scholarly journals Physical-Chemical Effects of Nanoparticles on Electropolymerized Polyaniline

2021 ◽  
Vol 12 (5) ◽  
pp. 5996-6009
Keyword(s):  
Tio2 Nanoparticles ◽  
Polymer Films ◽  
Au Nanoparticles ◽  
Chemical Properties ◽  
Chemical Effects ◽  
Physical Chemical ◽  
Polyaniline Films ◽  
Physical And Chemical ◽  
Chemical Influence ◽  
And Chemical Properties

The incorporation of nanoparticles on polymer films is possible to obtain materials with desired properties. In the present work, we address the physical-chemical influence of nanoparticles in polymer films by producing and characterizing polyaniline hybrids with SiO2 and Au nanoparticles and comparing them with films with TiO2 nanoparticles. The hybrid films were characterized by SEM, EDS, UV-Vis, AFM, Raman, and cyclic voltammetry. Unlike TiO2 nanoparticles, SiO2 and Au nanoparticles do not promote any noticeable change in polyaniline oxidation state in less acid environments (pH 5.9 and 6.15). However, in those environments, the presence of nanoparticles significantly increases the film's conductivity. At a pH of 1.5 and 3.9, all three kinds of nanoparticles are screened by ions from the solution diminishing their physical-chemical effects on polyaniline. Thus, our results suggest that, in general, nanoparticles don't have any physical-chemical effects on polyaniline films when deposited in acid enough environments but can change their physical and chemical properties when deposited in less acid environments.

scholarly journals [NO TITLE AVAILABLE]

2012 ◽  
Vol 32 (3) ◽  
pp. 621-628
Author(s):  
Grazielle Gebrim Santos ◽  
Mara Reis Silva
Keyword(s):  
Chemical Properties ◽  
Ice Cream ◽  
Physical And Chemical Properties ◽  
Low Fat ◽  
Fat Replacers ◽  
Sugar Substitutes ◽  
Physical Chemical ◽  
Physical And Chemical ◽  
Microbiological Analyses ◽  
And Chemical Properties

The effect of replacing shortening and sugar on the physical and chemical properties of mangaba ice cream and its acceptability were evaluated. Ice cream formulations were tested with the following fat replacers: Selecta Light, Litesse, and Dairy Lo and the following sugar substitutes: Lactitol and Splenda. All formulations were subjected to physical, chemical, and microbiological analyses and evaluated by acceptability tests. In the sensory analysis, it was observed a larger acceptance of the formulations containing Selecta Light (SL) and the combination of Litesse, Lactiol, and Splenda (LLS). The largest reduction in total energetic value (50%) was observed in the formulation LLS. The use of fat and/or sugar substitutes caused a reduction in the air incorporation (overrun) and affected viscosity. The highest melting speed was observed in the formulation with Dairy-Lo, Lactitol, and Splenda. All formulations showed good levels of global acceptability and appearance. The substitution of shortening for fat replacers caused a reduction in air incorporation and changes in ice-cream viscosity. The low-fat mangaba ice-cream elaborated with Selecta Light was the best formulation in terms of viscosity and air incorporation when compared with the control. It also showed a good level of acceptability and low fat content.

scholarly journals PRODUÇÃO E CARACTERIZAÇÃO DE BIOCARVÃO A PARTIR DE BIOSSÓLIDOS ARMAZENADOS EM BAG’s GEOTÊXTEIS NO MUNICÍPIO DE RANCHARIA -SP

2019 ◽  
Vol 11 (4) ◽  
pp. 142-155
Author(s):  
Beatriz Regina de Ângelo ◽  
Rafaela Pelegrini Vital ◽  
Marcelo Rodrigo Alves ◽  
Jaqueline Oliveira da Silva ◽  
Melissa Arantes Pinto ◽  
...  
Keyword(s):  
Organic Matter ◽  
Sewage Sludge ◽  
Chemical Properties ◽  
Physical And Chemical Properties ◽  
Pyrolysis Process ◽  
Physical Chemical ◽  
Physical And Chemical ◽  
Stable Material ◽  
And Chemical Properties

