scholarly journals Halloysite Nanoclay with High Content of Sulfonic Acid-Based Ionic Liquid: A Novel Catalyst for the Synthesis of Tetrahydrobenzo[b]pyrans

Catalysts ◽  
2021 ◽  
Vol 11 (10) ◽  
pp. 1172
Author(s):  
Samahe Sadjadi ◽  
Fatemeh Koohestani ◽  
Neda Abedian-Dehaghani ◽  
Majid M. Heravi
Keyword(s):  
Ionic Liquid ◽  
Ionic Liquids ◽  
Sulfonic Acid ◽  
High Performance ◽  
Acid Catalyst ◽  
One Pot ◽  
Heterocyclic Ligand ◽  
Novel Catalyst ◽  
Supported Ionic Liquids ◽  
Low Activity

One of the main drawbacks of supported ionic liquids is their low loading and consequently, low activity of the resultant catalysts. To furnish a solution to this issue, a novel heterocyclic ligand with multi imine sites was introduced on the surface of amino-functionalized halloysite support via successive reactions with 2,4,6-trichloro-1,3,5-triazine and 2-aminopyrimidine. Subsequently, the imine sites were transformed to sulfonic acid-based ionic liquids via reaction with 1,4-butanesultone. Using this strategy, high loading of ionic liquid was loaded on halloysite nanoclay. The supported ionic liquid was then characterized with XRD, SEM, TEM, EDS, FTIR, BET, TGA and elemental mapping analysis and utilized as a metal-free Brønsted acid catalyst for promoting one-pot reaction of aldehydes, dimedone and malononitrile to furnish tetrahydrobenzo[b]pyrans. The catalytic tests confirmed high performance of the catalyst. Moreover, the catalyst was stable upon recycling.

scholarly journals Synthesis of tetrazolo[1,5-a]pyrimidine-6-carbonitriles using HMTA-BAIL@MIL-101(Cr) as a superior heterogeneous catalyst

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Mohammad Hossein Abdollahi-Basir ◽  
Boshra Mirhosseini-Eshkevari ◽  
Farzad Zamani ◽  
Mohammad Ali Ghasemzadeh
Keyword(s):  
Ionic Liquid ◽  
Catalytic Activity ◽  
Reaction Time ◽  
Metal Organic Framework ◽  
One Pot ◽  
Short Reaction Time ◽  
Three Component Reaction ◽  
Metal Organic ◽  
Ft Ir ◽  
Novel Catalyst

AbstractA one-pot three component reaction of benzaldehydes, 1H-tetrazole-5-amine, and 3-cyanoacetyl indole in the presence of a new hexamethylenetetramine-based ionic liquid/MIL-101(Cr) metal–organic framework as a recyclable catalyst was explored. This novel catalyst, which was fully characterized by XRD, FE-SEM, EDX, FT-IR, TGA, BET, and TEM exhibited outstanding catalytic activity for the preparation of a range of pharmaceutically important tetrazolo[1,5-a]pyrimidine-6-carbonitriles with good to excellent yields in short reaction time.

scholarly journals Enhanced visible light photocatalytic activity of BiOBr by in situ reactable ionic liquid modification for pollutant degradation

RSC Advances ◽  
2018 ◽  
Vol 8 (15) ◽  
pp. 7956-7962 ◽  
Author(s):  
Zhidong Wei ◽  
Ruishuo Li ◽  
Rui Wang
Keyword(s):  
Ionic Liquid ◽  
Photocatalytic Activity ◽  
Ionic Liquids ◽  
Visible Light ◽  
Solvothermal Method ◽  
Pollutant Degradation ◽  
One Pot ◽  
Visible Light Photocatalytic Activity ◽  
Visible Light Photocatalytic

In this study, hierarchical BiOBr microspheres were synthesized via a one-pot solvothermal method in the presence of imidazole ionic liquids.

scholarly journals Ionic-liquid-assisted one-pot synthesis of Cu2O nanoparticles/multi-walled carbon nanotube nanocomposite for high-performance asymmetric supercapacitors

RSC Advances ◽  
2018 ◽  
Vol 8 (36) ◽  
pp. 20182-20189 ◽  
Author(s):  
Ying Lu ◽  
Jian-Long Xu ◽  
Shan Ren ◽  
Ya-Nan Zhong ◽  
Xu Gao ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Carbon Nanotube ◽  
High Performance ◽  
Room Temperature ◽  
Synergistic Effects ◽  
Asymmetric Supercapacitors ◽  
One Pot ◽  
Multi Walled Carbon Nanotube ◽  
Cu2o Nanoparticles ◽  
Cycling Life

