scholarly journals Additive Manufacturing as a Means of Gas Sensor Development for Battery Health Monitoring

Chemosensors ◽  
2021 ◽  
Vol 9 (9) ◽  
pp. 252
Author(s):  
Oleg Lupan ◽  
Helge Krüger ◽  
Leonard Siebert ◽  
Nicolai Ababii ◽  
Niklas Kohlmann ◽  
...  
Keyword(s):  
Structural Changes ◽  
Ethylene Carbonate ◽  
Size Control ◽  
Lithium Ion ◽  
Current Method ◽  
Direct Ink Writing ◽  
Physicochemical Processes ◽  
Heat Leakage ◽  
Annealing Step ◽  
A Current

Lithium-ion batteries (LIBs) still need continuous safety monitoring based on their intrinsic properties, as well as due to the increase in their sizes and device requirements. The main causes of fires and explosions in LIBs are heat leakage and the presence of highly inflammable components. Therefore, it is necessary to improve the safety of the batteries by preventing the generation of these gases and/or their early detection with sensors. The improvement of such safety sensors requires new approaches in their manufacturing. There is a growing role for research of nanostructured sensor’s durability in the field of ionizing radiation that also can induce structural changes in the LIB’s component materials, thus contributing to the elucidation of fundamental physicochemical processes; catalytic reactions or inhibitions of the chemical reactions on which the work of the sensors is based. A current method widely used in various fields, Direct Ink Writing (DIW), has been used to manufacture heterostructures of Al2O3/CuO and CuO:Fe2O3, followed by an additional ALD and thermal annealing step. The detection properties of these 3D-DIW printed heterostructures showed responses to 1,3-dioxolan (DOL), 1,2-dimethoxyethane (DME) vapors, as well as to typically used LIB electrolytes containing LiTFSI and LiNO3 salts in a mixture of DOL:DME, as well also to LiPF6 salts in a mixture of ethylene carbonate (EC) and dimethyl carbonate (DMC) at operating temperatures of 200 °C–350 °C with relatively high responses. The combination of the possibility to detect electrolyte vapors used in LIBs and size control by the 3D-DIW printing method makes these heterostructures extremely attractive in controlling the safety of batteries.

Nanocomposite Based Electrolytes for Lithium-Ion Batteries

1999 ◽  
Vol 575 ◽  
Author(s):  
M.W. Riley ◽  
P.S. Fedkiw ◽  
S.A. Khan
Keyword(s):  
Steady State ◽  
Elastic Modulus ◽  
Lithium Ion Batteries ◽  
Room Temperature ◽  
Ethylene Carbonate ◽  
Lithium Ion ◽  
Current Method ◽  
Transference Numbers ◽  
Steady State Current ◽  
Nanocomposite Electrolytes

ABSTRACTNanocomposite electrolytes based on lithium hectorite (LiHect) clay dispersed in highdielectric organic solvents such as ethylene carbonate (EC) and propylene carbonate (PC) are shown to exhibit room-temperature conductivities exceeding 10−4 S/cm. The LiHect-based composites reveal lithium ion transference numbers of ∼0.8, as measured by the steady-state current method. In addition, dynamic rheological techniques show this system to be mechanically stable with elastic modulus G' exceeding 107 dynes/cm 2 and yield stress exceeding 104 dynes/cm2.

scholarly journals Enhanced Electrochemical Performances of Hollow-Structured N-Doped Carbon Derived from a Zeolitic Imidazole Framework (ZIF-8) Coated by Polydopamine as an Anode for Lithium-Ion Batteries

Energies ◽  
2021 ◽  
Vol 14 (9) ◽  
pp. 2436
Author(s):  
Da-Won Lee ◽  
Achmad Yanuar Maulana ◽  
Chaeeun Lee ◽  
Jungwook Song ◽  
Cybelle M. Futalan ◽  
...  
Keyword(s):  
Carbon Materials ◽  
Hollow Structure ◽  
Lithium Ion ◽  
Reversible Capacity ◽  
Electrical Performance ◽  
Electrochemical Performances ◽  
Effective Surface ◽  
Voltage Range ◽  
Hollow Structures ◽  
A Current

Doping heteroatoms such as nitrogen (N) and boron (B) into the framework of carbon materials is one of the most efficient methods to improve the electrical performance of carbon-based electrodes. In this study, N-doped carbon has been facilely synthesized using a ZIF-8/polydopamine precursor. The polyhedral structure of ZIF-8 and the effective surface-coating capability of dopamine enabled the formation of N-doped carbon with a hollow structure. The ZIF-8 polyhedron served as a sacrificial template for hollow structures, and dopamine participated as a donor of the nitrogen element. When compared to ZIF-8-derived carbon, the HSNC electrode showed an improved reversible capacity of approximately 1398 mAh·g−1 after 100 cycles, with excellent cycling retention at a voltage range of 0.01 to 3.0 V using a current density of 0.1 A·g−1.

