scholarly journals Characteristics of Shale Wettability by Contact Angle and Its Influencing Factors: A Case Study in Songliao

2021 ◽  
Vol 9 ◽  
Author(s):  
Haitao Xue ◽  
Zhentao Dong ◽  
Shansi Tian ◽  
Shuangfang Lu ◽  
Ce An ◽  
...  

Wettability is a significant factor in the exploration and development of shale oil. Currently, shale wettability has yet to reach a unified understanding. The contact angle is widely used in the study of shale wettability. However, the pre-treatment of the shale profoundly affects the contact angle. In this paper, the contact angle errors introduced by the pre-treatment of samples are discussed. Shale wettability is influenced by many factors, and there is not yet a systematic study of its influencing factors. Based on the above issues, the shale of the northern Songliao Basin was taken as the subject. The wettability of the different lithofacies is characterized by an improved contact angle method. The compositional characteristics of the shales and oil in the study area were analyzed. Fresh minerals, a single component of oil, and different temperature/pressure conditions were set up to investigate the influencing factors of shale wettability. The studies show that Organic matter abundance and thermal maturity have a positive correlation with oil-wet. Siliceous minerals are positively correlated with water-wet. Carbonate and clay minerals are negatively correlated with water-wet. The mineralogical composition of the shale, the composition of the oil, the characteristics of the aqueous media, the asphaltene deposits on the surface, temperature, and pressure all impact wettability. The affinity of minerals for hydrocarbons is iron minerals > carbonate minerals > clay minerals > siliceous minerals. Minerals are more hydrophilic at low salinity conditions. The deposition of non-hydrocarbons and asphaltenes renders the surface oleophilic. Increasing temperatures will reduce the hydrophilicity of the “oil-water-rock”.

Sensors ◽  
2021 ◽  
Vol 21 (21) ◽  
pp. 7236
Author(s):  
Lorenzo Lunelli ◽  
Martina Germanis ◽  
Lia Vanzetti ◽  
Roberta Tatti ◽  
Cristina Potrich ◽  
...  

Antibiotics are widely used to both prevent and treat bacterial diseases as well as promote animal growth. This massive use leads to the presence of residual antibiotics in food with severe consequences for human health. Limitations and regulations on the tolerated amount of antibiotics in food have been introduced and analytical methods have been developed. The bioanalytical methods usually employed to detect antibiotic residues, however, are time-consuming, expensive and laboratory-based. Novel methods with improved rapidity, portability and cost that are easy-to-use and sustainable are therefore highly desirable. In the attempt to fulfill this need, a microfluidic system was set up herein for the purification and pre-concentration of tetracyclines from raw milk selected as the case-study. The system includes a polymeric microfluidic chip containing magnetic beads loaded with copper to exploit the preferential interaction of tetracycline with divalent ions. The microfluidic system was demonstrated to efficiently pre-concentrate tetracycline, oxytetracycline and chlortetracycline with similar performances and efficiently purify tetracycline from raw milk without any pre-treatment. The simplified method described in this paper could be easily integrated in a compact and portable device for the in-field detection of tetracyclines, with the economic advantage of preventing food wastes and guaranteeing food safety.


1984 ◽  
Vol 19 (1) ◽  
pp. 27-36 ◽  
Author(s):  
Alena Mudroch

Abstract Surface sediment samples obtained at the offshore and nearshore area of Lake Erie were separated into eight different size fractions ranging from <2 µm to 250 µm. The concentration of major elements (Si, Al, Ca, Mg, K, Na, Fe, Mn and P), metals (Zn, Cu, Cr, Ni, V, Co and Pb) and organic matter was determined together with the mineralogical composition and morphology of the particles in each size fraction. The distribution of the metals in the offshore sediment was bimodal with the majority of the metals divided between the 63 to 250 um size fraction which also contained the highest concentration of organic matter (about 20%) and the <4 µm fraction containing up to 60% of clay minerals. However, the metals in the nearshore sediment were associated mainly with the clay minerals.


Processes ◽  
2021 ◽  
Vol 9 (6) ◽  
pp. 1026
Author(s):  
Javier Tejera ◽  
Antonio Gascó ◽  
Daphne Hermosilla ◽  
Víctor Alonso-Gomez ◽  
Carlos Negro ◽  
...  

