scholarly journals Optical Characterization of Homogeneous and Heterogeneous Intralipid-Based Samples

2020 ◽  
Vol 10 (18) ◽  
pp. 6234
Author(s):  
Ines Delfino ◽  
Maria Lepore ◽  
Rosario Esposito
Keyword(s):  
Optical Properties ◽  
Light Scattering ◽  
Scattered Light ◽  
Industrial Applications ◽  
Point Of View ◽  
Turbid Media ◽  
Time Resolved ◽  
Propagation Of Light ◽  
First Time

Different scattering processes take place when photons propagate inside turbid media. Many powerful experimental techniques exploiting these processes have been developed and applied over the years in a large variety of situations from fundamental and applied research to industrial applications. In the present paper, we intend to take advantage of Static Light Scattering (SLS), Dynamic Light Scattering (DLS), and Time-Resolved Transmittance (TRT) for investigating all the different scattering regimes by using scattering suspensions in a very large range of scatterer concentrations. The suspensions were prepared using Intralipid 20%, a material largely employed in studies of the optical properties of turbid media, with concentrations from 10−5% to 50%. By the analysis of the angular and temporal dependence of the scattered light, a more reliable description of the scattering process occurring in these samples can be obtained. TRT measurements allowed us to obtain information on the reduced scattering coefficient, an important parameter largely used in the description of the optical properties of turbid media. TRT was also employed for the detection of inclusions embedded in Intralipid suspensions, by using a properly designed data analysis. The present study allowed us to better elucidate the dependence of scattering properties of Intralipid suspensions in a very large concentration range and the occurrence of the different scattering processes involved in the propagation of light in turbid media for the first time to our knowledge. In so doing, the complementary contribution of SLS, DLS, and TRT in the characterization of turbid media from an optical and structural point of view is strongly evidenced.

A Time-Resolved Low-Angle Light Scattering Apparatus. Application to Phase Separation Problems in Polymer Systems

2001 ◽  
Vol 66 (6) ◽  
pp. 973-982 ◽  
Author(s):  
Čestmír Koňák ◽  
Jaroslav Holoubek ◽  
Petr Štěpánek
Keyword(s):  
Phase Separation ◽  
Light Scattering ◽  
Signal To Noise Ratio ◽  
Scattered Light ◽  
Ccd Camera ◽  
Time Resolved ◽  
Polymer Systems ◽  
Software Analysis ◽  
Phase Separation Kinetics ◽  
Small Angle Light Scattering

A time-resolved small-angle light scattering apparatus equipped with azimuthal integration by means of a conical lens or software analysis of scattering patterns detected with a CCD camera was developed. Averaging allows a significant reduction of the signal-to-noise ratio of scattered light and makes this technique suitable for investigation of phase separation kinetics. Examples of applications to time evolution of phase separation in concentrated statistical copolymer solutions and dissolution of phase-separated domains in polymer blends are given.

scholarly journals Light-Scattering Simulations from Spherical Bimetallic Core–Shell Nanoparticles

Micromachines ◽  
2021 ◽  
Vol 12 (4) ◽  
pp. 359
Author(s):  
Francesco Ruffino
Keyword(s):  
Optical Properties ◽  
Light Scattering ◽  
Bimetallic Nanoparticles ◽  
Dominant Role ◽  
Scattered Light ◽  
Specific Interaction ◽  
Surface Enhanced Raman Spectroscopy ◽  
Localized Surface Plasmon ◽  
Core Shell ◽  
The Core

Bimetallic nanoparticles show novel electronic, optical, catalytic or photocatalytic properties different from those of monometallic nanoparticles and arising from the combination of the properties related to the presence of two individual metals but also from the synergy between the two metals. In this regard, bimetallic nanoparticles find applications in several technological areas ranging from energy production and storage to sensing. Often, these applications are based on optical properties of the bimetallic nanoparticles, for example, in plasmonic solar cells or in surface-enhanced Raman spectroscopy-based sensors. Hence, in these applications, the specific interaction between the bimetallic nanoparticles and the electromagnetic radiation plays the dominant role: properties as localized surface plasmon resonances and light-scattering efficiency are determined by the structure and shape of the bimetallic nanoparticles. In particular, for example, concerning core-shell bimetallic nanoparticles, the optical properties are strongly affected by the core/shell sizes ratio. On the basis of these considerations, in the present work, the Mie theory is used to analyze the light-scattering properties of bimetallic core–shell spherical nanoparticles (Au/Ag, AuPd, AuPt, CuAg, PdPt). By changing the core and shell sizes, calculations of the intensity of scattered light from these nanoparticles are reported in polar diagrams, and a comparison between the resulting scattering efficiencies is carried out so as to set a general framework useful to design light-scattering-based devices for desired applications.