Sewage sludge refers to a nutrient-rich by-product and organic matter from treatment plants and has become a challenge for many research segments to find a rational and sustainable destination for this material. In this context, the carbonization of biomass (by the pyrolysis process) results in biochar, characterized by a very stable material with specific physical and chemical properties and can represent a very important tool for this challenge. Thus, the objective of the present work was to transform, bypyrolysis process, small portions of the biosolid generated in Rancharia ETE into biochar. In addition, both the biosolid and the generated bicarbons were subjected to physical, chemical and structural analyzes in order to proceed with their respective characterization. From the analysis, it was found that the treatment submitted to temperature of 550°C as the best option for possible applications.Keywords:biosolid; pyrolysis; biochar.

The Physical and Chemical Properties Changes of Broth during Phellinus fermentation

2013 ◽  
Vol 295-298 ◽  
pp. 279-282
Author(s):  
Zi Ping Zhu ◽  
Jian Zhong Chen ◽  
Bei Bei Lv ◽  
Xue Ming Tang
Keyword(s):  
Fermentation Process ◽  
Chemical Properties ◽  
Physical And Chemical Properties ◽  
Soluble Protein Content ◽  
Physical Chemical ◽  
Initial Stage ◽  
Increasing Trend ◽  
Physical And Chemical ◽  
And Chemical Properties ◽  
Variation Tendency

The physical and chemical properties changes of broth in the fermentation process of Phellinus and its mutant strain were studied. The results showed that the mycelia yield of the two strains of Phellinus increased rapidly in the first 6 days and increased slowly 6 days later, the soluble protein content of broth took on an increasing trend, up to 0.15 mg/mL and 0.13 mg/mL respectively, the variation tendency of the content of polysaccharide and viscosities of broth were semblable, that was declined in the initial stage of fermentation and change little in later stage. The physical, chemical properties and viscosities show similarity in both two strains’ broth, therefore, the physical and chemical properties of broth in the fermentation process of Phellinus changed regularly.

scholarly journals Mechanical properties of plasma polymer films: a review

2021 ◽  
Vol 3 (6) ◽  
Author(s):  
Jamerson Carneiro de Oliveira ◽  
Aissam Airoudj ◽  
Philippe Kunemann ◽  
Florence Bally-Le Gall ◽  
Vincent Roucoules
Keyword(s):  
Mechanical Properties ◽  
Polymer Films ◽  
Chemical Properties ◽  
Plasma Polymer ◽  
List Type ◽  
Physical And Chemical Properties ◽  
Plasma Polymers ◽  
Physical And Chemical ◽  
And Chemical Properties

Abstract Plasma polymers are micro-, or more commonly, nano-sized coatings that can be deposited on a variety of substrates through different approaches. The versatility of these polymers is incremented by the possibility to use other precursors than conventional polymerization reactions and by potential changes in the polymerization mechanisms according to the intrinsic physical and chemical properties of the plasma. That flexibility offers a fruitful ground to a great range of scientific and engineering fields, but it also brings many challenges for universalization of empirical observations. In this review, the use of different precursors, substrates and changes in plasma external parameters were evaluated as common, but not necessarily ideal nor exhaustive, variables for the analysis of mechanical properties of plasma polymer films. The commonly reported trends are complemented with the exceptions, and a variety of hypothesis drawn by the empirical observations are shown. The techniques and methods used for determining the mechanical properties of plasma polymers, the effect of post-treatments on them and some applications are evaluated. Finally, a general conclusion highlighting the challenges of the field is provided. Article highlights The mechanical properties of plasma polymers are evaluated as a function of selected parameters. The techniques of characterization of mechanical properties of plasma polymers are summarized. A discussion of future and current demands for the analysis of mechanical properties of plasma polymers is done.

