and were more easily processed because of ester formation. The water resistance of the PHA-g-MA/WF composite was greater than that of PHA/WF. Moreover, WF enhanced the antibacterial activity of the composites. Composites of PHA-g-MA or PHA containing WF had better antibacterial activity.

scholarly journals The Effect of Modification on the Properties of Polyetherimide and Its Carbon-Filled Composite

Polymers ◽  
2020 ◽  
Vol 12 (5) ◽  
pp. 1056
Author(s):  
Azamat Slonov ◽  
Ismel Musov ◽  
Azamat Zhansitov ◽  
Elena Rzhevskaya ◽  
Diana Khakulova ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Thermal Properties ◽  
Heat Resistance ◽  
Mechanical And Thermal Properties ◽  
Melt Viscosity ◽  
Deposit Modeling ◽  
High Level ◽  
Filled Composite

The effect of oligophenylene sulfone (OPSU) and polycarbonate (PC) on the rheological, mechanical and thermal properties of polyetherimide (PEI) and a carbon-filled composite based on it was studied. It is shown that the introduction of OPSU and PC leads to a decrease in the melt viscosity of PEI and a carbon-filled composite based on it with the preservation of their mechanical properties and heat resistance at a sufficiently high level. It was found that composites with OPSU have higher mechanical and thermal properties compared with composites with PC. Samples from modified carbon-filled PEI were printed by the fused deposit modeling (FDM) method. Three-dimensionally printed samples from carbon-filled PEI modified by OPSU showed significantly higher mechanical properties than composites with PC.

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