scholarly journals Time-Resolved Reflectance Spectroscopy Applied to the Nondestructive Monitoring of the Internal Optical Properties in Apples

2001 ◽  
Vol 55 (10) ◽  
pp. 1368-1374 ◽  
Author(s):  
Rinaldo Cubeddu ◽  
Cosimo D'Andrea ◽  
Antonio Pifferi ◽  
Paola Taroni ◽  
Alessandro Torricelli ◽  
...  
Keyword(s):  
Optical Properties ◽  
Industrial Applications ◽  
Nondestructive Monitoring ◽  
Nondestructive Measurement ◽  
Time Resolved ◽  
Mean Values ◽  
Scattering Coefficients ◽  
Scattering Spectra ◽  
The Mean ◽  
Temporal Dispersion

Time-resolved reflectance has been used for the nondestructive measurement of optical properties in apples. The technique is based on the detection of the temporal dispersion of a short laser pulse injected into the probed medium. The time distribution of re-emitted photons interpreted with a solution of the diffusion equation yields the mean values of the absorption and reduced scattering coefficients of the medium. The proposed technique proved useful for the measurement of the absorption and scattering spectra of different varieties of apples, revealing the spectral shape of chlorophyll. No major variations were observed in the experimental data when the fruit was peeled, showing that the optical properties measured were those of the pulp. With this technique the change in chlorophyll absorption during storage and ripening could be followed. Finally, a compact prototype working at few selected wavelengths was designed and constructed, demonstrating potentialities of the technique for industrial applications.

scholarly journals Detection Limits of DLS and UV-Vis Spectroscopy in Characterization of Polydisperse Nanoparticles Colloids

2013 ◽  
Vol 2013 ◽  
pp. 1-10 ◽  
Author(s):  
Emilia Tomaszewska ◽  
Katarzyna Soliwoda ◽  
Kinga Kadziola ◽  
Beata Tkacz-Szczesna ◽  
Grzegorz Celichowski ◽  
...  
Keyword(s):  
Light Scattering ◽  
Dynamic Light Scattering ◽  
Point Of View ◽  
Spectroscopy Analysis ◽  
Force Microscopy ◽  
Atomic Force ◽  
Transmission Electron ◽  
Vis Spectroscopy ◽  
The One

Dynamic light scattering is a method that depends on the interaction of light with particles. This method can be used for measurements of narrow particle size distributions especially in the range of 2–500 nm. Sample polydispersity can distort the results, and we could not see the real populations of particles because big particles presented in the sample can screen smaller ones. Although the theory and mathematical basics of DLS technique are already well known, little has been done to determine its limits experimentally. The size and size distribution of artificially prepared polydisperse silver nanoparticles (NPs) colloids were studied using dynamic light scattering (DLS) and ultraviolet-visible (UV-Vis) spectroscopy. Polydisperse colloids were prepared based on the mixture of chemically synthesized monodisperse colloids well characterized by atomic force microscopy (AFM), transmission electron microscopy (TEM), DLS, and UV-Vis spectroscopy. Analysis of the DLS results obtained for polydisperse colloids reveals that several percent of the volume content of bigger NPs could screen completely the presence of smaller ones. The presented results could be extremely important from nanoparticles metrology point of view and should help to understand experimental data especially for the one who works with DLS and/or UV-Vis only.

scholarly journals Characterization of Simple and Double Yeast Cells Using Dielectrophoretic Force Measurement

Sensors ◽  
2019 ◽  
Vol 19 (17) ◽  
pp. 3813 ◽  
Author(s):  
Fernando-Juan García-Diego ◽  
Mario Rubio-Chavarría ◽  
Pedro Beltrán ◽  
Francisco J. Espinós
Keyword(s):  
Electric Fields ◽  
Force Measurement ◽  
Point Of View ◽  
Yeast Cells ◽  
Instrumental Method ◽  
Particle Characterization ◽  
Dielectrophoretic Force ◽  
Cell Velocity ◽  
First Time

Dielectrophoretic force is an electric force experienced by particles subjected to non-uniform electric fields. In recent years, plenty of dielectrophoretic force (DEP) applications have been developed. Most of these works have been centered on particle positioning and manipulation. DEP particle characterization has been left in the background. Likewise, these characterizations have studied the electric properties of particles from a qualitative point of view. This article focuses on the quantitative measurement of cells’ dielectric force, specifically yeast cells. The measures are obtained as the results of a theoretical model and an instrumental method, both of which are developed and described in the present article, based on a dielectrophoretic chamber made of two V-shaped placed electrodes. In this study, 845 cells were measured. For each one, six speeds were taken at different points in its trajectory. Furthermore, the chamber design is repeatable, and this was the first time that measurements of dielectrophoretic force and cell velocity for double yeast cells were accomplished. To validate the results obtained in the present research, the results have been compared with the dielectric properties of yeast cells collected in the pre-existing literature.