scholarly journals Commercial Cokes and Graphites as Anode Materials for Lithium - Ion Cells

1997 ◽  
Vol 496 ◽  
Author(s):  
David J. Derwin ◽  
Kim Kinoshita ◽  
Tri D. Tran ◽  
Peter Zaleski
Keyword(s):  
Electron Microscopy ◽  
Ethylene Carbonate ◽  
Average Particle Size ◽  
Chemical Properties ◽  
Lithium Ion ◽  
Reversible Capacity ◽  
Bet Surface Area ◽  
Average Particle ◽  
Electrochemical Characteristics ◽  
Wide Range

AbstractSeveral types of carbonaceous materials from Superior Graphite Co. were investigated for lithium ion intercalation. These commercially available cokes, graphitized cokes and graphites have a wide range of physical and chemical properties. The coke materials were investigated in propylene carbonate based electrolytes and the graphitic materials were studied in ethylene carbonate / dimethyl solutions to prevent exfoliation. The reversible capacities of disordered cokes are below 230 mAh / g and those for many highly ordered synthetic (artificial) and natural graphites approached 372 mAh / g (LiC6). The irreversible capacity losses vary between 15 to as much as 200 % of reversible capacities for various types of carbon. Heat treated cokes with the average particle size of 10 microns showed marked improvements in reversible capacity for lithium intercalation. The electrochemical characteristics are correlated with data obtained from scanning electron microscopy (SEM), high resolution transmission electron microscopy (TAM), X - ray diffraction (XRD) and BET surface area analysis. The electrochemical performance, availability, cost and manufacturability of these commercial carbons will be discussed.

scholarly journals Almacenamiento energético frente al inminente paradigma renovable: el rol de las baterías ion-litio y las perspectivas sudamericanas/Energy storage towards the imminent renewable paradigm: the role of ion-lithium batteries and South American perspectives

2018 ◽  
pp. 108-132 ◽  
Author(s):  
Martin Ariel Kazimierski
Keyword(s):  
Electric Propulsion ◽  
Fossil Fuels ◽  
Lithium Ion ◽  
Energy System ◽  
South American ◽  
Potential Market ◽  
Wide Range ◽  
New Energy ◽  
A Current

El actual sistema energético mundial se caracteriza por una alta dependencia de los combustibles fósiles, un paradigma que empieza a encontrar dificultades en tanto se agotan las reservas existentes y aumentan los costos ecológicos. Así, la incorporación de energías renovables, su generación en forma distribuida y el crecimiento del parque automotor eléctrico, se presentan como la triada más prometedora en la conformación de un nuevo paradigma más eficiente y sustentable. Este artículo se centra en la importancia que adquieren los acumuladores energéticos ante este panorama, principalmente por su rol en la estabilización de las redes y posibilitar el autoconsumo y la propulsión eléctrica. Identifica en las baterías de ion-litio un abanico de posibilidades para Sudamérica, que posee las reservas más importantes de litio en el mundo, incorporando la idea del desarrollo dentro del nuevo patrón energético y en un mercado actual y potencial de grandes dimensiones. Abstract The current global energy system is characterized by a high dependence on fossil fuels, a paradigm that begins to encounter difficulties as existing reserves are depleted and ecological costs increase. Thus, the incorporation of renewable energies, their generation in a distributed form and the growth of the electric motor park, are presented as the most promising triad in the conformation of a new, more efficient and sustainable paradigm. This article focuses on the importance that energy accumulators acquire in this scenario, mainly due to their role in stabilizing networks and enabling self-consumption and electric propulsion. It identifies lithium-ion batteries with a wide range of possibilities for South America, which has the most important reserves of lithium in the world, incorporating the idea of ​​development within the new energy pattern and in a current and potential market of large dimensions.

scholarly journals Waterborne polyurethane as a carbon coating for micrometre-sized silicon-based lithium-ion battery anode material

2018 ◽  
Vol 5 (8) ◽  
pp. 180311 ◽  
Author(s):  
Chunfeng Yan ◽  
Tao Huang ◽  
Xiangzhen Zheng ◽  
Cuiran Gong ◽  
Maoxiang Wu
Keyword(s):  
Carbon Coating ◽  
Lithium Ion ◽  
Waterborne Polyurethane ◽  
Cycling Performance ◽  
Capacity Retention ◽  
Lithium Ions ◽  
Rate Capacity ◽  
Silicon Based ◽  
Carbon Network ◽  
A Current

