scholarly journals Catalytic Technologies for Solving Environmental Problems in the Production of Fuels and Motor Transport in Kazakhstan

Catalysts ◽  
2020 ◽  
Vol 10 (10) ◽  
pp. 1197
Author(s):  
Alma Massenova ◽  
Maxat Kalykberdiyev ◽  
Alexandr Sass ◽  
Nail Kenzin ◽  
Abzal Ussenov ◽  
...  
Keyword(s):  
Combustion Engine ◽  
Hydrocarbon Composition ◽  
Exhaust Gas ◽  
Hydrocarbon Conversion ◽  
X Ray Diffraction ◽  
Motor Fuels ◽  
Co Conversion ◽  
Rh Catalyst ◽  
Catalytic Treatment ◽  
Toxic Components

This research is devoted to solving an environmental problem, cleaning of the Kazakhstan air basin, through treatment of auto-transport toxic exhaust by improving the hydrocarbon composition of motor fuels and neutralizing exhaust gas toxic components. The catalytic hydrodearomatization of gasoline fractions (from the reforming stage) of the Atyrau and Pavlodar Refineries and the neutralization of exhaust gas toxic components from an internal combustion engine (ICE) were studied. Two hydrotreated gasoline fractions were tested during ICE operation. The research shows that 100% benzene conversion is observed over Rh-Pt(9:1)/γ-Al2O3 catalysts; that is, benzene is completely removed from both fractions, and the aromatics content decreases from 56.24–58.12% to 21.29–21.89%, within the values of the Euro-5,6 standard. Catalytic treatment of fuels reduces fuel consumption of the ICE engine by 2–3% compared to the initial gasoline fractions, the CO content in the exhaust gases decreases by 6.6–16.2%, and the hydrocarbon content decreases by 7.8–24.7%. In order to neutralize the ICE exhaust gas toxic components, the catalyst 10% Co + 0.5% Pt/Al2O3 was used, with which the CO conversion reaches 100% and the hydrocarbon conversion 94.2% and 91.5% for both gasoline fractions. The catalysts were characterized by electron microscopy (EM), X-ray diffraction (XRD), Brunauer–Emmett–Teller (BET), thermoprogrammed desorption (TPD) and thermoprogrammed reduction (TPR) methods. It was shown by the TPD and EM methods that at the addition of Pt to the Rh-catalyst, the formation of mixed bimetallic Rh-Pt-agglomerates occurs, and hydrogen appears in the TPD spectrum, adsorbed in the form of a new single peak uncharacteristic for the Rh-catalyst. This leads to high activity and selectivity in the hydrogenation of benzene and aromatic compounds in the gasoline fractions. The XRD and TPR results show the formation of CoAl2O4 spinels, on which inactive oxygen is formed for the oxidation of CO and hydrocarbons. Modification of the catalyst by Pt and Mg prevents spinel formation, thereby increasing the activity of the catalysts.

scholarly journals Environmental effect of molecular degradation of internal combustion engine exhaust gases

2021 ◽  
pp. 31-35
Author(s):  
В.В. Мурамович ◽  
В.Ю. Каминский ◽  
С.Н. Турусов
Keyword(s):  
Power Plants ◽  
Internal Combustion Engines ◽  
Combustion Engine ◽  
Internal Combustion ◽  
Ecological Problem ◽  
Exhaust Gas ◽  
Combustion Engines ◽  
Exhaust Gases ◽  
Advantages And Disadvantages ◽  
Toxic Components

Рассматривается экологическая проблема очистки отработавших газов углеводородных энергетических установок от токсичных компонентов. Показан состав основных токсичных компонентов, приведены значения энергии связи их молекул. Представлены существующие методы улучшения экологических характеристик двигателей внутреннего сгорания: рециркуляция отработавших газов, снижение степени сжатия, уменьшение угла опережения впрыска, добавление присадок к топливу и др. Перечислены их достоинства и недостатки. Предлагается новый метод – использование электромагнитных полей для очистки отработавших газов от токсичных компонентов. Выполнен оценочный расчет его эффективности. Показано, что применение устройств модификации в топливной системе двигателей внутреннего сгорания, а также в системе выпуска отработавших газов позволяет существенно снизить выбросы в окружающую среду вредных веществ, и, при этом, не требует принципиальных изменений в конструкции двигателей. Рабочий ресурс предлагаемых устройств электромагнитной обработки обусловлен применяемыми для их изготовления материалами. The ecological problem of cleaning the exhaust gases of hydrocarbon power plants from toxic components is considered. The composition of the main toxic components is shown; the values of the binding energy of their molecules are given. The existing methods of improving the environmental characteristics of internal combustion engines are presented: exhaust gas recirculation, reduction of the compression ratio, reduction of the injection advance angle, addition of fuel additives, etc. Their advantages and disadvantages are listed. A new method is proposed – the use of electromagnetic fields for cleaning exhaust gases from toxic components. An estimated calculation of its effectiveness is performed. It is shown that the use of modification devices in the fuel system of internal combustion engines, as well as in the exhaust gas system, can significantly reduce emissions of harmful substances into the environment, and, at the same time, does not require fundamental changes in the design of engines. The materials used for their manufacture determine the working life of the proposed electromagnetic processing devices.

