scholarly journals EVALUASI KINERJA METHYL DIETHANOL AMINE (MDEA) DALAM PENYERAPAN KANDUNGAN H2S PADA PROSES PENGOLAHAN GAS ALAM

EKOLOGIA ◽  
2020 ◽  
Vol 20 (1) ◽  
pp. 45-51
Author(s):  
. Sutanto ◽  
Ade Heri Mulyati ◽  
. Hermanto

Drilling natural gas contains water vapor (H2O) and contaminant gases such as CO2 and H2S which must be removed because it reduced the calorie value of the product. H2S gas is also corrosive, easily damaging equipment so that it increased maintenance costs. The process of removing CO2 and H2S gas uses MDEA (methyl diethanolamine). This study aims to determine the optimal concentration and flow rate of absorbent methyl diethanolamine (MDEA) to absorb H2S in the plant I gas flow in Energy Equity Epic (Sengkang) Pty.Ltd. The study was carried out with a steady MDEA mix absorbent flow rate (50% pure amine and 50% demineralization water) fixed at 13 US Gallons per minute flowing continuously at the upper absorber inlet, sour gas flow rate, at the bottom of the absorber inlet with variations in the flow gas namely 7,9,11,13,15,17 MMSCFD and is contacted with amine solution counter-current. Purified natural gas (sweet gas) produced from the top absorber column outlet with an H2S content below 10 ppm. The results showed that the greater the flow rate of gas inlet, the greater the acid gas absorbed. The  amount  of gas  entering and  exiting gas follows the  equation        y = 0.003 x - 2.2537. The ability of the amine solution to absorb H2S follows the logarithmic equation y = 0.167 ln (x) + 101.02 with a value of R = 0.9857, y is H2S absorbed by the amine solution and x is the H2S rate.

2021 ◽  
Vol 6 (2) ◽  
pp. 81
Author(s):  
Muhrinsyah Fatimura ◽  
Rully Masriatini ◽  
Reno Fitriyanti

Gas CO2 atau gas asam (sour gas) merupakan salah satu kandungan dari gas alam yang sifatnya sebagai kontaminan. Adanya kandungan gas CO2 yang tinggi didalam gas alam perlu dilakukan treatment khusus dalam menghilangan kandungan gas asam (sour gas) tersebut dari gas alam dimana proses penghilangan gas asam dari gas alam disebut proses Sweetening. Proses Absorspi gas CO2 merupakan metode yang sering dilakukan. Penelitian ini bertujuan  mengetahui pengaruh laju alir absorben dan waktu kontak terhadap konsentrasi CO2 yang di serap. Metode yang dilakukan dalam penelitian ini yaitu dengan perancangan alat yang bisa menunujukan proses absorpsi CO2. Variabel penelitian yang digunakan memvariasikan  laju alir absorben 4,95 ml/s, 7,26 ml/s, 10,75 ml/s serta waktu kontak 2,4,6,8 menit dengan menggunakan absorben K2CO3 dan   Gas alam yang digunakan compress Natural Gas CNG.  Dari hasil penelitan laju alir Absorbenyang paling baik didapat pada  10,75 ml/s dengan penyerapan  CO2 sebesar  69,45 %. Waktu kontak  pada setiap waktu   tidak berpengaruh banyak  terhadap konsentarsi CO2 yang terserap .  Kata kunci: absorben, Sour gas, gas alam, laju alir  AbstractCO2 gas or acid gas (sour gas) is one of the contents of natural gas which is a contaminant. The presence of high CO2 gas content in natural gas requires special treatment to remove the sour gas content from natural gas where the process of removing acid gas from natural gas is called the Sweetening process. The CO2 gas absorption process is a method that is often used. This study aims to determine the effect of absorbent flow rate and contact time on the absorbed CO2 concentration. The method used in this research is to design a tool that can show the CO2 absorption process. The research variables used varied the absorbent flow rate of 4.95 ml/s, 7.26 ml/s, 10.75 ml/s and a contact time of 2,4,6,8 minutes using K2CO3 absorbent and natural gas used compressed Natural CNG gas. From the research results, the best absorbent flow rate was obtained at 10.75 ml/s with CO2 absorption of 69.45%. Contact time at any time did not have much effect on the concentration of CO2 absorbed. Keywords: absorbent, sour gas, natural gas, flow rate


