INVESTIGATING THE POSSIBILITY OF USING THE NATURAL BITUMEN OF GILSONITE TYPE FOR THE PRODUCTION OF ROAD BITUMEN

2019 ◽  
pp. 37-41
Author(s):  
Ivan Kopynets ◽  
Oleksii Sokolov ◽  
Оksana Sokolova ◽  
Alina Yunak
Keyword(s):  
Asphalt Concrete ◽  
Softening Point ◽  
Heavy Traffic ◽  
Petroleum Products ◽  
Natural Bitumen ◽  
Chemical Indicators ◽  
High Adhesion ◽  
Physico Chemical ◽  
Adverse Weather

The heavy traffic combined with the adverse weather and climate factors which are characteristic for most of the year, makes high demands for asphalt concrete. The quality of asphalt concrete is largely determined by the properties of bitumen which plays the role of a binder which provides the formation of a monolithic composite road-building material from separate mineral grains. Compound bitumen obtained by mixing the peroxidized bitumen with tar have the best ratio of all physico-chemical indicators, it is also possible the option to compound residual bitumen with oxidized. Oxidized bitumen obtained by the oxidation of tar or a mixture of tar with other petroleum products is characterized by low cohesive strength, poor adhesion and considerable aging. The use of natural bitumen of gilsonite type is the most common method to improve the properties of bitumen. When introducing into the bitumen of this natural bitumen, its penetration at a temperature of 25° C is reduced, as well as the softening point is increased. In fact, the nature of the change in the properties of bitumen during introduction of natural bitumen is the same as during its oxidation. That is, natural bitumen can be used to produce road bitumen by compounding it with tar. This paper presents the results of bitumen research obtained by combining tar with natural bitumen of gilsonite type. The production of bitumen by combining tar with natural bitumen of gilsonite type allows obtaining different grades of road bitumen by changing the content of natural bitumen. Bitumen obtained by this technology is more heat- and crack-resistant, have high adhesion to the aggregates and are not subjected to the technological aging. This bitumen has a higher softening point and a lower Fraass breaking point and therefore a higher plasticity interval. Keywords: bitumen, production, equiviscous temperatures, natural bitumen, mixing.

scholarly journals On some results of agroecological monitoring of soils and land resources of the Russian Federation in 2019

2021 ◽  
Vol 4 (46) ◽  
pp. 10-10
Author(s):  
Alexander Saakian ◽  
◽  
Keyword(s):  
Heavy Metals ◽  
Agricultural Land ◽  
Land Reclamation ◽  
Plant Protection ◽  
Plant Protection Products ◽  
Crop Productivity ◽  
Petroleum Products ◽  
Land Resources ◽  
Chemical Indicators ◽  
Physico Chemical

The article presents the results of long-term agroecological monitoring of the state of Russian land resources: the dynamics of changes in agrochemical and physico-chemical indicators, the content of organic matter and elements of mineral nutrition of plants in soils; crop productivity; contamination of soils and products with residual amounts of pesticides, oil and petroleum products, heavy metals, nitrates, radionuclides; the problems of erosion and reclamation of agricultural land are highlighted. Ключевые слова: AGROECOLOGICAL MONITORING, HUMUS, MOBILE PHOSPHORUS, EXCHANGE POTASSIUM, ACIDITY, CHEMICAL RECLAMATION, LIMING, PHOSPHORIZATION, GYPSUM, PLANT PROTECTION PRODUCTS, YIELD, FERTILIZERS, PESTICIDE RESIDUES, OIL AND PETROLEUM PRODUCTS, HEAVY METALS, NITRATES, WATER AND WIND EROSION OF SOILS, LAND RECLAMATION

scholarly journals The role of biotic and abiotic components of the aquatic ecosystem in the formation of ecological trouble of Tsimlyansk and Manych reservoirs

