scholarly journals Electrochemical Ammonia: Power to Ammonia Ratio and Balance of Plant Requirements for Two Different Electrolysis Approaches

2021 ◽  
Vol 3 ◽  
Author(s):  
Jessica Allen ◽  
Sebastien Panquet ◽  
Adrian Bastiani
Keyword(s):  
Energy Demand ◽  
High Efficiency ◽  
Ammonia Synthesis ◽  
Small Scale ◽  
Cell Potential ◽  
Efficient Operation ◽  
Faradaic Efficiency ◽  
Balance Of Plant ◽  
Trade Offs ◽  
Energy Inputs

Electrochemical ammonia generation allows direct, low pressure synthesis of ammonia as an alternative to the established Haber-Bosch process. The increasing need to drive industry with renewable electricity central to decarbonisation and electrochemical ammonia synthesis offers a possible efficient and low emission route for this increasingly important chemical. It also provides a potential route for more distributed and small-scale ammonia synthesis with a reduced production footprint. Electrochemical ammonia synthesis is still early stage but has seen recent acceleration in fundamental understanding. In this work, two different ammonia electrolysis systems are considered. Balance of plant (BOP) requirements are presented and modelled to compare performance and determine trade-offs. The first option (water fed cell) uses direct ammonia synthesis from water and air. The second (hydrogen-fed cell), involves a two-step electrolysis approach firstly producing hydrogen followed by electrochemical ammonia generation. Results indicate that the water fed approach shows the most promise in achieving low energy demand for direct electrochemical ammonia generation. Breaking the reaction into two steps for the hydrogen fed approach introduces a source of inefficiency which is not overcome by reduced BOP energy demands, and will only be an attractive pathway for reactors which promise both high efficiency and increased ammonia formation rate compared to water fed cells. The most optimised scenario investigated here with 90% faradaic efficiency (FE) and 1.5 V cell potential (75% nitrogen utilisation) gives a power to ammonia value of 15 kWh/kg NH3 for a water fed cell. For the best hydrogen fed arrangement, the requirement is 19 kWh/kg NH3. This is achieved with 0.5 V cell potential and 75% utilisation of both hydrogen and nitrogen (90% FE). Modelling demonstrated that balance of plant requirements for electrochemical ammonia are significant. Electrochemical energy inputs dominate energy requirements at low FE, however in cases of high FE the BOP accounts for approximately 50% of the total energy demand, mostly from ammonia separation requirements. In the hydrogen fed cell arrangement, it was also demonstrated that recycle of unconverted hydrogen is essential for efficient operation, even in the case where this increases BOP energy inputs.

scholarly journals Integrated Geothermal Energy Systems for Small-Scale Combined Heat and Power Production: Energy and Economic Investigation

2020 ◽  
Vol 10 (19) ◽  
pp. 6639 ◽  
Author(s):  
Pietropaolo Morrone ◽  
Angelo Algieri
Keyword(s):  
Geothermal Energy ◽  
Energy Demand ◽  
High Efficiency ◽  
Energy Performance ◽  
Combined Heat And Power ◽  
Integrated System ◽  
Operating Conditions ◽  
Economic Viability ◽  
Small Scale ◽  
Partial Load

In recent years, an increasing interest in geothermal energy has been registered in both the scientific community and industry. The present work aims to analyse the energy performance and the economic viability of an innovative high-efficiency geothermal-driven integrated system for a combined heat and power (CHP) application. The system consists of a heat exchanger (HEX) and a transcritical organic Rankine cycle (ORC) that work in parallel to exploit a high-temperature geothermal source (230 °C) and satisfy the energy demand of a commercial centre located in Southern Italy. The ORC and HEX sub-units can operate at partial load to increase the system flexibility and to properly react to continuous changes in energy request. A lumped model was developed to find the proper operating conditions and to evaluate the energy production on an hourly basis over the whole year. In particular, a multi-variable optimisation was implemented to find the most suitable configuration and a 101.4 kWel ORC was selected while the HEX nominal power was 249.5 kWth. The economic viability of the integrated system was evaluated in terms of net present value and payback period and different operating strategies were compared: thermal-driven, electric-driven, and a mixed strategy. The latter turned out to be the best solution according to both energy and economic criteria, with electric and thermal self-consumptions larger than 90%, with no heat dumping and a payback time close to five years.

