scholarly journals Permeability Evaluation of Clay-quartz Mixtures Based on Low-Field NMR and Fractal Analysis

2020 ◽  
Vol 10 (5) ◽  
pp. 1585 ◽  
Author(s):  
Zhen Lu ◽  
Aimin Sha ◽  
Wentong Wang
Keyword(s):  
Prediction Model ◽  
Decay Rate ◽  
Fractal Analysis ◽  
Bound Water ◽  
Free Water ◽  
Evaporation Process ◽  
Permeability Coefficients ◽  
Constant Rate ◽  
Saturated Mixture ◽  
Two Stages

Nuclear magnetic resonance (NMR) technology has been widely used for predicting permeability coefficients of porous medium, such as shales, sandstones, and coals. However, there have been limited studies on the prediction model of clay-quartz mixtures based on NMR technology. In this study, evaporation tests at 40 °C and NMR tests were simultaneously performed on eight clay-quartz mixtures with different mineral compositions. The results show that during the evaporation process, the decay rate of T2 total signal amplitudes was constant at first, and then decreased to 0 after a period of time. Based on the decay rate, the evaporation process was divided into two stages: the constant rate stage and the falling rate stage. Based on the two stages, the T2 cut-offs of eight mixtures were determined. The water in the mixture was divided into two parts by the T2 cut-off: the free water and the bound water. The prediction model of permeability coefficients of clay-quartz mixtures was established based on the Timur-Coates model. In order to simplify the process of predicting the permeability coefficient, fractal analysis was used to develop the relationship between the T2 cut-off and fractal dimension of the T2 spectrum of saturated mixture. A simplified method for predicting permeability coefficients of clay-quartz mixtures based on NMR technology without centrifugal and evaporation experiments was also proposed.

Determine the Moisture Distribution in Sewage Sludge by Drying Differential

2014 ◽  
Vol 665 ◽  
pp. 404-407 ◽  
Author(s):  
Wan Yu ◽  
Pei Sheng Li
Keyword(s):  
Sewage Sludge ◽  
Interstitial Water ◽  
Bound Water ◽  
Free Water ◽  
High Accuracy ◽  
Moisture Distribution ◽  
Municipal Sewage ◽  
Municipal Sewage Sludge ◽  
Hot Air ◽  
Critical Water Content

Moisture distribution in sewage sludge was considered as the essential of thermal drying. Some methods were given in literatures to test the moisture distribution, but there was no standard method to determine the critical water content between different kinds of water. The municipal sewage sludge was dried by hot air in this work. Based on the drying curve, the derivative of drying rate with respect to dry basis moisture content was brought out to analyze the moisture distribution in sewage sludge. Results show that this method can easily determine the free water, interstitial water, surface water and bound water with a high accuracy. The present work can provide new insight to determine the moisture distribution in sewage sludge, which was still lacking in the literatures.

scholarly journals Testing the effects of basic numerical implementations of water migration on models of subduction dynamics

Solid Earth ◽  
2014 ◽  
Vol 5 (1) ◽  
pp. 537-555 ◽  
Author(s):  
M. E. T. Quinquis ◽  
S. J. H. Buiter
Keyword(s):  
Upper Mantle ◽  
Water Distribution ◽  
Mantle Wedge ◽  
Bound Water ◽  
Free Water ◽  
Water Velocity ◽  
Water Migration ◽  
Creep Flow ◽  
Dehydration Reactions ◽  
Slab Dehydration

Abstract. Subduction of oceanic lithosphere brings water into the Earth's upper mantle. Previous numerical studies have shown how slab dehydration and mantle hydration can impact the dynamics of a subduction system by allowing a more vigorous mantle flow and promoting localisation of deformation in the lithosphere and mantle. The depths at which dehydration reactions occur in the hydrated portions of the slab are well constrained in these models by thermodynamic calculations. However, computational models use different numerical schemes to simulate the migration of free water. We aim to show the influence of the numerical scheme of free water migration on the dynamics of the upper mantle and more specifically the mantle wedge. We investigate the following three simple migration schemes with a finite-element model: (1) element-wise vertical migration of free water, occurring independent of the flow of the solid phase; (2) an imposed vertical free water velocity; and (3) a Darcy velocity, where the free water velocity is a function of the pressure gradient caused by the difference in density between water and the surrounding rocks. In addition, the flow of the solid material field also moves the free water in the imposed vertical velocity and Darcy schemes. We first test the influence of the water migration scheme using a simple model that simulates the sinking of a cold, hydrated cylinder into a dry, warm mantle. We find that the free water migration scheme has only a limited impact on the water distribution after 1 Myr in these models. We next investigate slab dehydration and mantle hydration with a thermomechanical subduction model that includes brittle behaviour and viscous water-dependent creep flow laws. Our models demonstrate that the bound water distribution is not greatly influenced by the water migration scheme whereas the free water distribution is. We find that a bound water-dependent creep flow law results in a broader area of hydration in the mantle wedge, which feeds back to the dynamics of the system by the associated weakening. This finding underlines the importance of using dynamic time evolution models to investigate the effects of (de)hydration. We also show that hydrated material can be transported down to the base of the upper mantle at 670 km. Although (de)hydration processes influence subduction dynamics, we find that the exact numerical implementation of free water migration is not important in the basic schemes we investigated. A simple implementation of water migration could be sufficient for a first-order impression of the effects of water for studies that focus on large-scale features of subduction dynamics.