2019 ◽  
Vol 46 (5) ◽  
pp. 544-554
Author(s):  
A. M. Nikanorov ◽  
T. A. Khoruzhaya
Keyword(s):  
Aquatic Ecosystem ◽  
Aquatic Ecosystems ◽  
Environmental Disaster ◽  
State Of Emergency ◽  
Chemical Indicators ◽  
Physico Chemical ◽  
State Of Water ◽  
Abiotic Component

The relative importance of indicators of biotic and abiotic components of aquatic ecosystems of Tsimlyansky and Manych (Proletarian and Veselovsky) reservoirs is investigated in the process of formation of States of ecological trouble: “environmental stress, environmental emergency and ecological disaster”, which are provided by a number of existing normative- methodological documents. For this purpose, the shares of indicators as a percentage of their total number in the dynamics of negative changes in aquatic ecosystems were compared on the basis of long-term monitoring information of Roshydromet and data of own expeditionary studies in reservoirs on hydrobiological, toxicological and physico-chemical indicators. It is established that the role of the biotic component increases with the deterioration of the aquatic ecosystem of the Tsimlyansk reservoir, on the contrary, decreases in Manych. The role of the abiotic component is great and similar in all reservoirs; it increases already in a state of emergency environmental situation, but in an environmental disaster is somewhat reduced. It is concluded that the proposed new approach to the analysis of the role of biotic and abiotic components in the development of negative changes in the ecosystem opens up new opportunities in the study of the water quality formation and the state of water bodies.

scholarly journals ASSESSMENT OF THE ROLE OF STORAGE OF LOW-RATED COTTON SEEDS ON ITS PHYSICO-CHEMICAL INDICATORS

2021 ◽  
Vol 82 (1-2) ◽  
Author(s):  
Azimjon Akhmedov ◽  
Saidakbar Abdurakhimov ◽  
Gulbahor Suvanova ◽  
Javlonbek Giyasov
Keyword(s):  
Chemical Indicators ◽  
Physico Chemical ◽  
Cotton Seeds

scholarly journals On some results of agroecological monitoring of soils and land resources of the Russian Federation in 2019

2021 ◽  
Vol 4 (46) ◽  
pp. 10-10
Author(s):  
Alexander Saakian ◽  
◽  
Keyword(s):  
Heavy Metals ◽  
Agricultural Land ◽  
Land Reclamation ◽  
Plant Protection ◽  
Plant Protection Products ◽  
Crop Productivity ◽  
Petroleum Products ◽  
Land Resources ◽  
Chemical Indicators ◽  
Physico Chemical

The article presents the results of long-term agroecological monitoring of the state of Russian land resources: the dynamics of changes in agrochemical and physico-chemical indicators, the content of organic matter and elements of mineral nutrition of plants in soils; crop productivity; contamination of soils and products with residual amounts of pesticides, oil and petroleum products, heavy metals, nitrates, radionuclides; the problems of erosion and reclamation of agricultural land are highlighted. Ключевые слова: AGROECOLOGICAL MONITORING, HUMUS, MOBILE PHOSPHORUS, EXCHANGE POTASSIUM, ACIDITY, CHEMICAL RECLAMATION, LIMING, PHOSPHORIZATION, GYPSUM, PLANT PROTECTION PRODUCTS, YIELD, FERTILIZERS, PESTICIDE RESIDUES, OIL AND PETROLEUM PRODUCTS, HEAVY METALS, NITRATES, WATER AND WIND EROSION OF SOILS, LAND RECLAMATION

Activation of cytochrome c to a peroxidase compound I-type intermediate by H2O2: relevance to redox signalling in apoptosis

2004 ◽  
Vol 71 ◽  
pp. 97-106 ◽  
Author(s):  
Mark Burkitt ◽  
Clare Jones ◽  
Andrew Lawrence ◽  
Peter Wardman
Keyword(s):  
Cytochrome C ◽  
Hydroxyl Radical ◽  
Redox Regulation ◽  
Chemotherapeutic Agents ◽  
Tyrosyl Radical ◽  
Compound I ◽  
Definitive Evidence ◽  
Enhanced Production ◽  
Physico Chemical