scholarly journals Characterization of ceramics based on laser speckle photometry

2020 ◽  
Vol 9 (2) ◽  
pp. 345-354
Author(s):  
Lili Chen ◽  
Ulana Cikalova ◽  
Beatrice Bendjus ◽  
Stefan Muench ◽  
Mike Roellig
Keyword(s):  
Defect Detection ◽  
Industrial Applications ◽  
Laser Speckle ◽  
Stress Monitoring ◽  
Time Resolved ◽  
Safety Control ◽  
Ceramic Components ◽  
Speckle Patterns ◽  
Surface Defect Detection

Abstract. Advanced ceramic components are frequently used in industrial applications. As a brittle material, ceramic reacts very suddenly to excessively high stresses. Existing defects lead to rapid crack growth followed by spontaneous destruction. This leads to a functional failure of the entire component. It is therefore important to develop innovative techniques to ensure a good quality condition of ceramic products. Laser speckle photometry (LSP) is an optical nondestructive testing method. It is based on the dynamic analysis of time-resolved speckle patterns that are generated by an external excitation. In this paper, we will present two investigations on ceramic components using the LSP technique. One is the nondestructive stress characterization on ceramic surfaces, and the other is the defect detection on ceramics components. The aim is to improve the quality and safety control of ceramic production in the challenging industrial field. Preliminary results have shown the potential of the LSP sensor system for the nondestructive characterization of ceramics in terms of stress monitoring and surface defect detection.

scholarly journals Characterization of the ECN spray A in different facilities. Part 1: boundary conditions characterization

2020 ◽  
Vol 75 ◽  
pp. 35
Author(s):  
Moez Ben Houidi ◽  
Camille Hespel ◽  
Michele Bardi ◽  
Ob Nilaphai ◽  
Louis-Marie Malbec ◽  
...  
Keyword(s):  
Boundary Conditions ◽  
Internal Combustion Engines ◽  
Operating Mode ◽  
Wall Layer ◽  
Time Resolved ◽  
Order Of Magnitude ◽  
Experimental Facilities ◽  
Proper Estimation ◽  
First Time

The Engine Combustion Network (ECN) community has greatly contributed to improve the fundamental understanding of spray atomization and combustion at conditions relevant to internal combustion engines. In this context, standardized spray experiments have been defined to facilitate the comparison of experimental and simulation studies performed in different facilities and with different models. This operating mode promotes collaborations among research groups and accelerates the advancement of research on spray. In efforts to improve the comparability of the ECN spray A experiments, it is of high importance to review the boundary conditions of different devices used in the community. This work is issued from the collaboration in the ECN France project, where two new experimental facilities from PPRIME (Poitiers) and PRISME (Orleans) institutes are validated to perform spray A experiments. The two facilities, based on Rapid Compression Machine (RCM) design, have been investigated to characterize their boundary conditions (e.g., flow velocity as well as fuel and gas temperatures). A set of standardized spray experiments were performed to compare their results with those obtained in other facilities, in particular the Constant Volume Pre-burn (CVP) vessel at IFPEN. It is noteworthy that it is the first time that RCM type facilities are used in such a way within the ECN. This paper (part 1) focuses on the facilities description and the fine characterization of their boundary conditions. A further paper (part 2) will present the results obtained with the same facilities performing ECN standard spray A characterizations. The reported review of thermocouple thermometry highlights that it is necessary to use thin-wires and bare-bead junction as small as possible. This would help to measure the temperature fluctuations with a minimal need for error corrections, which are highly dependent on the proper estimation of the velocity through the junction, and therefore it may introduce important uncertainties. Temperature heterogeneities are observed in all spray A devices. The standard deviation of the temperature distribution at the time of injection is approximately 5%. We report time-resolved temperature measurement from PPRIME RCM, performed in the near nozzle area during the injection. In inert condition, colder gases from the boundary layer are entrained toward the mixing area of the spray causing a further deviation from the target temperature. This emphasizes the importance of the temperature in the boundary (wall) layer. In reacting condition, the temperature of these entrained gases increases by the effect of the increased pressure, as the RCM has a relatively small volume. Generally, the velocity and turbulence levels are an order of magnitude higher in RCM and constant pressure flow compared to CVP vessels. The boundary characterization presented here will be the base for discussing spray behavior in the part 2 of this paper.

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