The objective of this trial was to assess the application of UVA-LED technology as an alternative source of irradiation for photo-Fenton processes, aiming to reduce treatment costs and provide a feasible treatment for landfill leachate. An optimized combination of coagulation with ferric chloride followed by photo-Fenton treatment of landfill leachate was optimized. Three different radiation sources were tested, namely, two conventional high-pressure mercury-vapor immersion lamps (100 W and 450 W) and a custom-designed 8 W 365 nm UVA-LED lamp. The proposed treatment combination resulted in very efficient degradation of landfill leachate (COD removal = 90%). The coagulation pre-treatment removed about 70% of the COD and provided the necessary amount of iron for the subsequent photo-Fenton treatment, and it further favored this process by acidifying the solution to an optimum initial pH of 2.8. The 90% removal of color improved the penetration of radiation into the medium and by extension improved treatment efficiency. The faster the Fenton reactions were, as determined by the stoichiometric optimum set-up reaction condition of [H2O2]0/COD0 = 2.125, the better were the treatment results in terms of COD removal and biodegradability enhancement because the chances to scavenge oxidant agents were limited. The 100 W lamp was the least efficient one in terms of final effluent quality and operational cost figures. UVA-LED technology, assessed as the application of an 8 W 365 nm lamp, provided competitive results in terms of COD removal, biodegradability enhancement, and operational costs (35–55%) when compared to the performance of the 450 W conventional lamp.


Healthcare ◽  
2021 ◽  
Vol 9 (1) ◽  
pp. 49
Author(s):  
Wonjung Ryu ◽  
Hyerin Yang

The purpose of this study is to investigate the influencing factors of parental child abuse by North Korean refugees who are living in South Korea. In-depth interviews were conducted with five parents who escaped from North Korea. The study identified three categories of factors impacting child abuse: the weakening of family functions from past experiences before and after defection, the stress of adapting to the culture of an unfamiliar society, and low parenting self-efficacy. North Korean parents suffered from emotional and functional crises from past traumatic events and, at the same time, experienced additional acculturative stress as a “minority” after entering South Korea, even as they continued to deal with Maternal Parenting Stress. These complex factors have been shown to lead to child abuse in migrant societies. This study contemplated the context of child abuse through specific examples. The results could provide thoughtful insights into child abuse among migrants and refugee parents, and provide evidence-based intervention plans for its prevention.


2019 ◽  
Vol 11 (17) ◽  
pp. 4679
Author(s):  
Carina Anderson ◽  
Robert Passey ◽  
Jeremy De Valck ◽  
Rakibuzzaman Shah

This paper reports on a case study of the community group Zero Emissions Noosa, whose goal is for 100% renewable electricity in the Noosa Shire (Queensland, Australia) by 2026. Described within this paper are the processes used by Zero Emissions Noosa to set up their zero emissions plan, involving community engagement and the use of an external consultant. The external consultant was employed to produce a detailed report outlining how to successfully achieve zero emissions from electricity in the Noosa Shire by 2026. This paper explains how and why the community engagement process used to produce the report was just as important as the outcomes of the report itself. Modeling was undertaken, and both detailed and contextual information was provided. Inclusion of the community in developing the scenario parameters for the modeling had a number of benefits including establishing the context within which their actions would occur and focusing their efforts on options that were technically feasible, financially viable and within their capabilities to implement. This provided a focal point for the community in calling meetings and contacting stakeholders. Rather than prescribing a particular course of action, it also resulted in a toolbox of options, a range of possible solutions that is flexible enough to fit into whatever actions are preferred by the community. The approach and outcomes discussed in this paper should, therefore, be useful to other communities with similar carbon emission reduction goals.


2017 ◽  
Vol 45 (4) ◽  
pp. 407-413
Author(s):  
Allan Effa

In 2015 the Truth and Reconciliation Commission of Canada concluded a six-year process of listening to the stories of Canada’s First Nations, Inuit and Métis peoples. More than 6000 witnesses came forth to share their personal experiences in listening sessions set up all across the country. These stories primarily revolved around their experience of abuse and cultural genocide through more than 100 years of Residential Schools, which were operated in a cooperative effort between churches and the government of Canada. The Commission’s Final Report includes 94 calls to action with paragraph #60 directed specifically to seminaries. This paper is a case study of how Taylor Seminary, in Edmonton, is seeking to engage with this directive. It explores the changes made in the curriculum, particularly in the teaching of missiology, and highlights some of the ways the seminary community is learning about aboriginal spirituality and the history and legacy of the missionary methods that have created conflict and pain in Canadian society.


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