scholarly journals Absolute Absorption Measurements in Optical Coatings by Laser Induced Deflection

Coatings ◽  
2019 ◽  
Vol 9 (8) ◽  
pp. 473 ◽  
Author(s):  
Simon Bublitz ◽  
Christian Mühlig

Absolute measurement of residual absorption in optical coatings is steadily becoming more important in thin film characterization, in particular with respect to high power laser applications. A summary is given on the current ability of the laser induced deflection (LID) technique to serve sensitive photo-thermal absorption measurements combined with reliable absolute calibration based on an electrical heater approach. To account for different measurement requirements, several concepts have been derived to accordingly adapt the original LID concept. Experimental results are presented for prominent UV and deep UV laser wavelengths, covering a variety of factors that critically can influence the absorption properties in optical coatings e.g., deposition process, defects and impurities, intense laser irradiation and surface/interface engineering. The experimental findings demonstrate that by combining high sensitivity with absolute calibration, photo-thermal absorption measurements are able to be a valuable supplement for the characterization of optical thin films and coatings.

2007 ◽  
Vol 12 (5) ◽  
pp. 656-667 ◽  
Author(s):  
Michael P. Maher ◽  
Nyan-Tsz Wu ◽  
Hong Ao

Many high-throughput ion channel assays require the use of voltage-sensitive dyes to detect channel activity in the presence of test compounds. Dye systems employing Förster resonance energy transfer (FRET) between 2 membrane-bound dyes are advantageous in combining high sensitivity, relatively fast response, and ratiometric output. The most widely used FRET voltage dye system employs a coumarin fluorescence donor whose excitation spectrum is pH dependent. The authors have validated a new class of voltage-sensitive FRET donors based on a pyrene moiety. These dyes are significantly brighter than CC2-DMPE and are not pH sensitive in the physiological range. With the new dye system, the authors demonstrate a new high-throughput assay for the acid-sensing ion channel (ASIC) family. They also introduce a novel method for absolute calibration of voltage-sensitive dyes, simultaneously determining the resting membrane potential of a cell. ( Journal of Biomolecular Screening 2007:656-667)


ISRN Optics ◽  
2012 ◽  
Vol 2012 ◽  
pp. 1-6 ◽  
Author(s):  
Suyong Wu ◽  
Xingwu Long ◽  
Kaiyong Yang

We present a novel fast robust design method of multilayer optical coatings. The sensitivity of optical films to production errors is controlled in the whole optimization design procedure. We derive an analytical calculation model for fast robust design of multilayer optical coatings. We demonstrate its effectiveness by successful application of the robust design method to a neutral beam splitter. It is showed that the novel robust design method owns an inherent fast computation characteristic and the designed film is insensitive to the monitoring thickness errors in deposition process. This method is especially of practical significance to improve the mass production yields and repetitive production of high-quality optical coatings.


2009 ◽  
Vol 7 (11) ◽  
pp. 1061-1064 ◽  
Author(s):  
陶春先 Chunxian Tao ◽  
赵元安 Yuanan Zhao ◽  
贺洪波 Hongbo He ◽  
李大伟 Dawei Li ◽  
邵建达 Jianda Shao ◽  
...  

2001 ◽  
Author(s):  
Sven Laux ◽  
Helmut Bernitzki ◽  
Michael Klaus ◽  
Hans Lauth ◽  
Norbert Kaiser

Author(s):  
Patrick H. Wagner ◽  
Jan Van herle ◽  
Lili Gu ◽  
Jürg Schiffmann

Abstract The blade tip clearance loss was studied experimentally and numerically for a micro radial fan with a tip diameter of 19.2mm. Its relative blade tip clearance, i.e., the clearance divided by the blade height of 1.82 mm, was adjusted with different shims. The fan characteristics were experimentally determined for an operation at the nominal rotational speed of 168 krpm with hot air (200 °C). The total-to-total pressure rise and efficiency increased from 49 mbar to 68 mbar and from 53% to 64%, respectively, by reducing the relative tip clearance from 7.7% to the design value of 2.2%. Single and full passage computational fluid dynamics simulations correlate well with these experimental findings. The widely-used Pfleiderer loss correlation with an empirical coefficient of 2.8 fits the numerical simulation and the experiments within +2 efficiency points. The high sensitivity to the tip clearance loss is a result of the design specific speed of 0.80, the highly-backward curved blades (17°), and possibly the low Reynolds number (1 × 105). The authors suggest three main measures to mitigate the blade tip clearance losses for small-scale fans: (1) utilization of high-precision surfaced-grooved gas-bearings to lower the blade tip clearance, (2) a mid-loaded blade design, and (3) an unloaded fan leading edge to reduce the blade tip clearance vortex in the fan passage.


Chemosensors ◽  
2020 ◽  
Vol 8 (4) ◽  
pp. 128
Author(s):  
Patrícia D. Barata ◽  
José V. Prata

Two highly fluorescent calix[4]arene-containing phenylene-alt-ethynylene-carbazolylene polymers (Calix-PPE-CBZs) were used in the detection of explosives from the nitroaromatic compounds (NACs) family, in solution and in vapour phases. Both fluorophores exhibit high sensitivity and selectivity towards NACs detection. The quenching efficiencies in solution, assessed through static Stern-Volmer constants (KSV), follow the order picric acid (PA) >> 2,4,6-trinitrotoluene (TNT) > 2,4-dinitrotoluene > (2,4-DNT) > nitrobenzene (NB). These correlate very well with the NACs electron affinities, as evaluated from their lowest unoccupied molecular orbitals (LUMOs) energies, indicating a photo-induced electron transfer as the dominant mechanism in fluorescence quenching. Moreover, and most interesting, detection of TNT, 2,4-DNT and NB vapours via thin-films of Calix-PPE-CBZs revealed a remarkably sensitive response to these analytes, comparable to state-of-the-art chemosensors. The study also analyses and compares the current results to previous disclosed data on the detection of NACs by several calix[4]arene-based conjugated polymers and non-polymeric calix[4]arenes-carbazole conjugates, overall highlighting the superior role of calixarene and carbazole structural motifs in NACs’ detection performance. Density functional theory (DFT) calculations performed on polymer models were used to support some of the experimental findings.


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