Characterization of thin water layers in pulp by tritium exchange. Part 1: Methods development

Holzforschung ◽  
2007 ◽  
Vol 61 (2) ◽  
pp. 115-119 ◽  
Author(s):  
Frances L. Walsh ◽  
Sujit Banerjee
Keyword(s):  
Water Content ◽  
Surface Area ◽  
Tritiated Water ◽  
Bound Water ◽  
Free Water ◽  
Fiber Surface ◽  
Bulk Water ◽  
Methods Development ◽  
A Value ◽  
A New Technique

Abstract A new technique for measuring the monolayer water content of fiber is presented. Tritiated water is added to a pulp/water suspension, whereupon the tritium partitions between the bulk water and the pulp. In the pulp phase the tritium can exchange with free water, bound water, and with hydroxyl and other protons present in the pulp matrix. The free water in the pulp is then removed by displacement with acetone. The tritium remaining in the pulp is mostly associated with tightly bound water, with a small fraction being tied up with the exchangeable hydrogen in pulp. The procedure provides a value of 10% for the tightly bound water content of hardwood or softwood fiber, either bleached or unbleached. If this water is assumed to cover the fiber surface as a monolayer, then an estimate of the wet surface area of the fiber can be obtained. This estimate compares well with independent measurements of surface area.

scholarly journals Water Adsorption to Leaves of Tall Cryptomeria japonica Tree Analyzed by Infrared Spectroscopy under Relative Humidity Control

Plants ◽  
2020 ◽  
Vol 9 (9) ◽  
pp. 1107
Author(s):  
Wakana A. Azuma ◽  
Satoru Nakashima ◽  
Eri Yamakita ◽  
Tamihisa Ohta
Keyword(s):  
Hydrogen Bonding ◽  
Relative Humidity ◽  
Cryptomeria Japonica ◽  
Water Adsorption ◽  
Bound Water ◽  
Free Water ◽  
High Water ◽  
Water Molecules ◽  
Cross Sectional ◽  
Tissue Properties

Leaf water storage is a complex interaction between live tissue properties (anatomy and physiology) and physicochemical properties of biomolecules and water. How leaves adsorb water molecules based on interactions between biomolecules and water, including hydrogen bonding, challenges our understanding of hydraulic acclimation in tall trees where leaves are exposed to more water stress. Here, we used infrared (IR) microspectroscopy with changing relative humidity (RH) on leaves of tall Cryptomeria japonica trees. OH band areas correlating with water content were larger for treetop (52 m) than for lower-crown (19 m) leaves, regardless of relative humidity (RH). This high water adsorption in treetop leaves was not explained by polysaccharides such as Ca-bridged pectin, but could be attributed to the greater cross-sectional area of the transfusion tissue. In both treetop and lower-crown leaves, the band areas of long (free water: around 3550 cm−1) and short (bound water: around 3200 cm−1) hydrogen bonding OH components showed similar increases with increasing RH, while the band area of free water was larger at the treetop leaves regardless of RH. Free water molecules with longer H bonds were considered to be adsorbed loosely to hydrophobic CH surfaces of polysaccharides in the leaf-cross sections.

Swelling Behaviors and Water States of Fibrous Membranes Electrospun from PHBV-g-PVP

2012 ◽  
Vol 482-484 ◽  
pp. 1478-1482
Author(s):  
Wei Wang ◽  
Jian Da Cao ◽  
Ping Lan
Keyword(s):  
Water Absorption ◽  
Fiber Diameter ◽  
Bound Water ◽  
Free Water ◽  
Great Capacity ◽  
Electrospun Membranes ◽  
Dsc Characterization ◽  
Fibrous Membranes ◽  
Water Swelling ◽  
Swelling Behaviors

Fibrous membranes with a fiber diameter between 320 and 460 nm were electrospun from poly(3-hydroxybutyrate-co-3-hydroxyvalerate)-graft-poly(N-vinylpyrrolidone) (PHBV-g-PVP) and their specific water absorption behaviors were investigated for biomaterial purposes. Water swelling experiments indicate that all samples have a great capacity for water uptake, while a remarkable overshoot occurs for the membranes electrospun from PHBV-g-PVP other than those from PHBV. DSC characterization indicates that only non-freezable bound water and free water can be distinguished in all electrospun membranes.