Shape transformation of self-assembled Au nanoparticles by the systematic control of deposition amount on sapphire (0001)

RSC Advances ◽  
2015 ◽  
Vol 5 (81) ◽  
pp. 66212-66220 ◽  
Author(s):  
Puran Pandey ◽  
Mao Sui ◽  
Ming-Yu Li ◽  
Quanzhen Zhang ◽  
Eun-Soo Kim ◽  
...  
Keyword(s):  
Au Nanoparticles ◽  
Chemical Properties ◽  
Shape Transformation ◽  
Au Nps ◽  
Size Dependent ◽  
Deposition Amount ◽  
Significant Research ◽  
Physical And Chemical ◽  
Systematic Control ◽  
And Chemical Properties

The shape and size dependent optical, physical and chemical properties of isotropic and anisotropic gold nanoparticles (Au NPs) have attracted significant research interest for their application in various optoelectronic devices.

Influence of residual solvent on physical and chemical properties of amorphous glassy polymer films

2013 ◽  
Vol 62 (11) ◽  
pp. 1566-1574 ◽  
Author(s):  
Julia Kostina ◽  
Galina Bondarenko ◽  
Maria Gringolts ◽  
Alexander Rodionov ◽  
Olga Rusakova ◽  
...  
Keyword(s):  
Polymer Films ◽  
Glassy Polymer ◽  
Chemical Properties ◽  
Physical And Chemical Properties ◽  
Residual Solvent ◽  
Physical And Chemical ◽  
And Chemical Properties

scholarly journals Determining the Physical and Chemical Properties of the Soils in Babylon and Al-Qadisiyyah for Manufacturing Clay Bricks

2021 ◽  
Vol 54 (2C) ◽  
pp. 100-116
Author(s):  
Muhsen O. Khalaf
Keyword(s):  
Chemical Properties ◽  
Strength Properties ◽  
Liquid Limit ◽  
Grain Size Analysis ◽  
Size Analysis ◽  
Suitable Material ◽  
Clay Bricks ◽  
Physical Chemical ◽  
Physical And Chemical ◽  
And Chemical Properties

The research included conducting a study of eight selected soil Stations in the Babylon and Al Qadisiyyah. The main target of the research is to study the physical, chemical, and compressive strength properties of these soils and their suitability for manufacturing ordinary clay bricks. It was found through the evaluation of the soils of the studied samples that their physical properties ranged as follows: the water content (13.52-31.88%) and the grain size analysis of the proportions of sand, silt, and clay as follows: (5-27%) (38-48%) (33-47%), respectively. The values of the Atterberg limits ranged as follows: the plastic limit ratios (13-21%), liquid limit (34-49%), plasticity index (13-28%), and the specific gravity ranged between (2.43-2.67). As for the chemical properties of the studied samples, they consist of a lot of silicates, carbonate calcium, and calcium oxide. Studied samples were characterized by water absorption 15-24%, and the efflorescence is varied from medium, low to nil. The soil samples are consequently considered as a suitable material for the manufacture of ordinary bricks in grades A and B based on Iraqi Standard specifications No. 25.

Study of Corrosion-Electrochemical Behavior of Aluminum-Beryllium Alloys Alloyed with Yttrium, Lanthanum and Cerium

2012 ◽  
Vol 510-511 ◽  
pp. 233-240
Author(s):  
A.S. Safarov ◽  
T.D. Dzhuraev ◽  
M.I. Halimova ◽  
Z.M. Karieva
Keyword(s):  
Experimental Data ◽  
Corrosion Resistance ◽  
Electrochemical Behavior ◽  
Chemical Properties ◽  
Physical And Chemical Properties ◽  
Physical Chemical ◽  
Foundry Alloys ◽  
Physical And Chemical ◽  
Corrosion Electrochemical Behavior ◽  
And Chemical Properties