DEVELOPMENT OF THE COMBUSTION CHAMBER OF GAS ENGINE, CONVERTED ON THE BASIS OF DIESELS D-120 OR D-144 ENGINES TO WORK FOR ON LIQUEFIED PETROLEUM GAS

2019 ◽  
pp. 2-8
Author(s):  
Serhii Kovalov
Keyword(s):  
Combustion Chamber ◽  
Compression Ratio ◽  
Diesel Engines ◽  
Combustion Engine ◽  
Motor Fuel ◽  
Liquefied Petroleum Gas ◽  
Gas Engine ◽  
Chamber Volume ◽  
Motor Fuels ◽  
Dynamic Cycle

The expediency of using vehicles of liquefied petroleum gas as a motor fuel, as com-pared with traditional liquid motor fuels, in particular with diesel fuel, is shown. The advantages of converting diesel engines into gas ICEs with forced ignition with respect to conversion into gas diesel engines are substantiated. The analysis of methods for reducing the compression ratio in diesel engines when converting them into gas ICEs with forced ignition has been carried out. It is shown that for converting diesel engines into gas ICEs with forced ignition, it is advisable to use the Otto thermo-dynamic cycle with a decrease in the geometric degree of compression. The choice is grounded and an open combustion chamber in the form of an inverted axisymmetric “truncated cone” is developed. The proposed shape of the combustion chamber of a gas internal combustion engine for operation in the LPG reduces the geometric compression ratio of D-120 and D-144 diesel engines with an unseparated spherical combustion chamber, which reduces the geometric compression ratio from ε = 16,5 to ε = 9,4. The developed form of the combustion chamber allows the new diesel pistons or diesel pistons which are in operation to be in operation to be refined, instead of making special new gas pistons and to reduce the geometric compression ratio of diesel engines only by increasing the combustion chamber volume in the piston. This method of reducing the geometric degree of compression using conventional lathes is the most technologically advanced and cheap, as well as the least time consuming. Keywords: self-propelled chassis SSh-2540, wheeled tractors, diesel engines D-120 and D-144, gas engine with forced ignition, liquefied petroleum gas (LPG), compression ratio of the internal com-bustion engine, vehicles operating in the LPG.

Research on Transmitting Efficiency of Supercharged Device

2011 ◽  
Vol 63-64 ◽  
pp. 237-240
Author(s):  
Qi Xin Sun ◽  
Limin Chen
Keyword(s):  
Diesel Engine ◽  
Environmental Performance ◽  
Combustion Engine ◽  
Exhaust Gas ◽  
Analysis Model ◽  
Turbocharged Diesel Engine ◽  
Technological Advances ◽  
Turbocharging System ◽  
Light Vehicle ◽  
Gas Supply

In recent years, the internal combustion engine has been widely used through technological advances to improve its environmental performance. Mechanical and electrical integration of the engine turbocharging system is based on conventional turbocharging system to increase motor in parallel with the turbocharger and the corresponding reversible energy storage components, so that achieve by adjusting the energy input or output direction and the size of the motor to adjust the exhaust turbocharger operating point and the gas supply function. According to matching requirements of light vehicle diesel engine, the analysis model of exhaust gas energy is obtained through qualitative analysis of exhaust gas energy in turbocharged diesel engine.

Different Configurations of Exhaust Gas Heat Recovery in Internal Combustion Engine: Evaluation on Different Driving Cycles Using Numerical Simulations

2018 ◽  
Vol 10 (4) ◽  
Author(s):  
Hanna Sara ◽  
David Chalet ◽  
Mickaël Cormerais
Keyword(s):  
Numerical Simulations ◽  
Fuel Consumption ◽  
Heat Recovery ◽  
Combustion Engine ◽  
Management Strategies ◽  
Driving Cycle ◽  
Maximum Temperature ◽  
Exhaust Gas ◽  
Direct Heating ◽  
Driving Cycles

