scholarly journals The Hazards Analysis of Nickel-Rich Lithium-Ion Battery Thermal Runaway under Different States of Charge

Electronics ◽  
2021 ◽  
Vol 10 (19) ◽  
pp. 2376
Author(s):  
Kun JIang ◽  
Pingwei Gu ◽  
Peng Huang ◽  
Ying Zhang ◽  
Bin Duan ◽  
...  

The lithium-ion battery industry has been developing rapidly, with energy density and capacity constantly improving. However, the ensuing safety accidents of lithium-ion power batteries have seriously threatened the personal safety of passengers. Therefore, more and more attention has been paid to the thermal safety research of lithium-ion batteries, such as thermal runaway (TR) mechanism analysis and prevention methods, etc. In this paper, the nickel-rich 18650 lithium-ion batteries with Li[Ni0.8Co0.1Mn0.1]O2 cathode in different states of charge (SOC) are taken to investigate the TR characteristics using an extended volume plus acceleration calorimeter (EV+-ARC). In order to evaluate the TR characteristics, some characteristic parameters such as battery voltage, surface temperature, temperature rise rate, etc. are selected from the experiment to analyze the influence of SOC on the critical state of TR. It can be seen from the experiment results that the maximum temperature of the battery surface decreases with the decrease of SOC, while the self-generated heat temperature and TR trigger temperature increases with the decrease of SOC.

Author(s):  
Corey T. Love ◽  
Christopher Buesser ◽  
Michelle D. Johannes ◽  
Karen E. Swider-Lyons

This paper for inclusion in the special issue provides a brief synopsis of lithium-ion battery safety research efforts at the Naval Research Laboratory (NRL) and presents the viewpoint that lithium-ion battery safety is a growing research area for both academic and applied researchers. We quantify how the number of lithium-ion battery research efforts worldwide has plateaued while publications associated with the safety aspect of lithium-ion batteries are on a rapid incline. The safety challenge creates a unique research opportunity to not only understand basic phenomena but also enhance existing fielded system through advanced controls and prognostics. As the number of lithium-ion battery safety research contributions climbs, significant advancements will come in the area of modeling across multiple time and length scales. Additionally, the utility of in situ and in operando techniques, several performed by the NRL and our collaborators, will feed the data necessary to validate these models. Lithium-ion battery innovations are no longer tied to performance metrics alone, but are increasingly dependent on safety research to unlock their full potential. There is much work to be done.


Processes ◽  
2019 ◽  
Vol 7 (10) ◽  
pp. 703 ◽  
Author(s):  
Md Said ◽  
Mohd Tohir

The high capacity and voltage properties demonstrated by lithium-ion batteries render them as the preferred energy carrier in portable electronic devices. The application of the lithium-ion batteries which previously circulating and contained around small-scale electronics is now expanding into large scale emerging markets such as electromobility and stationary energy storage. Therefore, the understanding of the risk involved is imperative. Thermal runaway is the most common failure mode of lithium-ion battery which may lead to safety incidents. Transport process of immense amounts of heat released during thermal runaway of lithium-ion battery to neighboring batteries in a module can lead to cascade failure of the whole energy storage system. In this work, a model is developed to predict the propagation of lithium-ion battery in a module for large scale applications. For this purpose, kinetic of material thermal decomposition is combined with heat transfer modelling. The simulation is built based on chemical kinetics at component level of a singular cell and energy balance that accounts for conductive and convective heat transfer.


2020 ◽  
Vol 34 (6) ◽  
pp. 8-13
Author(s):  
Moon-Woo Park ◽  
Woo-Bin Jang ◽  
Sung-Ho Hong ◽  
Don-Mook Choi

This study analyzes thermal runaway (TR) characteristics via experiments conducted on lithium-ion batteries. To generate the TR of lithium-ion batteries, overcharge was applied as an electrical abuse condition. The TR experiment was conducted in a chamber with the dimensions of 1.5 × 1.5 × 1.5 m by classifying the capacity of a pouch-type lithium-ion battery and cathode material employed. The experimental results demonstrated that the lithium-ion battery before TR exhibited repetitive voltage and temperature characteristics, and that TR could be detected in advance based on these characteristics. TR occurred after the cell surface temperature of the lithium ion battery was maintained at approximately 100 ℃ for a certain duration. The voltage of the lithium-ion battery gradually increased before TR; however, the voltage decreased after the inflection point (Vmax) was crossed. Then, the voltage increased sharply after decreasing for a certain duration and was higher than the voltage increase rate (V/min) observed before the inflection point (Vmax) was attained.


Polymers ◽  
2021 ◽  
Vol 13 (11) ◽  
pp. 1675
Author(s):  
Zhi-Hao Wu ◽  
An-Chi Huang ◽  
Yan Tang ◽  
Ya-Ping Yang ◽  
Ye-Cheng Liu ◽  
...  

In recent years, the prosperous electric vehicle industry has contributed to the rapid development of lithium-ion batteries. However, the increase in the energy density of lithium-ion batteries has also created more pressing safety concerns. The emergence of a new flame-retardant material with the additive ethoxy (pentafluoro) cyclotriphosphazene can ameliorate the performance of lithium-ion batteries while ensuring their safety. The present study proposes a new polymer composite flame-retardant electrolyte and adopts differential scanning calorimetry (DSC) and accelerating rate calorimetry to investigate its thermal effect. The study found that the heating rate is positively correlated with the onset temperature, peak temperature, and endset temperature of the endothermic peak. The flame-retardant modified polymer electrolyte for new lithium-ion batteries has better thermal stability than traditional lithium-ion battery electrolytes. Three non-isothermal methods (Kissinger; Kissinger–Akahira–Sunose; and Flynn–Wall–Ozawa) were also used to calculate the kinetic parameters based on the DSC experimental data. The apparent activation energy results of the three non-isothermal methods were averaged as 54.16 kJ/mol. The research results can provide valuable references for the selection and preparation of flame-retardant additives in lithium-ion batteries.


2019 ◽  
Vol 21 (41) ◽  
pp. 22740-22755 ◽  
Author(s):  
Mei-Chin Pang ◽  
Yucang Hao ◽  
Monica Marinescu ◽  
Huizhi Wang ◽  
Mu Chen ◽  
...  

Solid-state lithium batteries could reduce the safety concern due to thermal runaway while improving the gravimetric and volumetric energy density beyond the existing practical limits of lithium-ion batteries.


Author(s):  
Xia Hua ◽  
Alan Thomas

Lithium-ion batteries are being increasingly used as the main energy storage devices in modern mobile applications, including modern spacecrafts, satellites, and electric vehicles, in which consistent and severe vibrations exist. As the lithium-ion battery market share grows, so must our understanding of the effect of mechanical vibrations and shocks on the electrical performance and mechanical properties of such batteries. Only a few recent studies investigated the effect of vibrations on the degradation and fatigue of battery cell materials as well as the effect of vibrations on the battery pack structure. This review focused on the recent progress in determining the effect of dynamic loads and vibrations on lithium-ion batteries to advance the understanding of lithium-ion battery systems. Theoretical, computational, and experimental studies conducted in both academia and industry in the past few years are reviewed herein. Although the effect of dynamic loads and random vibrations on the mechanical behavior of battery pack structures has been investigated and the correlation between vibration and the battery cell electrical performance has been determined to support the development of more robust electrical systems, it is still necessary to clarify the mechanical degradation mechanisms that affect the electrical performance and safety of battery cells.


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