scholarly journals Depth Profile Analysis of the Modified Layer of Poly(vinyltrimethylsilane) Films Treated by Direct-Current Discharge

Coatings ◽  
2021 ◽  
Vol 11 (11) ◽  
pp. 1317
Author(s):  
Mikhail Piskarev ◽  
Elena Skryleva ◽  
Alla Gilman ◽  
Boris Senatulin ◽  
Alexander Zinoviev ◽  
...  

Previously, we found that modification of the membrane surface from polyvinyltrimethylsilane (PVTMS) by treatment with low-temperature plasma induced by low pressure DC discharge leads to a significant increase in gas separation characteristics. To understand the mechanism of this phenomenon, in this article XPS combined with precision etching 10 keV beam of Ar2500+ clusters was used for depth profiling of PVTMS spin-coated films before and after DC discharge treatment. The etching craters depths were measured by stylus surface profiler. The average etching rate of the untreated PVTMS film by Ar2500+ clusters was defined (230 nm/min). It was found that the low temperature plasma treatment of PVTMS leads to a sharp increase in the oxygen concentration on a surface with a simultaneous decrease in the carbon content. The experimental data obtained indicate also that the treatment of PVTMS film by plasma leads not only to a change in the chemical structure of the surface, but also to the formation of a gradient subsurface layer with a thickness of about 50 nm.

2021 ◽  
pp. 004051752110306
Author(s):  
Honglian Cong ◽  
Boyu Zhao ◽  
Hao Han ◽  
Xuliang Yu

Nine groups of knitted woolen fabrics for sportswear with different technical characteristics were treated with oxygen low-temperature plasma, and the changes in the surface morphology and chemical composition of wool fibers before and after plasma treatment, as well as the changes in the applicability indexes of knitted woolen fabrics, were studied. Finally, the comfort performance of the fabrics was evaluated by combining the concentration mapping method and the function evaluation value method. The analysis found that the surface scales of wool fibers were seriously etched after oxygen low-temperature plasma treatment, and the anti-felting, bursting strength and moisture absorption of the knitted woolen fabrics were improved. At the same time, the quick-drying index of the fabric has also been improved to a certain extent. This research provides a basis for the development of knitted woolen fabric for sportswear with excellent performance.


2016 ◽  
Vol 693 ◽  
pp. 77-83 ◽  
Author(s):  
Yi Fang Wen ◽  
Tai Yong Wang ◽  
Hong Wei Wang

Low temperature plasma, compared to liquid phase treatment, can effectively overcome the environment pollution, high energy loss and high cost as its high activity. The low temperature plasma, which is not only fairly friendly to the environment but also of less resource consumption, also can realize the cleaning, activating and grafting treatment for materials surface. Based on the numerical model of CRFHCP (Capacitive Radio Frequency Hollow Cathode Plasma) hollow cathode plasma discharge, the key point to affect plasma discharge was analyzed and the morphology of PP film before and after hollow cathode plasma discharge was analyzed. The results showed that the structure of plasma hollow cathode discharge can effectively improved the chemical behaviors of PP film.


2014 ◽  
Vol 1015 ◽  
pp. 303-307
Author(s):  
Jiang Yan Meng ◽  
Yun Ying Wang

Low-density polyethylene (LDPE) film was treated by low-temperature plasma. Scanning electronic microscope, electronic universal testing machine, contact angle/interfacial tension measuring instrument were used to analyze the surface morphology, surface contact angle, bonding strength and performance of LDPE film before and after they were treated by low-temperature plasma. The results show that air ambience is more appropriate than N2, CO2 for treatment. Specifically, plasma treatment in air ambience, under conditions of 44 W (power), 30 s (duration) and 60 Pa (vacuum degree), can decline static contact angle of LDPE film from 101° to 13.5°. The transiency of plasma-treated LDPE film is so obvious that storage time of longer than one hour will result in a contact angle up to 74° and loss of plasma treatment effect (timeliness). Therefore, the reversible plasma-treated LDPE film should be processed immediately.


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