Exhaust gas heat recovery is one of the interesting thermal management strategies that aim to improve the cold start of the engine and thus reduce its fuel consumption. In this work, an overview of the heat exchanger used as well as the experimental setup and the different tests will be presented first. Then numerical simulations were run to assess and valorize the exhaust gas heat recovery strategy. The application was divided into three parts: an indirect heating of the oil with the coolant as a medium fluid, a direct heating of the oil, and direct heating of the oil and the coolant. Different ideas were tested over five different driving cycles: New European driving cycle (NEDC), worldwide harmonized light duty driving test cycle (WLTC), common Artemis driving cycle (CADC) (urban and highway), and one in-house developed cycle. The simulations were performed over two ambient temperatures. Different configurations were proposed to control the engine's lubricant maximum temperature. Results concerning the temperature profiles as well as the assessment of fuel consumption were stated for each case.

scholarly journals Energy Harvesting Technology for turbocompounding automotive engines with waste-gate valve

2019 ◽  
Vol 113 ◽  
pp. 03020
Author(s):  
Vittorio Usai ◽  
Silvia Marelli ◽  
Avinash Renuke ◽  
Alberto Traverso
Keyword(s):  
Fuel Consumption ◽  
Environmental Protection Agency ◽  
Gate Valve ◽  
Combustion Engine ◽  
Power Level ◽  
Electrical Power ◽  
Residual Energy ◽  
Exhaust Gas ◽  
Passenger Cars ◽  
Automotive Engines

The reduction of CO2 and, more generally, GHG (Green House Gases) emissions imposed by the European Commission (EC) and the Environmental Protection Agency (EPA) for passenger cars has driven the automotive industry to develop technological solutions to limit exhaust emissions and fuel consumption, without compromising vehicle performance and drivability. In a mid-term scenario, hybrid powertrain and Internal Combustion Engine (ICE) downsizing represent the present trend in vehicle technology to reduce fuel consumption and CO2 emissions. Concerning downsizing concept, to maintain a reasonable power level in small engines, the application of turbocharging is mandatory for both Spark Ignition (SI) and Diesel engines. Following this aspect, the possibility to recover the residual energy of the exhaust gases is becoming more and more attractive, as demonstrated by several studies around the world. One method to recover exhaust gas energy from ICEs is the adoption of turbo-compounding technology to recover sensible energy left in the exhaust gas by-passed through the waste-gate valve. In the paper, an innovative option of advanced boosting system is investigated through a bladeless micro expander, promising attractive cost-competitiveness. The numerical activity was developed on the basis of experimental data measured on a waste-gated turbocharger for downsized SI automotive engines. To this aim, mass flow rate through the by-pass valve and the turbine impeller was measured for different waste-gate settings in steady-state conditions at the turbocharger test bench of the University of Genoa. The paper shows that significant electrical power can be harvested from the waste-gate gases, up to 94 % of compressor power, contributing to fuel consumption reduction.

Design of a Flow Reactor for Testing Multi-Brick Catalyst Systems Using Rapid Exhaust Gas Composition Switches

2009 ◽  
Author(s):  
Stefan Klinkert ◽  
John W. Hoard ◽  
Sakthish R. Sathasivam ◽  
Dennis N. Assanis ◽  
Stanislav V. Bohac
Keyword(s):  
Flow Reactor ◽  
Combustion Engine ◽  
Synergistic Effects ◽  
Control Program ◽  
Exhaust Gas ◽  
Gas Composition ◽  
Lean Burn ◽  
Exhaust Gas Aftertreatment ◽  
Scr Catalysts ◽  
Catalyst Systems

In recent years, diesel exhaust gas aftertreatment has become a core combustion engine research subject because of both increasingly stringent emission regulations and incentives toward more fuel-efficient propulsion systems. Lean NOX traps (LNT) and selective catalytic reduction (SCR) catalysts represent two viable pathways for the challenging part of exhaust gas aftertreatment of lean burn engines: NOX abatement. It has been found that the combination of LNT and SCR catalysts can yield synergistic effects. Switches in the operation mode of the engine, temporarily enriching the mixture, are required to regenerate the LNT catalyst and produce ammonia for the SCR. This paper describes the design of a catalyst flow reactor that allows studying multi-brick catalyst systems using rapid exhaust gas composition switches and its initial validation. The flow reactor was designed primarily to study the potential of combining different aftertreatment components. It can accommodate two sample bricks at a time in two tube furnaces, which allows for independent temperature control. Moreover, the flow reactor allows for very flexible control of the composition and flow rate of the synthetic exhaust, which is blended using mass flow controllers. By using a two-branch design, very fast switches between two exhaust gas streams, as seen during the regeneration process of a LNT catalyst, are possible. The flow reactor utilizes a variety of gas analyzers, including a 5-Hz FTIR spectrometer, an emissions bench for oxygen and THC, a hydrogen mass spectrometer, and gas chromatographs for HC speciation. An in-house control program allows for data recording, flow reactor control, and highly flexible automation. Additionally, the hardware and software incorporate features to ensure safe testing. The design also has provisions for engine exhaust sampling.

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