Simulation of Intermediate-Temperature SOFC for 60%+ Efficiency Distributed Generation

2015 ◽  
Author(s):  
Luca Mastropasqua ◽  
Stefano Campanari ◽  
Paolo Iora ◽  
Matteo Carmelo Romano
Keyword(s):  
Fuel Cell ◽  
Natural Gas ◽  
Case Studies ◽  
Distributed Generation ◽  
Process Simulation ◽  
High Efficiency ◽  
Intermediate Temperature ◽  
Small Scale ◽  
Efficient Operation ◽  
High Efficient

This work proposes a process simulation of high efficiency intermediate-temperature (660–730°C) SOFC systems for promising applications in the foreseeable future distributed power generation sector. Two case-studies have been considered: the kW-scale unit proposed by Ceramic Fuel Cell Limited (CFCL), which reaches up to 68% stack DC efficiency, and the FuelCell Energy (FCE) SOFC system, where a 65% DC efficiency has been verified on a 10 kW module. Both systems can be applied to distributed generation, yielding 60%+ net electric efficiency (LHV basis) from natural gas at small scale. This study aims at calibrating the two considered SOFC balance of plants with the Politecnico di Milano in-house software GS. Throughout a zero-dimensional model of the complete system a validation of the manufacturer’s claimed performance is possible. The general module configuration is made up of a natural gas pre-treating processor, a SOFC stack, an anodic spent fuel combustor and a waste heat recovery system for CHP applications. A pre-reforming adiabatic reactor has been proven to be an efficient choice to reduce the higher hydrocarbon chains content in the fuel stream and therefore to lessen the burden on the anodic channel, especially in terms of solid carbon deposition. The fuel is then pre-heated and, in the FCE case-study, mixed with the anodic outlet recycle; this last solution is regarded as of utmost importance for the attainment of the high overall fuel utilisation (≈80–85%) factors necessary to reach the proposed high efficiency targets, as well as to provide the steam required by the internal reforming process. Both the considered fuel cell systems performance have been verified and their extremely high efficient operation proven, according to those reported by their manufacturers. In addition to the process simulation, the work lays the foundations for a more thorough SOFC stack modelling throughout a 2D in-house developed software. This analysis gives valuable insights on the geometry characterisation and on the flow arrangement, as well as on their effects on cell internal temperature and composition profiles. In particular, the proposed analysis focuses on the case of a planar cross-flow arrangement, representative of the latter of the two case-studies. The understanding of the internal behaviour of the systems provides useful information to optimise the cell performance and design.

"Recent Patents on the Triboelectrostatic Separation of Fly Ash"

2019 ◽  
Vol 13 ◽  
Author(s):  
Haisheng Li ◽  
Wenping Wang ◽  
Yinghua Chen ◽  
Xinxi Zhang ◽  
Chaoyong Li
Keyword(s):  
Fly Ash ◽  
Power Plants ◽  
High Efficiency ◽  
Separation Efficiency ◽  
High Reliability ◽  
Operating Conditions ◽  
Security Requirements ◽  
Unburned Carbon ◽  
Efficient Operation ◽  
Triboelectrostatic Separation

Background: The fly ash produced by coal-fired power plants is an industrial waste. The environmental pollution problems caused by fly ash have been widely of public environmental concern. As a waste of recoverable resources, it can be used in the field of building materials, agricultural fertilizers, environmental materials, new materials, etc. Unburned carbon content in fly ash has an influence on the performance of resource reuse products. Therefore, it is the key to remove unburned carbon from fly ash. As a physical method, triboelectrostatic separation technology has been widely used because of obvious advantages, such as high-efficiency, simple process, high reliability, without water resources consumption and secondary pollution. Objective: The related patents of fly ash triboelectrostatic separation had been reviewed. The structural characteristics and working principle of these patents are analyzed in detail. The results can provide some meaningful references for the improvement of separation efficiency and optimal design. Methods: Based on the comparative analysis for the latest patents related to fly ash triboelectrostatic separation, the future development is presented. Results: The patents focused on the charging efficiency and separation efficiency. Studies show that remarkable improvements have been achieved for the fly ash triboelectrostatic separation. Some patents have been used in industrial production. Conclusion: According to the current technology status, the researches related to process optimization and anti-interference ability will be beneficial to overcome the influence of operating conditions and complex environment, and meet system security requirements. The intelligent control can not only ensure the process continuity and stability, but also realize the efficient operation and management automatically. Meanwhile, the researchers should pay more attention to the resource utilization of fly ash processed by triboelectrostatic separation.