The release of cytochrome c from mitochondria during apoptosis results in the enhanced production of superoxide radicals, which are converted to H2O2 by Mn-superoxide dismutase. We have been concerned with the role of cytochrome c/H2O2 in the induction of oxidative stress during apoptosis. Our initial studies showed that cytochrome c is a potent catalyst of 2′,7′-dichlorofluorescin oxidation, thereby explaining the increased rate of production of the fluorophore 2′,7′-dichlorofluorescein in apoptotic cells. Although it has been speculated that the oxidizing species may be a ferryl-haem intermediate, no definitive evidence for the formation of such a species has been reported. Alternatively, it is possible that the hydroxyl radical may be generated, as seen in the reaction of certain iron chelates with H2O2. By examining the effects of radical scavengers on 2′,7′-dichlorofluorescin oxidation by cytochrome c/H2O2, together with complementary EPR studies, we have demonstrated that the hydroxyl radical is not generated. Our findings point, instead, to the formation of a peroxidase compound I species, with one oxidizing equivalent present as an oxo-ferryl haem intermediate and the other as the tyrosyl radical identified by Barr and colleagues [Barr, Gunther, Deterding, Tomer and Mason (1996) J. Biol. Chem. 271, 15498-15503]. Studies with spin traps indicated that the oxo-ferryl haem is the active oxidant. These findings provide a physico-chemical basis for the redox changes that occur during apoptosis. Excessive changes (possibly catalysed by cytochrome c) may have implications for the redox regulation of cell death, including the sensitivity of tumour cells to chemotherapeutic agents.

THYROID STIMULATORS AND THYROID STIMULATION

1971 ◽  
Vol 66 (3) ◽  
pp. 558-576 ◽  
Author(s):  
Gerald Burke
Keyword(s):  
Regulatory System ◽  
Control Site ◽  
Thyroid Cell ◽  
Primary Control ◽  
Physico Chemical ◽  
Site Of Action ◽  
Long Acting

ABSTRACT A long-acting thyroid stimulator (LATS), distinct from pituitary thyrotrophin (TSH), is found in the serum of some patients with Graves' disease. Despite the marked physico-chemical and immunologic differences between the two stimulators, both in vivo and in vitro studies indicate that LATS and TSH act on the same thyroidal site(s) and that such stimulation does not require penetration of the thyroid cell. Although resorption of colloid and secretion of thyroid hormone are early responses to both TSH and LATS, available evidence reveals no basic metabolic pathway which must be activated by these hormones in order for iodination reactions to occur. Cyclic 3′, 5′-AMP appears to mediate TSH and LATS effects on iodination reactions but the role of this compound in activating thyroidal intermediary metabolism is less clear. Based on the evidence reviewed herein, it is suggested that the primary site of action of thyroid stimulators is at the cell membrane and that beyond the(se) primary control site(s), there exists a multifaceted regulatory system for thyroid hormonogenesis and cell growth.

Authenticity Identification of Carbonated Alcochol-Free Beverages

Food Industry ◽  
2020 ◽  
Vol 5 (1) ◽  
pp. 16-22
Author(s):  
Irina Reznichenko ◽  
Maria Kondratieva
Keyword(s):  
Mass Fraction ◽  
Soft Drinks ◽  
Alcoholic Beverages ◽  
Consumer Market ◽  
Score System ◽  
Regulatory Documents ◽  
Chemical Indicators ◽  
Physico Chemical ◽  
Alcoholic Drinks ◽  
Physical And Chemical