Waterborne polyurethane (WPU) is first used as a carbon-coating source for micrometre-sized silicon. The remaining nitrogen (N) and oxygen (O) heteroatoms during pyrolysis of the WPU interact with the surface oxide on the silicon (Si) particles via hydrogen bonding (Si–OH⋯N and Si–OH⋯O). The N and O atoms involved in the carbon network can interact with the lithium ions, which is conducive to lithium-ion insertion. A satisfactory performance of the Si@N, O-doped carbon (Si@CNO) anode is gained at 25 and 55°C. The Si@CNO anode shows stable cycling performance (capacity retention of 70.0% over 100 cycles at 25°C and 60.3% over 90 cycles at 55°C with a current density of 500 mA g −1 ) and a superior rate capacity of 864.1 mA h g −1 at 1000 mA g −1 (25°C). The improved electrochemical performance of the Si@CNO electrode is attributed to the enhanced electrical conductivity and structural stability.

Methylene ethylene carbonate: Novel additive to improve the high temperature performance of lithium ion batteries

2012 ◽  
Vol 208 ◽  
pp. 67-73 ◽  
Author(s):  
Dinesh Chalasani ◽  
Jing Li ◽  
Nicole M. Jackson ◽  
Martin Payne ◽  
Brett L. Lucht
Keyword(s):  
High Temperature ◽  
Lithium Ion Batteries ◽  
Ethylene Carbonate ◽  
Lithium Ion ◽  
Temperature Performance

scholarly journals Multishelled NiO Hollow Spheres Decorated by Graphene Nanosheets as Anodes for Lithium-Ion Batteries with Improved Reversible Capacity and Cycling Stability

2016 ◽  
Vol 2016 ◽  
pp. 1-6 ◽  
Author(s):  
Lihua Chu ◽  
Meicheng Li ◽  
Yu Wang ◽  
Xiaodan Li ◽  
Zipei Wan ◽  
...  
Keyword(s):  
Electrochemical Performance ◽  
Graphene Nanosheets ◽  
Hollow Spheres ◽  
Modern Science ◽  
Lithium Ion ◽  
Reversible Capacity ◽  
Graphene Sheets ◽  
Reduced Graphene ◽  
Graphene Nanocomposite ◽  
A Current

Graphene-based nanocomposites attract many attentions because of holding promise for many applications. In this work, multishelled NiO hollow spheres decorated by graphene nanosheets nanocomposite are successfully fabricated. The multishelled NiO microspheres are uniformly distributed on the surface of graphene, which is helpful for preventing aggregation of as-reduced graphene sheets. Furthermore, the NiO/graphene nanocomposite shows much higher electrochemical performance with a reversible capacity of 261.5 mAh g−1at a current density of 200 mA g−1after 100 cycles tripled compared with that of pristine multishelled NiO hollow spheres, implying the potential application in modern science and technology.

scholarly journals Integrated Anode Electrode Composited Cu–Sn Alloy and Separator for Microscale Lithium Ion Batteries

Materials ◽  
2019 ◽  
Vol 12 (4) ◽  
pp. 603 ◽  
Author(s):  
Yuxia Liu ◽  
Kai Jiang ◽  
Shuting Yang
Keyword(s):  
Current Density ◽  
Active Material ◽  
Specific Capacity ◽  
Lithium Ion ◽  
Cycle Performance ◽  
Electrode Structure ◽  
Microelectronic Devices ◽  
Anode Electrode ◽  
Integrated Anode ◽  
A Current

A novel integrated electrode structure was designed and synthesized by direct electrodepositing of Cu–Sn alloy anode materials on the Celgard 2400 separator (Cel-CS electrode). The integrated structure of the Cel-CS electrode not only greatly simplifies the battery fabrication process and increases the energy density of the whole electrode, but also buffers the mechanical stress caused by volume expansion of Cu–Sn alloy active material; thus, effectively preventing active material falling off from the substrate and improving the cycle stability of the electrode. The Cel-CS electrode exhibits excellent cycle performance and superior rate performance. A capacity of 728 mA·h·g−1 can be achieved after 250 cycles at the current density of 100 mA·g−1. Even cycled at a current density of 5 A·g−1 for 650 cycles, the Cel-CS electrode maintained a specific capacity of 938 mA·h·g−1, which illustrates the potential application prospects of the Cel-CS electrode in microelectronic devices and systems.

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