Integrated Design and Multi-Objective Optimization of a Single Stage Heat-Pump Turbocompressor

2013 ◽  
Author(s):  
J. Schiffmann
Keyword(s):  
Design Optimization ◽  
High Efficiency ◽  
Integrated Design ◽  
Heat Pumps ◽  
Small Scale ◽  
Multi Objective Optimization ◽  
Design Constraints ◽  
Multi Objective ◽  
Wide Range ◽  
Standard Design

Small scale turbomachines in domestic heat pumps reach high efficiency and provide oil-free solutions which improve heat-exchanger performance and offer major advantages in the design of advanced thermodynamic cycles. An appropriate turbocompressor for domestic air based heat pumps requires the ability to operate on a wide range of inlet pressure, pressure ratios and mass flows, confronting the designer with the necessity to compromise between range and efficiency. Further the design of small-scale direct driven turbomachines is a complex and interdisciplinary task. Textbook design procedures propose to split such systems into subcomponents and to design and optimize each element individually. This common procedure, however, tends to neglect the interactions between the different components leading to suboptimal solutions. The authors propose an approach based on the integrated philosophy for designing and optimizing gas bearing supported, direct driven turbocompressors for applications with challenging requirements with regards to operation range and efficiency. Using previously validated reduced order models for the different components an integrated model of the compressor is implemented and the optimum system found via multi-objective optimization. It is shown that compared to standard design procedure the integrated approach yields an increase of the seasonal compressor efficiency of more than 12 points. Further a design optimization based sensitivity analysis allows to investigate the influence of design constraints determined prior to optimization such as impeller surface roughness, rotor material and impeller force. A relaxation of these constrains yields additional room for improvement. Reduced impeller force improves efficiency due to a smaller thrust bearing mainly, whereas a lighter rotor material improves rotordynamic performance. A hydraulically smoother impeller surface improves the overall efficiency considerably by reducing aerodynamic losses. A combination of the relaxation of the 3 design constraints yields an additional improvement of 6 points compared to the original optimization process. The integrated design and optimization procedure implemented in the case of a complex design problem thus clearly shows its advantages compared to traditional design methods by allowing a truly exhaustive search for optimum solutions throughout the complete design space. It can be used for both design optimization and for design analysis.

scholarly journals Quasi-graphitic carbon shell-induced Cu confinement promotes electrocatalytic CO2 reduction toward C2+ products

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Ji-Yong Kim ◽  
Deokgi Hong ◽  
Jae-Chan Lee ◽  
Hyoung Gyun Kim ◽  
Sungwoo Lee ◽  
...  
Keyword(s):  
High Efficiency ◽  
Co2 Reduction ◽  
Value Added ◽  
Material Design ◽  
Catalyst System ◽  
Critical Issue ◽  
Reduction Reaction ◽  
Catalyst Design ◽  
Design Strategies ◽  
Faradaic Efficiency

AbstractFor steady electroconversion to value-added chemical products with high efficiency, electrocatalyst reconstruction during electrochemical reactions is a critical issue in catalyst design strategies. Here, we report a reconstruction-immunized catalyst system in which Cu nanoparticles are protected by a quasi-graphitic C shell. This C shell epitaxially grew on Cu with quasi-graphitic bonding via a gas–solid reaction governed by the CO (g) - CO2 (g) - C (s) equilibrium. The quasi-graphitic C shell-coated Cu was stable during the CO2 reduction reaction and provided a platform for rational material design. C2+ product selectivity could be additionally improved by doping p-block elements. These elements modulated the electronic structure of the Cu surface and its binding properties, which can affect the intermediate binding and CO dimerization barrier. B-modified Cu attained a 68.1% Faradaic efficiency for C2H4 at −0.55 V (vs RHE) and a C2H4 cathodic power conversion efficiency of 44.0%. In the case of N-modified Cu, an improved C2+ selectivity of 82.3% at a partial current density of 329.2 mA/cm2 was acquired. Quasi-graphitic C shells, which enable surface stabilization and inner element doping, can realize stable CO2-to-C2H4 conversion over 180 h and allow practical application of electrocatalysts for renewable energy conversion.