Author(s):  
B.S. Soroka ◽  
V.V. Horupa

Natural gas NG consumption in industry and energy of Ukraine, in recent years falls down as a result of the crisis in the country’s economy, to a certain extent due to the introduction of renewable energy sources along with alternative technologies, while in the utility sector the consumption of fuel gas flow rate enhancing because of an increase the number of consumers. The natural gas is mostly using by domestic purpose for heating of premises and for cooking. These items of the gas utilization in Ukraine are already exceeding the NG consumption in industry. Cooking is proceeding directly in the living quarters, those usually do not meet the requirements of the Ukrainian norms DBN for the ventilation procedures. NG use in household gas stoves is of great importance from the standpoint of controlling the emissions of harmful components of combustion products along with maintenance the satisfactory energy efficiency characteristics of NG using. The main environment pollutants when burning the natural gas in gas stoves are including the nitrogen oxides NOx (to a greater extent — highly toxic NO2 component), carbon oxide CO, formaldehyde CH2O as well as hydrocarbons (unburned UHC and polyaromatic PAH). An overview of environmental documents to control CO and NOx emissions in comparison with the proper norms by USA, EU, Russian Federation, Australia and China, has been completed. The modern designs of the burners for gas stoves are considered along with defining the main characteristics: heat power, the natural gas flow rate, diameter of gas orifice, diameter and spacing the firing openings and other parameters. The modern physical and chemical principles of gas combustion by means of atmospheric ejection burners of gas cookers have been analyzed from the standpoints of combustion process stabilization and of ensuring the stability of flares. Among the factors of the firing process destabilization within the framework of analysis above mentioned, the following forms of unstable combustion/flame unstabilities have been considered: flashback, blow out or flame lifting, and the appearance of flame yellow tips. Bibl. 37, Fig. 11, Tab. 7.


Author(s):  
Salavat K. Sibagatullin ◽  
◽  
Aleksandr S. Kharchenko ◽  
Vitaly A. Beginyuk ◽  
Valentin N. Selivanov ◽  
...  

2020 ◽  
pp. 44-50
Author(s):  
O. E. Seredyuk ◽  
N. M. Malisevich

The article is devoted to the study of the influence of the qualitative and quantitative composition of gas environments on the flame temperature of the combusted gas at different values of gas flow rate and changes volume ratio gas-air in its combustion. The functional scheme of the developed labo­ratory stand (Fig. 1), which provides temperature measurement during combustion of natural gas or propane-butane mixture, is considered. The design of the developed burner is described and the expe­rimental researches are carried out when measuring the flame temperature of the combusted gas during the operation of the laboratory stand. The opera­ting conditions of different thermocouples in measuring the temperature of the flared gas are investigated (Fig. 2). The temperature instability in the lower and upper flames was experimentally determined (Fig. 3) and its difference from the reference data [12, 13]. The measurement of the flame temperature with a uncased thermocouple and two thermocouples of different types with protective housings is reali­zed. Methodical error of temperature measurement by different thermocouples was estimated (Fig. 5). An algorithm for the implementation of measurement control in determining the heat of combustion of natural gas according to the patented method is outlined [11]. Experimental studies of temperature changes of combusted gas mixtures at different gas flow rates and different ratios with air, which is additionally supplied for gas combustion, were carried out (Figs. 4, 7). The computer simulation (Figs. 6, 8) of the change in the flame temperature was performed on the basis of the experimental data, which allowed to obtain approximate equations of the functional dependence of the flame temperature on the gas flow rate and the ratio of the additional air and gas consumption. The possibility of realization of the device of express control of the heating value of natural gas by measuring the combustion temperature of the investigated gases, which is based on the expe­rimentally confirmed increase in the flame temperature of the investigated gases with increasing their calorific value, is substantiated (Fig. 9). The necessity of further investigation of the optimization design characteristics of the burner and the operating conditions of combustion of the gases under rapid cont­rol of their combustion heat was established (Fig. 9).


2022 ◽  
Vol 964 (1) ◽  
pp. 012030
Author(s):  
Pham-Hung Duong ◽  
Ngoc-Han T. Huynh ◽  
Yong-Soo Yoon

Abstract This study was carried out to assess the treatment ability of color, dye, and COD in the dyeing wastewater containing C.I Reactive Blue 160 by ozonation system. Both batch and continuous operating modes with concurrent and counter-current flows were investigated. The effects of the ozone gas flow rate, pH, temperature, Na2CO3 concentration, and initial dye concentration were evaluated. The decolorization, dye removal efficiencies, and mineralization ability of COD by ozonation were determined. The results indicated that ozonation had high efficiency in the treatment of dyeing wastewater containing C.I Reactive Blue 160. The treatment performance was affected by the ozone gas flow rate, pH, temperature, Na2CO3 concentration, and initial dye concentration. The removal efficiency of color, dye, and COD were 98.04%, 99.84%, and 87.31% for the treatment of 200 mg/L initial dye concentration in batch mode with 30 min ozonation time, respectively. In the continuous operation and counter-current flow, the color, dye, and COD removal efficiencies reached 97.24%, 99.76%, and 86.38% after 30 min HRT, respectively, and higher than concurrent flow. The reaction of ozone and C. I Reactive Blue 160 was the first-order reaction in both batch and continuous operation. The complete mineralization required 90 min ozonation time.