Water migration in poplar wood during microwave drying studied by time domain nuclear magnetic resonance (TD-NMR)

Holzforschung ◽  
2017 ◽  
Vol 71 (11) ◽  
pp. 881-887 ◽  
Author(s):  
Xinyu Li ◽  
Yulei Gao ◽  
Minghui Zhang ◽  
Ximing Wang ◽  
Xinyue Wei
Keyword(s):  
Nuclear Magnetic Resonance ◽  
Magnetic Resonance ◽  
Time Domain ◽  
Bound Water ◽  
Free Water ◽  
Microwave Drying ◽  
Drying Rate ◽  
Drying Time ◽  
The Time Domain ◽  
Nuclear Magnetic

AbstractThe migration of bound water and free water has been investigated during microwave drying of wood by the time domain nuclear magnetic resonance (TD-NMR) technique. Both the heartwood (hW) and sapwood (sW) of Beijing poplar (Populus beijingensisW. Y. Hsu) and Qingpi poplar (Populus platyphyllaT. Y. Sun) were studied. The microwave drying is characterized by a fast drying rate, and there is a linear relation between moisture content (MC) and microwave drying time (t). The drying rate of free water is about 2.7 times more rapid than that of bound water. The spin-spin relaxation time (T2) revealed that most of the water was free water situated in smaller pores. The irregular T2 signal amplitudes of free water in hWs indicated that fractional water in smaller pores was transferred into bigger pores during drying.

Prediction of mobile water in a tight gas sandstone reservoir using NMR and fractional flow model

2014 ◽  
Vol 54 (2) ◽  
pp. 1
Author(s):  
Maria Anantawati ◽  
Suryakant Bulgauda
Keyword(s):  
Steady State ◽  
Relative Permeability ◽  
Flow Model ◽  
Bound Water ◽  
Free Water ◽  
Development Project ◽  
Asia Pacific ◽  
Fractional Flow ◽  
Reservoir Properties ◽  
Mobile Water

One of the objectives of petrophysical interpretation is the estimation of the respective volumes of formation fluids. With traditional interpretation using conventional openhole logs it is only possible to determine the total amount of water. The challenge is to determine the volumes of bound water (clay-bound and capillary-bound) and free water. At the moment, NMR is the only measurement that can help distinguish the volumes of each water component (clay-bound, capillary-bound and mobile), using cut-offs on T2 (transverse relaxation time). However NMR interpretation also requires information on reservoir properties. Alternatively, steady-state relative permeability and fractional flow of water can be used to determine the potential of mobile water. The study area, located in the Cooper Basin, South Australia, is the target of a planned gas development project in the Patchawarra formation. It comprises multiple stacked fluvial sands which are heterogeneous, tight and of low deliverability. The sands are completed with multi-stage pin-point fracturing as a key enabling technology for the area. A comprehensive set of data, including conventional logs, cores and NMR logs, were acquired. Routine and special core analysis were performed, including NMR, electrical properties, centrifuge capillary pressure, high-pressure mercury injection, and full curve steady state relative permeability. A fractional flow model was built based on core and NMR data to determine potential mobile water and the results compared with production logs. This paper (SPE 165766) was prepared for presentation at the SPE Asia Pacific Oil & Gas Conference and Exhibition, held in Jakarta, Indonesia, from 22–24 October 2013.

Bifurcation of Water Column Oscillator Behavior Simulating Reactor Safety System: 2nd Report, Analytical Model

2002 ◽  
Author(s):  
K. Kawamata ◽  
Y. Morimoto ◽  
Haruki Madarame ◽  
Koji Okamoto
Keyword(s):  
Water Column ◽  
Abrupt Change ◽  
Free Water ◽  
Reactor Safety ◽  
System Behavior ◽  
Analysis Model ◽  
Constant Rate ◽  
Gas System ◽  
Analytical Result ◽  
Closed Period

Behavior of a water column oscillator with a cover gas system was studied experimentally and analytically. One of the free water surfaces was sealed with the cover gas, while the other was open to the atmosphere. The cover gas was supplied with a constant rate, and it was ejected through a valve when the water level reached a certain point. As soon as the level reached another point, the valve closed and the cover gas quantity increased again. In the experiment, a bifurcation-like phenomenon was observed; the valve closed period usually had a single value, while it took two values under certain conditions. In order to examine the cause of this bifurcation-like phenomenon, a numerical analysis model was developed which described the system behavior precisely. The analytical result revealed that the bifurcation-like phenomenon was not bifurcation but an abrupt change of the value dimmed by superimposed noise. Finally the numerical model predicts that the water column oscillator behaves chaotically at certain conditions.

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