Three Spool High Efficiency Small Scale Gas Turbine Concept

2017 ◽  
Author(s):  
Matti Malkamäki ◽  
Ahti Jaatinen-Värri ◽  
Antti Uusitalo ◽  
Aki Grönman ◽  
Juha Honkatukia ◽  
...  
Keyword(s):  
Power Generation ◽  
Gas Turbine ◽  
Gas Turbines ◽  
High Efficiency ◽  
Small Scale ◽  
Inlet Temperature ◽  
Substantial Impact ◽  
Electrical Efficiency ◽  
Partial Load ◽  
Reciprocating Engines

Decentralized electricity and heat production is a rising trend in small-scale industry. There is a tendency towards more distributed power generation. The decentralized power generation is also pushed forward by the policymakers. Reciprocating engines and gas turbines have an essential role in the global decentralized energy markets and improvements in their electrical efficiency have a substantial impact from the environmental and economic viewpoints. This paper introduces an intercooled and recuperated three stage, three-shaft gas turbine concept in 850 kW electric output range. The gas turbine is optimized for a realistic combination of the turbomachinery efficiencies, the turbine inlet temperature, the compressor specific speeds, the recuperation rate and the pressure ratio. The new gas turbine design is a natural development of the earlier two-spool gas turbine construction and it competes with the efficiencies achieved both with similar size reciprocating engines and large industrial gas turbines used in heat and power generation all over the world and manufactured in large production series. This paper presents a small-scale gas turbine process, which has a simulated electrical efficiency of 48% as well as thermal efficiency of 51% and can compete with reciprocating engines in terms of electrical efficiency at nominal and partial load conditions.

No bush foods without people: the essential human dimension to the sustainability of trade in native plant products from desert Australia

2011 ◽  
Vol 33 (4) ◽  
pp. 395 ◽  
Author(s):  
Fiona Walsh ◽  
Josie Douglas
Keyword(s):  
Research And Development ◽  
Reference Group ◽  
Rainfall Variability ◽  
Forest Products ◽  
Annual Rainfall ◽  
Ecological Sustainability ◽  
Small Scale ◽  
Native Plant ◽  
Plant Products ◽  
Trade Offs

Improvement in Aboriginal people’s livelihoods and economic opportunities has been a major aim of increased research and development on bush foods over the past decade. But worldwide the development of trade in non-timber forest products from natural populations has raised questions about the ecological sustainability of harvest. Trade-offs and tensions between commercialisation and cultural values have also been found. We investigated the sustainability of the small-scale commercial harvest and trade in native plant products sourced from central Australian rangelands (including Solanum centrale J.M. Black, Acacia Mill. spp.). We used semi-structured interviews with traders and Aboriginal harvesters, participant observation of trading and harvesting trips, and analysis of species and trader records. An expert Aboriginal reference group guided the project. We found no evidence of either taxa being vulnerable to over-harvest. S. centrale production is enhanced by harvesting when it co-occurs with patch-burning. Extreme fluctuations in productivity of both taxa, due to inter-annual rainfall variability, have a much greater impact on supply than harvest effects. Landscape-scale degradation (including cattle grazing and wildfire) affected ecological sustainability according to participants. By contrast, we found that sustainability of bush food trade is more strongly impacted by social and economic factors. The relationship-based links between harvesters and traders are critical to monetary trade. Harvesters and traders identified access to productive lands and narrow economic margins between costs and returns as issues for the future sustainability of harvest and trade. Harvesters and the reference group emphasised that sustaining bush harvest relies on future generations having necessary knowledge and skills; these are extremely vulnerable to loss. Aboriginal people derive multiple livelihood benefits from harvest and trade. Aboriginal custodians and harvester groups involved in recent trade are more likely to benefit from research and development investment to inter-generational knowledge and skill transfer than from investments in plant breeding and commercial horticultural development. In an inductive comparison, our study found there to be strong alignment between key findings about the strategies used by harvesters and traders in bush produce and the ‘desert system’..

scholarly journals All-optical modulation based on MoS2-Plasmonic nanoslit hybrid structures

Nanophotonics ◽  
2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Feiying Sun ◽  
Changbin Nie ◽  
Xingzhan Wei ◽  
Hu Mao ◽  
Yupeng Zhang ◽  
...  
Keyword(s):  
High Efficiency ◽  
Single Layer ◽  
Complementary Metal Oxide Semiconductor ◽  
Oxide Semiconductor ◽  
Optical Modulator ◽  
Small Scale ◽  
Light Modulation ◽  
Optical Modulators ◽  
Signal Light ◽  
All Optical