The article concerns the counterfeiting problem of non-alcoholic drinks sold on the consumer market of the Russian Federation; provides data on drinks fraud methods (assortment, qualitative, quantitative and informational types). Strengthening quality control of soft drinks is one of the main directions of providing consumers with qualitative products. The authors presented authenticity identification results of carbonated soft drinks sold on the Kemerovo consumer market for compliance with the current regulatory documents requirements; run the consumer criteria analysis for the drinks identification of various brands. They obtained data on the labeling and packaging identification of selected non-alcoholic carbonated drinks samples for the compliance with current regulatory documents. A man recorded the compliance. There was an absence of the quantitative counterfeiting identification. The study described results of the organoleptic and physico-chemical quality indicators research. According to the GOST 28188-2014 “Non-Alcoholic Beverages. General Technical Conditions” the authors evaluated beverages quality by such physical and chemical indicators as the mass fraction of dry substances, acidity, and the mass fraction of carbon dioxide. The researchers run the organoleptic indicators analysis according to a score system. Authenticity identification of the selected drinks samples showed that there are no signs of counterfeiting and the products are of high quality.

The Influence of Benthic Biota on Copper Speciation and Distribution in Freshwater-Sediment Systems

1981 ◽  
Vol 16 (1) ◽  
pp. 45-58 ◽  
Author(s):  
G. Krantzberg ◽  
P.M. Stokes
Keyword(s):  
Freshwater Sediment ◽  
Benthic Macroinvertebrate ◽  
Macroinvertebrate Communities ◽  
Copper Species ◽  
Copper Speciation ◽  
Physico Chemical ◽  
Macro Benthos

Abstract An investigation was made of the effects exerted by benthic macroinvertebrate communities on copper speciation in sediments from a lake which is becoming acidified. In laboratory microcosms, benthic macroinvertebrate communities stimulated the flux of copper from sediment to water. The presence of the macro-benthos resulted in a redistribution of physico-chemical copper species within the sediment with a transfer from more strongly complexed forms (HC1 extractable) to adsorbed and cation exchangeable forms (MgCl2 extractable). The role of bio-turbation in copper transformations is discussed.

scholarly journals Occurrence of drug target residues within decantation tank sediments: a good clue to assess their historical excretion?

2021 ◽  
Vol 31 (1) ◽  
Author(s):  
Thomas Thiebault ◽  
Laëtitia Fougère ◽  
Anaëlle Simonneau ◽  
Emilie Destandau ◽  
Claude Le Milbeau ◽  
...  
Keyword(s):  
Drug Target ◽  
Chemical Properties ◽  
Deposition Process ◽  
Drug Consumption ◽  
Organic Layers ◽  
Sewer Systems ◽  
Physico Chemical ◽  
Deep Underground ◽  
Deposition Processes

AbstractThis study investigated the potential of sediments accumulated in sewer systems to record human activities through the occurrence of drug target residues (DTR). The installation studied is 17 m deep underground decantation tank that traps the coarse fractions of a unitary sewer system (northern part of Orléans, France), collecting both stormwater and wastewater. The sediments deposited in this tank could constitute a nonesuch opportunity to study the historical evolution of illicit and licit drug consumption in the catchment, however, the deposition processes and the record of DTRs remain largely unknown at present. Five cores were acquired from 2015 to 2017. One hundred fifty-two sediment samples were extracted using a mixture of ultra-pure water:methanol (1:1) prior to analysis of the extracts by high-pressure liquid chromatography coupled to tandem mass spectrometry. Several classical sedimentological analyses such as total organic carbon, facies description and granulometry were also performed on these samples, in order to understand the most important factors (e.g., physico-chemical properties of the DTRs, solid type, assumed load in wastewater) impacting their deposition.The key role of the speciation of DTRs was highlighted by the higher contents in neutral and anionic DTRs in organic layers, whereas only cationic DTRs were found in mineral layers. The considerable modifications in the sediments’ properties, generated by distinct origins (i.e., stormwater or wastewater), are therefore the most important drivers that must be taken into account when back-calculating the historical patterns of drug consumption from their DTR concentrations in decantation tank sediments. Further research remains necessary to fully understand the deposition process, but this study provides new clues explaining these temporal evolutions.

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