A one-pot room-temperature-ionic-liquid-assisted sputtering approach is designed to synthesize Cu2O/MWCNTs nanocomposite with high capacitance and long cycling life due to synergistic effects of oxygen-deficient Cu2O and conductive MWCNTs.

scholarly journals Microwave Assisted One Pot Synthesis of 3,4-Dihydropyrano[c]chromene Derivatives using [Emim]OH Ionic Liquid as Novel Catalyst

2019 ◽  
Vol 31 (4) ◽  
pp. 829-833
Author(s):  
D.S. Bhagat ◽  
S.G. Pande ◽  
M.V. Katariya ◽  
R.P. Pawar ◽  
P.S. Kendrekar
Keyword(s):  
Ionic Liquid ◽  
Reaction Time ◽  
High Yield ◽  
Reaction Conditions ◽  
One Pot ◽  
Short Reaction Time ◽  
Aryl Aldehydes ◽  
Microwave Assisted ◽  
Novel Catalyst ◽  
Work Up

One-pot efficient protocol to the synthesis of 2-amino-5-oxo-4,5-dihydropyrano(3,2-c)chromene-3-carbonitrile derivatives via condensation of various aryl aldehydes, dicyanomethane and 4-hydroxycoumarin in presence of Emim hydroxide as an excellent homogeneous liquid catalyst. The key advantages of this methodology are mild reaction conditions, novel catalyst, short reaction time, eco-friendly, easy work-up procedure and high yield of isolation of derivatives.

Self-assembled lipase nanosphere templated one-pot biogenic synthesis of silica hollow spheres in ionic liquid [Bmim][PF6]

RSC Advances ◽  
2015 ◽  
Vol 5 (128) ◽  
pp. 105800-105809 ◽  
Author(s):  
Sampa Sarkar ◽  
Kshudiram Mantri ◽  
Dinesh Kumar ◽  
Suresh K. Bhargava ◽  
Sarvesh K. Soni
Keyword(s):  
Ionic Liquid ◽  
Ionic Liquids ◽  
Structure Function ◽  
Self Assembly ◽  
Hollow Spheres ◽  
Biogenic Synthesis ◽  
One Pot ◽  
Lipase Enzyme ◽  
Self Assembled

Self-assembly of hydrophobic lipase enzyme in hydrophobic and hydrophilic ionic liquids and a correlation in structure–function and activity.

Efficient Synthesis 2,3-Dihydroquinazolin-4(1H)-Ones Using Coconut Shell Char Sulfonic Acid as a Reusable Catalyst in Ethanol

2014 ◽  
Vol 989-994 ◽  
pp. 83-86
Author(s):  
Xuan Yan Liu ◽  
Zhi Gao Yang
Keyword(s):  
Sulfonic Acid ◽  
Biginelli Reaction ◽  
Acid Catalyst ◽  
Coconut Shell ◽  
Reusable Catalyst ◽  
Efficient Synthesis ◽  
One Pot ◽  
Efficient Catalyst ◽  
Three Component Reaction ◽  
High Yields

3,4-Dihydropyrimidin-2(1H)-ones derivatives were synthesized in moderate to high yields in one-pot three component reaction from the corresponding aldehydes, 1,3-dicarbonyl compounds and urea, Coconut shell char sulfonic acid (CSCSA) used as a reusable, and efficient catalyst. Compared to the classical acid catalyst, This new protocol for the Biginelli reaction includes the following important features: excellent yields, non-toxic, inexpensive and easily available reagent.

l-proline N-sulfonic acid-functionalized magnetic nanoparticles: a novel and magnetically reusable catalyst for one-pot synthesis of 3,4-dihydropyrimidine-2-(1H)-thiones under solvent-free conditions

RSC Advances ◽  
2016 ◽  
Vol 6 (64) ◽  
pp. 59343-59351 ◽  
Author(s):  
M. Afradi ◽  
N. Foroughifar ◽  
H. Pasdar ◽  
H. Moghanian
Keyword(s):  
Magnetic Nanoparticles ◽  
Sulfonic Acid ◽  
Acid Catalyst ◽  
Solvent Free ◽  
Reusable Catalyst ◽  
One Pot ◽  
One Pot Synthesis ◽  
Solvent Free Conditions ◽  
Functionalized Magnetic Nanoparticles

Synthesis, characterization and utilization of the l-proline N-sulfonic acid-functionalized magnetic nanoparticles as a novel magnetically reusable acid catalyst for the synthesis of 3,4-dihydropyrimidine-2-[1H]thione derivatives is reported.

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