scholarly journals Characterization of Nano-Scale Hydroxyapatite Coating Synthesized from Eggshells Through Hydrothermal Reaction on Commercially Pure Titanium

Coatings ◽  
2020 ◽  
Vol 10 (2) ◽  
pp. 112 ◽  
Author(s):  
Hsing-Ning Yu ◽  
Hsueh-Chuan Hsu ◽  
Shih-Ching Wu ◽  
Cheng-Wei Hsu ◽  
Shih-Kuang Hsu ◽  
...  

Commercially pure titanium (c.p. Ti) is often used in biomedical implants, but its surface cannot usually combine with the living bone. A coating of hydroxyapatite (HA) on the surface of titanium implants provides excellent mechanical properties and has good biological activity and biocompatibility. For optimal osteocompatibility, the structure, size, and composition of HA crystals should be closer to those of biological apatite. Our results show that the surface of c.p. Ti was entirely covered by rod-like HA nanoparticles after alkali treatment and subsequent hydrothermal treatment at 150 °C for 48 h. Nano-sized apatite aggregates began to nucleate on HA-coated c.p. Ti surfaces after immersion in simulated body fluid (SBF) for 6 h, while no obvious precipitation was found on the uncoated sample. Higher apatite-forming ability (bioactivity) could be acquired by the samples after HA coating. The HA coating featured bone-like nanostructure, high crystallinity, and carbonate substitution. It can be expected that HA coatings synthesized from eggshells on c.p. Ti through a hydrothermal reaction could be used in dental implant applications in the future.

Materials ◽  
2020 ◽  
Vol 13 (22) ◽  
pp. 5280
Author(s):  
Saturnino Marco Lupi ◽  
Benedetta Albini ◽  
Arianna Rodriguez y Baena ◽  
Giulia Lanfrè ◽  
Pietro Galinetto

The osseointegration of titanium implants is allowed by the TiO2 layer that covers the implants. Titania can exist in amorphous form or in three different crystalline conformations: anatase, rutile and brookite. Few studies have characterized TiO2 covering the surface of dental implants from the crystalline point of view. The aim of the present study was to characterize the evolution of the TiO2 layer following different surface treatments from a crystallographic point of view. Commercially pure titanium and Ti-6Al-4V implants subjected to different surface treatments were analyzed by Raman spectroscopy to evaluate the crystalline conformation of titania. The surface treatments evaluated were: machining, sandblasting, sandblasting and etching and sandblasting, etching and anodization. The anodizing treatment evaluated in this study allowed to obtain anatase on commercially pure titanium implants without altering the morphological characteristics of the surface.


1994 ◽  
Vol 12 (2) ◽  
pp. 274-285 ◽  
Author(s):  
L. Carlsson ◽  
L. Regnér ◽  
C. Johansson ◽  
M. Gottlander ◽  
P. Herberts

2012 ◽  
Vol 24 (8) ◽  
pp. 896-903 ◽  
Author(s):  
Thallita P. Queiroz ◽  
Francisley Á. Souza ◽  
Antônio C. Guastaldi ◽  
Rogério Margonar ◽  
Idelmo R. Garcia-Júnior ◽  
...  

2019 ◽  
Vol 71 (10) ◽  
pp. 1166-1176
Author(s):  
Onur Çomakli ◽  
Mustafa Yazici ◽  
Tuba Yetim ◽  
Fatih Yetim ◽  
Ayhan Celik

Purpose This paper aims to investigate the structural, tribological and electrochemical properties of Ag2O, ZnO, NiO coatings and Ag2O/ZnO/NiO nanocomposite films deposited on commercially pure titanium. Design/methodology/approach Ceramic thin films (Ag2O, ZnO, NiO coatings and Ag2O/ZnO/NiO nanocomposite film) were deposited on commercially pure titanium (CP-Ti) substrate. Surface characterization of the uncoated and coated samples was made by structural surveys (scanning electron microscopic examinations and X-ray diffraction analyses), hardness measurements, tribological and corrosion experiments. Findings Results were indicated that sol-gel coatings improved the wear and corrosion resistance of CP-Ti, and the best results were seen at the nanocomposite coating. It may be attributed to its small grain size, high surface hardness and high film thickness. Originality/value This study can be a practical reference and offers insight into the influence of nanocomposite ceramic films on the increase of hardness, tribological and corrosion performance. Also, the paper displayed a promising approach to produce Ag2O/ZnO/NiO nanocomposite coating on commercially pure titanium implants for biomedical applications.


PLoS ONE ◽  
2016 ◽  
Vol 11 (6) ◽  
pp. e0157504 ◽  
Author(s):  
Furqan A. Shah ◽  
Martin L. Johansson ◽  
Omar Omar ◽  
Hanna Simonsson ◽  
Anders Palmquist ◽  
...  

2016 ◽  
Vol 10 (1) ◽  
pp. 486-496 ◽  
Author(s):  
Manuel Alberto Bortagaray ◽  
Claudio Arturo Antonio Ibañez ◽  
Maria Constanza Ibañez ◽  
Juan Carlos Ibañez

Objective: To determine whether the Noble Bond® Argen® alloy was electrochemically suitable for the manufacturing of prosthetic superstructures over commercially pure titanium (c.p. Ti) implants. Also, the electrolytic corrosion effects over three types of materials used on prosthetic suprastructures that were coupled with titanium implants were analysed: Noble Bond® (Argen®), Argelite 76sf +® (Argen®), and commercially pure titanium. Materials and Methods: 15 samples were studied, consisting in 1 abutment and one c.p. titanium implant each. They were divided into three groups, namely: Control group: five c.p Titanium abutments (B&W®), Test group 1: five Noble Bond® (Argen®) cast abutments and, Test group 2: five Argelite 76sf +® (Argen®) abutments. In order to observe the corrosion effects, the surface topography was imaged using a confocal microscope. Thus, three metric parameters (Sa: Arithmetical mean height of the surface. Sp: Maximum height of peaks. Sv: Maximum height of valleys.), were measured at three different areas: abutment neck, implant neck and implant body. The samples were immersed in artificial saliva for 3 months, after which the procedure was repeated. The metric parameters were compared by statistical analysis. Results: The analysis of the Sa at the level of the implant neck, abutment neck and implant body, showed no statistically significant differences on combining c.p. Ti implants with the three studied alloys. The Sp showed no statistically significant differences between the three alloys. The Sv showed no statistically significant differences between the three alloys. Conclusion: The effects of electrogalvanic corrosion on each of the materials used when they were in contact with c.p. Ti showed no statistically significant differences.


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