Abstract Two-dimensional (2D) materials with excellent optical properties and complementary metal-oxide-semiconductor (CMOS) compatibility have promising application prospects for developing highly efficient, small-scale all-optical modulators. However, due to the weak nonlinear light-material interaction, high power density and large contact area are usually required, resulting in low light modulation efficiency. In addition, the use of such large-band-gap materials limits the modulation wavelength. In this study, we propose an all-optical modulator integrated Si waveguide and single-layer MoS2 with a plasmonic nanoslit, wherein modulation and signal light beams are converted into plasmon through nanoslit confinement and together are strongly coupled to 2D MoS2. This enables MoS2 to absorb signal light with photon energies less than the bandgap, thereby achieving high-efficiency amplitude modulation at 1550 nm. As a result, the modulation efficiency of the device is up to 0.41 dB μm−1, and the effective size is only 9.7 µm. Compared with other 2D material-based all-optical modulators, this fabricated device exhibits excellent light modulation efficiency with a micron-level size, which is potential in small-scale optical modulators and chip-integration applications. Moreover, the MoS2-plasmonic nanoslit modulator also provides an opportunity for TMDs in the application of infrared optoelectronics.

scholarly journals A Novel Hybrid Technique of Frequency Control for Distributed Energy Resources

2021 ◽  
Vol 40 (1) ◽  
pp. 180-204
Author(s):  
Hasham Khan
Keyword(s):  
Power Distribution ◽  
Distribution System ◽  
Energy Demand ◽  
Frequency Control ◽  
Industrial Sector ◽  
Operating Conditions ◽  
Small Scale ◽  
Hybrid Technique ◽  
Operating Characteristics ◽  
Power Distribution System

The rapid increase in the population and fastest development in the industrial sector has increased the energy demand throughout the world. Frequent outages and load shedding has seriously deteriorated the efficiency of the electrical power distribution system. Under such circumstances, the implementation of Distributed Generation (DG) is increasing. Small hydel generators are considered as the most-clean and economical for generating electrical energy. These are very complex nonlinear generators which usually exhibits low frequency electromechanical oscillations due to insufficient damping caused by severe operating conditions. These DGs are not connected to the utility in many cases because, under varying load, they cannot maintain the frequency to the permissible value. This work presents detailed analysis of operating characteristics and proposes a hybrid frequency control strategy of the small hydel systems. The simulation and testing is performed in MATLAB, the results verified the improved performance with the recommended method. The proposed method conserves half of the power consumption. The control scheme regulates the dump load by connecting and disconnecting it affectively. The application of presented methodology is convenient in the deregulated environment, especially under the severe shortage of energy. The proposed model keeps the frequency of system at desired level. It reduces the noise, thereby improving the response time of the designed controller as compared to conventional controllers. The innovative scheme also provides power for small scale industrial, agricultural and other domestic application of far-off areas where the supply of utility main grid is difficult to provide. The recommended scheme is environmental friendly and easy to implement wherever small hydel resources are available.

Privacy in Control and Dynamical Systems

2018 ◽  
Vol 1 (1) ◽  
pp. 309-332 ◽  
Author(s):  
Shuo Han ◽  
George J. Pappas
Keyword(s):  
Dynamical Systems ◽  
Smart Grids ◽  
Differential Privacy ◽  
Side Information ◽  
Sensitive Information ◽  
Efficient Operation ◽  
The Public ◽  
Rigorous Approach ◽  
Trade Offs ◽  
User Data

Many modern dynamical systems, such as smart grids and traffic networks, rely on user data for efficient operation. These data often contain sensitive information that the participating users do not wish to reveal to the public. One major challenge is to protect the privacy of participating users when utilizing user data. Over the past decade, differential privacy has emerged as a mathematically rigorous approach that provides strong privacy guarantees. In particular, differential privacy has several useful properties, including resistance to both postprocessing and the use of side information by adversaries. Although differential privacy was first proposed for static-database applications, this review focuses on its use in the context of control systems, in which the data under processing often take the form of data streams. Through two major applications—filtering and optimization algorithms—we illustrate the use of mathematical tools from control and optimization to convert a nonprivate algorithm to its private counterpart. These tools also enable us to quantify the trade-offs between privacy and system performance.

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