Advantage of alloys on the basis of system Al-Be,Al-Be-REM is raised technological, physical, chemical and corrosion resistance properties in damp and excessively aggressive atmospheres [. According to literary reviews, this alloys basically are foundry-hypoeuthectic and hypereuthectic, and the technology of moulding of these alloys very difficult and demands application of operations modifying. Difficultly deleted impurity basically (Fe), specifically influence phase structure, naturally influencing on physical and chemical properties industrial silumines with the maintenance not less than 0.4-0.5 %. Many additives as Fe, Mg, Ti, Be, especially in hypoeuthectic silumines increasing strength and foundry properties, can reduce them corrosion-resistance. In connection with the above-stated is of interest researches of influence of impurity such elements as, Be and REM on corrosion resistance industrial alumines. Studies corrosion-resistance spent samples potentiostatic a method on device " Potentiostate P-50" with a registering recorder in the environment of the muriatic solutions in a mode "Potential". he analysis of experimental data have shown, that addition Be, positively modifying structure of foundry alloys, reduces influences containing in it Fe, increases strength and corrosion resistance, which calculations testify experimental data of electrochemical indicators [2,3].

Comprehensive Review on pH and Nutrients Detection Sensitive Materials and Methods for Agriculture Applications

2019 ◽  
Vol 17 (9) ◽  
pp. 663-670 ◽  
Author(s):  
A. Akshaya Kumar ◽  
S. K. Naveen Kumar
Keyword(s):  
Chemical Properties ◽  
Strong Relationship ◽  
Review Article ◽  
Ion Selective Electrodes ◽  
Optical Parameters ◽  
Physical And Chemical Properties ◽  
Physical Chemical ◽  
Materials Used ◽  
Physical And Chemical ◽  
And Chemical Properties

This review article elaborates the pH and nutrients detection sensitive materials and methods along with their principle of operations, merits, demerits, and application area. The sensitive materials used in the sensors react with the analytes and shows variation in electrical, physical, chemical, biological and optical parameters. The glass probe method, optical light spectroscopy, ion-selective electrodes, ion-selective field effective transistors, electrochemical interdigitated conductimetric method and microcantilever methods are the predominant techniques to detect the pH and nutrients in various medium. Most of the researchers have discussed the fabrication of pH and nutrients sensors individually in various applications, but very few numbers of sensitive materials and techniques discussed to detect the pH and nutrients in the soil. There is a strong relationship between pH and nutrients in the soil based on a number of important physical and chemical properties of the soil. We are strongly recommending that soil pH and nutrients measuring sensors can develop through the combinational approach of pH and nutrients with the help of nanostructured materials, seems to be more effective for agriculture applications.

scholarly journals Physico-chemical Evaluation of Some Introduced Date Fruits Cultivars grown under Sudanese conditions

2015 ◽  
Vol 3 (4) ◽  
pp. 731-736
Author(s):  
Islam K. Saeed ◽  
Fatima A. El-Rauof ◽  
H.D. Dawoud
Keyword(s):  
Crude Protein ◽  
Reducing Sugars ◽  
Chemical Properties ◽  
Fruit Weight ◽  
Chemical Evaluation ◽  
Physical Chemical ◽  
Physico Chemical ◽  
Fruit Samples ◽  
Physical And Chemical ◽  
And Chemical Properties

Fruit samples of five date cultivars, three cultivars of them were introduced from Emirates Tissue culture Laboratory-Alien Abu Dhabi and cultivated in Haj-Bashir orchard - Khartoum region were collected at the beginning of the Tamar stages. The present study was aimed to investigate the physical and chemical properties. The results showed that the physical characteristics like fruit weight, length, flesh thickness, seed weight differed significantly (P < 0.05) between the various cultivars. Chemical analysis indicated small amounts of crude fiber, crude protein, Fat and ash, while sugars predominated. In general the majority of date cultivars investigated was found to be of the soft date type characterized by the dominance of reducing sugars. The performance of introduced cultivars was well when compared with the indigenous cultivar of most physical, chemical characteristics and general evaluation.Int J Appl Sci Biotechnol, Vol 3(4): 731-736

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