2020 ◽  
Vol 12 (13) ◽  
pp. 5412
Author(s):  
Anita Turała ◽  
Andrzej Wieczorek

Biofiltration of air polluted with xylene vapors was carried out for nearly two years in a large laboratory-scale installation with a volume of the bed of expanded clay equal to 32 dm3. During the experiment, different xylene inlet concentrations were applied, within the range from 300 to over 1500 mg/m3 at a linear gas flow rate of 0.008, 0.016, and 0.033 m/s, as well as 0.12 and 0.24 dm3 of medium dispensed every 3 h on top of the bed. The progress of the process was followed by measuring the xylene concentration at the inlet and outlet of the column, column mass, and gas flow resistance. The capability to purify air polluted with xylene with an average efficiency of approx. 90% was demonstrated. The process was interrupted by a significant increase in gas flow resistance, caused by a large growth of biomass, resulting in an increase in the mass of the bed by more than 45%. Both intensive rinsing of the bed with a stream of water, causing its fluidization, and rinsing and mixing after removing the bed from the column allowed to reduce flow resistance to a value close to the initial one. To ensure the supply of biogenic elements, it was necessary to periodically spray the bed with a solution of the medium in an amount of up to about 0.1 dm3/h/m3 of purified air.


Energies ◽  
2018 ◽  
Vol 11 (7) ◽  
pp. 1868 ◽  
Author(s):  
Ehsan Barekat-Rezaei ◽  
Mahmood Farzaneh-Gord ◽  
Alireza Arjomand ◽  
Mohsen Jannatabadi ◽  
Mohammad Ahmadi ◽  
...  

In many industrial plants including petrochemicals and refineries, raw hydrocarbons (mostly flammable gas) are released during unplanned operations. These flammable gases (usually called flare gases) are sent to a combustor and the process is called flaring. Flaring wastes energy and produces environmental pollution. Consequently, recovering the flare gases is an important subject in these industries. In this work, an economical and technical analysis is presented for the production of valuable products, namely, liquefied natural gas and natural gas liquids from flare gas. The flare gas of Fajr Jam refinery, a refinery located in the south part of Iran, is selected as a case study. One of the issues in recovering flare gases is the nonconstant flow rate of these gases. For this reason, an auxiliary natural gas flow rate is employed to have a constant feed for the flare recovery process. The Poly Refrigerant Integrated Cycle Operations (PRICO) refrigeration cycle is employed for producing liquefied natural gas and natural gas liquids. In the PRICO cycle, the mixed refrigerant is used as the working fluid. The other issue is the existence of H2S in the flare gases. The main idea is that the flare gas components, including H2S, have different boiling points and it is possible to separate them. Consequently, flare gases are separated into several parts during a number of successive cooling and heating stages and passing through phase separators. It is shown that the proposed flare gas recovery process prevents burning of 12 million cubic meters of the gases with valuable hydrocarbons, which is almost 70% of the current flare gases. Furthermore, about 11,000 tons of liquefied natural gas and 1230 tons of natural gas liquids are produced in a year. Finally, the economic evaluation shows a payback period of about 1.6 years.


The use of natural gas in several countries, especially in Indonesia is essential. In gas distribution, every industry and household will not be separated from the measurement system that aims to find out how much natural gas has been used. For this reason, the use of a gas flow meter is necessary. There are several types of gas flow meter can be used in measuring the gas volume. Some types of gas flow meters are gas turbine meters, rotary gas meters and diaphragm gas meters. The primary difference of each type of gas flow meter is the pressure capacity and the speed of the gas flow through it. Flow meter gas turbine is one type of gas flow rate measuring device. There are moving parts consisting of a propeller whose rotation speed is proportional to the flow rate through the flow meter. The type of gas turbine meter is Fluxi 2000/TZ. Fluxi 2000/TZ is designed to measure natural gas and various non-corrosive gases. This tool can be used to measure low gas flow and high gas flow. This tool can also be used to measure flow under various pressure conditions. Corus is the name of the type of gas volume converter. Corus is one instrument that supports the reading process of various gas meters, and one of them is a gas turbine meter. Corus is designed to achieve high levels of performance and accuracy from robust electronic equipment so that the results of reading the fluid volume available on the gas turbine meter can be calculated more accurately regard to the amount of temperature, pressure and compressibility. The working principle and characteristics of the two instruments make the measurements more accurate.


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